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Table of Content
05 October 2009, Volume 28 Issue 10
    特约评述
    Status and prospect of biomass energy industry
    YUAN Zhenhong,LUO Wen,LÜ Pengmei,WANG Zhongming,LI Huiwen
    2009, 28(10):  1687. 
    Abstract ( 2124 )  
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    Biomass energy has an important status in renewable energy field. Biomass energy resource and its development potential were briefly analyzedThe present status of biomass energy industry at homemainly marsh gasliquid fuel from biomassgenerate electricity from biomass and solid moulding fuelwere reviewedThe policy condition for biomass energy exploitation and utilization in China were analyzed and the prospects of biomass energy were describedConsulting opinions were put forward for biomass developing in China.
    化工过程与装备
    Enhancing heat transfer ability of drag reducing surfactant solution
    PANG Mingjun,WEI Jinjia,WANG Jianfeng,ZHANG Chengwei,XUE Yanfang,LIU Haiyan
    2009, 28(10):  1693. 
    Abstract ( 1863 )  
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    Heat transfer characteristics and enhanced heat transfer methods were summarized. Mechanism of enhancing heat transfer was analyzed. The most effective results, influence factors, and merits and drawbacks of each method were compared. The results showed that the mean temperature distribution of surfactant solution was completely different from that of water. In the surfactant solution there were two thermal boundary layers. The largest heat resistance was not in the near wall region but in the buffer layer region where y+ ranged from 10 to 100. The method of enhancing heat transfer ability of the drag reducing surfactant solution was summarized as a general process, in which the microstructure of the surfactant solution was broken to yield turbulent flow, and thus enhancing heat transfer. Some views and suggestions on enhancing heat transfer ability of drag-reducing flow were presented.

    Progress of surfactant turbulent drag reduction
    ZHANG Hongxia,WANG Dezhong,GU Weiguo
    2009, 28(10):  1701. 
    Abstract ( 2063 )  
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    Surfactant additives in the turbulent drag reduction research,is a relatively hot topic in both scientific significance,and specific applications. The progress of surfactant turbulent drag reduction including surfactant solution physical properties,rheological properties,surfactant drag-reducing fluid turbulence and heat transfer characteristics is reviewed. Surfactant turbulent drag reduction and heat transfer are presented in terms of experimental research and numerical simulation. Finally,in addition to developing new surfactant additives,the trends of surfactant drag reduction research in the future are discussed.
    Microwave drying based on heating uniformity
    WANG Ruifang,LI Zhanyong
    2009, 28(10):  1707. 
    Abstract ( 1691 )  
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    Microwave drying is an advanced drying technique,in which thermal energy is generated inside the material by electromagnetic energy radiation and hence moisture is intensively evaporated toward the material surface. But heating non-uniformity is an inherent problem to microwave drying. In this paper,the factors relating to microwave heating non-uniformity were analyzed,and then feasible approaches to microwave heating uniformity were outlined by improving the uniformity of electromagnetic field distribution and moving the materials to be processed. At last,R & D trends of microwave drying with heating uniformity were pointed out and discussed.
    Construction of knowledge base of abnormal situation self-recovery system for propylene polymerization
    WANG Feng,GAO Jinji,CAI Jingbo
    2009, 28(10):  1712. 
    Abstract ( 2279 )  
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    By taking the propylene polymerization process as the research object,a method of constructing the knowledge base of the abnormal situation self-recovery system was presented. By applying the results of hazard and operability analysis,mechanism model and related accident cases to the propylene polymerization process,a technical basis for condition monitoring,early warning and self-recovery was established. Based on the results of hazard and operability analysis,alarm rules were formulated,the temperature,pressure,flow rate and liquid level of the process could be real-time monitored,and non-monitored variables could be calculated to give in-time alarm,reasons for abnormal situation,consequences,and preventive measures,which may be important for maintaining normal production.
    能源加工与技术
    Advance in catalytic steam reforming of biomass fast pyrolysis oil for hydrogen production
    LAN Ping,XU Qingli,WU Ceng,YAN Yongjie
    2009, 28(10):  1719. 
