全固态锂离子电池的研究进展与挑战

化工进展 ›› 2021, Vol. 40 ›› Issue (9): 5045-5060.

全固态锂离子电池的研究进展与挑战

宋洁尘¹^,²(), 夏青¹^,³^,⁴, 徐宇兴¹^,³^,⁴, 谭强强¹^,³^,⁴()

^1.中国科学院过程工程研究所多相复杂系统重点实验室，北京 100190
^2.中国科学院大学化学工程学院，北京 100049
^3.中科廊坊过程工程研究院，河北廊坊 065001
^4.河北省先进能源材料技术创新中心，河北廊坊 065001

收稿日期:2021-03-16 修回日期:2021-06-05 出版日期:2021-09-05 发布日期:2021-09-13
通讯作者: 谭强强
作者简介:宋洁尘（1996—），男，硕士研究生，研究方向为PEO-氧化物基复合固态电解质的制备和性能。E-mail：jcsong934733577@163.com。
基金资助:
国家自然科学基金(51902310);河北省自然科学基金(E2019103017);河北省重点研发计划(19214407D)

Recent progress and challenges on all-solid-state lithium ion battery

SONG Jiechen¹^,²(), XIA Qing¹^,³^,⁴, XU Yuxing¹^,³^,⁴, TAN Qiangqiang¹^,³^,⁴()

^1.State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
^2.School of Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
^3.Zhongke Langfang Institute of Process Engineering, Langfang 065001, Hebei, China
^4.Hebei Technology Innovation Center of Advanced Energy Materials, Langfang 065001, Hebei, China

Received:2021-03-16 Revised:2021-06-05 Online:2021-09-05 Published:2021-09-13
Contact: TAN Qiangqiang

摘要/Abstract

摘要：

全固态锂离子电池具有安全性高、电化学性能优异等优点，但存在电极与电解质界面相容性差、室温离子电导率低等问题。本文总结了以上问题产生的原因及解决方案。对于正极界面，可复合正极材料与固态电解质、构造三维多孔结构固态电解质或在界面处引入缓冲层。对于负极界面，可设计界面层、原位聚合生成固态电解质、构造固态电解质骨架或使用自愈合和弹性固态电解质。对于固态电解质自身，以聚氧化乙烯（PEO）固态聚合物电解质为例，可添加增塑剂、无机陶瓷填料或构造聚合物共混物与嵌段共聚物。最后，对今后的研究方向提出了建议：应注重优化电极/固态电解质界面层；探索锂离子传输机理；构建具有高离子电导率的固态电解质等。

关键词: 全固态锂离子电池, 界面, 聚氧化乙烯, 聚合物, 电解质, 电化学

Abstract:

All-solid-state lithium ion batteries have the advantages of high safety and excellent electrochemical performance, but they have many problems as well such as poor compatibility of the electrode/electrolyte interface and low ionic conductivity at room temperature. This paper reviews the causes and solutions of the above problems. For improving the cathode/electrolyte interfaces, the cathode materials can be combined with solid electrolyte, and solid electrolyte with three-dimensional porous structures can be constructed, or a buffer layer can be introduced at the interface. For improving the anode/electrolyte interfaces, the interface layer can be designed, or the solid electrolyte can be generated by in-situ polymerization. Besides, the solid electrolyte skeleton can be constructed, and the self-healing or elastic solid electrolyte can be used. For the solid electrolytes, taking polyethylene oxide (PEO) solid polymer electrolyte as an example, plasticizers, inorganic ceramic fillers, blend polymers, and block copolymers can be added. Finally, some suggestions on the future research directions are proposed. In future, more attention should be paid to optimize the electrode/electrolyte interfaces, explore the transporting mechanism of lithium ions, and construct solid electrolytes with high ionic conductivity.

Key words: all-solid-state lithium ion battery, interface, polyethylene oxide (PEO), polymer, electrolyte, electrochemistry

中图分类号:

TM911.3

宋洁尘, 夏青, 徐宇兴, 谭强强. 全固态锂离子电池的研究进展与挑战[J]. 化工进展, 2021, 40(9): 5045-5060.

SONG Jiechen, XIA Qing, XU Yuxing, TAN Qiangqiang. Recent progress and challenges on all-solid-state lithium ion battery[J]. Chemical Industry and Engineering Progress, 2021, 40(9): 5045-5060.

图/表 6

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