含氯挥发性有机化合物催化燃烧催化剂的研究进展

doi:10.16085/j.issn.1000-6613.2016.02.023

化工进展 ›› 2016, Vol. 35 ›› Issue (02): 499-505.DOI: 10.16085/j.issn.1000-6613.2016.02.023

含氯挥发性有机化合物催化燃烧催化剂的研究进展

阚家伟¹, 李兵¹, 李林¹, 王小军¹, 陈英文¹, 祝社民², 沈树宝¹

1 南京工业大学生物与制药工程学院, 江苏南京 210009;
2 南京工业大学材料科学与工程学院, 江苏南京 210009

收稿日期:2015-05-19 修回日期:2015-08-16 出版日期:2016-02-05 发布日期:2016-02-05
通讯作者: 陈英文,副教授,硕士生导师,主要从事大气污染处理技术及环保工程材料开发与应用。E-mail:ywchen@njtech.edu.cn。
作者简介:阚家伟(1991-),男,硕士研究生。E-mail:kanjw@njtech.edu.cn。
基金资助:
国家自然科学基金(21106072)及江苏省高校自然科学基金(14KJB430014)项目。

Advances in catalysts for catalytic combustion of chlorinated volatile organic compounds

KAN Jiawei¹, LI Bing¹, LI Lin¹, WANG Xiaojun¹, CHEN Yingwen¹, ZHU Shemin², SHEN Shubao¹

1 College of Biological and Pharmaceutical Engineering, Nanjing Tech. University, Nanjing 210009, Jiangsu, China;
2 College of Materials Science and Engineering, Nanjing Tech. University, Nanjing 210009, Jiangsu, China

Received:2015-05-19 Revised:2015-08-16 Online:2016-02-05 Published:2016-02-05

摘要/Abstract

摘要： 含氯挥发性有机化合物(CVOCs)是一类重要的大气污染物,催化燃烧是实现CVOCs高效减排的一种主流处理技术,但工艺过程中存在氯元素易吸附在催化剂表面致使催化剂失活的问题。本文从催化燃烧CVOCs的反应机理、催化剂活性组分、催化剂载体等几个方面,对近年来催化燃烧处理CVOCs的研究进行了综述,其中催化活性组分可分为以钌、钯为主的贵金属催化剂和集中在高活性的过渡金属复合氧化物、钙钛矿型非贵金属催化剂,并重点阐述了水蒸气对催化燃烧CVOCs反应活性的影响及机制。根据国内外研究状况和技术水平,提出了催化燃烧技术的研究及发展方向,充分利用一定浓度水蒸气的优点抑制催化剂氯中毒及产生较低含量的副产物,为CVOCs高效工业化处理提供了重要的参考。

关键词: 含氯挥发性有机化合物, 催化燃烧, 催化剂, 催化剂载体, 水蒸气

Abstract: Chlorinated volatile organic compounds(CVOCs) is a class of important air pollutants and catalytic combustion is a mainstream processing technology in efficiently reducing CVOCs' emission,but that chlorine is easily adsorbed on the catalyst surface has resulted in the deactivation of the catalyst in the process. In this paper,the recent development in catalytic combustion of CVOCs with regard to reaction mechanism,active species,catalyst supports were examined,active species of catalysts can be divided into noble metal catalysts based on ruthenium,palladium and concentrated transition metal composite oxide,perovskite type non-noble metal catalysts with high activity. Additionally,the mechanism and effect of water vapor on catalytic combustion process is discussed. According to the global research status,research and development directions of the catalysts for catalytic combustion in the future are presented. Taking full advantages of a certain concentration of water vapor to inhibit chlorine poisoning of catalyst and producing fewer by-products provide an important reference for the industrialization of CVOCs destructed by catalytic combustion.

Key words: chlorinated volatile organic compounds, catalytic combustion, catalysts, catalyst supports, water vapor

中图分类号:

O643

阚家伟, 李兵, 李林, 王小军, 陈英文, 祝社民, 沈树宝. 含氯挥发性有机化合物催化燃烧催化剂的研究进展[J]. 化工进展, 2016, 35(02): 499-505.

