SO42-/MxOy型固体超强酸催化剂的研究进展

doi:10.16085/j.issn.1000-6613.2017-1325

摘要/Abstract

摘要： SO₄^2-/M_xO_y型固体超强酸催化剂具有活性高、无污染、不腐蚀设备和可重复使用等优点，是一种典型的环境友好型催化剂。本文讨论了浸渍沉淀法、溶胶-凝胶法、低温陈化法和超声波共沉淀法4种制备方法对催化剂催化性能的影响。重点综述了SO₄^2-/M_xO_y型固体超强酸催化剂在载体和活性组分改性方面的研究进展。根据固体超强酸催化剂的结构模型，分析了SO₄^2-/M_xO_y型固体超强酸的成酸机理，介绍了催化剂的失活机理、表征手段以及在各个领域的应用实例，最后对SO₄^2-/M_xO_y型固体超强酸催化剂的结构理论和制备技术进行了展望。

关键词: 固体超强酸, 催化剂, 催化剂载体, 制备, 改性, 应用

Abstract: SO₄^2-/M_xO_y solid superacid catalysts have many advantages such as high activities,less pollution,no corrosion to reactor and easy recycle,so they are a type of typical eco-friendly catalysts. The effects of four preparation methods of impregnation,sol-gel,low-temperature aging and ultrasonic coprecipitation on the catalytic performance of the catalysts were discussed. The research progress in the modification of support and active component of SO₄^2-/M_xO_y solid superacid catalysts was reviewed. According to the structural model of solid superacid catalysts,the mechanism of acid formation of SO₄^2-/M_xO_y solid superacid was analyzed. The deactivation mechanism,characterization methods and some application examples of the catalysts were introduced. Finally,the structure theory and preparation technology of SO₄^2-/M_xO_y solid superacid catalysts were prospected.

Key words: solid superacid, catalyst, catalyst support, preparation, modification, application

中图分类号:

陈焕章, 张悦, 冯雪, 孙朝利. SO₄^2-/M_xO_y型固体超强酸催化剂的研究进展[J]. 化工进展, 2018, 37(05): 1795-1803.

CHEN Huanzhang, ZHANG Yue, FENG Xue, SUN Zhaoli. Research progress of SO₄^2-/M_xO_y solid superacid catalysts[J]. Chemical Industry and Engineering Progress, 2018, 37(05): 1795-1803.

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SO₄^2-/M_xO_y型固体超强酸催化剂的研究进展

Research progress of SO₄^2-/M_xO_y solid superacid catalysts

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