矿用聚氨酯注浆材料反应热控制技术研究进展

doi:10.16085/j.issn.1000-6613.2023-2229

摘要/Abstract

摘要：

针对目前矿用聚氨酯注浆材料在工程应用中潜在的反应热失控隐患问题，探索创新高效的聚氨酯材料改性技术具有重大的现实意义。本文分析了引发聚氨酯注浆材料反应热失控的原因，重点阐述了聚氨酯材料的本征性能缺陷，如固化反应放热量大、体系蓄热温度高以及阻燃性能差等内在因素，同时对环境、制度和人员等外在因素也进行了介绍。聚焦引发反应热失控的内在因素，综述了近年来国内外研究者围绕聚氨酯材料反应放热控制、体系蓄热温度控制和阻燃性能改性等领域取得的研究进展。最后围绕聚氨酯材料改性方法创新和产品安全准入制度管理两个方面进行总结，并结合目前材料改性研究存在的技术问题，对深化矿用聚氨酯注浆材料在煤矿井下的安全和绿色环保应用进行了合理的展望。

关键词: 矿用注浆材料, 聚氨酯, 反应热, 阻燃性能, 导热性能

Abstract:

In view of the potential risk of runaway reaction heat in the engineering application of current polyurethane grouting materials for mining, it is of great practical significance to explore innovative and efficient polyurethane material modification technology. In this work, the causes of runaway reaction heat of polyurethane grouting materials were analyzed with a focus on the intrinsic performance defects of polyurethane materials, such as high exothermic heat, strong heat storage and poor flame retardancy, which were mainly explained as the internal causes of the runaway reaction heat, and the external causes such as environment, system and personnel were also introduced. Focusing on the internal causes of runaway reaction heat, the research progresses of polyurethane modification both domestically and internationally in recent years were reviewed from the perspective of the control of reaction heat release and heat storage temperature as well as the modification of flame-retardant property. Finally, in terms of the innovation of polyurethane material modification methods and the management of product safety access systems combining with the existing technical problems in material modification research, the reasonable outlooks were made on deepening the safety and green environmental protection application of polyurethane grouting materials in mines.

Key words: grouting materials for mining, polyurethane, reaction heat, flame retardant, thermal conductivity

中图分类号:

TQ323.8

耿乾浩, 徐晓云, 李冰晶. 矿用聚氨酯注浆材料反应热控制技术研究进展[J]. 化工进展, 2025, 44(1): 319-328.

GENG Qianhao, XU Xiaoyun, LI bingjing. Research progress in control technology for reaction heat of polyurethane grouting materials in mines[J]. Chemical Industry and Engineering Progress, 2025, 44(1): 319-328.