    Abstract ( 2176 )  
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    Renewable energy could be an alternative of fossil fuel for hydrogen production. Catalytic steam reforming of biomass fast pyrolysis oil is an economically feasible method for hydrogen production. In this paper,some typical reactor designs,process engineering,operation conditions,catalyst,reaction mechanism,and thermal analysis of catalytic steam reforming of bio-oil are presented. The bottleneck of catalytic steam reforming of bio-oil is the catalyst deactivation cased by carbon deposition. Development of a catalyst of high activity,high selectivity,high mechanical strength,long life,and easy regeneration as well as optimized reactor design are the important research directions in the future.
    Carbon dioxide emission reduction and chemical utilization in coal chemical industry
    YANG Wenshu,LÜ Jianning,YE Xin,DING Ganhong
    2009, 28(10):  1728. 
    Abstract ( 1997 )  
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    Carbon dioxide emission is tremendous in coal chemistry industry,so CO2 emission reduction from coal conversion should be paid attention to. In this paper,possible large-scale CO2 emission reduction methods and measures were presented after analyzing and researching coal gasification technology,chemical process optimization and integration. CO2 chemical utilization with respect to industrial application and scientific research were also summarized and analyzed. It was found that conversion of dimethyl carbonate to high added value chemicals,and the reaction of CO2-CH4 to high added value chemicals are significant processes in CO2 emission reduction for coal chemical industry.
    A novel double-effect liquid desiccant dehumidifier with solar trough and flat plate dual collectors/regenerators
    ZUO Yuanzhi,YANG Xiaoxi,DING Jing
    2009, 28(10):  1734. 
    Abstract ( 1888 )  
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    A novel double-effect liquid desiccant dehumidifier with solar trough and flat plate dual collectors/regenerators for the liquid desiccant air conditioning system was presented, in which boiling regeneration was achieved through adopting the solar trough collector and the vapor-liquid separator and non-boiling regeneration was realized through adopting the flat plate collector and utilizing solar energy and heat recovery of steam condensation from the separator. Then a stable heat and mass transfer mathematical model was developed and numerical simulation was conducted by using calcium chloride as the desiccant. The results showed that the utilization factor of solar energy of the hybrid system could reach 68.8 percent and the regeneration effect was obviously improved in comparison with the common flat plate collectors/regenerators.
    工业催化
    Research progress of biodiesel preparation by catalytic transesterification
    YAO Yan,SHEN Boxiong,ZHU Guoying,WANG Lei,LU Hua,SUN Ying
    2009, 28(10):  1738. 
    Abstract ( 1661 )  
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    Homogeneouse and heterogeneous catalysts for the catalytic transesterification of biodiesel were summarized in the paper,including the comparison of different kinds of catalysts and their applications. It was found that solid catalysts would meet the requirement of green production of biodiesel,with the advantages of solid acid catalyst catalyzing transesterification of oils containing water and free fatty acid.
    Progress of catalytic preparation of downstream chemicals from ethanol
    CHEN Yu,WU Yulong,DAI Bin,YANG Mingde,CHEN Zhen
    2009, 28(10):  1742. 
    Abstract ( 1707 )  
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    With the depletion of fossil fuel resources and the soaring prices of crude oil,the production of petrochemicals from fossil fuel as raw materials has been a severe challenge. Renewable biomass as a substitute for crude oil to produce petrochemicals can reduce the reliance on fossil fuel resources,so it is of great significance to sustainable development. With bio-ethanol,produced by fermentation of biomass,as platform,production of downstream products through catalytic conversion is an important means. This paper reviews the catalytic process to convert ethanol into downstream chemicals,focuses on the development of the catalyst to produce main downstream chemicals,such as hydrogen,ethylene,acetaldehyde and acetic acid. In the end,key urgent problems are addressed and perspectives are discussed.
    Advances in non-metallocene ⅣB group metal catalysts for olefin polymerization
    YIN Xifeng,DING Wanyou,NIU Bo,JIANG Tao
    2009, 28(10):  1750. 
    Abstract ( 1957 )  
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    This paper reviews the advances in non-metallocene ⅣB group metal catalysts for olefin polymerization according to the type of ligands, including amidos, ketimides, pyrazoles, and phenoxyimine. The effects of steric structure and electronic effect of ligands on catalytic activity, polymer structure and molecular weight of the polymer are discussed. The merits of highly active non-metallocene ⅣB group metal catalysts for olefin polymerization are summarized.
