改性镧系钙钛矿催化剂强化挥发性有机物催化氧化的研究进展

doi:10.16085/j.issn.1000-6613.2020-0818

摘要/Abstract

摘要：

钙钛矿因其结构稳定并具有优异的物化性质，近年来在催化剂方面的应用受到了广泛关注。本文综述了采用不同方法对镧系钙钛矿进行改性来增强催化剂的活性、抗毒性、稳定性和选择性的研究进展；分析了镧系钙钛矿的结构、表面参数、活性氧和低温还原性对于挥发性有机物转化效率的影响，重点阐述了通过优选钙钛矿的制备方法、制备负载型钙钛矿和掺杂型钙钛矿等改性方法来提高镧系钙钛矿催化剂的性能，由此展望了未来改性镧系钙钛矿催化剂的研究方向：采用非金属元素掺杂或多种强化方法结合制备高效催化剂、利用催化燃烧协同光催化氧化转化挥发性有机物、进一步通过实验和仿真模拟制备理想钙钛矿催化剂催化氧化多种挥发性有机物混合物以满足工业化需求。

关键词: 钙钛矿, 镧系催化剂, 催化氧化, 活性, 挥发性有机物

Abstract:

The application of perovskite in catalysts has received extensive attention, due to its stable structure and special physical and chemical properties. In this paper, the research progress in strengthening the activity, anti-toxicity, stability and selectivity of La-based perovskite catalysts with different methods is reviewed. The effects of the structure, surface parameters, active oxygen and low-temperature reducibility of La-based perovskite catalysts on the conversion efficiency of volatile organic compounds were analyzed. The optimization of the perovskite synthesis, and the preparation of supported perovskite and doped perovskite to improve the performance of the La-based perovskite catalyst are also introduced. And the future research directions of the La-based perovskite catalysts are prospected, which are to prepare efficient catalysts by doping non-metal elements and combining multiple methods, to integrate catalytic combustion and photocatalytic oxidation for volatile organic compounds conversion, and to further use experiments and simulations in seeking the ideal catalyst for the catalytic oxidation of volatile organic compound mixtures to meet industrial needs.

Key words: perovskite, Lanthanum-based catalyst, catalytic oxidation, activity, volatile organic compounds

中图分类号:

X511

张巍, 汤云灏, 尹艳山, 龚蔚成, 宋健, 马英, 阮敏, 徐慧芳, 陈冬林. 改性镧系钙钛矿催化剂强化挥发性有机物催化氧化的研究进展[J]. 化工进展, 2021, 40(3): 1425-1437.

ZHANG Wei, TANG Yunhao, YIN Yanshan, GONG Weicheng, SONG Jian, MA Ying, RUAN Min, XU Huifang, CHEN Donglin. Research progress in enhanced catalytic oxidation of VOCs by modified La-based perovskite catalyst[J]. Chemical Industry and Engineering Progress, 2021, 40(3): 1425-1437.

图/表 5

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模板	模板比表面积/m²?g^-1	催化剂	催化剂比表面积/m²?g^-1	平均孔径/nm	孔体积/cm³?g^-1	参考文献
KIT-6	948	LaMnO₃	155	4.8	0.2	[18]
KIT-6	948	LaCoO₃	125	4.8	0.1	[18]
KIT-6	789	LaFeO₃	138	4.2	0.196	[19]
SBA-15	710.9	LaMnO₃	119.6	7.7	0.33	[20]
SBA-15	710.9	LaFeO₃	92.25	4.9	0.33	[20]
二氧化硅纳米球	192	LaFeO₃	65	5.6	0.116	[19]

模板	模板比表面积/m²?g^-1	催化剂	催化剂比表面积/m²?g^-1	平均孔径/nm	孔体积/cm³?g^-1	参考文献
KIT-6	948	LaMnO₃	155	4.8	0.2	[18]
KIT-6	948	LaCoO₃	125	4.8	0.1	[18]
KIT-6	789	LaFeO₃	138	4.2	0.196	[19]
SBA-15	710.9	LaMnO₃	119.6	7.7	0.33	[20]
SBA-15	710.9	LaFeO₃	92.25	4.9	0.33	[20]
二氧化硅纳米球	192	LaFeO₃	65	5.6	0.116	[19]

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