美国石化工业泄漏检测与修复技术进展

doi:10.16085/j.issn.1000-6613.2023-0641

摘要/Abstract

摘要：

美国环保署（EPA）在世界上最早推行泄漏检测与修复技术（LDAR），控制石化企业设备泄漏挥发性有机物（VOCs）排放，发展至今经历了初级（1983—1999年）和高级（2000—2020年前后）阶段，目前处于技术革新初期，其发展历程和经验对中国LDAR政策、法规、标准制定和技术发展有借鉴意义。本文简要介绍了美国LDAR的创建、发展、技术进步及质量升级的历程，评述了LDAR等效减排的机制及相关进展，以及传感器在线检测、红外气体成像（OGI）检测、低排放密封等LDAR革新技术进展，展望了LDAR未来发展趋势。文章提出，总体上，美国的传感器在线检测、OGI检测和低排放密封等LDAR新技术研发应用世界领先，传感器网络智能在线检测技术可能是LDAR技术革新或下一代LDAR研发的主方向，设备低排放密封技术是LDAR的重要辅助手段，OGI是重要的LDAR非常规检测技术。

关键词: 环境, 污染, 测量, 泄漏检测与修复, 石化工业

Abstract:

The U.S. Environmental Protection Agency (EPA) was the first in the world to introduce leak detection and repair technology (LDAR) to control fugitive volatile organic compounds (VOCs) emissions from equipment leaks in petroleum refining and petrochemical industry. They have experienced the primary (1983—1999) and enhanced (around 2000—2020) stages, and is currently in the early stage of technological innovation. Their development history and experience are significant reference for policies, regulations, standards and techniques related to LDAR in China. This paper outlines the foundation and development of LDAR, technological progress and quality improvement in the United States, as well as the equivalent emission reduction policies and alternative means of emission control for LDAR. Additionally, the progress of technical innovations and the application such as optical gas imaging (OGI) detection, low-emission techniques, sensor-based automated and continuous detection and other high temporal and spatial resolution monitoring technologies is discussed and compared to LDAR. The future development of LDAR technology upgrades and innovations is explored. In general, the United States lead the world in the development and application of innovative LDAR technologies such as sensor-based leak detection, OGI detection and low-emission sealing techniques. Intelligent leak detection sensor network will probably be the dominant direction of LDAR technology innovation or next-generation LDAR research and development. Low-emission sealing technology will probably be an important auxiliary method to LDAR, while OGI will be an important alternative and supplementary LDAR detection technology.

Key words: environment, pollution, measurement, leak detection and repair, petroleum refining and petrochemical industry

中图分类号:

X511

李凌波. 美国石化工业泄漏检测与修复技术进展[J]. 化工进展, 2024, 43(4): 2049-2062.

LI Lingbo. Practice and development of leak detection and repair technology in petroleum refining and petrochemical industry in the United States[J]. Chemical Industry and Engineering Progress, 2024, 43(4): 2049-2062.

图/表 7

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项目	主要规定或要求
检测频次	增加某些阀门、连接件、泵和搅拌器的检测频次，定期检测开口管线封闭设备；泵和搅拌器每月1次，阀和开口管线封闭设备每季度1次，连接件每年1次；如果联邦、州和地方性法规有更高的检测频次要求，则执行更高的检测频次；如果连续2年（或以上）无泄漏，阀和开口管线封闭设备可选择每年1次，连接件可选择每2年1次，一旦发现泄漏，接下来12个月每月1次
检测仪器	应配置电子数据记录仪，实时记录检测数据、检测时间、仪器和检测人员编号
泄漏认定	阀、连接件和开口管线封闭设备250μmol/mol、泵500μmol/mol、搅拌器1000μmol/mol、聚合物单体泵（或搅拌器）2000μmol/mol
泄漏修复	泄漏浓度≥200μmol/mol进行修复尝试；应用钻孔并注入密封剂修复技术以减少延迟修复设备数量；修复泄漏或安装新的阀门和连接件时使用经过认证的低排放技术或填料；严格限制延迟修复设备数量
设备升级	泄漏浓度≥250μmol/mol的阀更换为低排放阀或低排放填料，泄漏浓度在100~250μmol/mol之间的阀填料也须按规定比例修复或更换为低排放规格；法兰等连接件泄漏≥250μmol/mol须修复或更换；3个连续检测周期中有2次检测≥250μmol/mol的连接件须更换
审核整改	每1~2年1次内审/外审，第1、3、5次应选外审，第2、4次可选外审或内审，审核内容主要包括LDAR记录、组件识别与建档、检测校准及现场操作等，审核确定LDAR存在缺陷或抽检泄漏率与报告泄漏率的比值≥3.0（且抽检泄漏率≥0.5%），应采取整改措施
违规细则	文件、计划或报告上报超期、检测违规（检测频次、检测方法、电子记录、数据上传等违规）、修复违规（首次修复尝试超期、修复超期、未按要求钻孔并注入密封剂修复、记录违规、延迟修复管理违规）、阀和连接件更换/改进违规（未按要求更换低排放阀及低排放填料、超期更换低排放阀及低排放填料、未按要求在计划检修期间更换低排放阀及低排放填料、未按要求及时更换/改进安装连接件、未按要求在检修期间更换/改进安装连接件）等
违规罚款	一般以每个设备每次违规计费或每个设备每个违规事件按天计费，如每个工艺装置检测方法违规5000~25000USD、记录违规250~37500USD、报告违规250~37500USD、每个设备每次未按要求更换低排放阀或低排放填料20000USD、设备识别错误250~5000USD/密封点、未标识泄漏设备250~5000USD/密封点、设备执行标准违规750~2000USD/密封点、校准不合规250USD/次、检测漏测100~2000USD/密封点、延迟上传数据库每天150USD/数据、检测电子数据记录违规每次100USD/密封点、未及时修复泄漏或根本未修每天100~3000USD/密封点、1200USD/个、阀或连接件延迟修复清单管理违规每天300USD/个……

