火焰合成法制备TiO2的燃烧发生器研究进展

doi:10.16085/j.issn.1000-6613.2021-0232

摘要/Abstract

摘要：

火焰合成法是指前驱物在燃烧器中经过一系列复杂的物理化学反应过程得到产物纳米颗粒的方法，具有一步合成的优点，是现代工业规模化制备高性能材料的一种重要方法。火焰合成过程机理涉及物质的相态变化、颗粒生长团聚和热量质量交换等复杂过程，探究火焰合成过程是实现产物颗粒调控的关键。本文对火焰合成过程中的关键部分，如前驱物、为合成过程提供高温氧化环境的燃烧器、产物颗粒等进行分析，阐述了火焰气溶胶技术中颗粒的生长及转变路径、不同燃烧器的结构及其温度场、流场特点，并分析了不同燃烧器合成的纳米TiO₂进行了粒径及晶型特点的研究进展。指出火焰合成TiO₂生长机理和形态调控的基础研究对工业制备钛白粉具有指导意义。

关键词: 火焰合成, 纳米材料, 二氧化钛, 燃烧器

Abstract:

Flame synthesis refers to the reaction of precursors in burners to obtain nanoparticle products after combustion with a series of complex physical processes and chemical reactions which involve phase changes, particle growth, heat transfer and mass transfer. It has the advantage of one-step production and is an important modern industrial scale approach for preparing high performance materials. Exploring the flame synthesis process is the key to achieve particle product modulation, therefore, this work analyzed the key parts of the process, such as the precursors, burners, particles, etc. In line with these, the growth and transformation of particles, the structure of different burners, and the characteristics of temperature field and flow field were described. The characteristics of particle size and crystal form of TiO₂ nanoparticles synthesized by different burners were analyzed. The basic research on the growth mechanism and morphology regulation of particles from the flame synthesis was of guiding significance for the industrial preparation of TiO₂ particles.

Key words: flame synthesis, nanomaterials, titanium dioxide, burner

中图分类号:

TQ038.7

孙通, 许东东, 宋民航, 靳星, 黄云. 火焰合成法制备TiO₂的燃烧发生器研究进展[J]. 化工进展, 2022, 41(1): 17-29.

SUN Tong, XU Dongdong, SONG Minhang, JIN Xing, HUANG Yun. Research progress of the burners in synthesis of TiO₂ by combustion method[J]. Chemical Industry and Engineering Progress, 2022, 41(1): 17-29.

