芳烃模型化合物的热转化机理研究进展

doi:10.16085/j.issn.1000-6613.2017-0212

化工进展 ›› 2017, Vol. 36 ›› Issue (S1): 133-141.DOI: 10.16085/j.issn.1000-6613.2017-0212

芳烃模型化合物的热转化机理研究进展

韩乔昆, 范启明, 申海平

中国石化石油化工科学研究院, 北京 100083

收稿日期:2017-02-13 修回日期:2017-03-02 出版日期:2017-12-31 发布日期:2017-12-13
通讯作者: 韩乔昆(1989-),男,硕士研究生,研究方向为重油加工技术。
作者简介:韩乔昆(1989-),男,硕士研究生,研究方向为重油加工技术。E-mail:hqkacq@163.com。

Mechanism research on pyrolysis of aromatic model compounds

HAN Qiaokun, FAN Qiming, SHEN Haiping

Research Institute of Petroleum Processing, SINOPEC, Beijing 100083, China

Received:2017-02-13 Revised:2017-03-02 Online:2017-12-31 Published:2017-12-13

摘要/Abstract

摘要： 在煤和石油加工过程中，芳烃是重要的生焦初始反应物或中间产物。采用热处理方法制备优质炭材料，如针状焦、碳纤维等，反应过程主要是芳烃的热转化行为，包括缩合和裂解等复杂的反应历程。本文综述了近年来国内外学者采用芳烃模型化合物对芳烃液相非催化热转化反应机理的研究，重点介绍了萘、蒽、菲、芘、芴模型化合物的热转化反应机理，并总结了芳烃热转化反应规律。同时，对采用芳烃模型化合物进行共炭化研究进行了概述。通过对比国内外研究进展，指出国内相关研究存在的问题。基于芳烃模型化合物研究现状，展望了采用模型化合物研究芳烃热转化反应机理的发展趋势。现有研究存在理论计算与实验研究相孤立的问题，因而要加强模型化合物分子模拟计算与实验研究的结合。同时，充分利用现代精密分析仪器对实验产物进行分子水平的解析。

关键词: 裸环芳烃, 模型化合物, 热转化, 反应机理

Abstract: In the process of coal and petroleum processing, aromatics are important precursors or intermediate products.The preparation of advanced carbon materials, such as needle coke and carbon fiber, by heat treatment of coke tar or petroleum is mainly about pyrolysis of aromatics, including complex condensation and cracking reactions.In this paper, the study on the mechanism of the non-catalytic liquid phase pyrolysis reactions of aromatic model compounds, including naphthalene, anthracene, phenanthrene, pyrene and fluorine, has been summarized.Also, this paper summarized the rule of pyrolysis of aromatics.By comparing the research achievements of domestic and foreign scholars, this paper points out the existing problems in domestic research.Based on the research status of aromatic hydrocarbon compounds, the trend of the study of aromatic hydrocarbon pyrolysis mechanism was prospected.Previous research has the problem of isolated theoretical calculation and experimental research, so the combination of molecular simulation and experimental research should be strengthened.Meanwhile, modern precision analytical instruments should be fully used to analyze experimental products in molecular level.

Key words: aromatic hydrocarbons, model compounds, pyrolysis, reaction mechanism

中图分类号:

O625.1

韩乔昆, 范启明, 申海平. 芳烃模型化合物的热转化机理研究进展[J]. 化工进展, 2017, 36(S1): 133-141.

HAN Qiaokun, FAN Qiming, SHEN Haiping. Mechanism research on pyrolysis of aromatic model compounds[J]. Chemical Industry and Engineering Progress, 2017, 36(S1): 133-141.

