化工进展 ›› 2021, Vol. 40 ›› Issue (9): 5156-5165.DOI: 10.16085/j.issn.1000-6613.2021-0632
罗志斌1,2(), 龙冉2, 王小博1, 裴爱国1, 熊宇杰2(
)
收稿日期:
2021-03-29
修回日期:
2021-07-04
出版日期:
2021-09-05
发布日期:
2021-09-13
通讯作者:
熊宇杰
作者简介:
罗志斌(1989年—),男,博士,博士后,研究方向为氢能以及二氧化碳利用技术产业化。E-mail:基金资助:
LUO Zhibin1,2(), LONG Ran2, WANG Xiaobo1, PEI Aiguo1, XIONG Yujie2(
)
Received:
2021-03-29
Revised:
2021-07-04
Online:
2021-09-05
Published:
2021-09-13
Contact:
XIONG Yujie
摘要:
利用太阳光驱动二氧化碳(CO2)催化转化合成燃料是缓解能源危机和降低温室效应的理想途径。然而,当前面临的主要挑战在于CO2固有的化学稳定性使得光催化反应的转化效率低下。热量被认为是促进催化转化反应过程的重要推动力,可以有效提升光催化转化的效率。本文综述了不同形式的热增强光催化在CO2还原生产燃料方面的应用,包括外加热源的光催化CO2还原、光热效应促进的光催化CO2还原以及等离激元增强的光催化CO2还原体系。文章指出:热增强的光催化技术继承了光催化的高选择性和热催化的高反应活性的优势,实现了CO2还原反应的高效进行。具体分析如下:外加热源主要通过直接加热装置或者聚焦太阳光能实现,产物的生成效率明显增强,选择性影响不大;光热效应发挥着局部提高催化剂反应温度的作用,使能量利用效率更高,大幅度降低CO2还原反应所需的能量;等离激元效应除了发挥光热效应的作用,同时兼备增强光吸收、促进载流子分离和加速表面反应动力学的作用。文章最后指出,通过对反应机理进行深度研究,合理调控反应体系的反应条件,将极大促进热增强的光催化CO2还原技术发展,为CO2利用提供有效手段。
中图分类号:
罗志斌, 龙冉, 王小博, 裴爱国, 熊宇杰. 热增强的光催化二氧化碳还原技术[J]. 化工进展, 2021, 40(9): 5156-5165.
LUO Zhibin, LONG Ran, WANG Xiaobo, PEI Aiguo, XIONG Yujie. Thermal-enhanced photocatalytic carbon dioxide reduction[J]. Chemical Industry and Engineering Progress, 2021, 40(9): 5156-5165.
催化材料 | 反应物 | 产物 | 能量来源 | 催化性能 | 参考文献 |
---|---|---|---|---|---|
AuCu/g-C3N4 | CO2 | CH3CH2OH | 300W氙灯(λ>420nm)+外热120℃ | 产率为0.89mmol · g | [ |
Bi4TaO8Cl/W18O49异质结 | CO2 | CO | 模拟光源20mW · cm-2+外热120℃ | 产率为23.42μmol · g | [ |
Pt/TiO2-x | CO2 | CH4 | 模拟光源AM 1.5G+外热120℃ | 产率为0.3412μmol · g | [ |
In2O3-x(OH)y | CO2+H2 | CO | 聚焦氙灯光源约20kW · m-2 | 产率为22.0μmol · g | [ |
VIII族金属纳米颗粒 | CO2 | CH4 | 300W氙灯光源 | 相对于光催化方法,光热催化CO2还原产率级别提升了几个数量级,从μmol · g | [ |
B纳米颗粒 | CO2 | CO、CH4 | 300W氙灯光源 | CO和CH4的产率分别为1.0μmol · g | [ |
TiO2光子晶体 | CO2 | CH4 | 300W氙灯光源 | CH4产率达到35.0μmol · h-1 · m-2,分别达到商用P25和TiO2纳米管的15.9倍和4.7倍 | [ |
Ni/CexTiyO2 | CO2+H2 | CH4 | 300W氙灯光源 | CH4产率达到17.0mmol · g | [ |
TiO2-石墨烯 复合材料 | CO2 | CO、CH4 | 300W氙灯光源 4.38kW · m-2 | CO的产率达到了5.2μmol · g-1cat · h-1,CH4的产率达到了26.7μmol · g | [ |
Pd-TiO2 | CO2 | CO | 500W汞灯光源 | CO产率11.05μmol · g | [ |
Ni-CeO2/SiO2复合材料 | CO2+CH4 | H2、CO | 500W氙灯光源 | H2和CO的产率分别达到了33.42mmol · min-1 · g-1cat和41.53mmol · min-1 · g | [ |
MoO3-x | CO2 | CO、CH4 | 模拟太阳光能 | CO产率达到10.3μmol · g | [ |
表1 热增强光催化CO2还原技术的代表性研究工作
催化材料 | 反应物 | 产物 | 能量来源 | 催化性能 | 参考文献 |
---|---|---|---|---|---|
AuCu/g-C3N4 | CO2 | CH3CH2OH | 300W氙灯(λ>420nm)+外热120℃ | 产率为0.89mmol · g | [ |
Bi4TaO8Cl/W18O49异质结 | CO2 | CO | 模拟光源20mW · cm-2+外热120℃ | 产率为23.42μmol · g | [ |
Pt/TiO2-x | CO2 | CH4 | 模拟光源AM 1.5G+外热120℃ | 产率为0.3412μmol · g | [ |
In2O3-x(OH)y | CO2+H2 | CO | 聚焦氙灯光源约20kW · m-2 | 产率为22.0μmol · g | [ |
VIII族金属纳米颗粒 | CO2 | CH4 | 300W氙灯光源 | 相对于光催化方法,光热催化CO2还原产率级别提升了几个数量级,从μmol · g | [ |
B纳米颗粒 | CO2 | CO、CH4 | 300W氙灯光源 | CO和CH4的产率分别为1.0μmol · g | [ |
TiO2光子晶体 | CO2 | CH4 | 300W氙灯光源 | CH4产率达到35.0μmol · h-1 · m-2,分别达到商用P25和TiO2纳米管的15.9倍和4.7倍 | [ |
Ni/CexTiyO2 | CO2+H2 | CH4 | 300W氙灯光源 | CH4产率达到17.0mmol · g | [ |
TiO2-石墨烯 复合材料 | CO2 | CO、CH4 | 300W氙灯光源 4.38kW · m-2 | CO的产率达到了5.2μmol · g-1cat · h-1,CH4的产率达到了26.7μmol · g | [ |
Pd-TiO2 | CO2 | CO | 500W汞灯光源 | CO产率11.05μmol · g | [ |
Ni-CeO2/SiO2复合材料 | CO2+CH4 | H2、CO | 500W氙灯光源 | H2和CO的产率分别达到了33.42mmol · min-1 · g-1cat和41.53mmol · min-1 · g | [ |
MoO3-x | CO2 | CO、CH4 | 模拟太阳光能 | CO产率达到10.3μmol · g | [ |
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