氧化铈基HCl氧化循环制Cl2催化剂研究进展

doi:10.16085/j.issn.1000-6613.2017-0539

摘要/Abstract

摘要： 氯化氢催化氧化技术在副产氯化氢的处理和利用方面有着巨大的应用价值和良好的工业前景。CeO₂基催化剂因其廉价、不易烧结及抗氯化性能优良等诸多优点，被认为是目前最具有应用前景的氯化氢氧化催化剂之一。本文简要地介绍了氯化氢氧化制氯循环工艺，评述了近年来用于氯化氢氧化反应的CeO₂基催化材料，包括CeO₂催化剂、掺杂改性CeO₂催化剂以及CeO₂作助催化剂等。同时在文中还对CeO₂基材料催化HCl氧化的表面反应机理进行阐述。最后结合目前的研究现状，对如何进一步提升CeO₂基催化HCl氧化的反应活性进行了展望。

关键词: 催化, 氧化, 氯循环, 氧化铈, 氯气

Abstract: The catalytic oxidation of HCl is gaining increasing application and industrial prospects in the chlorine-related industry. CeO₂-based materials have been regarded as the most promising catalysts for HCl oxidation due to their excellent characteristics such as low-cost,sintering-resistant and anti-chlorination. After a brief introduction of the chlorine circulation process,this manuscript discusses different ceria-based catalytic materials for HCl catalyzed oxidation,including CeO₂ catalyst,modified CeO₂ catalyst and CeO₂ as catalyst promoter. Special focus has been put on the surface reaction mechanism of HCl oxidation on CeO₂. Considering the current research condition,this review also provides some future prospects for promoting the activity of CeO₂-based catalysts in HCl oxidation.

Key words: catalysis, oxidation, chlorine circulation, cerium oxide(CeO₂), chlorine

中图分类号:

O643.3

楼家伟, 费兆阳, 刘清, 陈献, 汤吉海, 崔咪芬, 张竹修, 乔旭. 氧化铈基HCl氧化循环制Cl₂催化剂研究进展[J]. 化工进展, 2018, 37(05): 1804-1814.

LOU Jiawei, FEI Zhaoyang, LIU Qing, CHEN Xian, TANG Jihai, CUI Mifen, ZHANG Zhuxiu, QIAO Xu. Research progress in recycle oxidation of HCl to Cl₂ over ceria based catalysts[J]. Chemical Industry and Engineering Progress, 2018, 37(05): 1804-1814.