    Research progress of epoxidation of styrene with molecular oxygen
    ZHANG Xu,ZHANG Cuige
    2009, 28(10):  1756. 
    Abstract ( 1905 )  
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    Environmentally benign catalytic epoxidation of alkenes is one of the important applications of catalytic oxidation. Molecular oxygen as an ideal oxidant is used in many catalytic systems. However,molecular oxygen is inactive and it is activated only by the presence of catalyst. In this paper,the recent progress of catalytic epoxidation of styrene with molecular oxygen as oxidant is summarized,and their application is also prospected.
    Synthesis of acrolein using H3PW12O40/Al2O3 as catalyst
    LIU Jianwu,ZHANG Yue,XIE Guohong,YAN Shenghu,SHEN Jiefa
    2009, 28(10):  1762. 
    Abstract ( 1984 )  
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    The H3PW12O40/Al2O3 heteropoly acid catalyst with Keggin structure was prepared by the volume impregnation method with Al2O3 as carrier, and characterized with IR, XRD and BET techniques. With the H3PW12O40/Al2O3 as catalyst, the conditions of preparing acrolein from glycerol were studied in a continuous fixed bed reactor. The results showed that the optimal conditions were as follows: H3PW12O40/Al2O3 exhibited high activity and selectivity at the optimal temperature 330℃ and the load content of heteropoly acid 40%, the glycerol conversion reached 100% with acrolein selectivity of 83.7%.
    材料科学与技术
    Progress of preparation of electrospun hierarchical porous materials
    OU Weifeng,YAN Yurong
    2009, 28(10):  1766. 
    Abstract ( 2263 )  
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    Electrospun hierarchical porous materials with micro- and nanometer scale porous structure offer high specific surface area and unique properties for various applications. The preparation of electrospun hierarchical porous nanofiber mats is reviewed,including organic series and ceramic series. For the organic series,phase separation induced by solvent evaporation and other factors is the main mechanism of forming porous structure. While the template methods are often used to prepare inorganic porous nanofibers. The hierarchical pore structure further enlarges the surface area and enhances the hydrophobic property of the fiber mat,which alters the performance of the mat greatly.
    Preparation and characterization of thermo-sensitive microspheres with β-cyclodextrin groups
    JIANG Jing,XIE Rui,JU Xiaojie,CHENG Changjing,CHU Liangyin
    2009, 28(10):  1771. 
    Abstract ( 1686 )  
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    By using precipitation polymerizationthermo-sensitive poly(N-isopropylacrylamide-co- glycidyl methacrylate) [P(NIPAM-co-GMA)] microspheres were synthesized via the one-step and two-step reaction methods. The one-step method proceeded with the polymerization reaction of all reactants at the same timewhile the two-step method proceeded by the polymerization reaction of NIPAM firstlyand then adding GMA to form P(NIPAM-co-GMA) microspheres. The poly(N- isopropylacrylamide-co-2- hydroxypropyl methacrylate/ethylenediamino-β-cyclodextrin) [P(NIPAM-co- GMA/β-CD)] microspheres were fabricated through chemical reaction of P(NIPAM-co-GMA) microspheres with modified ethylenediamino-β- cyclodextrin (EDA-β-CD). The morphologieschemical structures and thermo-sensitive properties of all prepared microspheres were characterized by scanning electron microscopyFourier transform infrared spectroscopydynamic light scattering and microscope. The results showed that the prepared microspheres by both methods had good monodispersity and sphericity. The microspheres with β-CD groups were prepared successfullyand all microspheres had good thermo-sensitive properties. In additionmicrospheres prepared by the two-step method were larger and hadve more pendent β-CD groups than that prepared by the one-step method.
    Properties of rigid polyurethane foam prepared with PIPA polyol
    XUE Haijiao,DING Xuejia,LI Hongbo,WU Henglan,TANG Bin
    2009, 28(10):  1777. 
