煤基液体燃料加氢脱氮催化剂的研究动态

doi:10.16085/j.issn.1000-6613.2021-1118

摘要/Abstract

摘要：

煤基粗油中氮含量高达4500mg/L左右，采用石油系的NiMoS催化剂很难实现含氮芳香族化合物的脱除。为开发针对性更强、更高效的加氢脱氮催化剂，本文对煤基粗油加氢脱氮的催化剂研究动态进行了综述。首先介绍了煤基粗油中含氮芳香族化合物的组成及特点，接着围绕传统硫化物催化剂和脱氮性能较高的贵金属催化剂，从活性相的构筑与调控、载体在催化剂中的作用等方面进行了分析，最后比较了上述两种催化剂的催化性能。结果表明：贵金属催化剂活性高于传统硫化物催化剂；添加助金属形成合金可提高贵金属耐硫性与稳定性；采用具有一定酸性、与活性中心相互作用适中的载体的催化剂脱氮性能更佳。在综合分析已有文献和工作基础上，得出只有依据反应体系、特定反应过程来设计专一的加氢脱氮催化剂，才能从根本上提高含氮化合物的脱除率。

关键词: 加氢反应, 碳氮键, 金属硫化物, 贵金属, 催化剂, 燃料

Abstract:

The nitrogen content in coal-based crude oil is as high as 4500mg/L, and it is difficult to achieve the removal of nitrogen-containing compounds in coal-based crude oil by using petroleum-based NiMoS catalyst. In order to develop more targeted and efficient hydrodenitrogenation catalyst, the research developments of coal-based crude oil hydrodenitrogenation catalyst is reviewed. Firstly, the composition and characteristics of nitrogen-containing compounds in coal-based crude oil are introduced. Secondly, around the traditional sulfide and noble metal catalysts with high denitrification performance, the construction and regulation of the active phase and the role of the support in the catalyst are analyzed. Finally, the activities of the two catalysts are compared. The analysis shows that the activity of noble metal catalysts is higher than that of traditional sulfide catalysts. The addition of promoter metals to form alloys is beneficial to the improvement of its sulfur resistance and stability. Catalysts with a certain acidity and moderate interaction with active centers have better denitrification performance. The HDN catalyst which designed based on reaction process can increase the removal rate of nitrogen-containing compounds basically.

Key words: hydrogenation, C—N bond, metal sulfides, noble metals, catalyst, fuel

中图分类号:

TQ536

薛怡凡, 宋云彩, 冯杰, 李文英. 煤基液体燃料加氢脱氮催化剂的研究动态[J]. 化工进展, 2021, 40(S2): 176-184.

XUE Yifan, SONG Yuncai, FENG Jie, LI Wenying. Research and development on coal-based liquid oil hydrodenitrogenation catalyst[J]. Chemical Industry and Engineering Progress, 2021, 40(S2): 176-184.

