铜基化合物的可见光催化研究进展

doi:10.16085/j.issn.1000-6613.2019-1470

摘要/Abstract

摘要：

与传统贵金属光催化剂相比，铜基光催化剂具有价格低廉、绿色环保、反应条件温和、光催化活性可调节等优势，受到合成化学家们广泛关注。本文简述了铜基催化剂的光催化历史，回顾了近五年来铜基化合物在可见光催化领域的研究成果与进展，总结了铜基催化剂的独立光催化机理与协同光催化机理；简要阐述了铜催化剂在不同类型反应中的应用，重点讨论了铜(Ⅰ)催化剂在烯烃官能化、碳-碳偶联、碳-杂偶联、原位催化等反应中的应用研究，表明铜基化合物在光催化合成领域具有很大的应用潜力。对未来的研究工作进行了展望，指出拓展催化剂的反应适用性、探索催化剂的氧化还原能力、进一步开发催化剂在手性合成中的应用将是该领域的研究重点。

关键词: 铜基化合物, 可见光, 催化, 氧化, 还原, 偶联

Abstract:

Compared with traditional noble photocatalysts, copper-based catalysts show the advantages of low price, environmental protection, mild reaction conditions and adjustable photocatalytic activity, which have attracted widespread attention from synthetic chemists. This paper briefly described the photocatalytic history of copper-based catalysts, reviewed the research achievements and progress, summarized the independent photocatalytic mechanism and synergistic photocatalytic mechanism of copper-based catalysts. The application of copper(Ⅰ) catalysts in olefin functionalization, carbon-carbon coupling, carbon-hetero coupling and in-situ catalysis was discussed, indicating that copper-based compounds had great application potential in photocatalytic synthesis. Expanding the reaction suitability, exploring the redox capacity and further developing the application of the catalyst in chiral synthesis would be the hotspots in the field.

Key words: copper-based complex, visible-light, catalysis, oxidation, reduction, coupling

中图分类号:

O621.3

余传明, 曾圣威, 江金娥, 林雯毓, 邓翠儿, 李泳. 铜基化合物的可见光催化研究进展[J]. 化工进展, 2020, 39(6): 2411-2421.

Chuanming YU, Shengwei ZENG, Jin'e JIANG, Wenyu LIN, Cuier DENG, Yong LI. Research progress in visible-light catalysis of copper-based complex[J]. Chemical Industry and Engineering Progress, 2020, 39(6): 2411-2421.

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