    Abstract ( 2099 )  
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    The rigid polyurethane foam blown by water was prepared with a polyisocyanate polyaddition (PIPA) polyol synthesized in lab and a polyol with a low hydroxyl value. The effects of such factors as the ratio of two polyols,chain extender and cross linker,isocyanate index on polyurethane product mechanical properties like compression,bend,impact strengths and dynamic rheological properties were studied. When the ratios of 1,4-butanediol,trimethylolpropane and TMN-3050 were 1.0pphp,1.0pphp,15pphp respectively,and the isocyanate index was 1.15,the product performed best with good strength and toughness.
    Preparation and properties of novel pH-sensitive chitosan/gelatin hydrogels
    WANG Xiaoyuan,YANG Xiaoquan
    2009, 28(10):  1781. 
    Abstract ( 1724 )  
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    Chitosan/gelatin hydrogels were prepared through the reaction between natural chitosan and gelatin. Swelling ratios of the hydrogels in buffer solutions at different pH values were studied. The structure was confirmed by FTIR and SEM. The results showed that the hydrogels were strongly pH-sensitive and the swelling ratio of the hydrogels in acid medium was higher than that in alkaline medium. Furthermore,the largest swelling ratio was obtained in a pH 3.0 buffer solution and the smallest was obtained in a pH 9.0 buffer solution. The hydrogels had good swelling-contracting reversibility in the solution which pH value was alternately changed. With the increase of glutaraldehyde dosage,the SR of the hydrogels decreased in buffer solutions at different pH values.
    Preparation of homoharringtonine imprinted polymer by precipitation polymerization
    LI Hui,FU Zaide,SHI Hui,ZHANG Zhaohui,LI Zhiping,YANG Zhaoxia,SHI Aihua
    2009, 28(10):  1787. 
    Abstract ( 1867 )  
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    The precipitation polymerization method was optimized by using a L9(34) orthogonal factorial design for the preparation of homoharringtonine imprinted polymer (HIP). Optimization of the synthesis condition for the HIP was performed by investigating the influence of four factors, i.e. solvent ( acetonitrile) dosage (A), reaction temperature (B), functional monomer (methacrylic acid, MAA) dosage (C) and crosslinker (ethylene glycol dimethyl acrylate, EGDMA) dosage (D), and the interaction of such factors on the adsorption capacity of HIP obtained under different conditions to the template molecule. The results indicated that the influence of these factors on the adsorption capacity of the HIP decreased in the order of C, D, A and B and the optimized synthesis condition was as follows:0.12 mmol MAA, 0.4 mmol EGDMA, 2.5 mL acetonitrile, reaction temperature at 65 ℃ under the fixed template dosage (0.01 mmol). Also, the interaction of such factors could influence the adsorption capacity of HIP to the template.
    生物化工
    Enhancement of asymmetric reduction efficiency for (R)- mandelic acid synthesis
    HAN Ying,MU Xiaoqing,XU Yan
    2009, 28(10):  1792. 
    Abstract ( 1718 )  
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    Enhancement of asymmetric reduction efficiency for (R)-mandelic acid (MA) from phenylglyoxylic acid (PGA) was investigated with whole cells of Saccharomyces ellipsoideus as catalyst. Utilization of fed-batch and addition of adsorbent resin could be effective in increasing substrate concentration and mitigating substrate inhibition. Absorbent resin NKA was selectedwhich had a large adsorption amount and a high adsorption rate of the substrate. By adding NKA adsorption resin in the reaction systemsubstrate inhibition was mitigatedand the initial substrate concentration was thus increased. Finally it was found that combining these two methods was the most effective way. Substrate concentration was increased from 33.31 mmol/L to 166.53 mmol/L, and a 95.6% yield of (R)-mandelic was obtained with fed-batch in a resin-added system. Reusability of cell was satisfactory.
    Ion-pairing conditions between bacillus subtilis neutral proteinase and surfactant AOT in solvent
    WANG Shugen,GU Jiadong,ZHANG Ying,FAN Xuerong
    2009, 28(10):  1798. 