参考文献

[1] TORRES J P,LEITE C,KRAUSS T,et al. Landfill mining from a deposit of the chlorine/organochlorine industry as source of dioxin contamination of animal feed and assessment of the responsible processes[J]. Environmental Science and Pollution Research,2013,20(4):1958-1965.
[2] MOUSSALLEM I,JÖRISSEN J,KUNZ U,et al. Chlor-alkali electrolysis with oxygen depolarized cathodes:history,present status and future prospects[J]. Journal of Applied Electrochemistry,2008,38(9):1177-1194.
[3] MORTENSEN M,MINET R G,TSOTSIS T T,et al. A two-stage cyclic fluidized bed process for converting hydrogen chloride to chlorine[J]. Chemical Engineering Science,1996,51(10):2031-2039.
[4] 乔旭,陈献,汤吉海,等. 一种氯化氢氧化催化剂及其制备方法:101357337[P]. 2009-02-04. QIAO X,CHEN X,TANG J H,et al. A method of catalyst preparation for hydrogen oxidation:101357337[P]. 2009-02-04.
[5] AGNEW J B,SHANKAR H S. Catalyst deactivation in acetylene hydrochlorination[J]. Industrial & Engineering Chemistry Product Research & Development,1986,25(1):19-22.
[6] PEREZRAMIREZ J,MONDELLI C,SCHMIDT T,et al. Sustainable chlorine recycling via catalysed HCl oxidation:from fundamentals to implementation[J]. Energy & Environmental Science,2011,4(12):4786-4799.
[7] MOTUPALLY S,MAH D T,FREIRE F J,et al. Recycling chlorine from hydrogen chloride:a new and economical electrolytic process[J]. Electrochemical Society Interface,1998,7(3):32-36.
[8] IWANAGA K,SEKI K,HIBI T,et al. The development of improved hydrogen chloride oxidation process[J]. Sumitomo Kagaku,2004,Ⅰ:1-11.
[9] 付振波,余正祥,陈烈峰. 盐酸电解工艺及概况[J]. 氯碱工业,2004(10):9,33. FU Z B,YU Z X,CHEN L F. Hydrochloric acid electrolysis process and its general situation[J]. Chlor-Alkali Industry,2004(10):9,33.
[10] SCHMITTINGER P,FLORKIEWICZ T,CURLIN L C,et al. Chlorine[M]//Ullmann's Encyclopedia of Industrial Chemistry. Weinheim:Wiley-VCH,2006:860-863.
[11] YEAGER Ernest,BINDRA Perminder. Sauerstoff-verzehrkathoden für die chloralkali-elektrolyse[J]. Chemie Ingenieur Technik,1980,52:384-391.
[12] DEACON H. Manufacture of chlorine:US85370[P]. 1868-12-29.
[13] MORTENSEN M,MINET R G,TSOTSIS T T,et al. A two-stage cyclic fluidized bed process for converting hydrogen chloride to chlorine[J]. Chemical Engineering Science,1996,51(10):2031-2039.
[14] HISHAM M W M,BENSON S W. Thermochemistry of the Deacon process[J]. Journal of Physical Chemistry,1995,99(16):6194-6198.
[15] WATTIMENA F,SACHTLER W M H. Catalyst research for the shell chlorine process[J]. Studies in Surface Science & Catalysis B,1981,7:816-827.
[16] 吴玉龙,魏飞,韩明汉,等. 回收利用副产氯化氢制氯气的研究进展[J]. 过程工程学报,2004,4(3):269-275. WU Y L,WEI F,HAN M H,et al. Research progress of recycling chlorine from hydrogen chloride[J]. The Chinese Journal of Process Engineering,2004,4(3):269-275.
[17] YOSHIKAWA Y,HIHARA T,YAMADA K,et al. Chromium oxide catalyst impregnation regeneration method:US5093292[P]. 1992-03-03.
[18] AMRUTE A P,MONDELLI C,PEREZ-RAMIREZ J. Kinetic aspects and deactivation behaviour of chromia-based catalysts in hydrogen chloride oxidation[J]. Catalysis Science & Technology,2012,2(10):2057-2065.
[19] TANG J,CHEN X,FEI Z,et al. HCl oxidation to recycle Cl₂ over a Cu/Ce composite oxide catalyst. Part 1. Intrinsic kinetic study[J]. Industrial & Engineering Chemistry Research,2013,52(34):11897-11903.
[20] Shell Int Research. Process for the preparation of chlorine,bromine or iodine and for the preparation of halogenated hydrocarbons:GB1046313[P]. 1966-10-19.
[21] IBI T,NISHIDA H,ABEKAWA H. Process for producing chlorine:US5871707[P]. 1999-02-16.
[22] WOLF A,MLECZKO L,SCHLÜTER O F,et al. Processes and apparatus for the production of chlorine by gas phase oxidation:US20070274897A1[P]. 2007-11-29.
[23] HAMMES M,VALTCHEV M,ROTH M B,et al. A search for alternative Deacon catalysts[J]. Applied Catalysis B:Environmental,2013,s132/133(1):389-400.
[24] MOSER M,MONDELLI C,AMRUTE A P,et al. HCl oxidation on IrO₂-based catalysts:from fundamentals to scale-up[J]. ACS Catalysis,2015,3(12):2813-2822.
[25] AMRUTE A P,KRUMEICH F,MONDELLI C,et al. Depleted uranium catalysts for chlorine production[J]. Chemical Science,2013,4(5):2209-2217.
[26] MOSER M,MONDELLI C,SCHMIDT T,et al. Supported CeO₂,catalysts in technical form for sustainable chlorine production[J]. Applied Catalysis B:Environmental,2013,s 132/133(9):123-131.
[27] ALESSANDRO Trovarelli. Catalytic properties of ceria and CeO₂-containing materials[J]. Catalysis Reviews,1996,38(4):439-520.