项目	主要规定或要求
检测频次	增加某些阀门、连接件、泵和搅拌器的检测频次，定期检测开口管线封闭设备；泵和搅拌器每月1次，阀和开口管线封闭设备每季度1次，连接件每年1次；如果联邦、州和地方性法规有更高的检测频次要求，则执行更高的检测频次；如果连续2年（或以上）无泄漏，阀和开口管线封闭设备可选择每年1次，连接件可选择每2年1次，一旦发现泄漏，接下来12个月每月1次
检测仪器	应配置电子数据记录仪，实时记录检测数据、检测时间、仪器和检测人员编号
泄漏认定	阀、连接件和开口管线封闭设备250μmol/mol、泵500μmol/mol、搅拌器1000μmol/mol、聚合物单体泵（或搅拌器）2000μmol/mol
泄漏修复	泄漏浓度≥200μmol/mol进行修复尝试；应用钻孔并注入密封剂修复技术以减少延迟修复设备数量；修复泄漏或安装新的阀门和连接件时使用经过认证的低排放技术或填料；严格限制延迟修复设备数量
设备升级	泄漏浓度≥250μmol/mol的阀更换为低排放阀或低排放填料，泄漏浓度在100~250μmol/mol之间的阀填料也须按规定比例修复或更换为低排放规格；法兰等连接件泄漏≥250μmol/mol须修复或更换；3个连续检测周期中有2次检测≥250μmol/mol的连接件须更换
审核整改	每1~2年1次内审/外审，第1、3、5次应选外审，第2、4次可选外审或内审，审核内容主要包括LDAR记录、组件识别与建档、检测校准及现场操作等，审核确定LDAR存在缺陷或抽检泄漏率与报告泄漏率的比值≥3.0（且抽检泄漏率≥0.5%），应采取整改措施
违规细则	文件、计划或报告上报超期、检测违规（检测频次、检测方法、电子记录、数据上传等违规）、修复违规（首次修复尝试超期、修复超期、未按要求钻孔并注入密封剂修复、记录违规、延迟修复管理违规）、阀和连接件更换/改进违规（未按要求更换低排放阀及低排放填料、超期更换低排放阀及低排放填料、未按要求在计划检修期间更换低排放阀及低排放填料、未按要求及时更换/改进安装连接件、未按要求在检修期间更换/改进安装连接件）等
违规罚款	一般以每个设备每次违规计费或每个设备每个违规事件按天计费，如每个工艺装置检测方法违规5000~25000USD、记录违规250~37500USD、报告违规250~37500USD、每个设备每次未按要求更换低排放阀或低排放填料20000USD、设备识别错误250~5000USD/密封点、未标识泄漏设备250~5000USD/密封点、设备执行标准违规750~2000USD/密封点、校准不合规250USD/次、检测漏测100~2000USD/密封点、延迟上传数据库每天150USD/数据、检测电子数据记录违规每次100USD/密封点、未及时修复泄漏或根本未修每天100~3000USD/密封点、1200USD/个、阀或连接件延迟修复清单管理违规每天300USD/个……