KAN Jiawei, LI Bing, LI Lin, WANG Xiaojun, CHEN Yingwen, ZHU Shemin, SHEN Shubao. Advances in catalysts for catalytic combustion of chlorinated volatile organic compounds[J]. Chemical Industry and Engineering Progree, 2016, 35(02): 499-505.

参考文献

[1] 张广宏,赵福真,季生福,等. 挥发性有机物催化燃烧消除的研究进展[J]. 化工进展,2007,26(5):624-631.
[2] LI W B,WANG J X,GONG H. Catalytic combustion of VOCs on non-noble metal catalysts[J]. Catalysis Today,2009,148(1):81-87.
[3] WU M,UNG K C,DAI Q,et al. Catalytic combustion of chlorinated VOCs over VO_x/TiO₂ catalysts[J]. Catalysis Communications,2012,18(1):72-75.
[4] MA R,HU P,JIN L,et al. Characterization of CrO_x/Al₂O₃ catalysts for dichloromethane oxidation[J]. Catalysis Today,2011,175(1):598-602.
[5] INTRIAGO L,DÍAZ E,ORDÓÑEZ S,et al. Combustion of trichloroethylene and dichloromethane over protonic zeolites:influence of adsorption properties on the catalytic performance[J]. Microporous & Mesoporous Materials,2006,91(1):161-169.
[6] 王争一. Ru/Ce-Al₂O₃催化剂催化燃烧氯苯和二氯甲烷的研究[D]. 上海:华东理工大学,2012.
[7] RINZEMA L C,SILVERSTEIN L G. Hazards from chlorinated hydrocarbon decomposition during welding[J]. American Industrial Hygiene Association Journal,2010,33(1):35-40.
[8] 李梦,杜刚. 挥发性有机废气治理技术的现状与进展[J]. 化工进展,2009,28(10):1833-1841.
[9] 潘红艳,张煜,林倩,等. 催化燃烧VOCs用非贵金属催化剂研究新进展[J]. 化工进展,2011,30(8):1726-1732.
[10] WU M,WANG X Y,DAI Q G,et al. Low temperature catalytic combustion of chlorobenzene over Mn-Ce-O/γ-Al₂O₃ mixed oxides catalyst[J]. Catalysis Today,2010,158(3/4):336-342.
[11] TARALUNGA M,MIJOIN J,MAGNOUX P. Catalytic destruction of chlorinated POPs—catalytic oxidation of chlorobenzene over PtHFAU catalysts[J]. Applied Catalysis B:Environmental,2005,60:163-171.
[12] DAI Q G,BAI S X,WANG X Y,et al. Catalytic combustion of chlorobenzene over Ru-doped ceria catalysts:mechanism study[J]. Applied Catalysis B:Environmental,2013,129(3):580-588.
[13] SINQUIN G,PETIT C,LIBS S,et al. Catalytic destruction of chlorinated C₁ volatile organic compounds (CVOCs) reactivity,oxidation and hydrolysis mechanisms[J]. Applied Catalysis B:Environmental,2000,27(2):105-115.
[14] ZHANG L L,LIU S Y,WANG G Y,et al. Catalytic combustion of dichloromethane over NaFAU and HFAU zeolites:a combined experimental and theoretical study[J]. Reaction Kinetics,Mechanisms and Catalysis,2014,112(1):249-265.
[15] DAI Q G,BAI S X,WANG J W,et al. The effect of TiO₂ doping on catalytic performances of Ru/CeO₂ catalysts during catalytic combustion of chlorobenzene[J]. Applied Catalysis B:Environmental,2013,142(5):222-233.
[16] FINOCCHIO E,RAMIS G,BUSCA G. A study on catalytic combustion of chlorobenzenes[J]. Catalysis Today,2011,169(1):3-9.
[17] GIRAUDON J M,ELHACHIMI A,LECLERCQ G. Catalytic oxidation of chlorobenzene over Pd/perovskites[J]. Applied Catalysis B:Environmental,2008,84:251-261.
[18] HE Chi,MEN Gaoshan,YU Yanke,et al. Chlorobenzene destruction over mesostructured CuO and MnO_x Co-Modified CeO₂ catalyst:activityand activation route[J]. Water Air Soil Pollut,2015,226:57.