参考文献

[1] KINNEY R,CROWLEY D.Pyrolysis of C2 and C3 hydrocar-bons[J].I&EC,1954,46(2):258-264.
[2] APPLEBY W,GIBSON J,GOOD G.Coke formation[J].I&EC,1962,1(2):102-110.
[3] 张德保.催化裂化油浆制备针状焦过程中中间相的研究[D].北京:石油化工科学研究院,2013.
[4] 苏栋根.石油系针状焦的市场现状与正产技术难点[J].石油化工技术与经济,2013,29(6):23-26.
[5] 马文斌.几种石油系重质原料焦炭化性能对比分析[J].石油炼制与化工,2014,45(9):30-35.
[6] 王朝刚.稠环芳烃炭化行为研究[D].北京:北京化工大学,2014
[7] WALKER P L,WEINSTEIN A.Carbons produced from known organic compounds Ⅰ——anthracene and phenanthrene[J]. Carbon,1967,5:13-17.
[8] LEWIS I C,EDSTROM T.Thermal reactivity of polynuclear aromatic hydrocarbons[J].The Journal of Organic Chemistry,1963,28(8):2050-2057.
[9] YOKONO Tetsuro,MIYAZAWA Kunio,SANDA Yuzo,et al.Relations between free valence and thermal reactivity of polynuclear aromatic hydrocarbons[J].Fuel,1979,58:692-694.
[10] MOCHIDA Isao,SHIMIZU Kiyoyuki,KORAI Yozo.Structure and carbonization properties of pitches produced catalytically from aromatic hydrocarbons with HF/BF3[J].Carbon,1988,26(6):843-852.
[11] LEWIS I C.Thermal polymerization of aromatic hydrocarbon[J]. Carbon,1979,18:191-196.
[12] LEWIS I C.Chemistry of carbonization[J].Carbon,1982,20(6):519-529.
[13] GREINKE R A,LEWIS I C.Carbonization of naphthalene and dimethylnaphthalene[J].Carbon,1983,22(3):305-314.
[14] 凌立成.模型芳烃及燃料系重油液相炭化初期阶段的结构变化[D]太原:中国科学院山西煤炭化学研究所,1988.
[15] WHANG P W,DACHILLE F,WALKER P L.Pressure effects on the initial carbonization reactions of anthracene[J].High Temperatures-High Pressure,1974,6:127-136.
[16] STEIN S E.Thermochemical kinetics of anthracene pyrolysis[J]. Carbon,1981,19(6):421-429.
[17] STEIN S E,GRIFFITH L L, BILLMERS R,et al. Pyrocon-densation of Anthracene[J].J.Org.Chem.,1987,52:1582-1591.
[18] SCARONI A W,JENKINS R G,WALKER P L.Carboniz-ation of Anthracene in a Batch Reactor[J].Carbon,1991,29(7):969-980.
[19] KINNEY C R,NUNN R C,WALKER P L.Carbonization of anthracene and graphitization of anthracene carbons[J].Industrial and Engineering Chemistry,1957,49(5):880-884.
[20] WANG Guohua.Molecular composition of needle coke feedstocks and mesophase development during carbonization[D].Pennsylvania:The Pennsylvania State University,2005.
[21] SASAKI Teruhiko,JENKINS Rotber G,ESER Semih,et al. Carbonization of anthracene and phenanthrene.2. Spectroscopy and mechanism[J].Energy & Fuels,1993,7:1047-1053.
[22] 李中亚.多环芳烃热缩和反应和生焦规律的研究[D].北京:石油化工科学研究院,2016.
[23] MUKHERJEE Jaideep,SAROFIM Adel F,LONGWELL John P.Polycyclic aromatic hydrocarbons from the high-temperature pyrolysis of pyrene[J].Combustion and Flame,1994,96:191-200.
[24] ESGUERRA David F,HOFFMAN Wesley P,THIES Mark C.Molecular structure of the constituents of pyrene pitchs[J].Fuel,2014,124:133-140
[25] MARSH H,DACHILLE F,MELVIN J,et al. The carbonization of anthracene and biphenyl ender pressures of 300MNm-2(3kbar)[J].Carbon,1971,9:159-177.
[26] LEWIS I C,KOVAC C A.The role of radicals and molecular size in mesophase pitch[J].Carbon,1978,16:425-429.

芳烃模型化合物的热转化机理研究进展

Mechanism research on pyrolysis of aromatic model compounds

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