咪唑类离子液体对水基钻井液抑制性的影响及机理

doi:10.16085/j.issn.1000-6613.2017-0905

化工进展 ›› 2017, Vol. 36 ›› Issue (11): 4209-4215.DOI: 10.16085/j.issn.1000-6613.2017-0905

咪唑类离子液体对水基钻井液抑制性的影响及机理

罗志华^1,2, 王龙祥¹, 夏柏如^1,2

1. 中国地质大学(北京)工程技术学院, 北京 100083;
2. 国土资源部深部地质钻探技术重点实验室, 北京 100083

收稿日期:2017-05-15 修回日期:2017-07-03 出版日期:2017-11-05 发布日期:2017-11-05
通讯作者: 罗志华(1975-),女,博士,讲师。研究方向为工程地质流体。
作者简介:罗志华(1975-),女,博士,讲师。研究方向为工程地质流体。E-mail:78702381@qq.com。
基金资助:
国家自然科学基金（51204150）及北京市自然科学基金（3123042）项目。

Effect of an ionic liquid with an imidazole cation on shale inhibitive property in water-based drilling fluids and its mechanism

LUO Zhihua^1,2, WANG Longxiang¹, XIA Bairu^1,2

1. School of Engineering and Technology, China University of Geosciences, Beijing 100083, China;
2. Key Laboratory on Deep GeoDrilling Technology, Ministry of Land and Resources, Beijing 100083, China

Received:2017-05-15 Revised:2017-07-03 Online:2017-11-05 Published:2017-11-05

摘要/Abstract

摘要： 油气钻井过程中泥页岩不稳定主要是由于泥页岩的水化作用造成。本文采用页岩滚动回收率法、毛细管吸入时间法和粒度分析法3种方法，与传统抑制剂KCl和新型抑制剂聚胺作对比，评价了离子液体RIL作为抑制剂对水基钻井液抑制性能的影响。结果表明高温作用下低浓度（质量分数0.05%）的离子液体RIL有着优异的抑制黏土膨胀和分散的能力，其抑制效果优于5% KCl，与2%聚胺相当；同时低浓度的离子液体RIL可以改善水基钻井液的高温流变性而不会使钻井液的滤失性变差。通过接触角和热稳定性测试分析了其抑制机理。离子液体RIL改性后的Na蒙脱土润湿性从亲水性向疏水性转变，可以阻止水分子进入Na蒙脱土的层间结构从而抑制Na蒙脱土的膨胀和分散。低浓度的离子液体RIL改性后的钠蒙脱土具有更好的热稳定性，可以提高高温作用下水基钻井液的抑制性。

关键词: 离子液体, 水基钻井液, 抑制性, 高温

Abstract: Shale instability is mainly induced by the hydration of shale in the drilling of oil and gas. An ionic liquid,as an inhibitor,was evaluated by hot-rolling recovery,capillary suction time,and particle size distribution tests. The results showed thatat high temperature the ionic liquid(RIL)with very low concentration had superior capacity to inhibit clay swelling and dispersing. It performed better than 5% KCl,a conventional inhibitor,and had similar performance of 2% polyether diamine,a novel inhibitor. RIL at very low concentration can improve the rheology of water-based drilling fluids and would not affectthe filtration performance at high temperature. The mechanism of inhibiting was investigated via contact angle tests and thermogravimetric analyses. It is found that RIL strengthened lipophilicity of Na-MMT,which prohibited water from ingress. The thermal stability of Na-MMT was greatly improved when Na-MMT was modified with lower concentration of RIL,leading to the excellent inhibition of ILB at high temperatures.

Key words: ionic liquid, water-based drilling fluids, inhibitive properties, high temperature

中图分类号:

TE254⁺.4

罗志华, 王龙祥, 夏柏如. 咪唑类离子液体对水基钻井液抑制性的影响及机理[J]. 化工进展, 2017, 36(11): 4209-4215.

LUO Zhihua, WANG Longxiang, XIA Bairu. Effect of an ionic liquid with an imidazole cation on shale inhibitive property in water-based drilling fluids and its mechanism[J]. Chemical Industry and Engineering Progress, 2017, 36(11): 4209-4215.

