三乙醇胺与烯胺混合胺液脱碳性能及配比优选实验研究

doi:10.16085/j.issn.1000-6613.2015.01.017

化工进展 ›› 2015, Vol. 34 ›› Issue (1): 95-101.DOI: 10.16085/j.issn.1000-6613.2015.01.017

三乙醇胺与烯胺混合胺液脱碳性能及配比优选实验研究

周丹¹, 陈杰¹, 花亦怀¹, 唐建峰², 褚洁¹, 冯颉¹, 王曰²

1 中海石油气电集团技术研发中心, 北京 100027;
2 中国石油大学(华东)储运与建筑工程学院, 山东青岛 266580

收稿日期:2014-04-26 修回日期:2014-05-15 出版日期:2015-01-05 发布日期:2015-01-05
通讯作者: 唐建峰,博士,副教授。E-mail tangpaper@126.com。
作者简介:周丹(1964-),男,硕士,高级工程师,中海石油气电集团研发中心总工程师,主要负责天然气液化技术及相关液化装置设计建设等研究开发工作。
基金资助:
国家工信部浮式液化天然气生产储卸(LNG-FPSO)总体设计关键技术。

Experimental study on performance and proportion optimization of TEA+enamine mixed solution for natural gas decarburization

ZHOU Dan¹, CHEN Jie¹, HUA Yihuai¹, TANG Jianfeng², CHU Jie¹, FENG Jie¹, WANG Yue²

1 CNOOC Gas & Power Group Research & Development Center, Beijing 100027, China;
2 School of Pipeline and Civil Engineering, China University of Petroleum (East China), Qingdao 266580, Shandong, China

Received:2014-04-26 Revised:2014-05-15 Online:2015-01-05 Published:2015-01-05

摘要/Abstract

摘要： 胺法脱碳以其脱除效果好、能耗低等优点在天然气预处理中得到广泛应用。目前国内外普遍采用以甲基二乙醇胺为主体的复配胺液为吸收剂,为适应寻找经济、高效的新型吸收剂的需求,本文选取同为叔胺的三乙醇胺(TEA)为主体进行实验研究,在TEA反应机理的研究基础上,添加二乙烯三胺/三乙烯四胺(DETA/TETA)进行混合胺液的吸收解吸性能分析,对比优选出综合表现较好的混合胺液,考察其不同配比下吸收、解吸及贴近实际生产的循环利用效果,完成配比优选研究。结果表明:添加烯胺后,可大大提高吸收性能,但会降低解吸效果;TEA+DETA吸收和解吸性能优于TEA+TETA;TEA+DETA的优选配比为2.0/1.0和2.4/0.6;经循环实验验证,2mol/L TEA+1mol/L DETA综合效果最佳。

关键词: 三乙醇胺, 烯胺, 天然气脱碳, 混合胺液, 吸收, 解吸, 循环实验

Abstract: Decarburization by mixed amine solution has been widely used because of its good purification ability and low energy consumption. MDEA is used as the main absorbent in the mixed amines. In order to meet the demands of finding economical and highly efficient new absorbents, TEA was selected as the main amine solution for experimental study in this paper, which was tertiary amine, the same as MDEA. Based on the study of TEA solution reaction mechanism, the absorption and desorption performance of the TEA+DETA/TETA mixed amine solutions with different concentrations were studied experimentally, and the better amine solution was selected based on comprehensive performance. Enamines could promote absorption ability, but it would reduce desorption performance. The absorption and desorption performance of the TEA+DETA mixed amine solution was better than the TEA+TETA mixed amine solution. The mixed amine solutions with DETA concentrations of 1mol/L and 0.6mol/L were better. According to cycle experiments, the comprehensive performance of the mixed amine solution with DETA concentration of 1mol/L was the best.

Key words: TEA, enamine, natural gas decarburization, mixed amine solution, absorption, desorption, cycling experiment

中图分类号:

TQ517.5

周丹, 陈杰, 花亦怀, 唐建峰, 褚洁, 冯颉, 王曰. 三乙醇胺与烯胺混合胺液脱碳性能及配比优选实验研究[J]. 化工进展, 2015, 34(1): 95-101.

ZHOU Dan, CHEN Jie, HUA Yihuai, TANG Jianfeng, CHU Jie, FENG Jie, WANG Yue. Experimental study on performance and proportion optimization of TEA+enamine mixed solution for natural gas decarburization[J]. Chemical Industry and Engineering Progree, 2015, 34(1): 95-101.

参考文献

[1] 许佳平. 煤气和天然气中CO₂化学脱除试验研究[D]. 杭州:浙江大学,2013.

[2] 刘露,段振红,贺高红. 天然气脱除CO₂方法的比较与进展[J]. 化工进展,2009,28(s1):290-292.

[3] Luo Peicheng,Zhang Zhibing,Jiao Zhen,et al. Investigation in the design of a CO₂ cleaner system by using aqueous solutions of monoethanolamine and diethanolamine[J]. Ind. Eng. Chem. Res.,2003,42(20):4861-4866.

[4] Aroonwilas A,Veawab A. Characterization and comparison of the CO₂ absorption performance into single and blended alkanolamines in a packed column[J]. Ind. Eng. Chem. Res.,2004,43(9):2228-2237.

[5] 陆建刚,王连军,郑有飞,等. MDEA-TBEE 复合溶液选择性吸收H₂S性能评价[J]. 化学工程,2007,35(8):14-16.

[6] 陈晏杰,姚月华,江振西,等. MEA-AMP 混合醇胺捕集烟气二氧化碳过程分析[J]. 计算机与应用化学,2012,29(1):113-116.

[7] 李伟斌,董立户,陈健. 仲胺和叔胺水溶液吸收 CO₂ 的动力学[J]. 过程工程学报,2011,11(3):422-428.

[8] 项菲.烯胺DETA/TETA溶液富集烟道气中CO₂的研究[D]. 杭州:浙江大学,2003.

[9] Jamal A,Meisen A,Jim Lim C. Kinetics of carbon dioxide absorption and desorption in aqueous alkanolamine solutions using a novel hemispherical contactor——Ⅰ. Experimental apparatus and mathematical modeling[J]. Chemical Engineering Science,2006,61(19):6571-6589.

[10] Hagewiesche D P,Ashour S S,Al-Ghawas H A,et al. Absorption of carbon dioxide into aqueous blends of monoethanolamine and N-methyldiethanolamine[J]. Chemical Engineering Science,1995,50(7):1071-1079.

[11] 景晓燕,董吉川. 醇胺吸收和解吸CO₂的研究[J]. 化学工程师,1999(5):8-10.

[12] 陈杰,郭清,花亦怀,等. MDEA活化胺液在天然气预处理工艺中的吸收性能[J]. 化工进展,2014,33(1): 80-84.

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三乙醇胺与烯胺混合胺液脱碳性能及配比优选实验研究

Experimental study on performance and proportion optimization of TEA+enamine mixed solution for natural gas decarburization

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