[28] HAGEMEYER A,TRÜBENBACH P,RIEKER C W,et al. Process for the production of chlorine from hydrogen chloride:EP0761594[P]. 1999-06-16.
[29] AMRUTE A P,MONDELLI C,HEVIA M A G,et al. Mechanism-performance relationships of metal oxides in catalyzed HCl oxidation[J]. ACS Catalysis,2011,1(1):583-590.
[30] LOPEZ N,GOMEZ-SEGURA J,MARIN R P. Mechanism of HCl oxidation (Deacon process) over RuO₂[J]. Journal of Catalysis,2008,255(1):29-39.
[31] AMRUTE A P,MONDELLI C,MOSER M,et al. Performance,structure,and mechanism of CeO₂,in HCl oxidation to Cl₂[J]. Journal of Catalysis,2012,286(4):287-297.
[32] MOSER M,VILE G,COLUSSI S,et al. Structure and reactivity of ceria-zirconia catalysts for bromine and chlorine production via the oxidation of hydrogen halides[J]. Journal of Catalysis,2015,331(5):444-447.
[33] KATTA L,SUDARSANAM P,THRIMURTHULU G,et al. Doped nanosized ceria solid solutions for low temperature soot oxidation:zirconium versus lanthanum promoters[J]. Applied Catalysis B:Environmental,2010,101(1/2):101-108.
[34] 徐希化,费兆阳,陈献,等. 气凝胶骨架镶嵌的CeO₂纳米团簇催化氧化HCl制Cl₂[J]. 化工学报,2015,66(9):3421-3427. XU X H,FEI Z Y,CHEN X,et al. CeO₂ nanoclusters stabilized in aerogel matrix as catalysts for chlorine production from hydrogen chloride oxidation[J]. CIESC Journal,2015,66(9):3421-3427.
[35] CHEN X,XU X H,FEI Z Y,et al. CeO₂ nanodots embedded in a porous silica matrix as an active yet durable catalyst for HCl oxidation[J]. Catalysis Science & Technology,2016,6(13):5116-5123.
[36] RYNKOWSKI J,FARBOTKO J,TOUROUDE R,et al. Redox behaviour of ceria-titania mixed oxides[J]. Applied Catalysis A:General,2000,203(2):335-348.
[37] TROVARELLI A,BOARO M,ROCCHINI E,et al. Some recent developments in the characterization of ceria-based catalysts[J]. Journal of Alloys & Compounds,2001,32(41):584-591.
[38] FARRA R,GARCIA-MELCHOR M,EICHEIBAUM M,et al. Promoted ceria:a structural,catalytic,and computational study[J]. ACS Catalysis,2015,3(10):2256-2268.
[39] 谢兴星,费兆阳,戴勇,等. 铈基复合氧化物的结构及其对HCl催化氧化性能的影响[J]. 分子催化,2014,28(6):507-514. XIE X X,FEI Z Y,DAI Y,et al. Structure of ceria-based mixed oxides and its influence on HCl catalytic oxidation performance[J]. Journal of Molecular Catalysis(China),2014,28(6):507-514.
[40] URBAN S,TARABANKO N,KANZLER C H,et al. Stable and active mixed Zr-Ce oxides for catalyzing the gas phase oxidation of HCl[J]. Catalysis Letters,2013,143(12):1362-1367.
[41] MÖLLER M,OVER H,SMARSLY B,et al. Electrospun ceria-based nanofibers for the facile assessment of catalyst morphological stability under harsh HCl oxidation reaction conditions[J]. Catalysis Today,2015,253:207-218.
[42] FEI Z Y,XIE X X,DAI Y,et al. HCl oxidation for sustainable Cl₂ recycle over the Ce_xZr_1-xO₂ catalysts:effects of Ce/Zr ratio on activity and stability[J]. Industrial & Engineering Chemistry Research,2014,53(50):19438-19445.
[43] MOSER M,VILE G,COLUSSI S,et al. Structure and reactivity of ceria-zirconia catalysts for bromine and chlorine production via the oxidation of hydrogen halides[J]. Journal of Catalysis,2015,331(5):128-137.
[44] 刘皓月,费兆阳,戴勇,等. 高比表面Ce_xTi_1-xO₂催化剂的结构表征及其HCl催化氧化性能[J]. 分子催化,2014(4):329-335. LIU H Y,FEI Z Y,DAI Y,et al. Structure characterization and catalytic performance of high surface area Ce_xTi_1-xO₂ catalysts in HCl oxidation[J]. Journal of Molecular Catalysis(China),2014(4):329-335.
[45] 陈献,吕高明,汤吉海,等. 负载于Y分子筛的纳米Ce-Cu-K催化剂制备及其性能研究[J]. 高校化学工程学报,2011,25(1):109-113. CHEN X,LV G M,TANG J H,et al. Research on preparation of nano complex Ce-Cu-K catalyst loaded in the Y-type zeolite and its performance[J]. Journal of Chemical Engineering of Chinese Universities,2011,25(1):109-113.
[46] 陈献,乔旭,汤吉海,等. 稀土-Cu-K/Y分子筛催化剂的制备与性能研究[J]. 高校化学工程学报,2008,22(1):118-121. CHEN X,QIAO X,TANG J H,et al. Preparation and catalytic performance of rare earth composite molecular sieve catalyst[J]. Journal of Chemical Engineering of Chinese Universities,2008,22(1):118-121.
[47] FEI Z Y,LIU H Y,DAI Y,et al. Efficient catalytic oxidation of HCl to recycle Cl₂,over the CuO-CeO₂,composite oxide supported on Y type zeolite[J]. Chemical Engineering Journal,2014,257(6):273-280.
[48] AMRUTE A P,MONDELLI C,HEVIA M A G,et al. Mechanism-performance relationships of metal oxides in catalyzed HCl oxidation[J]. ACS Catalysis,2011,1(1):583-590.
[49] FARRA R,WRABETZ S,SCHUSTER M E,et al. Understanding CeO₂ as a Deacon catalyst by probe molecule adsorption and infrared characterisations[J]. Physical Chemistry Chemical Physics,2013,15(10):3454-3465.