图/表 8

参考文献 36

1	侯凯, 王帅, 姚顺, 等. 矿用聚氨酯类注浆材料改性研究进展[J]. 煤炭科学技术, 2022, 50(10): 28-34.
	HOU Kai, WANG Shuai, YAO Shun, et al. Research progress on modification of polyurethane grouting materials in mines[J]. Coal Science and Technology, 2022, 50(10): 28-34.
2	秦传睿, 陆伟, 李金亮. 降温型聚氨酯/纳米粉煤灰注浆材料的降温机理分析[J]. 煤炭学报, 2019, 44(S1): 178-186.
	QIN Chuanrui, LU Wei, LI Jinliang. Cooling mechanism of cooling polyurethane/nano fly ash grouting material[J]. Journal of China Coal Society, 2019, 44(S1): 178-186.
3	党海春, 刘占洲, 雷春兴, 等. 支化与交联型聚氨酯弹性体的合成与性能分析[J]. 化工进展, 2021, 40(6): 3380-3388.
	DANG Haichun, LIU Zhanzhou, LEI Chunxing, et al. Preparation and properties of branched polyurethane elastomer via bulk prepolymerization[J]. Chemical Industry and Engineering Progress, 2021, 40(6): 3380-3388.
4	杨绍斌, 洪晓东, 董伟, 等. 自限温聚氨酯注浆加固材料的自限温机理及应用性能[J]. 煤炭学报, 2014, 39(7): 1315-1320.
	YANG Shaobin, HONG Xiaodong, DONG Wei, et al. Mechanism of self-controlling temperature for self-controlling temperature polyurethane grouting reinforced materials and its application properties[J]. Journal of China Coal Society, 2014, 39(7): 1315-1320.
5	许明路, 何小芳, 李杰飞, 等. 矿用聚氨酯注浆材料的应用研究[J]. 材料导报, 2014, 28(17): 96-100.
	XU Minglu, HE Xiaofang, LI Jiefei, et al. Research on application of polyurethane grouting material for mining[J]. Materials Review, 2014, 28(17): 96-100.
6	李国法, 郑化安, 付东升, 等. 煤矿瓦斯抽采钻孔封孔聚氨酯材料研究进展[J]. 洁净煤技术, 2014, 20(2): 94-98, 103.
	LI Guofa, ZHENG Hua’an, FU Dongsheng, et al. Research progress of polyurethane for coal mining bore hole sealing engineering[J]. Clean Coal Technology, 2014, 20(2): 94-98, 103.
7	郑德志, 辛梅华, 李明春. 软质聚氨酯泡沫塑料无卤阻燃技术研究进展[J]. 化工进展, 2015, 34(9): 3349-3355, 3362.
	ZHENG Dezhi, XIN Meihua, LI Mingchun. Research progress of halogen-free flame retardant flexible polyurethane foams[J]. Chemical Industry and Engineering Progress, 2015, 34(9): 3349-3355, 3362.
8	BOULKADID Moulai Karim, TOUIDJINE Sabri, TRACHE Djalal, et al. Analytical methods for the assessment of curing kinetics of polyurethane binders for high-energy composites[J]. Critical Reviews in Analytical Chemistry, 2022, 52(5): 1112-1121.
9	WANG Juan, ZHANG Chenxiao, DENG Yu, et al. A review of research on the effect of temperature on the properties of polyurethane foams[J]. Polymers, 2022, 14(21): 4586.
10	董军, 刘国忠, 刘朝文. 高分子泡沫材料反应放热控制技术及固化特性研究[J]. 煤炭学报, 2010, 35(3): 377-380.
	DONG Jun, LIU Guozhong, LIU Zhaowen. Exothermic reaction controlling technology and curing characteristics of polymer foam materials[J]. Journal of China Coal Society, 2010, 35(3): 377-380.
11	糜婧, 谢松明, 杜建新, 等. 含磷阻燃剂对硬质聚氨酯泡沫塑料阻燃性能和力学性能的影响[J]. 高分子材料科学与工程, 2013, 29(10): 64-67.
	MI Jing, XIE Songming, DU Jianxin, et al. Flame retardancy and physical properties of rigid polyurethane foam containing phosphorus flame retardants[J]. Polymer Materials Science & Engineering, 2013, 29(10): 64-67.
12	薛建英, 雷昊, 徐开玉. 改性聚氨酯硬泡复合材料的阻燃性能研究[J]. 消防科学与技术, 2022, 41(5): 694-697.
	XUE Jianying, LEI Hao, XU Kaiyu. Flame retardant performance of modified polyurethane rigid foam composite[J]. Fire Science and Technology, 2022, 41(5): 694-697.
13	张尧, 陈露, 黄小冬, 等. 阻燃聚氨酯的研究及应用进展[J]. 塑料助剂, 2020(1): 1-10.
	ZHANG Yao, CHEN Lu, HUANG Xiaodong, et al. Research of flame retardancy of polyurethane and its application progress[J]. Plastics Additives, 2020(1): 1-10.
14	张增誉. 安全型聚氨酯加固材料的制备及防火性能研究[J]. 煤炭科学技术, 2020, 48(12): 148-152.
	ZHANG Zengyu. Research on preparation and fire resistance performance of safety polyurethane reinforcing material[J]. Coal Science and Technology, 2020, 48(12): 148-152.
15	沈佳豪, 袁楠, 马彦龙, 等. 低温矿用聚氨酯注浆材料研究[J]. 化工新型材料, 2022, 50(10): 290-294.