图/表 1

参考文献 70

1	OHTSUKA Tadao. Catalyst for hydrodesulfurization of petroleum residua[J]. Catalysis Reviews, 1977, 16(1): 291-325.
2	KATZER J R, SIVASUBRAMANIAN R. Process and catalyst needs for hydrodenitrogenation[J]. Catalysis Reviews, 1979, 20(2): 155-208.
3	李军芳, 李文博, 史士东, 等. 石油系加氢精制剂用于煤直接液化油的研究[J]. 煤炭转化, 2013, 36(2): 36-39.
	LI Junfang, LI Wenbo, SHI Shidong, et al. Study on petroleum hydrofining catalysts for coal direct liquefaction oil[J]. Coal Conversion, 2013, 36(2): 36-39.
4	尚慧芸, 徐卫民. “句容坳陷海相原油的地球化学特征”概要[J]. 石油勘探与开发, 1983(6): 68.
	SHANG Huiyun, XU Weimin. Summary of “The geochemical characteristics of marine crude oil in Jurong depression”[J]. Petroleum Expoloration and Development, 1983(6): 68.
5	黄澎, 张晓静, 毛学锋, 等. 神府煤液化油加氢精制过程中硫氮化合物分布的变化[J]. 燃料化学学报, 2016, 44(1): 37-43.
	HUANG Peng, ZHANG Xiaojing, MAO Xuefeng, et al. Change of sulfur and nitrogen compounds in the direct liquefaction oil from Shenfu coal upon the hydrofining process[J]. Journal of Fuel Chemistry and Technology, 2016, 44(1): 37-43.
6	付殿岭. Mo₂C和Rh催化剂表面含硫含氮化合物反应机理的研究[D]. 青岛: 中国石油大学(华东), 2016.
	FU Dianling. Study on the reaction mechanism of sulfur- and nitrogen-containing compounds on Mo₂C and Rh Catalysts[D]. Qingdao: China University of Petroleum (East China), 2016.
7	WANG Wei, LI Huifeng, HAN Wei, et al. A DFT study of the adsorption behavior of sulfur and nitrogen compounds on the NiMoS phase[J]. China Petroleum Processing and Petrochemical Technology, 2020, 22(1): 40-48.
8	梁文杰. 石油化学[M]. 青岛: 中国石油大学出版社, 2009.
	LIANG Wenjie. Petroleum chemistry[M]. Qingdao: China University of Petroleum Press, 2009.
9	李伟林, 石智杰, 张晓静, 等. 煤直接液化油中硫氮化合物的类型分布[J]. 洁净煤技术, 2015, 21(4): 55-57.
	LI Weilin, SHI Zhijie, ZHANG Xiaojing, et al. Structures and composition of S and N compounds in direct coal liquefaction oil[J]. Clean Coal Technology, 2015, 21(4): 55-57.
10	李延红. 煤液化油中含氮化合物存在形式及分布的研究[D]. 上海: 华东理工大学, 2014.
	LI Yanhong. Study on the existence form and distribution of nitrogen compounds in coal liquefaction oil[D]. Shanghai: East China University of Science and Technology, 2014.
11	刘敏,陈贵锋,王永刚,等. 白石湖煤液化粗油加氢精制过程硫、氮化合物转化规律[J]. 燃料化学学报, 2019, 47(7): 870-875.
	LIU Min, CHEN Guifeng, WANG Yonggang, et al. Conversion of sulphur and nitrogen compounds in hydrofining process of Baishihu coal liquefaction oil[J]. Journal of Fuel Chemistry and Technology, 2019, 47(7): 870-875.
12	NØRSKOV J K. Electronic factors in catalysis[J]. Progress in Surface Science, 1991, 38(2): 103-144.
13	LIU Huan, LIU Chenguang, YIN Changlong, et al. Low temperature catalytic hydrogenation naphthalene to decalin over highly-loaded NiMo, NiW and NiMoW catalysts[J]. Catalysis Today, 2016, 276: 46-54.
14	ABSI-HALABI M, STANISLAUS A, AL-DOLAMA K. Performance comparison of alumina-supported Ni-Mo, Ni-W and Ni-Mo-W catalysis in hydrotreating vacuum residue[J]. Fuel, 1998, 77(7): 787-790.
15	HAANDEL Lennart van, BREMMER Marien, KOOYMAN Patricia J, et al. Structure-activity correlations in hydrodesulfurization reactions over Ni-promoted Mo_xW_(1-_x₎S₂/Al₂O₃ catalysts[J]. ACS Catalysis, 2015, 5(12): 7276-7287.