图/表 2

参考文献 83

1	LI S Q, REN Y H, BISWAS P, et al. Flame aerosol synthesis of nanostructured materials and functional devices: processing, modeling, and diagnostics[J]. Progress in Energy and Combustion Science, 2016, 55: 1-59.
2	陈信华. 颜料的物理形态对塑料着色性能影响[J]. 塑料助剂, 2019(3): 1-5, 32.
	CHEN X H. Impact of the physical forms of pigments on the application performance of plastic coloring[J]. Plastics Additives, 2019(3): 1-5, 32.
3	董如林, 莫剑臣, 张汉平, 等. 二氧化钛/氧化石墨烯复合光催化剂的合成[J]. 化工进展, 2014, 33(3): 679-684.
	DONG R L, MO J C, ZHANG H P, et al. Synthesis of the titania/graphene oxide composite photocatalyst[J]. Chemical Industry and Engineering Progress, 2014, 33(3): 679-684.
4	孙家伟, 刘娜, 翟尚儒, 等. 纳米TiO₂/ZSM-5型催化剂的制备及其光催化应用研究进展[J]. 化工进展, 2014, 33(1): 85-91, 123.
	SUN J W, LIU N, ZHAI S R, et al. Progress in the preparation of nanoTiO₂/ZSM-5 and its photocatalytic applications[J]. Chemical Industry and Engineering Progress, 2014, 33(1): 85-91, 123.
5	黄俊, 李荣兴, 田林, 等. 氯化法钛白生产工艺中四氯化钛氧化微观反应机理研究进展[J]. 化工进展, 2018, 37(3): 1054-1061.
	HUANG J, LI R X, TIAN L, et al. Research progress of oxidation mechanism in the chloride process for titanium dioxide production[J]. Chemical Industry and Engineering Progress, 2018, 37(3): 1054-1061.
6	FRIEDLANDER S K, PUI D Y H. Emerging issues in nanoparticle aerosol science and technology[J]. Journal of Nanoparticle Research, 2004, 6(2): 313-320.
7	HAWA T, ZACHARIAH M R. Molecular dynamics study of particle-particle collisions between hydrogen-passivated silicon nanoparticles[J]. Physical Review B, 2004, 69(3): 035417.
8	ROTH P. Particle synthesis in flames[J]. Proceedings of the Combustion Institute, 2007, 31(2): 1773-1788.
9	ZHANG Y Y, XIONG G, LI S Q, et al. Novel low-intensity phase-selective laser-induced breakdown spectroscopy of TiO₂ nanoparticle aerosols during flame synthesis[J]. Combustion and Flame, 2013, 160(3): 725-733.
10	REN Y H, CAI J Z, PITSCH H. Theoretical single-droplet model for particle formation in flame spray pyrolysis[J]. Energy & Fuels, 2021, 35(2): 1750-1759.
11	JOSSEN R, PRATSINIS S E, STARK W J, et al. Criteria for flame-spray synthesis of hollow, shell-like, or inhomogeneous oxides[J]. Journal of the American Ceramic Society, 2005, 88(6): 1388-1393.
12	SOKOLOWSKI M, SOKOLOWSKA A, MICHALSKI A, et al. The “in-flame-reaction” method for Al₂O₃ aerosol formation[J]. Journal of Aerosol Science, 1977, 8(4): 219-230.
13	ROSEBROCK C D, RIEFLER N, WRIEDT T, et al. Disruptive burning of precursor/solvent droplets in flame-spray synthesis of nanoparticles[J]. AIChE Journal, 2013, 59(12): 4553-4566.
14	ROSEBROCK C D, WRIEDT T, MÄDLER L, et al. The role of microexplosions in flame spray synthesis for homogeneous nanopowders from low-cost metal precursors[J]. AIChE Journal, 2016, 62(2): 381-391.
15	REN Y, LI S, ZHANG Y, et al. Absorption-ablation-excitation mechanism of laser-cluster interactions in a nanoaerosol system[J]. Physical Review Letters, 2015, 114(9): 093401.
16	ZHANG Y Y, WANG Z H, WU X X, et al. In situ laser diagnostics of nanoparticle transport across stagnation plane in a counterflow flame[J]. Journal of Aerosol Science, 2017, 105: 145-150.
17	WEI J L, LI S Q, REN Y H, et al. Investigating the role of solvent formulations in temperature-controlled liquid-fed aerosol flame synthesis of YAG-based nanoparticles[J]. Proceedings of the Combustion Institute, 2019, 37(1): 1193-1201.