	SHEN Jiahao, YUAN Nan, MA Yanlong, et al. Research on low-temperature mining PU grouting material[J]. New Chemical Materials, 2022, 50(10): 290-294.
16	徐军, 魏光曦, 李明友, 等. 低放热双组分聚氨酯加固材料的开发研究[J]. 聚氨酯工业, 2020, 35(4): 53-56.
	XU Jun, WEI Guangxi, LI Mingyou, et al. Development of low exothermic two-component polyurethane reinforcing material[J]. Polyurethane Industry, 2020, 35(4): 53-56.
17	XIN Haihui, ZHANG Pengcheng, ZHANG Boyang, et al. Polyurethane exothermic polymerization and phase change material thermal delay matching: An approach to reducing fire risks in mining polymer materials[J]. ACS Applied Polymer Materials, 2023, 5(10): 7887-7898.
18	张迅韬, 张兆鑫, 黄娇, 等. 热塑性聚氨酯基导热纳米复合材料的制备及性能研究进展[J]. 工程塑料应用, 2021, 49(3): 161-165.
	ZHANG Xuntao, ZHANG Zhaoxin, HUANG Jiao, et al. Research progress on preparation and properties of thermoplastic polyurethane thermal conductive nanocomposites[J]. Engineering Plastics Application, 2021, 49(3): 161-165.
19	ZHU Zezhou, LI Chaowei, Songfeng E, et al. Enhanced thermal conductivity of polyurethane composites via engineering small/large sizes interconnected boron nitride nanosheets[J]. Composites Science and Technology, 2019, 170(20): 93-100.
20	YU Xiaofeng. Preparation and structure analysis of aluminum oxide/water glass/polyurethane composite grouting material for mining[J]. Journal of Building Engineering, 2023, 76: 107170.
21	李星宇, 陈占春. 导热聚氨酯弹性体/石墨烯纳米片复合材料的制备及性能[J]. 高分子材料科学与工程, 2020, 36(4): 156-160.
	LI Xingyu, CHEN Zhanchun. Preparation for thermally conductive polyurethane elastomer/graphene nanosheets composites and their properties[J]. Polymer Materials Science & Engineering, 2020, 36(4): 156-160.
22	武思蕊, 李斌, 赵梁成, 等. 磁性石墨烯/聚氨酯柔性复合材料的制备及自修复效能[J]. 化工进展, 2020, 39(4): 1422-1430.
	WU Sirui, LI Bin, ZHAO Liangcheng, et al. Preparation and self-repairing efficiency of magnetic graphene/polyurethane flexible composites[J]. Chemical Industry and Engineering Progress, 2020, 39(4): 1422-1430.
23	赵梦阳, 张宇昂, 唐炳涛. 导热增强聚氨酯基柔性定形相变材料的制备及性能[J]. 精细化工, 2022, 39(6): 1155-1161, 1189.
	ZHAO Mengyang, ZHANG Yuang, TANG Bingtao. Preparation and properties of thermal conductivity enhanced polyurethane based flexible and form-stable phase change materials[J]. Fine Chemicals, 2022, 39(6): 1155-1161, 1189.
24	王兵, 吉海峰, 刘迎春, 等. 功能化氮化硼纳米片的制备及在导热聚氨酯复合材料中的应用[J]. 高分子材料科学与工程, 2022, 38(9): 66-71.
	WANG Bing, JI Haifeng, LIU Yingchun, et al. Preparation of functionalized boron nitride nanosheets and their application in thermally conductive composites on the matrix of polyurethane[J]. Polymer Materials Science & Engineering, 2022, 38(9): 66-71.
25	石林, 马忠雷, 景佳瑶, 等. 双导热网络功能化氮化硼纳米片/聚氨酯复合材料的制备与导热性能[J]. 复合材料学报, 2022, 39(10): 4531-4539.
	SHI Lin, MA Zhonglei, JING Jiayao, et al. Preparation and thermally conductive properties of functionalized boron nitride nanosheets/polyurethane composites with double heat-conduction networks[J]. Acta Materiae Compositae Sinica, 2022, 39(10): 4531-4539.
26	WONDU Eyob, LULE Zelalem, KIM Jooheon. Thermal conductivity and mechanical properties of thermoplastic polyurethane-/silane-modified Al₂O₃ composite fabricated via melt compounding[J]. Polymers, 2019, 11(7): 1103.
27	SOONG Yu-Chian, CHIU Chih-Wei. Multilayered graphene/boron nitride/thermoplastic polyurethane composite films with high thermal conductivity, stretchability, and washability for adjustable-cooling smart clothes[J]. Journal of Colloid and Interface Science, 2021, 599: 611-619.
28	杨佳, 张迅韬, 杨尚科, 等. CNTs-Al₂O₃协同改性热塑性聚氨酯复合材料的制备与性能[J]. 工程塑料应用, 2022, 50(7): 20-27.
	YANG Jia, ZHANG Xuntao, YANG Shangke, et al. Preparation and properties of CNTs-Al₂O₃ synergistic modified thermoplastic polyurethane composite[J]. Engineering Plastics Application, 2022, 50(7): 20-27.