[19] ZHAO P,WANG C,HE F,et al. Effect of ceria morphology on the activity of MnO_x/CeO₂ catalysts for the catalytic combustion of chlorobenzene[J]. RSC Advances,2014,86(86):45665-45672.
[20] 宋灿,易全瑞,李经纬,等. 不同形貌Mn₂O₃的制备及其催化氧化氯苯性能的研究[J]. 功能材料,2014(13):13050-13055.
[21] ROZDYALOVSKAYA T,CHEKRYSHKIN Y,FEDOROV A,et al. Deep oxidation of chlorobenzene on complex catalysts[J]. Russian Journal of Applied Chemistry,2010,83(8):1466-1469.
[22] 黄海凤,宁星杰,蒋孝佳,等. V-M/TiO₂(M=Cu、Cr、Ce、Mn、Mo)催化燃烧含氯有机废气[J]. 中国环境科学,2014(9):2179-2185.
[23] WANG X,KANG Q,LI D. Low-temperature catalytic combustion of chlorobenzene over MnO_x-CeO₂ mixed oxide catalysts[J]. Catalysis Communications,2008,9(13):2158-2162.
[24] LU Y J,DAI Q G,WANG X Y. Catalytic combustion of chlorobenzene on modified LaMnO₃ catalysts[J]. Catalysis Communications,2014,54:114-117.
[25] 刘亚芹,蔡文祥,余中平,等. 钙钛矿型La_0.8Sr_0.2MnO₃催化剂对氯苯催化燃烧的性能研究[J]. 浙江工业大学学报,2007,35(5):477-481.
[26] ZHANG C H,WANG C,ZHAN W C,et al. Catalytic oxidation of vinyl chloride emission over LaMnO₃ and LaB_0.2Mn_0.8O₃ (B=Co,Ni,Fe) catalysts[J]. Applied Catalysis B:Environmental,2013,129(3):509-516.
[27] DAI Q G,BAI S X,WANG X Y,et al. Facile synthesis of HZSM-5 with controlled crystal morphology and size as efficient catalysts for chlorinated hydrocarbons oxidation and xylene isomerization[J]. Journal of Porous Materials,2014,21(6):1041-1049.
[28] HUANG H,GU Y,ZHAO J,et al. Catalytic combustion of chlorobenzene over VO_x/CeO₂ catalysts[J]. Journal of Catalysis,2015,326:54-68.
[29] MICHALIK-ZYM A,DULA R,DURACZYŃSKA D,et al. Active,selective and robust Pd and/or Cr catalysts supported on Ti-,Zr- or [Ti,Zr]-pillared montmorillonites for destruction of chlorinated volatile organic compounds[J]. Applied Catalysis B:Environmental,2015,174:293-307.
[30] 孙忠,吴婷婷,潘烈群,等. 各类VOCs在蜂窝陶瓷型La_(0.8)Sr_(0.2)MnO₃催化剂上的催化燃烧性能[J]. 环境工程学报,2010(8):1863-1866.
[31] 龚浩,黎维彬. 1,2-二氯乙烷在担载铈钛复合氧化物的蜂窝陶瓷催化净化[J]. 中国粉末技术,2010,16(2):1-3.
[32] CEN W L,LIU Y,WU Z B,et al. Cl species transformation on CeO₂(111) surface and its effects on CVOCs catalytic abatement:a first-principles investigation[J]. J. Phys. Chem. C,2014,118(13):6758-6766.
[33] BERTINCHAMPS F,ATTIANESE A,MESTDAGH M M,et al. Catalysts for chlorinated VOCs abatement:MULTIPLE effects of water on the activity of VO_x based catalysts for the combustion of chlorobenzene[J]. Catalysis Today,2006,112(1/2/3/4):165-168.
[34] DAI Q G,WANG X Y,LU G Z. Low-temperature catalytic destruction of chlorinated VOCs over cerium oxide[J]. Catalysis Communications,2007,8(11):1645-1649.
[35] PERSSON K,PFEFFERLE L D,SCHWARTZ W,et al. Stability of palladium-based catalysts during catalytic combustion of methane:THE influence of water[J]. Applied Catalysis B:Environmental,2007,74:242-250.
[36] LÓPEZ-FONSECA R,GUTIÉRREZ-ORTIZ J I,GUTIÉRREZ-ORTIZ M A,et al. Catalytic oxidation of aliphatic chlorinated volatile organic compounds over Pt/H-BETA zeolite catalyst under dry and humid conditions[J]. Catalysis Today,2005,44:200-207.