参考文献

[1] 张东晓,杨婷云. 页岩气开发综述[J]. 石油学报,2013,34(4):792-799. ZHANG D X,YANG T Y. An overview of shale-gas production[J]. Acta Petrolei Sinica,2013,34(4):792-799.
[2] 王倩,王刚,蒋宏伟,等. 泥页岩井壁稳定耦合研究[J]. 断块油气田, 2012,19(4):517-521. WANG Q,WANG G,JIANG H W,et al. Study on shale wellbore stability coupling[J]. Fault-Block Oil & Gas Field,2012,19(4):517-521.
[3] 孙金生,张希. 钻井液技术的现状、挑战、需求与发展趋势[J]. 钻井液与完井液,2011,28(6):67-76. SUN J S,ZHANG X. Situation,challenges,demands and trends of drilling fluid technology[J]. Drilling Fluid & Completion Fluid,2011,28(6):67-76.
[4] VAN OORT E. On the physical and chemical stability shale[J]. Journal of Petroleum Science and Engineering,2003,38:213-235.
[5] PEREZ A D,MONROY I C,ROEGIERS J C. The role of water/clay interaction in the shale characterization[J]. Journal of Petroleum Science and Engineering,2007,58:83-98.
[6] RAJAT J,VIKAS M. Evaluation of polyacrylamide/clay composite as a potential drilling fluid additive in water based drilling fluid system[J]. Journal of Petroleum Science and Engineering,2015,133:612-621.
[7] 鄢捷年. 钻井液工艺学[M]. 东营:中国石油出版社,2012. YAN J N. Technology of drilling fluid[M]. Dongying:China Petroleum University Press,2012.
[8] KJ?SNES I,L?KLINGHOLM G,SAASEN A,et al. Successful water based drilling fluid design for optimizing hole cleaning and hole stability[C]//Middle East Drilling Technology Conference & Exhibition. 2003,SPE 85330.
[9] GHOLIZADEH-DOONECHALY N,TAHMASBI K,DACANI E. Development of high-performance water-based mud formulation based on amine derivatives[C]//SPE International Symposium on Oilfield Chemistry. 2009,SPE 121228.
[10] GUERRERO X,GUERRERO M, WARREN B. Use of amine/PHPA system to drill high reactive shales in the Orito field in Colombia[C]//First International Oil Conference and Exhibition. 2006,SPE 104010.
[11] DYE W,D'AUGEREAU K,HANSEN N,et al. New water-based mud balances high-performance drilling and environmental compliance[C]//Drilling Conference,Amsterdam,2006,IADC/SPE 92367.
[12] KHODJA M,CANSELIER P J,BERGAYA F,et al. Shale problems and water-based drilling fluid optimization in the Hassi Messaoud Algerian oil field[J]. Applied Clay Science,2010,49:383-393.
[13] TAKAHASHI C, TAKASHI S,MASAYOSHI F. Study on intercalation of ionic liquid into montmorillonite and its property evaluation[J]. Material Chemistry and Physics,2012,135:681-686.
[14] ANA-EVA J,MARIA-DOLORES B. Imidazolium ionic liquids as additives of the synthetic ester propylene glycol dioleate in aluminium-steel lubrication[J]. Wear,2008,265(5/6):787-798.
[15] 孙宏伟, 陈建峰. 我国化工过程强化技术理论与应用研究进展[J]. 化工进展,2011,30(1):1-15. SUN H W,CHEN J F. Advances in fundamental study and application of chemical process intensification technology in China[J]. Chemical Industry and Engineering Progress,2011,30(1):1-15.
[16] BERRY S L, BOLES J L,BRANNON H D,et al. Performance evaluation of ionic liquids as a clay stabilizer and shale inhibitor[C]//SPE International Symposium and Exhibition on Forrnation Damage Control,Lafayette,Louisiana,USA. 2008,SPE 112540.
[17] LUO Z H,PEI J J,WANG L X,et al. Influence of an ionic liquid on rheological and filtration properties of water-based drilling fluids at high temperatures[J]. Applied Clay Science,2017,136:96-102.
[18] Recommended practice for laboratory testing of drilling fluids:API RP 13I[S]. Seventh Edition,American Petroleum Institute,2004.
[19] Recommended practice for field testing of water-based drilling fluids:API RP 13B-1[S]. Fourth Edition,American Petroleum Institute 2009.
[20] 张春光,侯万国,孙德军. 电性抑制性井壁稳定与油层保护[J]. 钻井液与完井液,2002,19(6):5-8. ZHANG C G,HOU W G,SUN D J. Electrical behavior,inhibition,wall stability and reservoir protection[J]. Drilling Fluid & Completion Fluid,2002,19(6):5-8.
[21] BLAND R G,WAYGHMAN R R,TOMKINS P G,et al. Water-based alternatives to oil-based muds:do they actually exist?[C]//Drilling Conference,2002,IADC/SPE 74542.
[22] 高海英,杨仁斌,龚道新. 蒙脱石的吸附行为及其环境意义[J]. 农业环境科学学报,2006,25:438-442 GAO H Y,YANG R B,GONG D X. Adsorption behavior of microorganisms and environmental significant[J]. Journal of Agro-Environment Science,2006,25:438-442
[23] ZHONG H Y, QIU Z S,HUANG W A,et al. Shale inhibitive properties of polyether diamine in water-based drilling fluid[J]. Journal of Petroleum Science and Engineering, 2011,78:510-515.
[24] REID C A. Maximum rate with good hole condition[R]. API Drilling and Production,1966:109-119.
[25] TAKAHASHI C,TAKASHI S,MASAYOSHI F. Study on intercalation of ionic liquid into montmorillonite and its property evaluation[J]. Material Chemistry and Physics,2012,135:681-686.
[26] 丁运生,王僧山,查敏,等. 有机阳离子[C₁₈min]⁺在蒙脱土层间的物理化学吸附与聚集状态[J]. 物理化学学报,2006,22(5):548-551. DING Y S,WANG S S,ZHANG M,WANG Z G,et al. Physico chemical adsorption and aggregative structures of the organic cation[C₁₈mim]⁺ in the layer of montmorillonite[J]. Acta Physico-Chimica Sinica,2006,22:548-551.
[27] ZHUANG G Z,ZHANG Z P,FU M,et al. Comparative study on the use of cationic-nonionic-organo-montmorillonite in oil-based drilling fluids[J]. Applied Clay Science,2015,116:257-262.
[28] XIE W,GAO Z,PAN W P,et al. Thermal degradation chemistry of alkyl quaternary ammonium montmorillonite[J]. Chemistry Material,2001,13:2979-2990.

