微孔有机硅膜在CO2分离中的研究进展

doi:10.16085/j.issn.1000-6613.2024-1854

摘要/Abstract

摘要：

有机硅膜具有可控的微孔结构、优异的稳定性以及丰富的有机官能团，在CO₂高效分离领域具有良好的应用前景。本文综述了有机硅膜的前体类型、制备方法和孔径调控机理，归纳了有机硅膜的制备优化策略，梳理了有机硅膜在CO₂/N₂、CO₂/CH₄、H₂/CO₂分离领域中的应用，并对比了不同结构的有机硅膜在上述领域的分离性能，总结了有机硅膜性能提升的可行方法。最后对有机硅膜的发展进行了展望。

关键词: 二氧化碳, 分离, 膜, 有机硅, 微孔结构

Abstract:

Organosilica membranes exhibit controllable microporous structures, excellent stabilities and abundant organic functional groups, which endow them with great potential in the field of efficient CO₂ separation. This article reviewed the precursor types, preparation methods and pore size control mechanisms of organosilica membranes, summarized the preparation optimization strategies of organosilica membranes and discussed the applications of organosilica membranes in the fields of CO₂/N₂, CO₂/CH₄ and H₂/CO₂ separations. The separation performances of different organosilica membranes in the above fields were compared. The optimization strategies for enhancing the performances of organosilica membranes were summarized. The future development of organosilica membranes was also proposed.

Key words: carbon dioxide, separation, membrane, organosilica, microporous structure

中图分类号:

TQ028.2

顾晟燊, 郭猛, 任秀秀, 潘阳, 靳栋梁, 钟璟. 微孔有机硅膜在CO₂分离中的研究进展[J]. 化工进展, 2025, 44(5): 2846-2855.

GU Shengshen, GUO Meng, REN Xiuxiu, PAN Yang, JIN Dongliang, ZHONG Jing. Research progress of microporous organosilica membranes in CO₂ separation[J]. Chemical Industry and Engineering Progress, 2025, 44(5): 2846-2855.

图/表 12

参考文献 51

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有机硅膜	测试温度/℃	进气组成（体积比）	CO₂渗透率/GPU	CO₂/N₂选择性	参考文献
BTESA-APTES	25	CO₂/N₂（15/85）	3230	31	[30]
BTESE-BPh	25	纯气	7437	22.2	[31]
PhTES	25	CO₂/N₂（15/85）	1087	30	[32]
BTESB	25	CO₂/N₂（15/85）	2600	34	[32]
BTESBPh	25	CO₂/N₂（15/85）	5465	13	[32]
BTESA-B	25	纯气	5495	25	[33]
BTESA-BPh	25	纯气	9716	12	[33]
BTESA-P30	25	CO₂/N₂（14/86）	3807	40	[34]

有机硅膜	测试温度/℃	进气组成（体积比）	CO₂渗透率/GPU	CO₂/N₂选择性	参考文献
BTESA-APTES	25	CO₂/N₂（15/85）	3230	31	[30]
BTESE-BPh	25	纯气	7437	22.2	[31]
PhTES	25	CO₂/N₂（15/85）	1087	30	[32]
BTESB	25	CO₂/N₂（15/85）	2600	34	[32]
BTESBPh	25	CO₂/N₂（15/85）	5465	13	[32]
BTESA-B	25	纯气	5495	25	[33]
BTESA-BPh	25	纯气	9716	12	[33]
BTESA-P30	25	CO₂/N₂（14/86）	3807	40	[34]

有机硅膜	测试温度/℃	进气组成（体积比）	CO₂渗透率/GPU	CO₂/CH₄选择性	参考文献
APTES-20%	120	纯气	687	40	[37]
AP-PECVD silica	50	CO₂/CH₄（50/50）	568	166	[22]
BTESE	50	纯气	1613	90	[38]
MIL-53-NH₂/organosilica	25	CO₂/CH₄（50/50）	430	18.2	[39]

有机硅膜	测试温度/℃	进气组成（体积比）	CO₂渗透率/GPU	CO₂/CH₄选择性	参考文献
APTES-20%	120	纯气	687	40	[37]
AP-PECVD silica	50	CO₂/CH₄（50/50）	568	166	[22]
BTESE	50	纯气	1613	90	[38]
MIL-53-NH₂/organosilica	25	CO₂/CH₄（50/50）	430	18.2	[39]

有机硅膜	测试温度/℃	进气组成	H₂渗透率 /GPU	H₂/CO₂ 选择性	参考文献
Si600	200	纯气	1493	70	[43]
BTESE	200	纯气	138	36	[44]
VTES	600	纯气	1613	95	[45]
Pd/SiO₂	200	纯气	31661	11.12	[46]
POS	200	纯气	2168	4.3	[48]
POS-1	200	纯气	484	13.6	[49]
Pd-Nb-BTESE	300	纯气	335	107	[50]
PNB-Pd	200	纯气	2986	17.2	[51]

微孔有机硅膜在CO₂分离中的研究进展

Research progress of microporous organosilica membranes in CO₂ separation

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