SnO2-C复合负极材料的维度设计用于锂、钠离子电池

doi:10.16085/j.issn.1000-6613.2019-1536

摘要/Abstract

摘要：

新能源汽车的高速发展，对电池材料的能量密度提出了更高的要求。SnO₂-C复合材料因比容量高、倍率性能好、资源丰富、价格低廉等优点而被视为下一代锂、钠离子电池最有潜力的负极材料之一。基于SnO₂-C复合材料的尺寸变化和尺寸复合方式，本文对SnO₂-C复合材料进行了分类，并且详细综述了SnO₂-C复合材料的最新代表性进展，重点涉及尺寸设计公式以及由此产生的协同效应和提高性能的潜力。最后，讨论了该领域未来的发展方向和前景，鉴于协同效应的优良体现，以后该研究将偏于多重复合方向，同时会探索出简单、环保、廉价的合成工艺，不断向商品化的方向靠近。其概念和策略对实际锂离子、钠离子电池金属氧化物-C复合材料的合理设计和可扩展构造提供了一些依据。

关键词: SnO₂-C复合负极材料, 锂离子电池, 钠离子电池, 维度设计, 活性碳, 电化学

Abstract:

With the rapid development of new energy vehicles, more and more attention is paid to battery materials with high energy density. Due to the advantages of high specific capacity, good rate performance, abundant resources, and low price, SnO₂-C composites are regarded as one of the most promising anode materials for next-generation lithium and sodium ion batteries. Based on the dimensional changes and dimensional compounding methods of SnO₂-C composites, we firstly classifies different SnO₂-C composites and then summarizes the latest representative progress of them in detail. The focus is placed on the dimensional design formulas and the resulting synergistic effect that could potentially improve the performance. In view of the excellent results from the synergistic effect, future research could focus upon multiple composite. At the same time, simple, environmental-friendly and cheap synthetic processes should be explored. The concept and strategy presented in this work could provide some basis for the practical rational design and scalable construction of the metal oxide-C composites of lithium ion and sodium ion batteries.

Key words: SnO₂-C composite anode material, lithium ion battery, sodium ion battery, dimensional design, activated carbon, electrochemistry

中图分类号:

TM911

魏润宏, 徐汝辉, 胡学军, 张克宇, 张业男, 梁风, 姚耀春. SnO₂-C复合负极材料的维度设计用于锂、钠离子电池[J]. 化工进展, 2020, 39(7): 2677-2686.

Runhong WEI, Ruhui XU, Xuejun HU, Keyu ZHANG, Yenan ZHANG, Feng LIANG, Yaochun YAO. Dimensional design of SnO₂-C composite anode material for lithium and sodium ion batteries[J]. Chemical Industry and Engineering Progress, 2020, 39(7): 2677-2686.