18	REN Y H, ZHANG Y Y, LI S Q. Simultaneous single-shot two-dimensional imaging of nanoparticles and radicals in turbulent reactive flows[J]. Physical Review Applied, 2020, 13(4): 044002.
19	CAILLAT R, CUER J P, ELSTON J, et al. Preparation doxydes homodisperses dans la flamme hydrogene-oxygene et quelques proprietes de ces composes[J]. Bulletin de la Societe Chimique de France, 1959 (1): 152-156.
20	FORMENTI M, JUILLET F, MERIAUDEAU P, et al. Preparation in a hydrogen-oxygen flame of ultrafine metal oxide particles. Oxidative properties toward hydrocarbons in the presence of ultraviolet radiation[J]. Journal of Colloid and Interface Science, 1972, 39(1): 79-89.
21	王宝璐, 额日其太. 甲烷反扩散火焰光谱特性实验研究[J]. 推进技术, 2016, 37(1): 105-111.
	WANG Baolu, ERIQITAI. Experiment study of inverse methane/air diffusion flame emission spectrum properties[J]. Journal of Propulsion Technology, 2016, 37(1): 105-111.
22	XIE F, ZHOU Y, SONG X D, et al. Investigation of OH* chemiluminescence with lift-off characteristic in methane-oxygen inverse diffusion flame[J]. International Journal of Hydrogen Energy, 2021, 46(2): 1461-1472.
23	XU Y T, DAI Z H, LI C, et al. Numerical simulation of natural gas non-catalytic partial oxidation reformer[J]. International Journal of Hydrogen Energy, 2014, 39(17): 9149-9157.
24	STELZNER B, HUNGER F, VOSS S, et al. Experimental and numerical study of rich inverse diffusion flame structure[J]. Proceedings of the Combustion Institute, 2013, 34(1): 1045-1055.
25	程易, 陈家琦, 丁石. 高温气相法可控制备纳米TiO₂[J]. 化工学报, 2007, 58(8): 2103-2109.
	CHENG Y, CHEN J Q, DING S. Controlled synthesis of nano-sized TiO₂ powders using high-temperature vapor phase process[J]. Journal of Chemical Industry and Engineering (China), 2007, 58(8): 2103-2109.
26	RESENDE P R, AYOOBI M, AFONSO A M. Numerical investigations of micro-scale diffusion combustion: a brief review[J]. Applied Sciences, 2019, 9(16): 3356.
27	XIANG Y, YUAN Z L, WANG S X, et al. Effects of flow rate and fuel/air ratio on propagation behaviors of diffusion H₂/air flames in a micro-combustor[J]. Energy, 2019, 179: 315-322.
28	SUNSAP P, KIM D J, CHARINPANITKUL T, et al. Analysis of preparation of TiO₂ particles by diffusion flame reactor for photodegradation of phenol and toluene[J]. Research on Chemical Intermediates, 2008, 34(4): 319-329.
29	ULRICH G D, MILNES B A, SUBRAMANIAN N S. Particle growth in flames. Ⅱ: Experimental results for silica particles[J]. Combustion Science and Technology, 1976, 14(4/5/6): 243-249.
30	ULRICH G D. Flame synthesis of fine particles[J]. Chemical & Engineering News, 1984, 62: 22-29.
31	EHRMAN S H, FRIEDLANDER S K, ZACHARIAH M R. Characteristics of SiO₂/TiO₂ nanocomposite particles formed in a premixed flat flame[J]. Journal of Aerosol Science, 1998, 29(5/6): 687-706.
32	ZHANG M, WANG J H, XIE Y L, et al. Measurement on instantaneous flame front structure of turbulent premixed CH₄/H₂/air flames[J]. Experimental Thermal and Fluid Science, 2014, 52: 288-296.
33	JIN W, WANG J H, NIE Y H, et al. Experimental study on flame instabilities of laminar premixed CH₄/H₂/air non-adiabatic flat flames[J]. Fuel, 2015, 159: 599-606.
34	JIN W, WANG J H, YU S B, et al. Cellular instabilities of non-adiabatic laminar flat methane/hydrogen oxy-fuel flames highly diluted with CO₂[J]. Fuel, 2015, 143: 38-46.
35	JIANG L Q, GU C, ZHOU G Z, et al. Cellular instabilities of n-butane/air flat flames probing by PLIF-OH and PLIF-CH₂O laser diagnosis[J]. Experimental Thermal and Fluid Science, 2020, 118: 110155.
