Chemical Industry and Engineering Progress ›› 2024, Vol. 43 ›› Issue (12): 6957-6967.DOI: 10.16085/j.issn.1000-6613.2023-2163
• Resources and environmental engineering • Previous Articles
LYU Longyi(), HAN Muda, MA Peiyu, JI Wenbo, WANG Xinyuan, GAO Wenfang(
), REN Zhijun(
)
Received:
2023-12-07
Revised:
2024-02-23
Online:
2025-01-11
Published:
2024-12-15
Contact:
GAO Wenfang, REN Zhijun
吕龙义(), 韩沐达, 马培禹, 及文博, 王新元, 高文芳(
), 任芝军(
)
通讯作者:
高文芳,任芝军
作者简介:
吕龙义(1989—),男,副教授,博士生导师,研究方向为水污染控制与资源化。E-mail:lvlongyi@hebut.edu.cn。
基金资助:
CLC Number:
LYU Longyi, HAN Muda, MA Peiyu, JI Wenbo, WANG Xinyuan, GAO Wenfang, REN Zhijun. Conductive materials for enhanced anaerobic digestion of wastewater and influence of their properties[J]. Chemical Industry and Engineering Progress, 2024, 43(12): 6957-6967.
吕龙义, 韩沐达, 马培禹, 及文博, 王新元, 高文芳, 任芝军. 强化废水厌氧消化过程的导电材料及其特性影响[J]. 化工进展, 2024, 43(12): 6957-6967.
导电材料 | 废水种类 | 投加量/g·L-1 | 反应体系 | 强化效果 | 参考文献 |
---|---|---|---|---|---|
活性炭 | 食物垃圾废水 | 15 | 血清瓶 | 同等OLR下,平均CH4产率为4.7g/(L·d),是无AC反应器的2.5倍 | [ |
颗粒活性炭 | 乳品废水 | 2 | SBR | 在每个循环运行结束时,CH4产量增加了68%~125% | [ |
颗粒活性炭 | 垃圾焚烧渗滤液 | 75 | UASB | 对照组立即变质并在17天内坍塌;GAC组OLR提高到25.0kg/m3时,COD去除率保持在90%左右 | [ |
颗粒活性炭 | 合成废水 | 25 | UASB | COD去除率从56%提高到82%,CH4产量从132mL/g提高到264mL/g | [ |
粉末活性炭 | 葡萄糖、生物油 | 10 | 血清瓶 | CH4产量提高24%,COD去除率提高15% | [ |
粉末活性炭 | 垃圾渗滤液 | 10 | SBR | 与对照组相比,PAC和PAC双反应沉淀组COD去除效率分别提高140%和78% | [ |
生物炭 | 葡萄糖 | 10 | 血清瓶 | CH4产率相比于对照组提高17.80% | [ |
生物炭 | 合成废水 | 5 | UASB | CH4产率相比于对照组提高1.47倍 | [ |
碳布 | 新鲜渗滤液 | 10块 | UASB | 高有机负荷下,COD去除率从30%提高到80% | [ |
碳毡 | 葡萄糖和甘氨酸 | — | CSTR | 相比对照组,实验组的CH4产率提高10.1%~23.0% | [ |
碳纤维 | 丙酸-丁酸盐 | — | CSTR | CH4比产量(mL/g)和产CH4速率(d-1)分别增加约2.4倍和6.7倍 | [ |
单壁碳纳米管 | 葡萄糖 | 1 | CSTR | CH4产量和产率分别提高1.63倍和1.92倍 | [ |
多壁碳纳米管 | 甜菜糖废水 | 1.5 | EGSB | CH4产量相比于对照组提高1.12倍 | [ |
石墨 | 垃圾渗滤液 | — | AnMBR | 当进水COD浓度为3000mg/L时,COD去除率为78%;石墨可有效缓解膜污染 | [ |
石墨毡 | 丙酸盐 | — | ASBR | 与对照组相比,CH4产率提高19.1% | [ |
石墨烯 | 氨基乙酸 | 0.25~2 | 血清瓶 | 材料投加量为0.5~1g/L时,CH4产量提高4%~6% | [ |
纳米石墨烯 | 合成废水 | 0.12 | 血清瓶 | CH4产量和产率分别提高1.5倍和1.51倍 | [ |
