微型流化床反应分析的方法基础与应用研究

doi:10.16085/j.issn.1000-6613.2016.06.009

化工进展 ›› 2016, Vol. 35 ›› Issue (06): 1687-1697.DOI: 10.16085/j.issn.1000-6613.2016.06.009

微型流化床反应分析的方法基础与应用研究

曾玺¹, 王芳², 余剑¹, 岳君容¹, 姚梅琴¹, 许光文¹

1. 中国科学院过程工程研究所多相复杂系统国家重点实验室, 北京, 100190;
2. 中国矿业大学(北京)化学与环境工程学院, 北京, 100083

收稿日期:2016-01-04 修回日期:2016-01-26 出版日期:2016-06-05 发布日期:2016-06-05
通讯作者: 许光文,博士,研究员。E-mail:gwxu@ipe.ac.cn。
作者简介:曾玺(1982-),男,博士,副研究员。
基金资助:
科技部重大仪器专项(2011YQ120039)、国家自然科学基金(21306209)及国家高技术研究发展计划(2015AA050505-02)项目。

Fundamentals and applications of micro fluidized bed reaction analysis

ZENG Xi¹, WANG Fang², YU Jian¹, YUE Junrong¹, YAO Meiqin¹, XU Guangwen¹

1. State Key Laboratory of Multi-phase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
2. School of Chemical and Environmental Engineering, China University of Mining & Technology (Beijing), Beijing 100083, China

Received:2016-01-04 Revised:2016-01-26 Online:2016-06-05 Published:2016-06-05

摘要/Abstract

摘要： 准确测试气-固反应特性、求算动力学参数和推导反应机理是能源、化工、冶金等过程工程领域的重要研究课题。通过分析现有气-固反应分析测试方法与测试仪器优缺点,本文作者提出了利用微型流化床(MFB,micro fluidized bed)实现低扩散、快速升温条件下的反应微分化和等温分析的测试方法,系统研究了反应器内的流体力学特性,研制了微型流化床反应分析仪(MFBRA,micro fluidized bed reaction analyzer),验证和展示了其对热解、燃烧(氧化)、气化、还原、催化、吸收等典型气-固反应的应用,充分揭示了微型流化床反应分析仪强化传热传质、降低扩散抑制、实现实时在线微分分析的特性,尤其为快速复杂反应提供了有效的研究分析手段,并且拓展了水蒸气气氛、在线颗粒采样、串联反应解耦等系列气-固反应研究与表征功能,形成了与热重分析互补的气-固反应分析方法和分析仪。

关键词: 微型流化床, 热重分析仪, 气固反应, 反应分析, 动力学, 微型流化床反应分析仪

Abstract: Accurate measurement of gas-solids reaction characteristics,calculation of reaction kinetics and analysis of reaction mechanism are important to studies and developments of process engineering technologies in areas of energy,chemical engineering,and metallurgy. Analyzing various existing gas-solids reaction analysis approaches and instruments,we propose the use of micro fluidized bed (MFB) to realize isothermal differential reaction under conditions with rapid heating and low diffusion limitation. After systematic studies on hydrodynamics of micro fluidized bed,we have developed a micro fluidized bed reaction analyzer (MFBRA) and further verified its applications for many typical gas solids reactions,including pyrolysis,combustion,gasification,reduction,catalysis,and absorption. These applications well demonstrated MFBRA for its inherent advantages of intensified heat and mass transfer,minimized diffusion limitation and online real-time isothermal differential reaction. It particularly is applicable to analysis of rapid complex reactions and enables several extended functions for gas-solids reaction analysis like using steam atmosphere,on-line particle sampling and decoupling of reactions in series. MFBRA provides actually an effective TGA-complementary approach and instrument for gas-solids reaction analysis.

Key words: micro fluidized bed, thermogravimetric analyzer (TGA), gas-solid reaction, reaction analysis, kinetics, MFBRA

中图分类号:

TQ051.1

曾玺, 王芳, 余剑, 岳君容, 姚梅琴, 许光文. 微型流化床反应分析的方法基础与应用研究[J]. 化工进展, 2016, 35(06): 1687-1697.

ZENG Xi, WANG Fang, YU Jian, YUE Junrong, YAO Meiqin, XU Guangwen. Fundamentals and applications of micro fluidized bed reaction analysis[J]. Chemical Industry and Engineering Progree, 2016, 35(06): 1687-1697.