36	ARABI-KATBI O I, PRATSINIS S E, MORRISON P W, et al. Monitoring the flame synthesis of TiO₂ particles by in situ FTIR spectroscopy and thermophoretic sampling[J]. Combustion and Flame, 2001, 124(4): 560-572.
37	KAMMLER H K, PRATSINIS S E, MORRISON P W, et al. Flame temperature measurements during electrically assisted aerosol synthesis of nanoparticles[J]. Combustion and Flame, 2002, 128(4): 369-381.
38	WOOLDRIDGE M S, TOREK P V, DONOVAN M T, et al. An experimental investigation of gas-phase combustion synthesis of SiO₂ nanoparticles using a multi-element diffusion flame burner[J]. Combustion and Flame, 2002, 131(1/2): 98-109.
39	FENG D, GOLDBERG B M, SHNEIDER M N, et al. Optimization of filtered Rayleigh scattering for the measurement of pressure and temperature[J]. Combustion Science and Technology, 2020. DOI: 10.1080/00102202.2020.1822345.
40	QI S, WANG Z H, COSTA M, et al. Ignition and combustion of single pulverized biomass and coal particles in N₂/O₂ and CO₂/O₂ environments[J]. Fuel, 2021, 283: 118956.
41	HUANG Q, MA P, GAO Q, et al. Ultrafine particle formation in pulverized coal, biomass, and waste combustion: understanding the relationship with flame synthesis process[J]. Energy & Fuels, 2020, 34(2): 1386-1395.
42	MA P, HUANG Q, GAO Q, et al. Effects of Na and Fe on the formation of coal-derived soot in a two-stage flat-flame burner[J]. Fuel, 2020, 265: 116914.
43	CHUNG S L, KATZ J L. The counterflow diffusion flame burner: a new tool for the study of the nucleation of refractory compounds[J]. Combustion and Flame, 1985, 61(3): 271-284.
44	HUNG C H, KATZ J L. Formation of mixed oxide powders in flames: Part Ⅰ. TiO₂-SiO₂[J]. Journal of Materials Research, 1992, 7(7): 1861-1869.
45	HUNG C H, MIQUEL P F, KATZ J L. Formation of mixed oxide powders in flames: Part Ⅱ. SiO₂-GeO₂ and Al₂O₃-TiO₂[J]. Journal of Materials Research, 1992, 7(7): 1870-1875.
46	LIANG M Q, HE Y T, LIAO S Y, et al. Coupling effects of hydrogen transport and reactivity on NO production in laminar nonpremixed methane/air flames[J]. Fuel, 2021, 288: 119725.
47	SKANDAN G, CHEN Y J, GLUMAC N, et al. Synthesis of oxide nanoparticles in low pressure flames[J]. Nanostructured Materials, 1999, 11(2): 149-158.
48	FENG L, WANG Q L, LIU H F, et al. Effect of the stagnation plate on PAHs, soot and OH distributions in partially premixed laminar flames fueled with a blend of n-heptane and toluene[J]. Combustion and Flame, 2021, 227: 52-64.
49	SAITO K, YI E, LAINE R M, et al. Preparation of Nb-doped TiO₂ nanopowder by liquid-feed spray pyrolysis followed by ammonia annealing for tunable visible-light absorption and inhibition of photocatalytic activity[J]. Ceramics International, 2020, 46(2): 1314-1322.
50	GRÖHN A J, PRATSINIS S E, SÁNCHEZ-FERRER A, et al. Scale-up of nanoparticle synthesis by flame spray pyrolysis: the high-temperature particle residence time[J]. Industrial & Engineering Chemistry Research, 2014, 53(26): 10734-10742.
51	DE IULIIS S, MIGLIORINI F, DONDÈ R. Laser-induced emission of TiO₂ nanoparticles in flame spray synthesis[J]. Applied Physics B, 2019, 125(11): 1-11.
52	DE IULIIS S, DONDÈ R, ALTMAN I. On thermal regime of nanoparticles in synthesis flame[J]. Chemical Physics Letters, 2021, 769: 138424.
