木质纤维素复合生物质薄膜材料的功能化应用研究进展

doi:10.16085/j.issn.1000-6613.2021-2469

摘要/Abstract

摘要：

为了解决传统石油基高分子薄膜不可降解等问题，纤维素、淀粉、壳聚糖等生物质薄膜材料因其具有绿色可降解性等优点而备受关注并展现出良好的发展前景。但生物质薄膜往往存在强度低、耐水性差等问题，限制了其进一步发展及功能化应用。本文综述了以木质纤维素作为添加剂增强生物质薄膜的力学强度、防水性、紫外屏蔽等性能的研究进展，重点探讨了不同结构性质的木质素和不同尺度的微纳米木质纤维素对生物质薄膜性能的影响，并进一步综述了木质纤维素复合生物质薄膜材料在包装材料、电极材料以及催化材料领域中的功能化应用研究进展。分析并展望了木质纤维素复合生物质薄膜在制备及功能化方面的优势、不足以及发展方向，以期为采用木质纤维素改良生物质薄膜的研究提供借鉴。

关键词: 木质纤维素, 生物质, 膜, 复合材料, 增强, 功能化应用

Abstract:

For non-degradability of traditional petroleum-based polymer films, biomass-based films such as cellulose, starch and chitosan have attracted much attention due to their advantages of degradability with good development prospects. However, the problems of biomass-based films such as low strength and poor water resistance limit the further development and functional application. This paper summarizes related researches about the lignocellulose as an additive for enhancing the mechanical strength, water resistance, UV shielding and other properties of biomass-based films. It focuses on discussing the effects of lignin with various properties and lignocellulose with different diameter on the physical properties of biomass-based films. Furthermore, the research progress on the application fields of lignocellulose-based composite films in packaging materials, electrode materials and catalytic materials is reviewed. The advantages, disadvantages and development progress of the lignocellulose-based composite films in preparation technology and functional application are also analyzed. It is expected to provide some new insights/inspirations for subsequent study based on lignocellulose- enhanced composite films.

Key words: lignocellulose, biomass, film, composites, enhancement, functional applications

中图分类号:

TQ352.77

黄岳峰, 马丽莎, 张莉莉, 王志国. 木质纤维素复合生物质薄膜材料的功能化应用研究进展[J]. 化工进展, 2022, 41(9): 4840-4854.

HUANG Yuefeng, MA Lisha, ZHANG Lili, WANG Zhiguo. Research progress on functional application of lignocellulose composite biomass film materials[J]. Chemical Industry and Engineering Progress, 2022, 41(9): 4840-4854.

图/表 5

图1 不同聚集态木质素与纳米纤维素之间的相互作用[11]

图2 木质素纳米粒子复合纳米纤维素防水防紫外薄膜[11]

图3 微纳米/纳米木质纤维复合生物质薄膜材料

图4 木质纤维素复合生物质薄膜在包装材料中的应用

图5 木质纤维素复合生物质薄膜在电极材料和重金属催化材料中的应用

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