锂-二氧化碳电池阴极催化剂的研究进展

doi:10.16085/j.issn.1000-6613.2019-1767

摘要/Abstract

摘要：

锂-二氧化碳电池通过捕获、转化二氧化碳为储能物质，既可以减少二氧化碳排放量又可以作为创新的储能装置，引起了研究者们的广泛关注。本文简单介绍了锂-二氧化碳电池的工作机理、发展历程和目前研究存在的难题，通过对研究工作的总结、电池性能的对比，将不同类型的催化剂进行了系统的分类和简单的概括，综述了催化剂的设计理念和研究现状，提出了催化剂目前存在的难题与挑战，并展望了催化剂未来的发展方向。本文主要针对锂-二氧化碳电池阴极催化剂的最新研究进展进行了详细的阐述，指出高效的阴极催化剂是促进锂-二氧化碳电池电化学反应动力学、降低充电平台和过电势的关键所在。

关键词: 锂-二氧化碳电池, 空气电极, 催化剂, 纳米材料, 电化学

Abstract:

Due to the ability of capturing and converting carbon dioxide into energy storage materials, Li-CO₂ battery can not only reduce carbon dioxide emission, but also serve as an innovative energy storage device, so it has attracted extensive attentions from researchers. In this review, the working mechanism, development history and existing problems of Li-CO₂ battery were briefly introduced. Based on the summary of the current research works and the performance comparison of various batteries, different types of catalysts were systematically classified and briefly summarized, the design concept and research status of the cathode catalysts were reviewed, the problems and challenges for these catalysts were proposed, and the future research directions of cathode catalysts for Li-CO₂ batteries were also presented. It was indicated that high-performance cathode catalysts is the key factor to promote the electrochemical reaction kinetics, and reduce the charge platform and overpotential of Li-CO₂ battery.

Key words: Li-CO₂ batteries, air electrode, catalyst, nanomaterials, electrochemistry

中图分类号:

TQ152

王朕, 吴刚, 董鹏, 张英杰, 曾晓苑. 锂-二氧化碳电池阴极催化剂的研究进展[J]. 化工进展, 2020, 39(9): 3677-3684.

Zhen WANG, Gang WU, Peng DONG, Yingjie ZHANG, Xiaoyuan ZENG. Research progress of cathode catalysts for Li-CO₂batteries[J]. Chemical Industry and Engineering Progress, 2020, 39(9): 3677-3684.

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