导电材料 | 废水种类 | 投加量/g·L-1 | 反应体系 | 强化效果 | 参考文献 |
---|---|---|---|---|---|
活性炭 | 食物垃圾废水 | 15 | 血清瓶 | 同等OLR下,平均CH4产率为4.7g/(L·d),是无AC反应器的2.5倍 | [ |
颗粒活性炭 | 乳品废水 | 2 | SBR | 在每个循环运行结束时,CH4产量增加了68%~125% | [ |
颗粒活性炭 | 垃圾焚烧渗滤液 | 75 | UASB | 对照组立即变质并在17天内坍塌;GAC组OLR提高到25.0kg/m3时,COD去除率保持在90%左右 | [ |
颗粒活性炭 | 合成废水 | 25 | UASB | COD去除率从56%提高到82%,CH4产量从132mL/g提高到264mL/g | [ |
粉末活性炭 | 葡萄糖、生物油 | 10 | 血清瓶 | CH4产量提高24%,COD去除率提高15% | [ |
粉末活性炭 | 垃圾渗滤液 | 10 | SBR | 与对照组相比,PAC和PAC双反应沉淀组COD去除效率分别提高140%和78% | [ |
生物炭 | 葡萄糖 | 10 | 血清瓶 | CH4产率相比于对照组提高17.80% | [ |
生物炭 | 合成废水 | 5 | UASB | CH4产率相比于对照组提高1.47倍 | [ |
碳布 | 新鲜渗滤液 | 10块 | UASB | 高有机负荷下,COD去除率从30%提高到80% | [ |
碳毡 | 葡萄糖和甘氨酸 | — | CSTR | 相比对照组,实验组的CH4产率提高10.1%~23.0% | [ |
碳纤维 | 丙酸-丁酸盐 | — | CSTR | CH4比产量(mL/g)和产CH4速率(d-1)分别增加约2.4倍和6.7倍 | [ |
单壁碳纳米管 | 葡萄糖 | 1 | CSTR | CH4产量和产率分别提高1.63倍和1.92倍 | [ |
多壁碳纳米管 | 甜菜糖废水 | 1.5 | EGSB | CH4产量相比于对照组提高1.12倍 | [ |
石墨 | 垃圾渗滤液 | — | AnMBR | 当进水COD浓度为3000mg/L时,COD去除率为78%;石墨可有效缓解膜污染 | [ |
石墨毡 | 丙酸盐 | — | ASBR | 与对照组相比,CH4产率提高19.1% | [ |
石墨烯 | 氨基乙酸 | 0.25~2 | 血清瓶 | 材料投加量为0.5~1g/L时,CH4产量提高4%~6% | [ |
纳米石墨烯 | 合成废水 | 0.12 | 血清瓶 | CH4产量和产率分别提高1.5倍和1.51倍 | [ |
导电材料 | 反应底物 | 投加量/g·L-1 | 反应器 | 强化效果 | 参考文献 |
---|---|---|---|---|---|
针铁矿 | 醋酸、丙酸和丁酸 | 5 | 血清瓶 | CH4产量增加40%~165%,改善酸胁迫下的性能 | [ |
磁铁矿 | 醋酸盐 | 2 | ASTR | COD去除率和CH4产量相比对照组分别提高31.1%和101.5% | [ |
赤铁矿 | 合成废水 | 0.75 | 血清瓶 | CH4产量相比对照组增加35% | [ |
ZVI | 合成废水 | 0.2~5 | 血清瓶 | 投加量为2g/L时,CH4产量提高84.12% | [ |
Fe3O4 | 合成废水 | 10 | ASBR | 最大CH4产率提高15.4%,滞后期缩短13.9% | [ |
Fe2O3 | 合成废水 | 30mmol/L | 血清瓶 | CH4产量相比于对照组提高22.4% | [ |
Fe(OH)3 | 合成废水 | 30mmol/L | 血清瓶 | CH4产量比对照组高38.2% | [ |
nZVI | 合成蔗糖废水 | 50mmol/L | 塑料厌氧反应器 | COD去除率降低30.4%,CH4产量降低22.5% | [ |
nFe3O4 | 合成蔗糖废水 | 50mmol/L | 塑料厌氧反应器 | COD去除率提高26.1%,CH4产量提高76.2% | [ |
导电材料 | 反应底物 | 投加量/g·L-1 | 反应器 | 强化效果 | 参考文献 |
---|---|---|---|---|---|
针铁矿 | 醋酸、丙酸和丁酸 | 5 | 血清瓶 | CH4产量增加40%~165%,改善酸胁迫下的性能 | [ |
磁铁矿 | 醋酸盐 | 2 | ASTR | COD去除率和CH4产量相比对照组分别提高31.1%和101.5% | [ |
赤铁矿 | 合成废水 | 0.75 | 血清瓶 | CH4产量相比对照组增加35% | [ |