参考文献

1	徐汝辉, 姚耀春, 梁风. 磷基负极材料在金属离子电池中的现状与趋势[J]. 化工进展, 2019, 38(9): 4143-4155.
1	XU R H, YAO Y C, LIANG F. Status and development trend of phosphorus-based materials applied in metal ion battery anode[J]. Chemical Industry and Engineering Progress, 2019, 38(9): 4143-4155.
2	张学谦. SnO₂/石墨烯包覆棉碳纤维柔性锂离子电池负极材料的研究[D]. 哈尔滨: 哈尔滨工业大学, 2017.
2	ZHANG X Q. Study on SnO₂/graphene coated cotton carbon fiber flexible lithium ion battery anode material[D]. Haerbin: Harbin Institute of Technology, 2017.
3	OXIEDO J, GILLAN M J. Energetics and structure of stoichiometric SnO₂ surfaces studied by first-principles calculations[J]. Surface Science, 2000, 463(2): 93-101.
4	CUI J, YAO S S, HUANG J Q, et al. Sb-doped SnO₂/graphene-CNT aerogels for high performance Li-ion and Na-ion battery anodes[J]. Energy Storage Materials, 2017, 9: 85-95.
5	AO X, JING J J, RUAN Y J, et al. Honeycomb-inspired design of ultrafine SnO₂@C nanospheres embedded in carbon film as anode materials for high performance lithium- and sodium-ion battery[J]. Journal of Power Sources, 2017, 359: 340-348.
6	HAN B, ZHANG W, GAO D, et al. Encapsulating tin oxide nanoparticles into holey carbon nanotubes by melt infiltration for superior lithium and sodium ion storage[J]. Journal of Power Sources, 2019, 449: 227564.
7	SAHOO M, RAMAPRABHU S. One-pot environment-friendly synthesis of boron doped graphene-SnO₂ for anodic performance in Li ion battery[J]. Carbon, 2018, 127: 627-635.
8	XIA Y, HAN S B, ZHU Y M, et al. Stable cycling of mesoporous Sn₄P₃/SnO₂@C nanosphere anode with high initial coulombic efficiency for Li-ion batteries[J]. Energy Storage Materials, 2019, 18: 125-132.
9	TIAN Q H, YAN J B, YANG L, et al. Fabrication of three-dimensional carbon coating for SnO₂/TiO₂ hybrid anode material of lithium-ion batteries[J]. Electrochimica Acta, 2018, 282: 38-47.
10	ZHANG S G, YUE L C, WANG M, et al. SnO₂ nanoparticles confined by N-doped and CNTs-modified carbon fibers as superior anode material for sodium-ion battery[J]. Solid State Ionics, 2018, 323: 105-111.
11	HU X J, WANG G, WANG B B, et al. Co₃Sn₂/SnO₂ heterostructures building double shell micro-cubes wrapped in three-dimensional graphene matrix as promising anode materials for lithium-ion and sodium-ion batteries[J]. Chemical Engineering Journal, 2019, 355: 986-998.
12	FAN L L, SONG X S, XING D B, et al. Nitrogen-doping of graphene enhancing sodium storage of SnO₂ anode[J]. Journal of Electroanalytical Chemistry, 2019, 833: 340-348.
13	DURSUN B, TOPAC E, ALIBEYLI R, et al. Fast microwave synthesis of SnO₂@graphene/N-doped carbons as anode materials in sodium ion batteries[J]. Journal of Alloys and Compounds, 2017, 728: 1305-1314.
14	阮筱津. NiO和SnO₂基负极材料的制备及其电化学储锂性能研究[D]. 杭州: 浙江大学, 2018.
14	RUAN X J. Preparation of NiO and SnO₂ based anode materials and their electrochemical lithium storage properties[D]. Hangzhou: Zhejiang University, 2018.
15	程娅伊. 锂/钠离子电池用锡基负极材料的制备及电化学性能研究[D]. 西安: 陕西科技大学, 2018.
15	CHENG Y Y. Preparation and electrochemical performance of tin-based anode materials for lithium/sodium ion batteries[D]. Xi’an: Shaanxi University of Science and Technology, 2018.
16	LIANG J, YU X Y, ZHOU H, et al. Bowl-like SnO₂@carbon hollow particles as an advanced anode material for lithium-ion batteries[J]. Angewandte Chemie International Edition, 2014, 53(47): 12803-12807.
17	TIAN Q H, ZHANG F, ZHANG W, et al. Non-smooth carbon coating porous SnO₂ quasi-nanocubes towards high lithium storage[J]. Electrochimica Acta, 2019, 307: 393-402.
18	ZHOU X S, YU L, LOU X W. Formation of uniform N-doped carbon-coated SnO₂ submicroboxes with enhanced lithium storage properties[J]. Advanced Energy Materials, 2016, 6(14): 1600451.
19	HUANG W J, CHEN L, CHEN Y, et al. Improved reaction kinetics and reserved spacial structure of Fe₃C-SnO₂@void@C toward high-performance lithium storage[J]. Journal of Alloys and Compounds, 2019, 785: 925-931.
20	SUN L, SI H C, ZHANG Y X, et al. Sn-SnO₂ hybrid nanoclusters embedded in carbon nanotubes with enhanced electrochemical performance for advanced lithium ion batteries[J]. Journal of Power Sources, 2019, 415: 126-135.
21	ZHAN L, ZHOU X S, LUO J, et al. Binder-free multilayered SnO₂/graphene on Ni foam as a high-performance lithium ion batteries anode[J]. Ceramics International, 2019, 45(6): 6931-6936.