16	CUI Wengang, ZHENG Huaan, NIU Menglong, et al. Product compositions from catalytic hydroprocessing of low temperature coal tar distillate over three commercial catalysts[J]. Reaction Kinetics Mechanisms & Catalysis, 2016, 119(2): 491-509.
17	Henrik TOPSØE, CLAUSEN Bjerne S, CANDIA Roberto, et al. In situ Mössbauer emission spectroscopy studies of unsupported and supported sulfided Co-Mo hydrodesulfurization catalysts: evidence for and nature of a Co-Mo-S phase[J]. Journal of Catalysis, 1981, 68(2): 433-452.
18	WIVEL Carsten, CANDIA Roberto, CLAUSEN Bjerne S, et al. On the catalytic significance of a Co-Mo-S phase in Co-Mo/Al₂O₃ hydrodesulfurization catalysts: combined in situ Mössbauer emission spectroscopy and activity studies[J]. Journal of Catalysis, 1981, 68(2): 453-463.
19	TOPSØE Nan Yu, Henrik TOPSØE. Characterization of the structures and active sites in sulfided Co-Mo/Al₂O₃ and Ni-Mo/Al₂O₃ catalysts by NO chemisorption[J]. Journal of Catalysis, 1983, 84(2): 386-401.
20	Henrik TOPSØE, CLAUSEN Bjerne S. Importance of Co-Mo-S type structures in hydrodesulfurization[J]. Catalysis Reviews, 1984, 26(3/4): 395-420.
21	DAAGE M, CHIANELLI R. Structure-function relations in molybdenum sulfide catalysts: the “rim-edge” model[J]. Journal of Catalysis, 1994, 149(2): 414-427.
22	王广建, 赵强, 陈国良, 等. 柠檬酸引入方式对CoMo/TiO₂-Al₂O₃催化剂加氢脱硫性能的影响[J]. 工业催化, 2019, 27(7): 54-60.
	WANG Guangjian, ZHAO Qiang, CHEN Guoliang, et al. Effect of citric acid introduction methods on hydrodesulfurization performance of CoMo/TiO₂-Al₂O₃ catalysts[J]. Industrial Catalysis, 2019, 27(7): 54-60.
23	CHEN Jianjun, MI Jinxing, LI Kezhi, et al. The role of citric acid in preparing highly active CoMo/Al₂O₃ catalyst: from aqueous impregnation solution to active site formation[J]. Industrial & Engineering Chemistry Research, 2017, 56(48): 14172-14181.
24	BRAGGIO Flávia A, MELLO Matheus D, MAGALHÃES Bruno C, et al. Effect of pH on activity of NiMo/Al₂O₃ catalysts prepared with citric acid in simultaneous hydrodesulfurization and hydrodenitrogenation reactions[J]. Catalysis Letters, 2017, 147(5): 1104-1113.
25	BADOGA Sandeep, DALAI Ajay K, ADJAYE John, et al. Insights into individual and combined effects of phosphorus and EDTA on performance of NiMo/MesoAl₂O₃ catalyst for hydrotreating of heavy gas oil[J]. Fuel Processing Technology, 2017, 159: 232-246.
26	武瑞明, 张少华, 王晓蔷, 等. Ni-Mo-W非负载型催化剂加氢脱硫性能的改进[J]. 石油化工, 2018, 47(4): 17-23.
	WU Ruiming, ZHANG Shaohua, WANG Xiaoqiang, et al. Improvement of hydrodesulfurization performance of Ni-Mo-W unsupported catalyst[J]. Petrochemical Technology, 2018, 47(04): 17-23.
27	YI Xiaodong, GUO Dongyun, LI Pengyun, et al. One pot synthesis of NiMo-Al₂O₃ catalysts by solvent-free solid-state method for hydrodesulfurization[J]. RSC Advances, 2017, 7: 54468-54474.
28	ZHAO Ruiyu, LU Pingjuan, ZHAO Yuansheng, et al. Effect of phosphorus modification on the acidity, nanostructure of the active phase, and catalytic performance of residue hydrodenitrogenation catalysts[J]. ACS Omega, 2020, 5: 19111-19119.
