Chemical Industry and Engineering Progress ›› 2019, Vol. 38 ›› Issue (05): 2471-2478.DOI: 10.16085/j.issn.1000-6613.2018-1647

• Resources and environmental engineering • Previous Articles     Next Articles

In-duct injection mercury removal characteristics of biochar prepared under biomass reburning condition

Ping LU(),Jiateng SHI,Yangtian YE,Hewei JIANG   

  1. School of Energy and Mechanical Engineering, Nanjing Normal University, Nanjing 210042, Jiangsu, China
  • Received:2018-08-10 Revised:2018-09-22 Online:2019-05-05 Published:2019-05-05

生物质再燃焦管道喷射脱汞性能

卢平(),史加腾,叶扬天,蒋何伟   

  1. 南京师范大学能源与机械工程学院,江苏 南京 210042
  • 作者简介:<named-content content-type="corresp-name">卢平</named-content>(1968—),男,博士,教授,主要从事燃烧及其污染物控制的研究。E-mail:<email>luping@njnu.edu.cn</email>。
  • 基金资助:
    国家自然科学基金(51476079);江苏省高校自然科学研究重大项目(15KJA610002)

Abstract:

Biochars (called RH1050, RH 1150, WS1050 and WS1150) were prepared under reburning with biomass of rice husk and wheat straw at 1050°C and 1105°C in an entrained flow reactor, and four kinds of sorbents for mercury removal were obtained through blending above biochars and calcined coal-fired flyash, respectively. Elenmental mercury (Hg0) removal characteristics of different sorbents was carried out in an in-duct sorbent injection apparatus. The effects of biomass species, adsorption temperature, initial mercury concentration, and flue gas components (SO2, NO and HCl) on Hg0 removal were analyzed, and mercury removal mechanism was also discussed. The obtained results indicated that the average mercury removal efficiency of four biochars is around 30%, and mercury removal efficiency of RH-biochar is a little bit larger than that of WS-biochar. Mercury removal efficiency of RH1050 continuously increases with the increase of adsorption temperature, but mercury removal efficiency of RH1150 presents fluctuating trend. The average mercury removal efficiency of RH-biochar behaves the trend of increase first and decrease later, and the maximum average mercury removal efficiencies of 35.6% and 37.1% through in-duct injection of RH1050 and RH1150 are achieved at initial mercury concentration of 25μg/m3. The presence of SO2 suppresses Hg0 removal, NO enhances Hg0 removal, and HCl has a significant promoting effect. The average mercury removal efficiency can achieve more than 90% while HCl content in the simulated flue gas is larger than 50μL/L.

Key words: biomass reburning, biochar, in-duct sorbent injection, mercury removal, flue gas component

摘要:

采用高温携带流反应装置在1050℃和1150℃条件下制备了稻壳再燃焦(RH1050和RH1150)和小麦秸秆再燃焦(WS1050和WS1150),并分别将其与燃煤灼烧飞灰混合制成相应的脱汞吸附剂。在吸附剂管道喷射脱汞实验装置上,研究了生物质种类、吸附温度、初始汞浓度和烟气组分(SO2、NO和HCl)对生物质再燃焦管道喷射脱汞性能的影响,并结合生物质及其再燃焦的理化特性分析,探讨了单质汞(Hg0)脱除机理。结果表明:4种生物质再燃焦平均脱汞效率相差不大,约为30%,稻壳再燃焦的脱汞效率略高于小麦秸秆焦。随着吸附温度的升高,RH1050脱汞效率持续增加,RH1150脱汞效率则呈现波动变化趋势。随着初始汞浓度的升高,稻壳再燃焦的平均脱汞效率均呈现先增大后减小的趋势,初始汞浓度为25μg/m3时RH1050和RH1150的平均脱汞效率最大,分别为35.6%和37.1%。SO2对生物质再燃焦管道喷射脱汞具有一定的抑制作用,NO具有一定促进作用,而HCl的促进作用更为显著,且当HCl浓度大于50μL/L时,生物质再燃焦的平均脱汞效率均在90%以上。

关键词: 生物质再燃, 生物质焦, 管道喷射, 脱汞, 烟气组分

CLC Number: 

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