29	张弛, 聂士斌. 不同原料组分对聚氨酯泡沫反应温度及泡沫密度、泡体结构、热稳定性的影响[J]. 安徽理工大学学报(自然科学版), 2016, 36(6): 39-46.
	ZHANG Chi, NIE Shibin. Effects of different components on reaction temperature, the foam density, bubble structure and thermal stability of the polyurethane[J]. Journal of Anhui University of Science and Technology (Natural Science), 2016, 36(6): 39-46.
30	ZHANG Bei, WANG Baolin, ZHONG Yanhui, et al. Experimental study on reducing the heat of curing reaction of polyurethane polymer grouting material[J]. Advances in Polymer Technology, 2021, 2021: 9954498.
31	CHEN Hong, DENG Cong, ZHAO Zeyong, et al. Novel piperazine-containing oligomer as flame retardant and crystallization induction additive for thermoplastics polyurethane[J]. Chemical Engineering Journal, 2020, 400: 125941.
32	施永乾, 叶涵, 刘川, 等. 一种新型MXene基热塑性聚氨酯的制备与阻燃性能分析[J]. 福州大学学报(自然科学版), 2022, 50(2): 278-285.
	SHI Yongqian, YE Han, LIU Chuan, et al. Study on flame retardancy of a novel MXene-based on thermoplastic polyurethane[J]. Journal of Fuzhou University (Natural Science Edition), 2022, 50(2): 278-285.
33	LU Shaolin, FENG Yechang, ZHANG Peikun, et al. Preparation of flame-retardant polyurethane and its applications in the leather industry[J]. Polymers, 2021, 13(11): 1730.
34	杨绍斌, 董伟, 周晓谦, 等. 矿用聚氨酯注浆材料阻燃及加固性能研究[J]. 中国安全科学学报, 2012, 22(8): 48-53.
	YANG Shaobin, DONG Wei, ZHOU Xiaoqian, et al. Study on flame retarding and reinforcement properties of mine polyurethane grouting material[J]. China Safety Science Journal, 2012, 22(8): 48-53.
35	施永乾, 马苏宁, 杨晔, 等. 碳化钛-二氧化锰/热塑性聚氨酯纳米复合材料的制备及阻燃性能[J]. 复合材料学报, 2022, 39(10): 4561-4571.
	SHI Yongqian, MA Suning, YANG Ye, et al. Preparation and flame retardancy of titanium carbide-manganese dioxide/thermoplastic polyurethane nanocomposites[J]. Acta Materiae Compositae Sinica, 2022, 39(10): 4561-4571.
37	WANG Guisong, XU Wenzong, CHEN Rui, et al. Synergistic effect between zeolitic imidazolate framework-8 and expandable graphite to improve the flame retardancy and smoke suppression of polyurethane elastomer[J]. Journal of Applied Polymer Science, 2020, 137(1): e48048.
38	CHEN Xilei, CHEN Xihong, LI Shaoxiang, et al. Copper metal-organic framework toward flame-retardant enhancement of thermoplastic polyurethane elastomer composites based on ammonium polyphosphate[J]. Polymers for Advanced Technologies, 2021, 32(8): 2829-2842.
39	SHI Congling, WAN Mei, HOU Zhengbo, et al. Co-MOF@MXene hybrids flame retardants for enhancing the fire safety of thermoplastic polyurethanes[J]. Polymer Degradation and Stability, 2022, 204: 110119.
40	李齐敏, 王靖宇, 陈腊梅, 等. 磷-氮多元醇浸渍可膨胀石墨协同增强硬质聚氨酯泡沫的隔热及阻燃性能[J]. 高分子材料科学与工程, 2019, 35(5): 57-62, 70.
	LI Qimin, WANG Jingyu, CHEN Lamei, et al. Enhancing thermal insulation and flame retardancy of RPUF filled with reactive flame retardant containing phosphorus-nitrogen soaking into expandable graphite[J]. Polymer Materials Science & Engineering, 2019, 35(5): 57-62, 70.
41	周威, 郑开梅, 周永红, 等. 新型含磷阻燃型桐油基聚氨酯硬泡的制备及性能表征[J]. 化工进展, 2019, 38(7): 3285-3290.
	ZHOU Wei, ZHENG Kaimei, ZHOU Yonghong, et al. Preparation and characterization of novel phosphorus-containing flame retardant tung oil-based rigid polyurethane foam[J]. Chemical Industry and Engineering Progress, 2019, 38(7): 3285-3290.
42	WANG Haiyan, TIAN Yao, CHEN Xiao, et al. Kinetic and synergetic effect analysis of the co-combustion of coal blended with polyurethane materials[J]. ACS Omega, 2020, 5(40): 26005-26014.
36	ZHAO Sijia, YIN Lian, ZHOU Qianqian, et al. In situ self-assembly of zeolitic imidazolate frameworks on the surface of flexible polyurethane foam: Towards for highly efficient oil spill cleanup and fire safety[J]. Applied Surface Science, 2020, 506: 144700.