    Abstract ( 2061 )  
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    Positively charged Bacillus subtilis neutral proteinase dissolved in the aqueous phase at a pH value below its pI could form hydrophobic ion-pair with the anionic surfactant AOT in isooctane when they are mixed together due to electrostatic attraction. Thus,the hydrophilic enzyme could be “solubilized” into the hydrophobic isooctane. In this paper,the factors affecting the ion pair formation were investigated,such as,mixing conditions of the two phases,initial pH value and ionic strength,salts,the concentrations of the enzyme and surfactant AOT. The results indicated that magnetic stirring at 120r/min for 6 h was better than other mixing methods. The initial pH value of the aqueous phase affected both formation of enzyme-surfactant ion pair and transfer of the enzyme into isooctane. The optimal pH value was about 5.0. Addition of CaCl2 could partially prevent emulsifying during mixing,but excessive CaCl2 could negatively affect formation of ion pair and transfer of the enzyme from aqueous phase into isooctane. The transferred amount of enzyme into isooctane increased when AOT concentration increased within the limit (below the critical concentration of reverse micelle formation,4.9 mmol/L),although the initial concentration of the enzyme in the aqueous phase was kept constant. However,with a constant AOT in isooctane,the enzyme transfer increased with increasing initial concentration of the enzyme in the aqueous phase first but decreased with further increase. The results showed that Bacillus subtilis neutral proteinase extracted into the organic phase was still active and could catalyze the transesterification.
    Permeability of chitosan/alginate microcapsules
    ZHAO Binran,XUE Weiming,ZHANG Hongliang,LIU Bo,ZNU Minli,XUE Meichen
    2009, 28(10):  1803. 
    Abstract ( 2000 )  
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    With the necessary carbon source for cell culture, glucose and citric acid and the nitrogen source- L-glutamic acid as the small molecul models,and a series of poly(ethylene-glycol)s (PEG) of different molecular weights as the large molecule models,the permeability of chitosan/alginate microcapsules was studied and the influence of preparation conditions on microcapsules permeability was investigated. Experimental results showed that glucose,L-glutamic acid,citric acid could diffuse through the membrane into the microcapsules,the molecular mass cut-off (MMCO) of microcapsules prepared from 20 mg/mL sodium alginate and 2 mg/mL chitosan of molecular weight 50 000 was approximately 1500,and the peameability of chitosan/alginate microcapsules increased with the decrease of the concentration of chitosan solution and chitosan molecular weight,and the increase of microcapsule diameter.
    Purification and enzymatic catalysis mechanism of formate dehydrogenase from Candida boidinii
    PENG Yiqiang,FANG Baishan
    2009, 28(10):  1808. 
    Abstract ( 1755 )  
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    NAD+ depended formate dehydrogenase (FateDH) from Candida boidinii was purified by diethylaminoethyl (DEAE) Sepharoses Fast Flow chromatography after the strain was cultured by two-step fermentation and crude cell extract was obtained by crushing and separation. The enzyme specific activity increased from 0.83 U/mg to 2.67 U/mg and a 3.22 fold purification was achieved with the recovery of 29.7% activity. The ordered BiBi reaction mechanism of FateDH enzymatic reaction was confirmed by the study of possible course from reactant consumption to product production. NAD+ was the first substrate with HCOONa as the second substrate. NADH was the first release product with HCO3ˉ as the subsequent release second product. The kinetics parameter including Vmax, KiS1, KmS2, KmS1 were solved by quadratic drawing and the BiBi reaction kinetic model of FateDH was established as .
    精细化工
    Research on photostability of metal complexd dyes
    ZHOU Leiyun,TANG Bingtao,ZHANG Shufen
    2009, 28(10):  1814. 
    Abstract ( 1540 )  
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    The effect of different metal ions on the photo-stability of complexed azo dyes,formazan dyes and phthalocyanine dyes was reviewed. The metal ions included Co(Ⅲ),Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ) and were introduced into the structure of dyes. Such metal ions played a key role as the energy absorber from the triplet dye,reduced the quantum yield of triplet dye and improved the photostability of the dyes.
    Progress of surfactin extraction and purification technologies
    HUANG Xiangfeng,PENG Kaiming,LIU Jia,LU Lijun,ZHU Wei
    2009, 28(10):  1820. 
    Abstract ( 1982 )  
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    The progress of extraction and purification of surfactin is reviewed,including precipitation,solvent extraction,chromatographic purification,ultrafiltration,adsorption,foam fractionation and liquid film separation,with emphasis on selection and integrated application of these methods. In-situ product removal (ISPR),as one of integrated bioprocessing technologies,is an important research direction in industrial production of surfactin.
