富氧燃烧下含油污泥中痕量元素的迁移特性

doi:10.16085/j.issn.1000-6613.2017.01.049

化工进展 ›› 2017, Vol. 36 ›› Issue (01): 378-382.DOI: 10.16085/j.issn.1000-6613.2017.01.049

富氧燃烧下含油污泥中痕量元素的迁移特性

海云龙, 阎维平

华北电力大学能源动力与机械工程学院, 河北保定 071003

收稿日期:2016-05-12 修回日期:2016-06-15 出版日期:2017-01-05 发布日期:2017-01-05
通讯作者: 阎维平,博士,教授,从事高效低污染煤燃烧理论、新能源开发与利用、电站锅炉煤粉燃烧技术、富氧燃烧等方向的研究。E-mail:yanweiping@263.net。
作者简介:海云龙(1992-),男,硕士研究生,从事富氧燃烧及固体废弃物处理方面研究。E-mail:hdhaiyunlong@126.com。

Trace element migration characteristics of oily sludge in oxygen-enriched combustion

HAI Yunlong, YAN Weiping

School of Energy Power and Mechanical Engineering, North China Electric Power University, Baoding 071003, Hebei, China

Received:2016-05-12 Revised:2016-06-15 Online:2017-01-05 Published:2017-01-05

摘要/Abstract

摘要： 在水平管式炉上对含油污泥进行了富氧燃烧实验，采用AFS-933原子荧光分度计对灰渣中痕量元素含量进行测量，研究了燃烧温度、燃烧气氛（O₂/CO₂气氛和空气气氛）对Hg、As、Pb和Zn等痕量元素迁移特性的影响。实验结果表明：当燃烧温度高于500℃时，Hg的释放率接近100%，燃烧温度和燃烧气氛的变化对Hg的释放影响较小。O₂/CO₂气氛下，As、Pb、Zn的释放率均随温度的增加而增加，释放率分别由35%、22%、15%增加到65%、40%、16.5%。随着氧浓度的提高，Pb的释放率由34%增加到46%，As的释放率由53%下降到20%，而Zn的释放率呈先增大后减小的趋势，释放率先从14%增加到19%，再下降到15%。空气气氛下As、Pb、Zn的释放率均大于同等温度下21% O₂/79% CO₂气氛的释放率，释放率分别由54.5%、38%、17%下降到53%、34%、14%。

关键词: 富氧燃烧, 含油污泥, 痕量元素, 迁移特性

Abstract: Oxygen-enriched combustion experiments of oily sludge in the horizontal tube furnace were studied. Trace element content in ash was measured by using AFS-933 atomic fluorescence meter. The migration characteristics of trace elements Hg,As,Pb and Zn was investigated at different temperature and atmosphere(including O₂/CO₂ and air atmospheres). The results showed that Hg release rate is close to 100% at the temperature above 500℃.The change of combustion temperature and atmosphere has little effect on the release of Hg. In O₂/CO₂ atmosphere,As,Pb and Zn release rate increases with combustion temperature increase,and the release rate increases from 35%,22%,15% to 65%,40%,16.5%,respectively. Pb release rate increases from 34% to 46% with the increase of oxygen concentration. As release rate decreases from 53% to 20% with the increase of oxygen concentration. Zn release rate first increases and then decreases with the increase of oxygen concentration from 14% to 19% and then to 15%. As,Pb,Zn release rate in air atmosphere is greater than that in 21%O₂/79%CO₂ atmosphere at the same temperature,and the release rate decreases from 54.5%,38%,17% to 53%,34%,14%,respectively.

Key words: oxygen-enriched combustion, oily sludge, trace element, migration characteristics

中图分类号:

TK16

海云龙, 阎维平. 富氧燃烧下含油污泥中痕量元素的迁移特性[J]. 化工进展, 2017, 36(01): 378-382.

HAI Yunlong, YAN Weiping. Trace element migration characteristics of oily sludge in oxygen-enriched combustion[J]. Chemical Industry and Engineering Progree, 2017, 36(01): 378-382.