22	SAIKIA D, DEKA J R, CHOU C J, et al. 3D interpenetrating cubic mesoporous carbon supported nanosized SnO₂as an efficient anode for high performance lithium-ion batteries[J]. Journal of Alloys and Compounds, 2019, 791: 892-904.
23	ZHANG W, DU R, ZHOU C G, et al. Ultrafine SnO₂ aggregates in interior of porous carbon nanotubes as high-performance anode materials of lithium-ion batteries[J]. Materials Today Energy, 2019, 12: 303-310.
24	WU B Z, LI G H, LIU F Q. 3D SnO₂/sulfonated graphene composites with interpenetrating porous structure as anode material for lithium-ion batteries[J]. International Journal of Hydrogen Energy, 2017, 42(34): 21849-21854.
25	DENG Y F, FANG C C, CHEN G H. The developments of SnO₂/graphene nanocomposites as anode materials for high performance lithium ion batteries: a review[J]. Journal of Power Sources, 2016, 304: 81-101.
26	CHEN L C, MA X H, WANG M Z, et al. Hierarchical porous SnO₂/reduced graphene oxide composites for high-performance lithium-ion battery anodes[J]. Electrochimica Acta, 2016, 215: 42-49.
27	CUI D G, ZHENG Z, PENG X, et al. Fluorine-doped SnO₂ nanoparticles anchored on reduced graphene oxide as a high-performance lithium ion battery anode[J]. Journal of Power Sources, 2017, 362: 20-26.
28	HUANG S F, WANG M, JIA P, et al. N-graphene motivated SnO₂@SnS₂heterostructure quantum dots for high performance lithium/sodium storage[J]. Energy Storage Materials, 2019, 20: 225-233.
29	DOU P, CAO Z Z, WANG C, et al. Multilayer Zn-doped SnO₂ hollow nanospheres encapsulated in covalently interconnected three-dimensional graphene foams for high performance lithium-ion batteries[J]. Chemical Engineering Journal, 2017, 320: 405-415.
30	KIM D S, SHIM H W, DAR M A, et al. Revisiting the conversion reaction in ultrafine SnO₂ nanoparticles for exceptionally high-capacity Li-ion battery anodes: the synergetic effect of graphene and copper[J]. Journal of Alloys and Compounds, 2018, 769: 1113-1120.
31	XU Z X, YUE W B, YUAN X, et al. Exceptional anodic performance of Sb-doped SnO₂ nanoparticles on electrochemically exfoliated graphene for lithium-ion batteries[J]. Journal of Alloys and Compounds, 2019, 795: 168-176.
32	ZHANG L F,YANG M Y, ZHANG S L, et al. V₂O₅-C-SnO₂ hybrid nanobelts as high performance anodes for lithium-ion batteries[J]. Scientific Reports, 2016, 6: 33597.
33	WANG Q S, XU J Q, SHEN G Y, et al. Large-scale carbon framework microbelts anchoring ultrafine SnO₂ nanoparticles with enhanced lithium storage properties[J]. Electrochimica Acta, 2019, 297: 879-887.
34	CHOI J, MYUNG Y, GU M G, et al. Nanohybrid electrodes of porous hollow SnO₂ and graphene aerogel for lithium ion battery anodes[J]. Journal of Industrial and Engineering Chemistry, 2019, 71: 345-350.
35	BHASKAR A, DEEPA M, RAMAKRISHNA M, et al. Poly(3,4-ethylenedioxythiophene) sheath over a SnO₂ hollow spheres/graphene oxide hybrid for a durable anode in Li-ion batteries[J]. The Journal of Physical Chemistry C, 2014, 118(14): 7296-7306.
36	HU X, ZENG G, CHEN J X, et al. 3D graphene network encapsulating SnO₂ hollow spheres as a high-performance anode material for lithium-ion batteries[J]. Journal of Materials Chemistry A, 2017, 5(9): 4535-4542.
37	XIN W P, GAO T T, ZHANG W Q, et al. Three-dimensional hollow SnO₂@TiO₂ spheres encapsulated in reduced graphene oxide aerogels as promising anodes for lithium-ion storage[J]. Journal of Alloys and Compounds, 2019, 784: 157-164.
38	YAO W Q, WU S B, ZHAN L, et al. Two-dimensional porous carbon-coated sandwich-like mesoporous SnO₂/graphene/mesoporous SnO₂ nanosheets towards high-rate and long cycle life lithium-ion batteries[J]. Chemical Engineering Journal, 2019, 361: 329-341.
39	陈泽华, 麻鹏程, 曹建亮, 等. 锂离子电池负极材料SnO₂掺杂石墨烯与多孔碳的改性研究[J]. 河南理工大学学报（自然科学版）, 2018, 37(5): 142-146.
39	CHEN Z H, MA P C, CAO J L, et al. Study on lithium ion batteries anode material SnO₂ doped with graphene and porous carbon[J]. Journal of Henan Polytechnic University (Natural Science), 2018, 37(5): 142-146.
40	SU W M, LIANG Y, TANG Y F. Facile situ synthesis of C@SnO₂/Sn@rGO hybrid nanosheets as high performance anode materials for lithium-ion batteries[J]. Journal of Alloys and Compounds, 2019, 801: 402-408.
41	HONG Y, MAO W F, HU Q Q, et al. Nitrogen-doped carbon coated SnO₂ nanoparticles embedded in a hierarchical porous carbon framework for high-performance lithium-ion battery anodes[J]. Journal of Power Sources, 2019, 428: 44-52.