编辑推荐 0

Metrics

阅读次数

全文

HTML			PDF

最新录用	在线预览	正式出版	最新录用	在线预览	正式出版
0	0	1	0	0	13

来源	本网站	其他网站

次数	12	2
比例	86%	14%

摘要

最新录用	在线预览	正式出版

0	0	66

来源	本网站	其他网站

次数	10	56
比例	15%	85%

[1]	万立祥, 崔锦峰, 郭军红, 包雪梅, 杨保平. 聚酰胺酸-聚氨酯嵌段共聚物及其热亚胺化弹性体的制备与性能[J]. 化工进展, 2025, 44(1): 398-406.
[2]	黄雪, 范燕香, 周红军, 周新华, 窦瑶. 蓖麻油基水性聚氨酯载药乳液的制备及性能[J]. 化工进展, 2024, 43(12): 6913-6924.
[3]	李珍明, 李春祺, 李征光, 李秀敏, 赵俭波. 棉纺黑液提取物基聚氨酯泡沫的制备及性能[J]. 化工进展, 2024, 43(10): 5704-5711.
[4]	胡锦健, 李龙, 董子靖. 碳纳米材料在PU纱线基柔性应变传感器中的应用[J]. 化工进展, 2023, 42(2): 872-883.
[5]	席慧敏, 钱坤, 俞科静, 李杰, 张中威, 熊自明, 张耀良. 基于二硫键和氢键的自修复聚氨酯弹性体的制备、改性及其应用[J]. 化工进展, 2023, 42(2): 934-943.
[6]	辛华, 彭琪, 李阳帆, 张岩, 陈悦, 李新琦. 含氟聚氨酯二甲基丙烯酸酯为芯材的微胶囊制备及自修复性能[J]. 化工进展, 2023, 42(10): 5406-5413.
[7]	胡瑶瑶, 魏铭, 李博申, 董月林, 董群峰, 刘传奇. 硅/巯基复合改性光固化WPUA涂料制备及其性能[J]. 化工进展, 2022, 41(6): 3186-3193.
[8]	李博申, 魏铭, 胡瑶瑶, 董月林, 董群锋, 杨立峰. 改性h-BN/聚氨酯丙烯酸酯涂料的制备与性能[J]. 化工进展, 2022, 41(6): 3194-3202.
[9]	陆少锋, 崔杉杉, 师文钊, 李苏松, 谢艳, 杨乾诚. 交联水性聚氨酯固-固相变材料的制备及性能[J]. 化工进展, 2022, 41(5): 2574-2581.
[10]	史慕杨, 芦博慧, 王锦康, 晋阳, 葛明桥. 染料掺杂发光聚氨酯复合材料的制备及性能[J]. 化工进展, 2022, 41(4): 2029-2037.
[11]	严成飞, 余彩莉, 张发爱. 松香基荧光水性聚氨酯的制备及性能[J]. 化工进展, 2022, 41(11): 6061-6067.
[12]	李婷, 杜少辉, 崔锦峰, 王仰辉, 李虎林, 郭润兰, 王蓬, 王振军, 郭军红, 杨保平. 磷-硼杂化预聚物嵌段水性聚氨酯纸张施胶剂的制备和性能[J]. 化工进展, 2022, 41(10): 5549-5557.
[13]	王东亮, 谢江鹏, 孟文亮, 李婧玮, 周怀荣. 基于酸度系数（pK_a）模型的胺法SO₂捕集过程多目标效能分析[J]. 化工进展, 2022, 41(10): 5669-5676.
[14]	蒯子函, 闫霆, 吴韶飞, 周宇翔, 潘卫国. 硬脂醇/膨胀石墨复合相变材料的制备及储热性能[J]. 化工进展, 2021, 40(S1): 301-310.
[15]	党海春, 刘占洲, 雷春兴, 许召赞, 李振中. 支化与交联型聚氨酯弹性体的合成与性能分析[J]. 化工进展, 2021, 40(6): 3380-3388.