参考文献

[1] 刘洋,杨勇平. 扩散过程对气固反应影响的模型研究[J]. 华北电力大学学报,2015,42:58-95.
[2] MUHAMMAD F I,MUHAMMAD R U,KUSAKABE K. Coal gasification in CO₂ atmosphere and its kinetics since 1948:a brief review [J]. Energy,2011,36:12-40.
[3] 尹静姝,方园,朱贤青,等. 微型流化床快速过程红外热分析仪对热分解的动力学研究[J]. 工程热物理学报,2014,35:1216-1220.
[4] 陈香云,张永锋,崔景东. 热重法研究褐煤的富氧燃烧特性[J]. 化工进展,2012,31(s1):232-235.
[5] 李洪钟,郭慕孙. 回眸与展望流态化科学与技术[J]. 化工学报,2013,64(1):52-62.
[6] 王伟文,周忠涛,陈光辉,等. 流态化过程模拟的研究进展[J]. 化工进展,2011,30(1):58-65.
[7] 鞠付栋,陈汉平,杨海平,等. 化工行业节能减排新技术和战略选择[J]. 化工进展,2009,28(s1):1-5.
[8] 徐继红,陶俊. 返混对化学反应的影响[J]. 洛阳工学院学报,2001,22:89-92.
[9] GÓMez-BAREA A,OLLERO P,LECKNER B. Mass transport effects during measurements of gas-solid reaction kinetics in a fluidised bed [J]. Chemical Engineering Science,2007,62:1477-1493.
[10] LUO C,WATANABE T,NAKAMUR M.,et al. Development of FBR measurement of char reactivity to carbon dioxide at elevated temperatures [J]. Fuel,2001,80:233-243.
[11] POTIC B,KERSTN S R A,YE M,et al. Fluidization with hot compressed water in micro-reactors [J]. Chemical Engineering Science,2005,60:5982-5990.
[12] LIU X H,XU G W,GAO S Q. Micro fluidized beds:wall effect and operability [J]. Chemical Engineering Journal,2008,137:302-307.
[13] JOHN Blamey,MOHAMAD J Al-Jeboori,VASILIJE Manovic,et al. CO₂ capture by calcium aluminate pellets in a small fluidized bed [J]. Fuel Processing Technology ,2016,142:100-106.
[14] LI Yanjun,LIU Mingyan,LI Xiangnan. Single bubble behavior in gas-liquid-solid mini-fluidized beds [J]. Chemical Engineering Journal,2016,286:497-507.
[15] LIU Xiaoxing,ZHU Chuanqiang,GENG Shujun,et al. Two-fluid modeling of Geldart A particles in gas-solid micro-fluidized beds [J]. Particuology,2015,21:118-127.
[16] WEI F,LIN S,YANG G. Gas and solid mixing in a commercial FCC regenerator [J]. Chemical Engineering & Technology,1993,16:109-111.
[17] 耿爽,余剑,张聚伟,等. 微型流化床内气体返混[J]. 化工学报,2013,64(3):867-875.
[18] 杨旭,刘雅宁,余剑,等. 微型流化床内混合特性的数值模拟[J]. 化工学报,2014,65(9),3323-3330.
[19] GÓMEZ-BAREA A,LECKNER B.,OLLERO P,et al. Reduction of physical effects during reactivity tests in fluidized bed[J]. Industrial & Engineering Chemistry Research,2006,45:7344-7350.
[20] 余剑,朱剑虹,岳君容,等. 微型流化床反应动力学分析仪的研制与应用[J]. 化工学报,2009,60(10):2669-2674.
[21] YU J,YUE J R.,XU G X.,et al. Kinetics and mechanism of solid reactions in a micro fluidized bed reactor [J]. AIChE J.,2010,56:2905-2912.
[22] WANG F,ZENG X,SHAO R Y,et al. Isothermal gasification of in situ/ex situ coal char with CO₂ in a micro fluidized bed reaction analyzer [J]. Energy Fuels,2015,29:4795-4802.
[23] LUA A C,SU J C. Isothermal and non-isothermal pyrolysis kinetics of Kapton polyimide [J]. Polymer Degradation and Stability,2006,91:144-153.
[24] VYAZOVKIN S,WIGH C A. Isothermal and non-isothermal kinetics of thermally stimulated reactions of solids [J]. Review of Physical Chemistry,1998,17:407-33.
[25] PRASAD TP,KANUNGO SB,RAY HS. Non-isothermal kinetics:some merits and limitations[J]. Thermochim Acta,1992,203:503-514.
[26] 王芳,曾玺,韩江则,等. 微型流化床与热重测定煤焦- CO₂气化反应动力学的对比研究[J]. 燃料化学学报,2013,41:407-414.