参考文献

[1] 甘晓娟. 油田含油污泥的处理和资源化利用综述[J]. 中国化工贸易,2014,6(23):005. GAN X J. A summary of treatment and resource utilization of oil sludge in oil field[J]. China Chemical Trade,2014,6(23):005.
[2] 阎维平. 洁净煤发电技术[M]. 北京:中国电力出版,2008. YAN W P. Clean coal power generation technology[M]. 2nd edition. Beijing:China Electric Power Press,2008.
[3] 骆仲泱,方梦祥,李明远,等. 二氧化碳捕集、封存和利用技术[M]. 北京:中国电力出版社,2012. LUO Z Y,FANG M X,LI M Y. The capture,storage,utilization technology of carbon oxides:capture5[M]. Beijing:China Electric Power Press,2012.
[4] 刘慧敏,王春波,黄星智,等. 富氧燃烧方式下煤中砷的挥发行为[J]. 化工学报,2015,66(12):5079-5087. LIU H M,WANG C B,HUANG X Z,et al. Volatilization of arsenic in coal during oxy-fuel combustion[J]. CIESC Journal,2015,66(12):5079-5087.
[5] 卢骏营,陈晓平,段伦博,等. O₂/CO₂气氛下痕量元素的赋存和迁移特性[J]. 中国电机工程学报,2009(23):40-44. LU J Y,CHEN X P,DUAN L B,et al.Trace elements occurrence and migration characteristics in O₂/CO₂ atmosphere[J]. Proceedings of the CSEE,2009(23):40-44.
[6] 卢骏营,陈晓平,段伦博. 等. O₂/CO₂气氛下痕量元素迁移特性实验研究[J]. 热能动力工程,2009(5):648-651,684. LU J Y,CHEN X P,DUAN L B,et al. Experimental Study of trace element migration characteristics in an O₂/CO₂ atmosphere[J]. Journal of Engineering for Thermal Energy and Power,2009(5):648-651,684.
[7] 刘彦,韦宏敏,徐江荣,等. O₂/CO₂与空气对燃煤汞形态分布的影响[J]. 中国电机工程学报,2008(11):48-53. LIU Y,WEI H M,XU J R,et al.Effect of O₂/CO₂ and air on mercury speciation in coal fired flue gases[J]. Proceedings of the CSEE,2008(11):48-53.
[8] 王学涛,金保升,仲兆平等.气氛对焚烧飞灰熔融过程中重金属行为的影响[J]. 中国电机工程学报,2006(7):47-52. WANG X T,JIN B S,ZHONG Z P,et al. Influence of atmospheres on behavior of heavy metals during melting process of fly ashes from municipal solid waste incinerator[J]. Proceedings of the CSEE,2006(7):47-52.
[9] 王泉海,邱建荣,温存,等. 氧燃烧方式下痕量元素形态转化的实验和模拟研究[J]. 工程热物理学报,2006(s2):199-202 WANG Q H,QIU J R,WEN C,et al. A experimental and simulative study on the morphological transformation of the trace element under oxygen-combustion atmosphere[J]. Journal of Engineering Thermophysics,2006(s2):199-202.
[10] 赵连勤,刘建国. 145t/d油污泥循环流化床锅炉及其运行[J]. 工业锅炉,2010(2):45-48. ZHAO L Q,LIU J G. 145t/d oil sludge CFB boiler and its operation[J]. Industrial Boiler,2010(2):45-48.
[11] 王磊,袁隆基. 75t/h循环流化床锅炉富氧燃烧系统设计[J]. 煤炭科技,2015(4):28-30. WANG L,YUAN LJ. 75t/h circulating fluidized bed boiler oxygen-enriched combustion system design[J]. Coal Science &Technology,2015(4):28-30.
[12] GALBREATH Kevin C,ZYGARLICKE Christopher J. Mercury transformations in coal combustion flue gas[J]. Fuel processing Technology,2000,65:289-310.
[13] 唐磊,虞江萍,季宏兵,等. 石煤砷的赋存形态及对砷迁移释放的影响[J]. 环境科学与技术,2009,32(11):58-61. TANG L,YU J P,JI H B,et al.Influence of chemical speciation of arsenic in stone-like coal on arsenic release and migration[J]. Environment Science &Technology,2009,32(11):58-61.
[14] ZENG T,SAROFIM A F,SENIOR C L.Vaporization of arsenic,selenium and antimony during coal combustion[J]. Combustion and Flame,2001,126(3):1714-1724.
[15] 刘彦丰.煤粉在高浓度CO₂下的燃烧与气化[D]. 北京:华北电力大学,2002. LIU Y F. Combustion and gasification of pulverized-coal in high concentration carbon dioxide[D]. Beijing:North China Electric Power University,2001.
[16] Lin M,Ning X,Liang X,et al. Study of the heavy metals residual in the incineration slag of textile dyeing sludge[J]. Journal of the Taiwan Institute of Chemical Engineers,2014,45(4):1814-1820.

