基于均匀设计法的含油污泥超临界水气化制氢实验

doi:10.16085/j.issn.1000-6613.2019-1950

化工进展 ›› 2020, Vol. 39 ›› Issue (9): 3819-3825.DOI: 10.16085/j.issn.1000-6613.2019-1950

基于均匀设计法的含油污泥超临界水气化制氢实验

蒋华义¹^,²(), 段远望¹, 王玉龙¹^,²^,³(), 邹少杰¹, 张兰新¹, 李瑾¹, 王冰⁴

^1.西安石油大学石油工程学院，陕西西安 710065
^2.西安石油大学陕西省油气田特种增产技术重点实验室，陕西西安 710065
^3.西安交通大学能源与动力工程学院，陕西西安 710049
^4.新疆油田公司黑油山有限责任公司，新疆克拉玛依 834000

出版日期:2020-09-05 发布日期:2020-09-11
通讯作者: 王玉龙
作者简介:蒋华义（1973—），男，博士，教授，研究方向为油气高效处理与输送技术。E-mail：hyjiang@xsyu.edu.cn。
基金资助:
陕西省自然科学基础研究计划(2019JQ-819);陕西省教育厅专项科研计划(16JK1594)

Supercritical water gasification of oily sludge to produce hydrogen based on uniform design method

Huayi JIANG¹^,²(), Yuanwang DUAN¹, Yulong WANG¹^,²^,³(), Shaojie ZOU¹, Lanxin ZHANG¹, Jin LI¹, Bing WANG⁴

^1.College of Petroleum Engineering, Xi’an Shiyou University, Xi’an 710065, Shaanxi, China
^2.Shaanxi Key Laboratory of Advanced Stimulation Technology for Oil & Gas Reservoirs, Xi’an 710065, Shaanxi, China
^3.School of Energy and Power Engineering, Xi’an Jiaotong University, Xi’an 710049, Shaanxi, China
^4.Heiyoushan Limited Liability Company of Xinjiang Oilfield Company, Karamay 834000, Xinjiang, China

Online:2020-09-05 Published:2020-09-11
Contact: Yulong WANG

摘要/Abstract

摘要：

在原油采输过程中会产生大量含油污泥，传统处理方式存在回收效率低、环境二次污染等弊端，应用超临界水气化含油污泥进行氢能回收，对含油污泥进行高效处理和利用具有重要意义。本文应用均匀设计方法研究超临界水的反应温度、反应压力、反应时间和物料比与最终单位污泥产氢量之间的关系，并通过反应结果拟合出它们之间的经验公式，分析超临界水反应参数对含油污泥气化制氢影响规律。结果表明，通过均匀设计进行多元线性拟合在含油污泥气化实验中具有较好的可行性，拟合出的经验公式具有良好的预测性，单位污泥产氢量与反应温度、反应时间呈正相关，与物料比呈负相关，伴随压力的增加单位污泥产氢量先增加后减小。在反应参数为544℃、2.2MPa、150min、10%下，单位污泥产氢量最高为5.92mmol/g。

关键词: 均匀设计, 含油污泥, 超临界水, 气化, 制氢, 最优反应参数

Abstract:

A large amount of oily sludge will be produced during crude oil production and transportation. Traditional methods for treatment of oily sludge have the disadvantages of low recovery efficiency and risk of secondary pollution. The supercritical water gasification of oily sludge for hydrogen energy recovery is of great significance for the efficient treatment and utilization of oily sludge. In this study, a uniform design method was used to investigate the relationship between the reaction temperature, reaction pressure, reaction time, material ratio and the hydrogen production, and the empirical formula was fitted by applying the reaction results. The influence of reaction parameters of supercritical water on hydrogen production from oily sludge was analyzed. The results showed that the multivariate linear fitting through uniform design had good feasibility in oily sludge gasification experiments. The fitted empirical formula gained good predictability. The hydrogen production per unit sludge was positively related with the reaction temperature and the reaction time, but had a negative correlation with the material ratio. With the increase of pressure, the hydrogen production per unit sludge increased first and then decreased. In the conditions of reaction parameters of 544℃, 2.2MPa, 150min, and 10%, respectively, the maximum hydrogen production per unit sludge achieved was 5.92mmol/g.

Key words: uniform design, oily sludge, supercritical water, gasification, hydrogen, optimal reaction parameters

中图分类号:

TE09

蒋华义, 段远望, 王玉龙, 邹少杰, 张兰新, 李瑾, 王冰. 基于均匀设计法的含油污泥超临界水气化制氢实验[J]. 化工进展, 2020, 39(9): 3819-3825.

Huayi JIANG, Yuanwang DUAN, Yulong WANG, Shaojie ZOU, Lanxin ZHANG, Jin LI, Bing WANG. Supercritical water gasification of oily sludge to produce hydrogen based on uniform design method[J]. Chemical Industry and Engineering Progress, 2020, 39(9): 3819-3825.