53	LIANG Y J, KU K, LIN Y L, et al. Process engineering to increase the layered phase concentration in the immediate products of flame spray pyrolysis[J]. ACS Applied Materials & Interfaces, 2021, 13(23): 26915-26923.
54	TEOH W Y, AMAL R, MÄDLER L. Flame spray pyrolysis: an enabling technology for nanoparticles design and fabrication[J]. Nanoscale, 2010, 2(8): 1324.
55	SCHAEFER D,WIEGAND A, ALFF H, et al. Producing mixed oxide comprising lithium, zirconium and other than lithium and zirconium metal by means of flame spray pyrolysis, solution of metal precursors, comprises lithium carboxylate and/or zirconium carboxylate: WO2021048249-A1[P]. 2021-03-08.
56	SCHAEFER D, WIEGAND A, ALFF H,et al. Producing lithium zirconium mixed oxide as e.g., coating or doping material for electrodes of lithium batteries by flame spray pyrolysis and optional further thermal treatment using solution of metal precursors comprising metal carboxylate: WO2021048251-A1[P]. 2021-03-18.
57	SUEMATSU R, MISAKI N, YAMAZAKI H, et al. Producing inorganic oxide particles, involves spraying mist from nozzle in internal combustion type spray pyrolysis apparatus equipped with nozzle, and thermally decomposing mist: JP2020142949-A[P]. 2020-09-10.
58	ZHU W H, PRATSINIS S E. Flame synthesis of nanosize powders - effect of flame configuration and oxidant composition [M]//ZHU W H, PRATSINIS S E. Nanotechnology: Molecularly designed materials. Washington: American Chemical Society, 1996: 64-78.
59	WEGNER K, PRATSINIS S E. Nozzle-quenching process for controlled flame synthesis of titania nanoparticles[J]. AIChE Journal, 2003, 49(7): 1667-1675.
60	YANG G X, BISWAS P. Study of the sintering of nanosized titania agglomerates in flames using in situ light scattering measurements[J]. Aerosol Science and Technology, 1997, 27(4): 507-521.
61	MA H K,YANG H A. A comparative study of TiO₂ nanoparticles synthesized in premixed and diffusion flames[J]. Journal of Thermal Science, 2010, 19(6): 567-575.
62	MEMON N K, ANJUM D H, CHUNG S H. Multiple-diffusion flame synthesis of pure anatase and carbon-coated titanium dioxide nanoparticles[J]. Combustion and Flame, 2013, 160(9): 1848-1856.
63	RULISON A J, MIQUEL P F, KATZ J L. Titania and silica powders produced in a counterflow diffusion flame[J]. Journal of Materials Research, 1996, 11(12): 3083-3089.
64	GLUMAC N G, CHEN Y J, SKANDAN G. Diagnostics and modeling of nanopowder synthesis in low pressure flames[J]. Journal of Materials Research, 1998, 13(9): 2572-2579.
65	符春林, 魏锡文. 二氧化钛晶型转变研究进展[J]. 材料导报, 1999, 13(3): 37-38, 47.
	FU C L, WEI X W. Recent advances in the crystalline phase transition of titania[J]. Materials Review, 1999, 13(3): 37-38, 47.
66	王若泽, 杨振, 龙翔, 等. X射线衍射仪和X荧光光谱仪在钛白粉分析中的应用[J]. 中国涂料, 2017, 32(7): 63-66.
	WANG R Z, YANG Z, LONG X, et al. Application of X-ray diffractometer and X-ray fluorescence spectrometer in titanium dioxide analysis[J]. China Coatings, 2017, 32(7): 63-66.
67	施利毅, 李春忠, 朱以华, 等. TiCl₄高温气相氧化合成纳米二氧化钛颗粒的研究Ⅰ. 颗粒粒度控制[J]. 功能材料, 2000, 31(6): 622-624.
	SHI L Y, LI C Z, ZHU Y H, et al. Study on the nanosized TiO₂ particles synthesized by TiCl₄ high temperature gas phase oxidation Ⅰ. Particles size controlling[J]. Journal of Functional Materials, 2000, 31(6): 622-624.
68	施利毅, 李春忠, 陈爱平, 等. TiCl₄高温气相氧化合成纳米二氧化钛颗粒的研究Ⅱ.颗粒晶型结构控制[J]. 功能材料, 2000, 31(6): 625-627.
	SHI L Y, LI C Z, CHEN A P, et al. Study on the nanosized TiO₂ particles synthesized by TiCl₄ high temperature gas phase oxidation Ⅱ. Crystal structure controlling[J]. Journal of Functional Materials, 2000, 31(6): 625-627.