咪唑类离子液体对水基钻井液抑制性的影响及机理

Effect of an ionic liquid with an imidazole cation on shale inhibitive property in water-based drilling fluids and its mechanism

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	李昕, 杨早, 钟欣茹, 韩昊轩, 庄绪宁, 白建峰, 董滨, 徐祖信. 污泥超高温堆肥衍生胡敏酸对Pb²⁺的结合机制[J]. 化工进展, 2023, 42(9): 4957-4966.
[2]	吴亚, 赵丹, 方荣苗, 李婧瑶, 常娜娜, 杜春保, 王文珍, 史俊. 用于复杂原油乳液的高效破乳剂开发及应用研究进展[J]. 化工进展, 2023, 42(8): 4398-4413.
[3]	杨许召, 李庆, 袁康康, 张盈盈, 韩敬莉, 吴诗德. 含Gemini离子液体低共熔溶剂热力学性质[J]. 化工进展, 2023, 42(6): 3123-3129.
[4]	吕超, 张习文, 金理健, 杨林军. 新型两相吸收剂-离子液体系统高效捕获CO₂[J]. 化工进展, 2023, 42(6): 3226-3232.
[5]	陈明星, 王新亚, 张威, 肖长发. 纤维基耐高温空气过滤材料研究进展[J]. 化工进展, 2023, 42(5): 2439-2453.
[6]	刘广平, 陆振能, 龚宇烈. 高温热泵蒸汽系统的动态响应及扰动优化[J]. 化工进展, 2023, 42(4): 1719-1727.
[7]	宗悦, 张瑞君, 高珊珊, 田家宇. “特殊稳定型”压力驱动薄膜复合（TFC）脱盐膜的研究进展[J]. 化工进展, 2023, 42(4): 2058-2067.
[8]	赵重阳, 赵磊, 石详文, 黄俊, 李治尧, 沈凯, 张亚平. O₂/H₂O/SO₂ 对改性富铁凹凸棒石高温吸附PbCl₂ 的影响[J]. 化工进展, 2023, 42(4): 2190-2200.
[9]	侯婉, 陈汇龙, 程谦, 陈英健, 卫泽鹏, 赵斌娟. 高温密封润滑膜汽液固流动特性数值计算分析[J]. 化工进展, 2023, 42(2): 699-710.
[10]	华渠成, 段庆华. 离子液体极压抗磨剂的研究进展[J]. 化工进展, 2022, 41(S1): 331-339.
[11]	陈钰, 刘冲, 邱于荟, 贲梓欣, 牟天成. 离子液体和低共熔溶剂绿色回收废旧锂离子电池的研究进展[J]. 化工进展, 2022, 41(S1): 485-496.
[12]	罗源皓, 林凌, 郭拥军, 杨玉坤, 熊贵霞, 任仁, 屈沅治. 纳米材料在抗高温钻井液中的应用进展[J]. 化工进展, 2022, 41(9): 4895-4906.
[13]	韩明阳, 乔慧, 付佳铭, 马泽雯, 王妍, 欧阳嘉. 非水溶剂预处理木质纤维原料研究进展[J]. 化工进展, 2022, 41(8): 4086-4097.
[14]	单清雯, 张娟, 王亚娟, 刘文强. 聚合离子液体的合成及其吸附脱硫性能[J]. 化工进展, 2022, 41(8): 4571-4579.
[15]	王新宇, 黄亚继, 徐力刚, 李志远, 李偲, 刘晓东. 调节同层二次风以缓解双切圆锅炉高温腐蚀的数值模拟[J]. 化工进展, 2022, 41(5): 2292-2300.