参考文献

1	黄静, 刘建坤, 蒋廷学, 等. 含油污泥热解技术研究进展[J]. 化工进展, 2019, 38(11): 232-239.
1	HUANG Jing, LIU Jiankun, JIANG Tingxue, et al. Research progress on pyrolysis of oily sludge [J]. Chemical Industry and Engineering Progress, 2019, 38(11): 232-239.
2	赵晓非, 张晓阳, 刘立新, 等. 新型油泥处理技术展望[J]. 化工进展, 2016, 35(S1): 276-280.
2	ZHAO Xiaofei, ZHANG Xiaoyang, LIU Lixin, et al. Prospect of new treatment of oil sludge [J]. Chemical Industry and Engineering Progress, 2016, 35(S1): 276-280.
3	徐如良, 韩子兴. 油罐底泥的减量化和资源化技术[J]. 石油与天然气化工, 2004, 33(5): 369-374.
3	XU Ruliang, HAN Zixing. Reduction and resource recovery of tank bottom mud [J]. Petroleum and Natural Gas Chemical Industry, 2004, 33(5): 369-374.
4	谢志海, 蔡清, 龚德, 等. 石油油泥综合处理技术[J]. 化工进展, 2011, 30(S1): 497-499.
4	XIE Zhihai, CAI Qing, GONG De, et al. Comprehensive treatment technology of petroleum sludge [J]. Chemical Industry and Engineering Progress, 2011, 30(S1): 497-499.
5	王金利, 李秀灵, 严波. 含油污泥处理技术研究进展[J]. 能源化工, 2015, 36(5): 71-76.
5	WANG Jinli, LI Xiuling, YAN Bo. Research progress of oily sludge treatment [J]. Energy Chemical Industry, 2015, 36(5): 71-76.
6	史利芳, 潘利祥, 李朝晖, 等. 含油污泥处理技术及相关设备现状[J]. 环境工程, 2015, 33(s1): 526-529+534.
6	SHI Lifang, PAN Lixiang, LI Zhaohui, et al. Treatment technologies and eqquipments for oil-containing sludge [J]. Environmental Engineering, 2015, 33(s1): 526-529+534.
7	陆柒安, 张军, 赵亮, 等. 生物质超临界水气化制氢研究进展[J]. 现代化工, 2018, 38(12): 29-33.
7	LU Qi’an, ZHANG Jun, ZHAO Liang, et al. Research progress on hydrogen production through biomass gasification in supercritical water [J]. Modern Chemical Industry, 2018, 38(12): 29-33.
8	MUHAMMAD K K, HANDI S C, SUNG-MIN K, et al. Efficient oil recovery from highly stable toxic oily sludge using supercritical water [J]. Fuel, 2019, 235: 460-472.
9	ZHANG Linghong. Catalytic supercritical water gasification of sewage sludge/secondary pulp/paper-mill sludge for hydrogen production [D]. Kingston, Ontario, Canada: Queen's University, 2011.
10	RANA R, NANDA S, KOZINSKI J A, et al. Investigating the applicability of Athabasca bitumen as a feedstock for hydrogen production through catalytic supercritical water gasification [J]. Journal of Environmental Chemical Engineering, 2018, 6(1): 182-189.
11	HAO Xiaohong, GUO Liejin, MAO X, et al. Hydrogen production from glucose used as a model compound of biomass gasified in supercritical water [J]. International Journal of Hydrogen Energy, 2003, 28(1): 55-64.
12	LU Youjun, GUO Liejin, ZHANG Ximin, et al. Thermodynamic modeling and analysis of biomass gasification for hydrogen production in supercritical water [J]. Chemical Engineering Journal, 2007, 131(1/2/3): 233-244.
13	ZHAI Yunbo, WANG Chang, CHEN Hongmei, et al. Digested sewage sludge gasification in supercritical water [J]. Waste Management & Research, 2013, 31(4): 393-400.
14	XU Donghai, WANG Shuzhong, TANG Xingying, et al. Design of the first pilot scale plant of China for supercritical water oxidation of sewage sludge [J]. Chemical Engineering Research & Design, 2012, 90(2): 288-297.
15	邹江文, 杨欣运, 张永明, 等. 均匀设计在微乳液法制备纳米氧化铝中的应用[J]. 化工进展, 2018, 37(7): 2748-2752.
15	ZOU Jiangwen, YANG Xinyun, ZHANG Yongming, et al. Application of uniform design in the preparation of nano-alumina by microemulsion method [J]. Chemical Industry and Engineering Progress, 2018, 37(7): 2748-2752.
16	王计敏, 顾明言, 刘国华, 等. 基于均匀设计法的富氧底吹铜熔池熔炼炉热力学回归分析[J]. 化工进展, 2016, 35(5): 1303-1308.
16	WANG Jimin, GU Mingyan, LIU Guohua, et al. A thermodynamic regression analysis of oxygen bottom-blown copper smelting furnace based on uniform design method [J]. Chemical Industry and Engineering Progress, 2016, 35(5): 1303-1308.
17	蒋华义, 魏爱军, 黄莉. 应用均匀设计法研究原油的微波破乳脱水规律[J]. 西安石油大学学报: 自然科学版, 2006, 21(1): 39-41.
17	JIANG Huayi, WEI Aijun, HUANG Li. Study on the law of microwave demulsification dehydration using uniform design method [J]. Journal of Xi’an Shiyou University (Naturnal Science Edition), 2006, 21(1): 39-41.
18	张珂, 朱建华, 周勇, 等. 含油污泥中油水含量的3种测定方法比较[J]. 环境工程学报, 2014, 8(1): 385-391.
18	ZHANG Ke, ZHU Jianhua, ZHOU Yong; et al. Comparison of three kinds of determination methods on oil and water content of oily sludge [J]. Chinese Journal of Environmental Engineering, 2014, 8(1): 385-391.
19	方开泰. 均匀设计与均匀设计表[M]. 北京: 科学出版社, 1994: 24-100.
19	FANG Kaitai. Uniform design and uniform design table [M]. Beijing: Science Press, 1994: 24-100.

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基于均匀设计法的含油污泥超临界水气化制氢实验

Supercritical water gasification of oily sludge to produce hydrogen based on uniform design method

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