42	KONG Z, LIU X H, WANG T, et al. Three-dimensional hollow spheres of porous SnO₂/rGO composite as high-performance anode for sodium ion batteries[J]. Applied Surface Science, 2019, 479: 198-208.
43	CHANG P Y, DOONG R A. Microwave-assisted synthesis of SnO₂/mesoporous carbon core-satellite microspheres as anode material for high-rate lithium ion batteries[J]. Journal of Alloys and Compounds, 2019, 775: 214-224.
44	ABOUALI S, AKBARI GARAKANI M, KIM J K. Ultrafine SnO₂ nanoparticles encapsulated in ordered mesoporous carbon framework for Li-ion battery anodes[J]. Electrochimica Acta, 2018, 284: 436-443.
45	LI X, SUN X H, GAO Z W, et al. Fabrication of porous carbon sphere@SnO₂@carbon layer coating composite as high performance anode for sodium-ion batteries[J]. Applied Surface Science, 2018, 433: 713-722.
46	TAN Q K, KONG Z, CHEN X J, et al. Synthesis of SnO₂/graphene composite anode materials for lithium-ion batteries[J]. Applied Surface Science, 2019, 485: 314-322.
47	WANG K, HUANG J G. Natural cellulose derived nanofibrous Ag-nanoparticle/SnO₂/carbon ternary composite as an anodic material for lithium-ion batteries[J]. Journal of Physics and Chemistry of Solids, 2019, 126: 155-163.
48	TIAN Q H, ZHANG F, YANG L. Fabricating thin two-dimensional hollow tin dioxide/carbon nanocomposite for high-performance lithium-ion battery anode[J]. Applied Surface Science, 2019, 481: 1377-1384.
49	LIU H D, HUANG J M, LI X L, et al. Flower-like SnO₂/graphene composite for high-capacity lithium storage[J]. Applied Surface Science, 2012, 258(11): 4917-4921.
50	CHOI J H, PARK G D, JUNG D S, et al. Pitch-derived carbon coated SnO₂-CoO yolk-shell microspheres with excellent long-term cycling and rate performances as anode materials for lithium-ion batteries[J]. Chemical Engineering Journal, 2019, 369: 726-735.
51	LIU X, JIANG Y H, LI K F, et al. Electrospun free-standing N-doped C@SnO₂ anode paper for flexible Li-ion batteries[J]. Materials Research Bulletin, 2019, 109: 41-48.
52	JIANG S, ZHAO B, RAN R, et al. A freestanding composite film electrode stacked from hierarchical electrospun SnO₂ nanorods and graphene sheets for reversible lithium storage[J]. RSC Adv., 2014, 4(18): 9367-9371.
53	WANG Y, JIN Y H, ZHAO C C, et al. 1D ultrafine SnO₂ nanorods anchored on 3D graphene aerogels with hierarchical porous structures for high-performance lithium/sodium storage[J]. Journal of Colloid and Interface Science, 2018, 532: 352-362.
54	TIAN Q H, TIAN Y, ZHANG Z X, et al. Fabrication of CNT@void@SnO₂@C with tube-in-tube nanostructure as high-performance anode for lithium-ion batteries[J]. Journal of Power Sources, 2015, 291: 173-180.
55	WU P, XU X L, ZHU Q Y, et al. Self-assembled graphene-wrapped SnO₂nanotubes nanohybrid as a high-performance anode material for lithium-ion batteries[J]. Journal of Alloys and Compounds, 2015, 626: 234-238.
56	JIA R, YUE J L, XIA Q Y, et al. Carbon shelled porous SnO₂-δ nanosheet arrays as advanced anodes for lithium-ion batteries[J]. Energy Storage Materials, 2018, 13: 303-311.
57	KIM A, KIM J S, HUDAYA C, et al. An elastic carbon layer on echeveria-inspired SnO₂ anode for long-cycle and high-rate lithium ion batteries[J]. Carbon, 2015, 94: 539-547.
58	LU X X, WU G L, XIONG Q Q, et al. A novel microstructural reconstruction phenomenon and electrochemical performance of cactus-like SnO₂/carbon composites as anode materials for Na-ion batteries[J]. Electrochimica Acta, 2017, 245: 587-596.
59	MA C, JIANG J L, HAN Y J, et al. The composite of carbon nanotube connecting SnO₂/reduced graphene clusters as highly reversible anode material for lithium-/sodium-ion batteries and full cell[J]. Composites Part B: Engineering, 2019, 169: 109-117.
60	WANG M Y, WAG X L, YAO Z J, et al. Molybdenum-doped tin oxide nanoflake arrays anchored on carbon foam as flexible anodes for sodium-ion batteries[J]. Journal of Colloid and Interface Science, 2020, 560: 169-176.
61	ZHU J, DENG D. Uniform distribution of 1-D SnO₂ nanorod arrays anchored on 2-D graphene sheets for reversible sodium storage[J]. Chemical Engineering Science, 2016, 154: 54-60.
62	CHANG L M, YI Z, WANG Z M, et al. Ultrathin SnO₂ nanosheets anchored on graphene with improved electrochemical kinetics for reversible lithium and sodium storage[J]. Applied Surface Science, 2019, 484: 646-654.
63	LIU Y H, FANG X, GE M Y, et al. SnO₂ coated carbon cloth with surface modification as Na-ion battery anode[J]. Nano Energy, 2015, 16: 399-407.