富氧燃烧下含油污泥中痕量元素的迁移特性

Trace element migration characteristics of oily sludge in oxygen-enriched combustion

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	杨子育, 朱玲, 王文龙, 于超凡, 桑义敏. 阴燃法处理含油污泥的研究及应用进展[J]. 化工进展, 2023, 42(7): 3760-3769.
[2]	杨娟娟, 何林, 贺常晴, 李鑫钢, 隋红. 含油污泥多相复合调质降黏破乳分离过程[J]. 化工进展, 2023, 42(2): 614-623.
[3]	段一航, 高宁博, 全翠. 水热处理对含油污泥热解特性及动力学影响[J]. 化工进展, 2023, 42(2): 603-613.
[4]	蒋华义, 胡娟, 齐红媛, 游琰真, 王玉龙, 武哲. 磁性纳米粒子类型和质量浓度对微波热解含油污泥的影响[J]. 化工进展, 2022, 41(7): 3908-3914.
[5]	王宇晶, 张楠, 刘涉江, 苗辰, 刘秀丽. 热化学清洗含油污泥的效果评价及机理[J]. 化工进展, 2022, 41(6): 3333-3340.
[6]	樊相汝, 羊依金, 郭旭晶, 张全碧. 软锰矿-含油污泥基活性炭对亚甲基蓝的吸附特性[J]. 化工进展, 2022, 41(12): 6664-6671.
[7]	贾文龙, 宋硕硕, 李长俊, 吴瑕, 杨帆, 张员瑞. 超临界CO₂萃取含油污泥研究现状与进展[J]. 化工进展, 2022, 41(12): 6573-6585.
[8]	郑发, 李浩文, 林法伟, 张岩, 吴越强, 陈钊, 马文臣, 陈冠益. 大庆罐底油泥热解特性及污染物释放特性[J]. 化工进展, 2022, 41(1): 476-484.
[9]	包清华, 黄立信, 修建龙, 俞理, 崔庆锋, 马原栋, 伊丽娜. 油气田含油污泥生物处理技术研究进展[J]. 化工进展, 2021, 40(5): 2762-2773.
[10]	张楠, 王宇晶, 刘涉江, 张凯. 含油污泥化学热洗技术研究现状与进展[J]. 化工进展, 2021, 40(3): 1276-1283.
[11]	王亭亭, 赵智强, 张耀斌. 碱预处理耦合零价铁强化含油污泥厌氧消化[J]. 化工进展, 2021, 40(1): 534-541.
[12]	张军, 贾悦, 刘博, 张则俊, 安静, 蔡贤明. 油气集输过程中含油污泥减量化[J]. 化工进展, 2020, 39(S2): 372-378.
[13]	蒋华义, 段远望, 王玉龙, 邹少杰, 张兰新, 李瑾, 王冰. 基于均匀设计法的含油污泥超临界水气化制氢实验[J]. 化工进展, 2020, 39(9): 3819-3825.
[14]	黄朝琦,秦志文,尚绪敏,侯影飞. 含油污泥化学热洗的药剂配方及工艺优化[J]. 化工进展, 2020, 39(4): 1478-1484.
[15]	沈昊天, 王卉, 沈畅, 吴建飞. 富氧气氛下改性生物质焦脱汞的氧化机理[J]. 化工进展, 2020, 39(11): 4734-4741.