29	KLIMOV O V, NADEINA K A, VATUTINA Yu V, et al. CoMo/Al₂O₃ hydrotreating catalysts of diesel fuel with improved hydrodenitrogenation activity[J]. Catalysis Today, 2018, 307: 73-83.
30	SOLTANALI Saeed, MASHAYEKHI Maryam, MOHADDECY Seyed Reza Seif. Comprehensive investigation of the effect of adding phosphorus and/or boron to NiMo/γ‍-Al₂O₃ catalyst in diesel fuel hydrotreating[J]. Process Safety and Environmental Protection, 2020, 137: 273-281.
31	HAN Wei, NIE Hong, LONG Xiangyun, et al. Preparation of F-doped MoS₂/Al₂O₃ catalysts as a way to understand the electronic effects of the support Brønsted acidity on HDN activity[J]. Journal of Catalysis, 2016, 339: 135-142.
32	YAO Songdong, ZHENG Ying, DING Lianhui, et al. Co-promotion of fluorine and boron on NiMo/Al₂O₃ for hydrotreating light cycle oil[J]. Catalysis Science & Technology Cambridge, 2012, 2: 1925-1932.
33	CUI Wengang, LI Wenhong, GAO Rong, et al. Hydroprocessing of low-temperature coal tar for the production of clean fuel over fluorinated NiW/Al₂O₃-SiO₂ catalyst[J]. Energy & Fuels, 2017, 31(4): 3768-3783.
34	张轩, 牛梦龙, 潘柳依, 等. F改性NiW/Al₂O₃-SiO₂催化剂煤焦油加氢性能研究[J]. 石油化工, 2018, 47(9): 936-942.
	ZHANG Xuan, NIU Menglong, PAN Liuyi, et al. Hydroprocessing of coal tar on fluorine modification NiW/Al₂O₃-SiO₂ catalysts[J]. Petrochemical Technology, 2018, 47(9): 936-942.
35	DING Lianhui, ZHANG Zisheng, ZHENG Ying, et al. Effect of fluorine and boron modification on the HDS, HDN and HDA activity of hydrotreating catalysts[J]. Applied Catalysis A: General, 2006, 301: 241-250.
36	JOO H S, GUIN James A. Activity of noble metal-promoted hydroprocessing catalysts for pyridine HDN and naphthalene hydrogenation[J]. Fuel Processing Technology, 1996, 49(1): 137-155.
37	INFANTES-MOLINA A, ROMERO-PÉREZ A, FINOCCHIO E, et al. HDS and HDN on SBA-supported RuS₂ catalysts promoted by Pt and Ir[J]. Journal of Catalysis, 2013, 305: 101-117.
38	李矗, 王安杰, 鲁墨弘, 等. 加氢脱氮反应与加氢脱氮催化剂的研究进展[J]. 化工进展, 2003, 22(6): 583.
	LI Chu, WANG Anjie, LU Mohong, et al. Advance in research on hydrodenitrogenation and its catalysts[J]. Chemical Industry and Engineering Progress, 2003, 22(6): 583.
39	CINIBULK J, Vı́T Z. Selective Mo-Ir/Al₂O₃ sulfide catalysts for hydrodenitrogenation[J]. Applied Catalysis A: General, 2000, 204(1): 107-116.
40	EIJSBOUTS Sonja, SUDHAKAR Christopher, BEER de V H J, et al. Hydrodenitrogenation of decahydroquinoline, cyclohexylamine and O-propylaniline over carbon-supported transition metal sulfide catalysts[J]. Journal of Catalysis, 1991, 127(2): 605-618.
41	LEDOUX Marc J, DJELLOULI Brahim. Hydrodenitrogenation activity and selectivity of well-dispersed transition metal sulfides of the second row on activated carbon[J]. Journal of Catalysis, 1989, 115(2): 580-590.
42	SANTEN Rutger A van, NEUROCK Matthew, SHETTY Sharan G. Reactivity theory of transition-metal surfaces: a Brønsted-Evans-Polanyi linear activation energy-free-energy analysis[J]. Chemical Reviews, 2010, 110: 2005-2048.