    Progress of synthesis techology of N-acetylmorpholine
    LIU Ruijiang,ZHANG Yewang,WEN Chongwei,LU Zheng
    2009, 28(10):  1828. 
    Abstract ( 2276 )  
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    The progress of synthesis of N-acetylmorpholine was reviewed, and the properties and application as well as the synthesis methods including acetic acid method, acetyl chloride method, acetate method, acetic anhydride method were presented and discussed. The trends of synthesis of N-acetylmorpholine were also analyzed.
    资源与环境工程
    Status and progress of treating volatile organic compounds
    WANG Han,GUO Guiyue,ZHOU Yuying,LIANG Zhongyue
    2009, 28(10):  1833. 
    Abstract ( 2117 )  
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    The research progress and application of adsorption,catalytic combustion and biodegradation for VOCs removal in recent years are reviewed,and the development trend of VOCs treatment is discussed.
    Biodegradation of methyl tert-butyl ether (MTBE) and key enzymes
    ZHANG Ruiling,LI Xingang,SUI Hong,ZHENG Yanmei,HUANG Guoqiang, LIU Xueyan
    2009, 28(10):  1842. 
    Abstract ( 2155 )  
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    :As a fuel oxidizing agent,methyl tert-butyl ether (MTBE) is added to gasoline in replacement of tetraethyl lead to enhance octane number. The addition of MTBE also improves the combustion efficiency and therefore decreases the emission of pollutants like CO and O3. On the other hand,because of gasoline spills,mainly due to leaking underground storage tanks,MTBE has become a prevalent contaminant in groundwater. The reason for such widespread contamination is that MTBE is highly soluble in water and recalcitrant to biodegradation. The chemical characteristics of MTBE make it a challenge to treatment in the natural environment. Biological treatment of soil and groundwater is expected to be a cost-effective technique. It was reported that MTBE was able to degrade through co-oxidation or could be used as a carbon and energy source by many microorganisms. In China,the studies on MTBE removal by bioremediation techniques are still at their infancy for both fundamental research and on-site application. Based on previous studies,the reported microorganisms able to degrade MTBE were summarized,and then emphasis was put on the key catabolic enzymes involved in MTBE degradation.
    Electrochemical desulfurization for raw coal and flue gas
    LU Qingqing,GAO Yunfang,YU Lili
    2009, 28(10):  1849. 
    Abstract ( 1778 )  
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    Desulfuriztion methods,including electrochemical desulfurization of raw coal in acidic/ alkaline medium,electrochemical flotation of raw coal,and flue gas electrochemical desulfurization are presented. Valuable references are given for choosing the conditions of desulfurization by comparing the rates of sulfur removal and discussing the factors of FGD. The development direction and prospect of electrochemical desulfurization are discussed.
    Alkalinity improved production of volatile fatty acid from anaerobic fermentation of textile dyeing sludge
    ZHANG Jingjing,LIU He,DU Guocheng,CHEN Jian
    2009, 28(10):  1855. 
    Abstract ( 1800 )  
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    The study of acidity (pH 5, pH 6), neutrality (pH 7) and alkalinity (pH 810) conditions on the type of fermentation, maximum concentration of total VFA and major acids, VFA distributionyields and the production rates of total VFA and acetic acid from the textile dyeing sludge by anaerobic fermentation were investigated, and the mechanisms of the alkalinity condition beneficial to producing the organic acids were revealed. The results showed that acetic acid-type fermentation was the main type at different pH, but a lower pH was in favor of the accumulation of butyric acid. The concentrations of total VFA and acetic acid increased with increasing pH. The alkalinity condition could promote production of VFA because a high pH could promote the degradation of organic matter, improve conversion efficiency and inhibit the degradation of organic acids. pH at 10 was the optimum value to reach the best total VFA and acetic acid production from the sludge. At that pH value, the concentrations of acetic acid and total VFA were 8.21 g/L and 14.08 g/L respectively. The yields of acetic acid and total VFA could reach 34.97% and 75.72% respectively. In addition, the rate of acetic acid and total VFA production could reach 2.41g/(L·d) and 3.48 g/(L·d), respectively; Meanwhile, when the pH was 6, butyric acid could reach the highest concentration of 1.89g/L, suggesting that the pH value at 6 is suitable for the butyric acid-type fermentation.