[1]	张明焱, 刘燕, 张雪婷, 刘亚科, 李从举, 张秀玲. 非贵金属双功能催化剂在锌空气电池研究进展[J]. 化工进展, 2023, 42(S1): 276-286.
[2]	胡喜, 王明珊, 李恩智, 黄思鸣, 陈俊臣, 郭秉淑, 于博, 马志远, 李星. 二硫化钨复合材料制备与储钠性能研究进展[J]. 化工进展, 2023, 42(S1): 344-355.
[3]	张杰, 白忠波, 冯宝鑫, 彭肖林, 任伟伟, 张菁丽, 刘二勇. PEG及其复合添加剂对电解铜箔后处理的影响[J]. 化工进展, 2023, 42(S1): 374-381.
[4]	马伊, 曹世伟, 王家骏, 林立群, 邢延, 曹腾良, 卢峰, 赵振伦, 张志军. 低共熔溶剂回收废旧锂离子电池正极材料的研究进展[J]. 化工进展, 2023, 42(S1): 219-232.
[5]	雷伟, 姜维佳, 王玉高, 和明豪, 申峻. N、S共掺杂煤基碳量子点的电化学氧化法制备及用于Fe³⁺检测[J]. 化工进展, 2023, 42(9): 4799-4807.
[6]	杨涵, 张一波, 李琦, 张俊, 陶莹, 杨全红. 面向实用化的钠离子电池碳负极：进展及挑战[J]. 化工进展, 2023, 42(8): 4029-4042.
[7]	王耀刚, 韩子姗, 高嘉辰, 王新宇, 李思琪, 杨全红, 翁哲. 铜基催化剂电还原二氧化碳选择性的调控策略[J]. 化工进展, 2023, 42(8): 4043-4057.
[8]	刘毅, 房强, 钟达忠, 赵强, 李晋平. Ag/Cu耦合催化剂的Cu晶面调控用于电催化二氧化碳还原[J]. 化工进展, 2023, 42(8): 4136-4142.
[9]	张亚娟, 徐惠, 胡贝, 史星伟. 化学镀法制备NiCoP/rGO/NF高效电解水析氢催化剂[J]. 化工进展, 2023, 42(8): 4275-4282.
[10]	王帅晴, 杨思文, 李娜, 孙占英, 安浩然. 元素掺杂生物质炭材料在电化学储能中的研究进展[J]. 化工进展, 2023, 42(8): 4296-4306.
[11]	李海东, 杨远坤, 郭姝姝, 汪本金, 岳婷婷, 傅开彬, 王哲, 何守琴, 姚俊, 谌书. 炭化与焙烧温度对植物基铁碳微电解材料去除As(Ⅲ)性能的影响[J]. 化工进展, 2023, 42(7): 3652-3663.
[12]	徐伟, 李凯军, 宋林烨, 张兴惠, 姚舜华. 光催化及其协同电化学降解VOCs的研究进展[J]. 化工进展, 2023, 42(7): 3520-3531.
[13]	张鹏, 潘原. 单原子催化剂在电催化氧还原直接合成过氧化氢中的研究进展[J]. 化工进展, 2023, 42(6): 2944-2953.
[14]	陈少华, 王义华, 胡强飞, 胡坤, 陈立爱, 李洁. 电化学修饰电极在检测Cr(Ⅵ)中的研究进展[J]. 化工进展, 2023, 42(5): 2429-2438.
[15]	李华华, 李逸航, 金北辰, 李隆昕, 成少安. 厌氧氨氧化-生物电化学耦合废水处理系统的研究进展[J]. 化工进展, 2023, 42(5): 2678-2690.

SnO₂-C复合负极材料的维度设计用于锂、钠离子电池

Dimensional design of SnO₂-C composite anode material for lithium and sodium ion batteries

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价