43	GUO Yang, HE Hao Ran, LIU Xu, et al. Ring-opening and hydrodenitrogenation of indole under hydrothermal conditions over Ni, Pt, Ru, and Ni-Ru bimetallic catalysts[J]. Chemical Engineering Journal, 2021, 406: 126853.
44	LEDESMA Brenda C, ANUNZIATA Oscar A, BELTRAMONE Andrea R. HDN of indole over Ir-modified Ti-SBA-15[J]. Applied Catalysis B: Environmental, 2016, 192(5): 220-233.
45	GUTTIERI Mary J, MAIER Wilhelm F. Selective cleavage of carbon-nitrogen bonds with platinum[J]. The Journal of Organic Chemistry, 1984, 49(16): 2875-2880.
46	PEETERS Elisabeth, CATTENOT Martine, GEANTET Christophe, et al. Hydrodenitrogenation on Pt/silica-alumina catalysts in the presence of H₂S: role of acidity[J]. Catalysis Today, 2008, 133-135: 299-304.
47	JI Yongjun, WU Yuen, ZHAO Guofeng, et al. Porous bimetallic Pt-Fe nanocatalysts for highly efficient hydrogenation of acetone[J]. Nano Research, 2015, 8(8): 2706-2713.
48	ZDENĔK V T, Daniela GULKOVÁ, Luděk KALUŽA, et al. Pd-Pt catalysts on mesoporous SiO₂-Al₂O₃ with superior activity for HDS of 4,6-dimethyldibenzothiophene: effect of metal loading and support composition[J]. Applied Catalysis B: Environmental, 2015, 179: 44-53.
49	焦金庆. 介孔SiO₂负载型催化剂合成及其HDS 催化性能研究[D]. 北京: 中国石油大学, 2018.
	JIAO Jinqing. Synthesis of mesoporous silica-supported catalysts and their HDS catalytic performances[D]. Beijing: China University of Petroleum, 2018.
50	LIU Juan, LI Wenying, FENG Jie, et al. Promotional effect of TiO₂ on quinoline hydrodenitrogenation activity over Pt/γ-Al₂O₃ catalysts[J]. Chemical Engineering Science, 2019, 207: 1085-1095.
51	LIU Juan, LI Wenying, FENG Jie, et al. Molecular insights into the hydrodenitrogenation mechanism of pyridine over Pt/γ-Al₂O₃ catalysts[J]. Molecular Catalysis, 2020, 495: 111148.
52	LIU Juan, LI Wenying, FENG Jie, et al. Effects of Fe species on promoting the dibenzothiophene hydrodesulfurization over the Pt/γ-Al₂O₃ catalysts[J]. Catalysis Today, 2020, 371: 247-257.
53	OLIVIERO Laetitia, TRAVERT Arnaud, GARCIA Dominguez Elizabeth, et al. Catalysis by sulfides: advanced IR/CO spectroscopy for the identification of the most active sites in hydrodesulfurization reactions[J]. Journal of Catalysis, 2021. .
54	TANABE K, SASAKI H, HATTORI H, et al. Activity tests of various catalysts for hydrocracking of coal by means of high-pressure differential thermal analysis[J]. Fuel Processing Technology, 1979, 2(4): 253-259.
55	RALSTON D, GOVEK M, GRAF C, et al. Catalytic activities and selectivities of MoO₃-NiSO₄ supported on various oxides for hydrocracking of solvent refined lignite: novel low surface area active catalysts[J]. Fuel Processing Technology, 1978, 1(2): 143-150.
56	MOCHIDA Isao, OISHI Taiji, KORAI Yozo, et al. Roles of catalyst support in the selective hydrotreatment of a solvent-refined coal[J]. Industrial & Engineering Chemistry Product Research and Development, 1984, 23(2): 203-205.
57	BREYSSE M, PORTEFAIX J L, VRINAT M. Support effects on hydrotreating catalysts[J]. Catalysis Today, 1991, 10(4): 489-505.
