钠离子电池正极材料Na0.44MnO2的研究进展

doi:10.16085/j.issn.1000-6613.2017-0015

摘要/Abstract

摘要： 钠离子电池的研究开发在国内外处于迅速发展的浪潮中，而具有隧道结构的Na_0.44MnO₂作为正极材料具有既可以支持高能量密度和长循环寿命的非水电解质电池，也可以支持安全和高倍率的水溶液电解质电池的优点，成为一个重要的研究热点。本文比较系统地综述了Na_0.44MnO₂作为钠离子电池正极材料的研究现状，从晶体结构和充放电机理等方面进行了讨论，重点阐述了Na_0.44MnO₂材料的合成方法以及不同的合成方法对其结构形貌和电化学性能的影响，同时，也介绍了Na_0.44MnO₂材料在全电池和水系电池中的应用现状和前景以及对Na_0.44MnO₂正极材料掺杂和表面包覆等改性方面的研究进展，并且总结分析了改性工艺对其结构与电化学性能的影响，认为Na_0.44MnO₂材料对于钠离子电池仍具有极大的科研价值和应用前景。

关键词: 钠离子电池, 正极材料, 锰酸钠, 电化学, 合成, 纳米材料

Abstract: Sodium-ion secondary batteries have attracted global attentions nowadays,and the tunnel-structure-crystalized Na_0.44MnO₂,as one of the main cathode materials,not only well provides the non-aqueous batteries with high energy density and outstanding cyclic stability,but also applies promisingly in the safe and high rate aqueous batteries. To summarize the relevant progress,the crystal structure,principles of charging and discharging of Na_0.44MnO₂ are discussed with the focus on the synthesis methods and their effects on the structure and electrochemical properties of Na_0.44MnO₂. In addition,the applications of Na_0.44MnO₂ material in the full-cells and the aqueous batteries and the recent research progress on the doping and coating modification of this material are also briefly introduced. It is concluded that Na_0.44MnO₂ material has great scientific value and application prospects as sodium-ion battery cathode material in the future.

Key words: sodium ion battery, cathode material, Na_0.44MnO₂, electrochemistry, synthesis, nanomaterials

中图分类号:

TM912.9

史文静, 燕永旺, 徐守冬, 陈良, 刘世斌, 张鼎. 钠离子电池正极材料Na_0.44MnO₂的研究进展[J]. 化工进展, 2017, 36(09): 3343-3352.

SHI Wenjing, YAN Yongwang, XU Shoudong, CHEN Liang, LIU Shibin, ZHANG Ding. Research progress of sodium manganate oxide Na_0.44MnO₂ as cathode for sodium-ion batteries[J]. Chemical Industry and Engineering Progress, 2017, 36(09): 3343-3352.

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钠离子电池正极材料Na_0.44MnO₂的研究进展

Research progress of sodium manganate oxide Na_0.44MnO₂ as cathode for sodium-ion batteries

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