氧化铈基HCl氧化循环制Cl₂催化剂研究进展

Research progress in recycle oxidation of HCl to Cl₂ over ceria based catalysts

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	杨寒月, 孔令真, 陈家庆, 孙欢, 宋家恺, 王思诚, 孔标. 微气泡型下向流管式气液接触器脱碳性能[J]. 化工进展, 2023, 42(S1): 197-204.
[2]	杨建平. 降低HPPO装置反应系统原料消耗的PSE[J]. 化工进展, 2023, 42(S1): 21-32.
[3]	王福安. 300kt/a环氧丙烷工艺反应器降耗减排分析[J]. 化工进展, 2023, 42(S1): 213-218.
[4]	王胜岩, 邓帅, 赵睿恺. 变电吸附二氧化碳捕集技术研究进展[J]. 化工进展, 2023, 42(S1): 233-245.
[5]	张明焱, 刘燕, 张雪婷, 刘亚科, 李从举, 张秀玲. 非贵金属双功能催化剂在锌空气电池研究进展[J]. 化工进展, 2023, 42(S1): 276-286.
[6]	时永兴, 林刚, 孙晓航, 蒋韦庚, 乔大伟, 颜彬航. 二氧化碳加氢制甲醇过程中铜基催化剂活性位点研究进展[J]. 化工进展, 2023, 42(S1): 287-298.
[7]	谢璐垚, 陈崧哲, 王来军, 张平. 用于SO₂去极化电解制氢的铂基催化剂[J]. 化工进展, 2023, 42(S1): 299-309.
[8]	杨霞珍, 彭伊凡, 刘化章, 霍超. 熔铁催化剂活性相的调控及其费托反应性能[J]. 化工进展, 2023, 42(S1): 310-318.
[9]	郑谦, 官修帅, 靳山彪, 张长明, 张小超. 铈锆固溶体Ce_0.25Zr_0.75O₂光热协同催化CO₂与甲醇合成DMC[J]. 化工进展, 2023, 42(S1): 319-327.
[10]	戴欢涛, 曹苓玉, 游新秀, 徐浩亮, 汪涛, 项玮, 张学杨. 木质素浸渍柚子皮生物炭吸附CO₂特性[J]. 化工进展, 2023, 42(S1): 356-363.
[11]	王正坤, 黎四芳. 双子表面活性剂癸炔二醇的绿色合成[J]. 化工进展, 2023, 42(S1): 400-410.
[12]	高雨飞, 鲁金凤. 非均相催化臭氧氧化作用机理研究进展[J]. 化工进展, 2023, 42(S1): 430-438.
[13]	王乐乐, 杨万荣, 姚燕, 刘涛, 何川, 刘逍, 苏胜, 孔凡海, 朱仓海, 向军. SCR脱硝催化剂掺废特性及性能影响[J]. 化工进展, 2023, 42(S1): 489-497.
[14]	顾永正, 张永生. HBr改性飞灰对Hg⁰的动态吸附及动力学模型[J]. 化工进展, 2023, 42(S1): 498-509.
[15]	邓丽萍, 时好雨, 刘霄龙, 陈瑶姬, 严晶颖. 非贵金属改性钒钛基催化剂NH₃-SCR脱硝协同控制VOCs[J]. 化工进展, 2023, 42(S1): 542-548.