58	TANIMU Abdulkadir, ALHOOSHANI Khalid. Advanced hydrodesulfurization catalysts: a review of design and synthesis[J]. Energy & Fuels, 2019, 33(4): 2810-2838.
59	董昆明. 碳纳米管负载/促进Co-Mo-S基HDS/HDN催化剂研究[D]. 厦门: 厦门大学, 2005.
	DONG Kunming. Co-Mo-S catalysts supported/promoted by CNIs for HDS/HDN[D]. Xiamen: Xiamen University, 2005.
60	GUTI RREZ-ALEJANDRE Aída, Jorge RAMÍREZ, Ioscani Jiménez-del VAL, et al. Activity of NiW catalysts supported on TiO₂-Al₂O₃ mixed oxides: effect of Ti incorporation method on the HDS of 4,6-DMDBT[J]. Catalysis Today, 2005, 107/108: 879-884.
61	ZHOU Wenwu, YANG Li, LIU Lang, et al. Synthesis of novel NiMo catalysts supported on highly ordered TiO₂-Al₂O₃ composites and their superior catalytic performance for 4,6-dimethyldibenzothiophene hydrodesulfurization[J]. Applied Catalysis B: Environmental, 2020, 268: 118428.
62	ZHANG Pengfei, MU Fujun, ZHOU Yasong, et al. Synthesis of highly ordered TiO₂-Al₂O₃ and catalytic performance of its supported NiMo for HDS of 4, 6-dimethyldibenzothiophene[J]. Catalysis Today, 2020. .
63	NGUYEN Thanh Tung, IMAI Kazunari, PU Jianglong, et al. Effect of TiO₂ coating on morphology of active phase on sulfided CoMo/Al₂O₃ hydrotreating catalysts[J]. Energy & Fuels, 2018, 32(2): 1665-1673.
64	Jorge RAMÍREZ, RAYO Patricia, Aída GUTIÉRREZ-ALEJANDRE, et al. Analysis of the hydrotreatment of Maya heavy crude with NiMo catalysts supported on TiO₂-Al₂O₃ binary oxides: effect of the incorporation method of Ti[J]. Catalysis Today, 2005, 109(1/2/3/4): 54-60.
65	BORQUE M P, LÓPEZ-AGUDO A, OLGUı́N E, et al. Catalytic activities of Co(Ni)Mo/TiO₂-Al₂O₃ catalysts in gasoil and thiophene HDS and pyridine HDN: effect of the TiO₂-Al₂O₃ composition[J]. Applied Catalysis A: General, 1999, 180(1): 53-61.
66	RODSEANGLUNG Thirada, RATANA Tanakorn, PHONGAKSORN Monrudee, et al. Effect of TiO₂ Incorporated with Al₂O₃ on the hydrodeoxygenation and hydrodenitrogenation CoMo sulfide catalysts[J]. Energy Procedia, 2015, 79: 378-384.
67	黄文斌, 魏强, 周亚松. 均一介孔Al₂O₃劣质蜡油加氢脱氮催化剂研究进展[J]. 化工进展, 2020, 39(S2): 196-203.
	HUANG Wenbin, WEI Qiang, ZHOU Yasong. Research progress of homogeneous mesoporous Al₂O₃ of hydrodenitrogenation catalyst for inferior gas oil[J]. Chemical Industry and Engineering Progress, 2020, 39(S2): 196-203.
68	田静宇, 马时运, 付希, 等. TiSi复合氧化物性质对NiMo基催化剂加氢脱氧性能的影响[J]. 化学反应工程与工艺, 2017, 33(1): 8-14.
	TIAN Jingyu, MA Shiyun, FU Xi, et al. Effect of the properties of TiSi composite oxide on the hydrodeoxygenation performance of the NiMo based catalyst[J]. Chemical Reaction Engineering and Technology, 2017, 33(1): 8-14.
69	石冈, 蔡震, 鲍晓军, 等. Ti-Mg-Al复合氧化物催化材料的制备及其加氢脱硫性能[J]. 石油与天然气化工, 2013, 42(2): 112-118.
	SHI Gang, CAI Zhen, BAO Xiaojun, et al. Preparation and hydrodesulfurization performance of Ti-Mg-Al composite oxides[J]. Chemical Engineering of Oil and Gas, 2013, 42(2): 112-118.
70	HIRSCHON A S, LAINE R M. Bulk ruthenium as an HDN catalyst[J]. Energy & Fuels, 1988, 2(3): 292-295.

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