    Preparation and adsorption properties of chitosan beads for acidic dyes
    MENG Fanping,YI Huaichang
    2009, 28(10):  1861. 
    Abstract ( 1778 )  
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    Chitosan beads were prepared by the dripping granulation method,using chitosan (CS) as the raw material,sodium tripolyphosphate (TPP) and epichlorohydrin (ECH) as the cross-linking reagent. The adsorption properties of the chitosan beads for two kinds of acidic dyes,acid bordeaux B(ABB) and nylosan yellow N-3RL(NYN) from water was investigated. Under the initial concentration of dye waste water 100 mg / L and volume 50 mL,the optimum adsorption conditions of chitosan beads for the two dye waste waters were obtained as follows:particle size of chitosan beads 0.5mm,dosage 20.0mg,contact time 16 h,pH value 3, temperature 20℃ for ABB,30—50℃ for NYN,oscillating rate 150r/min. Under the optimum adsorption conditions,the adsorption process of ABB and NYN fitted well with both Freundlich model and Langmuir model,and the maximum adsorption capacity for ABB and NYN were 714.29 mg/g and 769.23 mg/g respectively,which exceeded the maximum adsorption capacity by non-bead chitosan 443.99 mg/g,102.53 mg/g respectively. The saturated chitosan beads were desorbed by 0.01mol/L NaOH,the regeneration rate were 99.08%,99.35% for each dye,and the beads could be used repeatedly which would reduce the decoloration cost.
    Effect of different pretreatment methods on enzymatic hydrolysis of corn stalk with added Tween-80
    LIU WeiPANG HaoJI HongguoLIAO Bing
    2009, 28(10):  1868. 
    Abstract ( 1858 )  
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    Four different pretreatment methods,namely,diluted sulfuric acid method,sodium hydroxide method,aqueous ammonia method and hydrated lime method,were tested to study the effect on enzymatic hydrolysis of corn stalk with added Tween-80. The results showed that the total reduced sugars of corn stalk treated by sodium hydroxide were 10.7 times more than those of the untreated corn stalk. As is shown by X-ray and IR,the lignin content of corn stalk treated by sodium hydroxide reduced by 62%. Besides,the degree of crystallinity of cellulose decreased.

    应用技术
    Application of centrifugal molecular distillation equipment to L-lactic acid refining process
    SUN Bo,XU Ning,YAO Wanying,ZHAO Chuanyu,LIU Sicheng
    2009, 28(10):  1872. 
    Abstract ( 1850 )  
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    Centrifugal molecular distillation equipment was employed for refining lactic acid. The effects of temperature and rotary speed of evaporating plate,distance from evaporating plate and temperature difference on the purity and yield of L-lactic acid were studied. The results indicated that the optimal conditions to refine L-lactic acid by centrifugal molecular distillation were obtained at the pressure of 0.1Pa,feed-in temperature of 50—70℃,evaporating temperature at 60—75℃,rotary speed of the evaporating plate of 700—900 r/min,distance from the evaporating plate of 20—30 mm and temperature difference of 40—45℃.The purity of L-lactic acid increased from 80% to 95%,accompanied by the yield of 70% under the optimized conditions.
    Operation parameter of O3 -GAC process removing Chironomid larvae from drinking water
    SUN Xingbin,WANG Shutao,CUI Fuyi,HAN Jinzhu
    2009, 28(10):  1876. 
    Abstract ( 2350 )  
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    The operation parameter of ozone-granular activated carbon (O3-GAC) process for removing young Chironomid larvae form drinking water was studied. The results indicated that complete inactivation of young Chironomid larvae in filtrated water could be performed under the condition of 1.0mg/L of ozone with 11 min disposal. The removal efficiency of the Chironomid larvae can be further advanced O3-GAC combined process. The Chironomid larvae with low activity could be entirely eliminated in ozone-GAC process with the ozone dosage of 0.7mg/L at the condition of the Empty Bed Contact Time (EBCT) from 11min to 13.5min.
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