[27] OCHOA J,CASSANELLO M C, BONELLI P R,et al. CO₂ gasification of Argentinean coal chars:a kinetic characterization [J]. Fuel Processing Technology,2001,74:161-176.
[28] WANG F.,ZENG X,WANG Y G,et al. Non-isothermal coal char gasification with CO₂ in a micro fluidized bed reaction analyzer and a thermogravimetric analyzer [J]. Fuel,2016,164:403-409.
[29] 张乾,李庆峰,张林仙,等. 重油残渣与不同煤阶煤共热解/气化实验研究[J]. 燃料化学学报,2014,42:392-398.
[30] YU J,ZENG X,ZHANG J W,et al. Isothermal differential characteristics of gas–solid reaction in micro-fluidized bed reactor [J]. Fuel,2013,103,29-36.
[31] 刘文钊,余剑,张聚伟,等. 多孔物质气固反应动力学研究[J]. 中国科学(化学),2012,42:1210-1216.
[32] CHEN H S,ZHENG Z,SHI W Y. Investigation on the kinetics of iron ore fines reduction by CO in a micro-fluidized bed [J]. Procedia Engineering,2015,102:1726-1735.
[33] LIN Y H,GUO Z C,TANG H Q.,et al. Kinetics of reduction reaction in micro-fluidized bed [J]. Journal of Iron and Steel Research (International),2012,19:6-8.
[34] YU J,YAO C B,ZENG X,et al. Biomass pyrolysis in a micro-fluidized bed reactor:characterization and kinetics [J]. Chemical Engineering Journal,2011,168:839-847.
[35] GUO F Q,DONG Y P,LV Z C,et al. Pyrolysis kinetics of biomass (herb residue) under isothermal condition in a micro fluidized bed [J]. Energy Conversion and Management,2015,93:367-376.
[36] 蔡连国,刘文钊,余剑,等. 煤程序升温与等温热解特性及动力学比较研究[J]. 煤炭转化,2012,35:6-14.
[37] MAO Y B,DONG L,DONG Y P,et al. Fast co-pyrolysis of biomass and lignite in a micro fluidized bed reactor analyzer [J]. Bioresource Technology,2015,181:155-162.
[38] 季颖,曾玺,余剑,等. 微型流化床反应分析仪中煤半焦水蒸气气化反应特性[J]. 化工学报,2014,65(9):3447-3456.
[39] WANG F,ZENG X,WANG Y G.,et al. Characterization of coal char gasification with steam in a micro-fluidized bed reaction analyzer[J]. Fuel Processing Technology,2016,141:2-8.
[40] GUO F Q,DONG Y P,LV Z C,et al. Kinetic behavior of biomass under oxidative atmosphere using a micro-fluidized bed reactor[J]. Energy Conversion and Management,2016,108:210-218.
[41] ZHANG Y M,SUN G G,GAO S Q,et al. Regeneration kinetics of spent FCC catalyst via coke gasification in a micro fluidized bed [J]. Procedia Engineering,2015,102:1758-1765.
[42] YU J,ZENG X,ZHANG G Y,et al. Kinetics and mechanism of direct reaction between CO₂ and Ca(OH)₂ in micro fluidized bed [J]. Environmental Science & Technology,2013,47:7514-7520.
[43] GAI C,DONG Y P,LV Z C,et al. Pyrolysis behavior and kinetic study of phenol as tar model compound in micro fluidized bed reactor [J]. International Journal of Hydrogen Energy,2015,40:7956-7964.
[44] SONG Y,WANG Y,YANG W,et al. Reduction of NO over biomass tar in micro-fluidized bed [J]. Fuel Processing Technology,2014,118:270-277.
[45] ZHANG Y M,YAO M Q,GAO S Q,et al. Reactivity and kinetics for steam gasification of petroleum coke blended with black liquor in a micro fluidized bed [J]. Applied Energy,2015,160:820-828.

微型流化床反应分析的方法基础与应用研究

Fundamentals and applications of micro fluidized bed reaction analysis

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