Ni-Fe基析氧阳极材料的研究进展

doi:10.16085/j.issn.1000-6613.2016.07.017

化工进展 ›› 2016, Vol. 35 ›› Issue (07): 2057-2062.DOI: 10.16085/j.issn.1000-6613.2016.07.017

Ni-Fe基析氧阳极材料的研究进展

何杨华¹, 徐金铭¹, 王发楠¹, 毛庆², 黄延强¹

1. 中国科学院大连化学物理研究所航天催化与新材料研究室, 辽宁大连 116023;
2. 大连理工大学化工学院, 辽宁大连 116024

收稿日期:2015-09-25 修回日期:2016-02-12 出版日期:2016-07-05 发布日期:2016-07-05
通讯作者: 毛庆,博士,副教授,从事燃料电池诊断及电极反应动力学的非线性谱学研究;黄延强,博士,副研究员,从事负载型高分散金属催化剂的制备以及结合高分辨电镜等技术的表征工作。
作者简介:何杨华(1990-),女,本科,从事Ni-Fe基析氧阳极材料的制备与应用研究。E-mail:yanghuahe@hotmail.com。
基金资助:
国家自然科学基金项目(21403029,21403218,21476226)。

Recent advances in Ni-Fe-based electrocatalysts for oxygen evolution reaction

HE Yanghua¹, XU Jinming¹, WANG Fanan¹, MAO Qing², HUANG Yanqiang¹

1. Laboratory of Catalysts and New Materials for Aerospace, Dalian Institution of Chemical Physics, Chinese Academy of Science, Dalian 116023, Liaoning, China;
2. School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning, China

Received:2015-09-25 Revised:2016-02-12 Online:2016-07-05 Published:2016-07-05

摘要/Abstract

摘要： 寻找一种高效、稳定和低成本的析氧阳极材料对于在碱性环境中电解水的研究具有非常重要的实际意义。近年来,Ni-Fe基材料以其低成本及在碱性条件下具有高催化活性的特点成为析氧反应电极材料的研究热点。本文概述了近几年国内外学者对不同的Ni-Fe基析氧材料(包括Ni-Fe合金、Ni-Fe氧化物、Ni-Fe层状双金属氢氧化物及Ni-Fe基复合材料等)在合成方法、物理形态、化学结构和催化性能等方面所进行的研究,介绍了Ni-Fe基材料的析氧反应机理的进展,探究了析氧反应活性相以及Fe的掺入对Ni基氢氧化物的结构和活性的影响,最后指出了合成方法的改进及详细反应机理的探究将会成为未来Ni-Fe基析氧阳极材料的重点研究方向。

关键词: Ni-Fe基材料, 催化剂, 电解, 析氧反应, 反应动力学

Abstract: Highly efficient, stable, and low cost electrocatalysts for the oxygen evolution reaction (OER) to evolve oxygen gas are key to water-splitting in alkaline media. Recently, researchers have designed advanced Ni-Fe-based OER electrocatalysts with higher catalytic activity for efficient and durable water electrolysis. In this review, we present the latest progress in advanced Ni-Fe-based materials with excellent activity and stability, including Ni-Fe-based alloy, oxide and layered double hydroxide and their composites. Furthermore, detailed OER electrocatalysis mechanisms for Ni-Fe based materials are discussed to provide insight into the nature of active catalytic sites as well as the effect of Fe incorporated in Ni-based electrocatalsyts. Finally, it is also pointed out that the future studies should focus on the development of novel Ni-Fe-based materials with superior catalytic activity and the detailed mechanisms responsible for improved OER activity.

Key words: Ni-Fe based materials, catalyst, electrolysis, oxygen evolution reaction, reaction kinetics

中图分类号:

TQ151.1

何杨华, 徐金铭, 王发楠, 毛庆, 黄延强. Ni-Fe基析氧阳极材料的研究进展[J]. 化工进展, 2016, 35(07): 2057-2062.

HE Yanghua, XU Jinming, WANG Fanan, MAO Qing, HUANG Yanqiang. Recent advances in Ni-Fe-based electrocatalysts for oxygen evolution reaction[J]. Chemical Industry and Engineering Progree, 2016, 35(07): 2057-2062.

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Ni-Fe基析氧阳极材料的研究进展

Recent advances in Ni-Fe-based electrocatalysts for oxygen evolution reaction

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