含氯挥发性有机化合物催化燃烧催化剂的研究进展

Advances in catalysts for catalytic combustion of chlorinated volatile organic compounds

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	张明焱, 刘燕, 张雪婷, 刘亚科, 李从举, 张秀玲. 非贵金属双功能催化剂在锌空气电池研究进展[J]. 化工进展, 2023, 42(S1): 276-286.
[2]	时永兴, 林刚, 孙晓航, 蒋韦庚, 乔大伟, 颜彬航. 二氧化碳加氢制甲醇过程中铜基催化剂活性位点研究进展[J]. 化工进展, 2023, 42(S1): 287-298.
[3]	谢璐垚, 陈崧哲, 王来军, 张平. 用于SO₂去极化电解制氢的铂基催化剂[J]. 化工进展, 2023, 42(S1): 299-309.
[4]	杨霞珍, 彭伊凡, 刘化章, 霍超. 熔铁催化剂活性相的调控及其费托反应性能[J]. 化工进展, 2023, 42(S1): 310-318.
[5]	许家珩, 李永胜, 罗春欢, 苏庆泉. 甲醇水蒸气重整工艺的优化[J]. 化工进展, 2023, 42(S1): 41-46.
[6]	王乐乐, 杨万荣, 姚燕, 刘涛, 何川, 刘逍, 苏胜, 孔凡海, 朱仓海, 向军. SCR脱硝催化剂掺废特性及性能影响[J]. 化工进展, 2023, 42(S1): 489-497.
[7]	邓丽萍, 时好雨, 刘霄龙, 陈瑶姬, 严晶颖. 非贵金属改性钒钛基催化剂NH₃-SCR脱硝协同控制VOCs[J]. 化工进展, 2023, 42(S1): 542-548.
[8]	程涛, 崔瑞利, 宋俊男, 张天琪, 张耘赫, 梁世杰, 朴实. 渣油加氢装置杂质沉积规律与压降升高机理分析[J]. 化工进展, 2023, 42(9): 4616-4627.
[9]	王鹏, 史会兵, 赵德明, 冯保林, 陈倩, 杨妲. 过渡金属催化氯代物的羰基化反应研究进展[J]. 化工进展, 2023, 42(9): 4649-4666.
[10]	张启, 赵红, 荣峻峰. 质子交换膜燃料电池中氧还原反应抗毒性电催化剂研究进展[J]. 化工进展, 2023, 42(9): 4677-4691.
[11]	王伟涛, 鲍婷玉, 姜旭禄, 何珍红, 王宽, 杨阳, 刘昭铁. 醛酮树脂基非金属催化剂催化氧气氧化苯制备苯酚[J]. 化工进展, 2023, 42(9): 4706-4715.
[12]	葛亚粉, 孙宇, 肖鹏, 刘琦, 刘波, 孙成蓥, 巩雁军. 分子筛去除VOCs的研究进展[J]. 化工进展, 2023, 42(9): 4716-4730.
[13]	吴海波, 王希仑, 方岩雄, 纪红兵. 3D打印催化材料开发与应用进展[J]. 化工进展, 2023, 42(8): 3956-3964.
[14]	向阳, 黄寻, 魏子栋. 电催化有机合成反应的活性和选择性调控研究进展[J]. 化工进展, 2023, 42(8): 4005-4014.
[15]	王耀刚, 韩子姗, 高嘉辰, 王新宇, 李思琪, 杨全红, 翁哲. 铜基催化剂电还原二氧化碳选择性的调控策略[J]. 化工进展, 2023, 42(8): 4043-4057.