无硫磷三嗪杂环衍生物水基润滑添加剂的制备及其摩擦性能

doi:10.16085/j.issn.1000-6613.2017.01.044

化工进展 ›› 2017, Vol. 36 ›› Issue (01): 343-349.DOI: 10.16085/j.issn.1000-6613.2017.01.044

无硫磷三嗪杂环衍生物水基润滑添加剂的制备及其摩擦性能

公丕建^1,2,3, 王海彦¹, 唐海燕^2,3, 徐红彬^2,3, 张懿^2,3

1 辽宁石油化工大学化学化工与环境学部, 辽宁省车用清洁燃料工程技术研究中心, 辽宁抚顺 113006;
2 中国科学院过程工程研究所, 湿法冶金清洁生产技术国家工程实验室, 北京 100190;
3 中国科学院, 绿色过程与工程重点实验室, 北京 100190

收稿日期:2016-05-26 修回日期:2016-09-07 出版日期:2017-01-05 发布日期:2017-01-05
通讯作者: 王海彦,博士,教授,主要从事清洁燃料生产技术方面的研究;E-mail:fswhy@126.com;唐海燕,博士,主要从事金属有机物与精细化工产品合成。E-mail:hytang@ipe.ac.cn。
作者简介:公丕建(1989-),男,硕士研究生,主要从事润滑油添加剂的合成及性能研究。
基金资助:
国家自然科学基金项目（21406233）。

Synthesis and tribological properties of non-phosphorus and sulfur-free heterocyclic derivatives of triazine as lubricant additives in water

GONG Pijian^1,2,3, WANG Haiyan¹, TANG Haiyan^2,3, XU Hongbin^2,3, ZHANG Yi^2,3

1 Liaoning Vehicle Clean Fuel Engineering Technology Research Center, Liaoning Shihua University, Fushun 113006, Liaoning, China;
2 National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
3 Key Laboratory of Green Process and Engineering, Chinese Academy of Sciences, Beijing 100190, China

Received:2016-05-26 Revised:2016-09-07 Online:2017-01-05 Published:2017-01-05

摘要/Abstract

摘要： 以三聚氯氰和二乙醇胺为原料合成出一种含氮、但不含硫磷的三嗪杂环衍生物2，4-二（N，N-二羟乙氨基）-6-羟基-均三嗪（CDDA）水基润滑添加剂，以CDDA为原料制得一种添加剂2，4-二吗啉基-6-羟基-均三嗪（CMDA），并采用FTIR、元素分析以及电喷雾电离质谱（ESI-MS）对其结构进行了表征。考察了CDDA和CMDA的热稳定性及溶解性；采用四球摩擦磨损试验研究了CDDA和CMDA用作水基润滑添加剂的减摩、抗磨以及极压性能；并采用SEM和EDS观察和分析了摩擦表面的形貌特征及元素。研究结果表明，合成的产物为目标产物CDDA和CMDA。在相同的实验条件下，CMDA的分解温度范围是278.26~460.15℃，CDDA的分解温度范围是110.46~457.58℃，CMDA的热稳定性优于CDDA；在不同载荷、添加比例等条件下CMDA的摩擦学性能优于CDDA。CMDA优异的摩擦学性能得益于含有更多的杂环结构，在摩擦过程中，添加剂与摩擦副表面发生化学反应，生成了含氮杂环的复合边界润滑膜，起到极压、抗磨的作用。

关键词: 无硫磷, 三嗪衍生物, 水基添加剂, 合成, 摩擦性能

Abstract: A non-phosphorus and sulfur-free triazine derivative lubricant additive 2,4-bi(N,N-bihydroxyethylamino)-6-hydroxyl-sym-triazine(named as CDDA)was synthesized using cyanuric chloride and diethanol amine as raw materials. Another non-phosphorus and sulfur-free triazine derivative lubricant additive 2,4-bimorpholinyl-6-hydroxyl-sym-triazine(named as CMDA)was synthesized using CDDA as raw material. The structure of CDDA and CMDA were characterized by FTIR,elemental analysis and ESI-MS. The solubilities of CDDA and CMDA in water were tested and their thermal stabilities were studied by thermal analysis. The friction reducing,anti-wear and load-carrying capacities of CDDA and CMDA in water were investigated by four-ball testing. The surface morphology and the elemental composition of the tribofilms wereinvestigated using scanning electron microscopy(SEM)and energy dispersive X-ray spectroscopy(EDS),respectively. The results revealed that the synthetic products were the target compounds CDDA and CMDA. They were completely dissolved and had good soluble properties in water. The decomposition temperature of CMDA and CDDA ranged from 278.26℃ to 460.15℃,and from 110.46℃ to 457.58℃,respectively,the thermal stability of CMDA was better than that of CDDA. CDMA exhibited better tribological performances than CDDA under different experimental conditions of test loads and additive concentrations. The excellent tribological property of CMDA may be due to the nitrogen heterocyclic structure and more heterocyclic structure in its molecule,which plays an important role in extreme pressure and anti-wear of boundary lubrication.

Key words: non-phosphorus and sulfur-free, triazine derivatives, water lubricant additive, synthesistribological properties

中图分类号:

O626.43

公丕建, 王海彦, 唐海燕, 徐红彬, 张懿. 无硫磷三嗪杂环衍生物水基润滑添加剂的制备及其摩擦性能[J]. 化工进展, 2017, 36(01): 343-349.

GONG Pijian, WANG Haiyan, TANG Haiyan, XU Hongbin, ZHANG Yi. Synthesis and tribological properties of non-phosphorus and sulfur-free heterocyclic derivatives of triazine as lubricant additives in water[J]. Chemical Industry and Engineering Progree, 2017, 36(01): 343-349.

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无硫磷三嗪杂环衍生物水基润滑添加剂的制备及其摩擦性能

Synthesis and tribological properties of non-phosphorus and sulfur-free heterocyclic derivatives of triazine as lubricant additives in water

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