69	戚蓉. 氯化法钛白粉的粒径与粒径分布[J]. 现代涂料与涂装, 2007, 10(5): 44-46, 50.
	QI R. Particle size and distribution of titanium dioxide produced by chloride procedure[J]. Modern Paint & Finishing, 2007, 10(5): 44-46, 50
70	王亚锋, 李俊峰, 张兵兵. TiCl₄气相氧化制备TiO₂颗粒的粒径控制研究[J]. 河南科学, 2016, 34(5): 662-666.
	WANG Y F, LI J F, ZHANG B B. Size control of TiO₂ particle produced by gas-phase oxidation of titanium tetrachloride[J]. Henan Science, 2016, 34(5): 662-666.
71	MAHENDER C, MURALI B, VENKATESHWARARAO M, et al. Synthesis of titanium nanorods with LPG as fuel and oxygen as oxidant in diffusion flame reactor[J]. Journal of Industrial and Engineering Chemistry, 2012, 18(6): 1884-1887.
72	ALMQUIST C B, BISWAS P. Role of synthesis method and particle size of nanostructured TiO₂ on its photoactivity[J]. Journal of Catalysis, 2002, 212(2): 145-156.
73	BICKMORE C R, WALDNER K F, TREADWELL D R, et al. Ultrafine spinel powders by flame spray pyrolysis of a magnesium aluminum double alkoxide[J]. Journal of the American Ceramic Society, 1996, 79(5): 1419-1423.
74	BICKMORE C R, WALDNER K F, BARANWAL R, et al. Ultrafine titania by flame spray pyrolysis of a titanatrane complex[J]. Journal of the European Ceramic Society, 1998, 18(4): 287-297.
75	KHO Y K, TEOH W Y, MÄDLER L, et al. Dopant-free, polymorphic design of TiO₂ nanocrystals by flame aerosol synthesis[J]. Chemical Engineering Science, 2011, 66(11): 2409-2416.
76	JIANG Y J, SCOTT J, AMAL R. Exploring the relationship between surface structure and photocatalytic activity of flame-made TiO₂-based catalysts[J]. Applied Catalysis B: Environmental, 2012, 126: 290-297.
77	BETTINI L G, DOZZI M V, FOGLIA F D, et al. Mixed-phase nanocrystalline TiO₂ photocatalysts produced by flame spray pyrolysis[J]. Applied Catalysis B: Environmental, 2015, 178: 226-232.
78	MAHENDER C, MURALI B. Synthesis of nano phase titanium dioxide (TiO₂) in diffusion flame reactor and it application in photocatalytic reaction[J]. Journal of Engineering Research and Applications, 2014, 4(2): 209-213.
79	DHAND V, PRASAD J, RAO M V, et al. Design and development of flame reactor unit for carbon nanorods (CNRs) production[J]. Indian Journal of Engineering and Materials Sciences, 2007, 14(3): 235-239.
80	ZHANG H Z, BANFIELD J F. Thermodynamic analysis of phase stability of nanocrystalline titania[J]. Journal of Materials Chemistry, 1998, 8(9): 2073-2076.
81	MEMARZADEH S, TOLMACHOFF E D, PHARES D J, et al. Properties of nanocrystalline TiO₂ synthesized in premixed flames stabilized on a rotating surface[J]. Proceedings of the Combustion Institute, 2011, 33(2): 1917-1924.
82	胡悦, 谭建国, 吕良. 甲烷-空气预混火焰中化学发光定量化测量放热率的实验研究[J]. 推进技术, 2019, 40(5): 1083-1092.
	HU Y, TAN J G, LYU L. Experimental investigation of heat release rate quantitative measurement using chemiluminescence in premixed methane-air flames[J]. Journal of Propulsion Technology, 2019, 40(5): 1083-1092.
83	张浪, 谭建国, 刘瑶. 甲烷/空气同轴射流火焰反应热与OH^/CH^定量表征特性研究[J]. 光谱学与光谱分析, 2020, 40(6): 1703-1709.
	ZHANG L, TAN J G,LIU Y. Methane/air coaxial jet flame reaction heat and quantitative characterization of OH^/CH^[J]. Spectroscopy and Spectral Analysis, 2020, 40(6): 1703-1709.

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火焰合成法制备TiO₂的燃烧发生器研究进展

Research progress of the burners in synthesis of TiO₂ by combustion method

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