项目	CWP	AWP（OGI）
适用标准	EPA方法21	EPA AWP（未配套标准检测方法）
检测仪器	便携式有机气体分析仪	红外气体相机
检测原理	火焰离子化检测（FID）	被动式红外气体成像
检测能力	检测限0.3~1.0μmol/mol^[33]	检测限约为1~16g/h^[33-34]
检测速度	250~600个设备密封/(人·天)^[35]	1500~2000个设备密封/(2人·天)^[33]
技术特点	探头距密封点1~2cm检测，结果为泄漏浓度，检测灵敏，但速度较慢，在一定区域内将发现更多泄漏，适合定期全面检测泄漏	几米外扫描烟羽，结果为烟羽视频，检测速度快，但灵敏度不高，在一定时段内可能发现更多泄漏，适合高频次检测较大泄漏以及不可达密封泄漏检测
排放定量	EPA相关方程^[9]	泄漏/不泄漏排放因子^[33]、基于泄漏图像像素计算^[36]
检测操作	较为简单	操作技能要求较高，通常需约200h的专业培训和考核
仪器重量	约6kg	2~3kg
仪器价格	0.6~2.2万美元/台^[33]	8～11万美元/台^[33]

项目	CWP	AWP（OGI）
适用标准	EPA方法21	EPA AWP（未配套标准检测方法）
检测仪器	便携式有机气体分析仪	红外气体相机
检测原理	火焰离子化检测（FID）	被动式红外气体成像
检测能力	检测限0.3~1.0μmol/mol^[33]	检测限约为1~16g/h^[33-34]
检测速度	250~600个设备密封/(人·天)^[35]	1500~2000个设备密封/(2人·天)^[33]
技术特点	探头距密封点1~2cm检测，结果为泄漏浓度，检测灵敏，但速度较慢，在一定区域内将发现更多泄漏，适合定期全面检测泄漏	几米外扫描烟羽，结果为烟羽视频，检测速度快，但灵敏度不高，在一定时段内可能发现更多泄漏，适合高频次检测较大泄漏以及不可达密封泄漏检测
排放定量	EPA相关方程^[9]	泄漏/不泄漏排放因子^[33]、基于泄漏图像像素计算^[36]
检测操作	较为简单	操作技能要求较高，通常需约200h的专业培训和考核
仪器重量	约6kg	2~3kg
仪器价格	0.6~2.2万美元/台^[33]	8～11万美元/台^[33]

项目	CWP	LDSN
减排原理	建立受控设备密封点电子档案，采用便携式仪器以一定频次检测密封点，发现泄漏，在规定时间内修复，实现VOCs减排	通过部署连续在线检测传感器网络，高时空分辨监测和溯源泄漏，及时/尽早发现并修复泄漏，缩短泄漏排放时间，实现VOCs减排
执行标准	美国HON等设备泄漏控制标准、美国EPA与石化企业谈判达成的CD	EPA AMEL，2023年1月美国 EPA批准首个基于传感器网络在线检测的AMEL
技术规范	美国EPA方法21、EPA AWP （OGI）	尚未规范化
检测方法	人工便携式 FID逐点检测每个受控设备密封，或人工OGI扫描受控设备密封	传感器网络在线检测一定空间范围内的设备密封泄漏，人工检测辅助定位密封点
管理平台	集成密封点建档、检测、维修、核算及质控全流程管理及手持端应用的信息化平台	集成场地及传感器空间部署、传感器健康与质控、检测数据可视化、移动端应用及泄漏扩散迁移、泄漏溯源、机器学习和深度学习等模型的智能化平台
发现泄漏	检测时发现泄漏，但不同类别设备密封检测周期为30~180d，发现泄漏时间估计为15~90d（泄漏发生平均按检测周期中点估算）	传感器检测到区块泄漏，智能平台引导人工检测精确定位泄漏，发现泄漏的时间一般≤1~3d
应用进展	美国1983—1999年常规LDAR，2000年至今强化LDAR	2021年在美国两套炼油装置完成工业试验，2023年获美国EPA批准AMEL，可替代这两套装置的常规LDAR
技术优点	建档、检测、平台等成套技术及标准规范成熟，能检测中小泄漏，直接定位泄漏源，检测数据可用于估算无组织排放清单	连续在线检测，智能高效，通过优化传感器选型、部署密度及位置、溯源模型及平台智能算法，可实现等效或优于传统LDAR的泄漏控制效果，能同步实现厂区VOCs及异味网格化在线监测，以及相关安全监控
技术局限	周期性检测发现泄漏不及时、检测效率低、劳动密集、人为因素影响大、检测人员潜在安全隐患等	仅能检测较大泄漏，不能直接定位泄漏源，传感器、空间部署、泄漏溯源、智能平台及技术规范尚在发展