ZVI | 合成废水 | 0.2~5 | 血清瓶 | 投加量为2g/L时,CH4产量提高84.12% | [ |
Fe3O4 | 合成废水 | 10 | ASBR | 最大CH4产率提高15.4%,滞后期缩短13.9% | [ |
Fe2O3 | 合成废水 | 30mmol/L | 血清瓶 | CH4产量相比于对照组提高22.4% | [ |
Fe(OH)3 | 合成废水 | 30mmol/L | 血清瓶 | CH4产量比对照组高38.2% | [ |
nZVI | 合成蔗糖废水 | 50mmol/L | 塑料厌氧反应器 | COD去除率降低30.4%,CH4产量降低22.5% | [ |
nFe3O4 | 合成蔗糖废水 | 50mmol/L | 塑料厌氧反应器 | COD去除率提高26.1%,CH4产量提高76.2% | [ |
导电材料 | 反应底物 | 投加量/g·L-1 | 反应器 | 强化效果 | 参考文献 |
---|---|---|---|---|---|
PANI | 偶氮染料废水 | 0.1~0.8 | 血清瓶 | 添加0.4g/L PANI可以使厌氧污泥的脱色效率提高约20% | [ |
PANI纳米棒 | 蔗糖 | 0.6 | 血清瓶 | 0.6g/L PANI纳米棒的剂量使CH4的产生加速了约2倍 | [ |
Fe3O4@PANI | 葡萄糖 | 0.6~5.4 | 血清瓶 | CH4产率提高26.98%;最佳用量为0.6g/L | [ |
Fe2O3@PANI | 葡萄糖 | 1.2 | 血清瓶 | Fe2O3@PANI复合改良厌氧系统的CH4产量是添加氧化铁和PANI的系统总和的约1.5倍 | [ |
ZVI@C@PANI | 合成废水 | 1.8~2.5 | 血清瓶 | 在最佳剂量(2g/L)下,与未添加纳米复合材料的厌氧系统相比,CH4产量增加了71.36% | [ |
PPy@PANI | 葡萄糖 | 0.2~1.4 | 血清瓶 | 在初始4h内,CH4产率提高70.2%,产量增加28.3%;最佳用量为0.6g/L | [ |
PU/(PPy+PANI) | 城市废水 | 1.8 | nMBR | 投加PU/(PPy+PANI)的中试组在间歇模式下COD去除率为80% | [ |
PANI水凝胶 | 蔗糖 | 0.1~0.4 | 血清瓶 | 材料添加0.3g/L,CH4生成率提高了28.77% | [ |
PANI + PET | 醋酸钠 | — | 血清瓶 | 与空白组相比,CH4产率提高9% | [ |
PANI + PVDF | 醋酸钠 | — | 血清瓶 | 与空白组相比,CH4产率提高25% | [ |
PPy | 废弃污泥 | 0.3 | 血清瓶 | PPy使累积CH4产量提高了27.83% | [ |
聚乙烯+石墨粉 | 合成废水 | 0.0181~0.0354 | 连续流反应器 | 与无石墨的HDPE组相比,CH4的产率提高7.8%~26.6%;与空白组相比,提高了15.5%~31.3% | [ |
改性黑磷 | 合成废水 | 0.03%~0.15% | 玻璃反应釜 | 质量分数0.03%组沼气产量和TCOD去除率(387.6mL/g和71.5%)高于空白组(326.3mL/g和55.5%) | [ |
高炉粉尘 | 合成废水 | 0.02~0.05 | UASB | CH4产量增加了73%~346% | [ |
胆碱 | 废弃活性污泥 | 0~1 | 蒸煮器 | 以0.75g/L作为最佳胆碱给药浓度,EGs中的累积沼气产量增加了35.55%~36.73% | [ |
次氯酸钙 | 废弃活性污泥 | 0~1.25 | 血清瓶 | CH4含量从0提高到1.0g/L,CH4的产量从(164.8±4.2)mL/g增加到(220.5±6.2)mL/g | [ |
钨酸钠 | 废弃污水污泥 | 0~0.25 | 分批厌氧消化器 | 在钨酸钠存在下,甲烷菌的占比从3.02%显著增加到31.20% | [ |
不锈钢 | 合成废水 | 0~6.4 | UASB | CH4产量从39.4mL/d增加到159.9mL/d | [ |
TiO2 | 合成废水 | 0~2 | 厌氧间歇反应器 | CH4产量相比于对照组提高14% | [ |
泡沫镍 | 乙醇 | 2.45 | 槽式反应器 | CH4的最大产率达到94.5mL/(g·d),与对照相比增加了27.4% | [ |
导电材料 | 反应底物 | 投加量/g·L-1 | 反应器 | 强化效果 | 参考文献 |
---|---|---|---|---|---|
PANI | 偶氮染料废水 | 0.1~0.8 | 血清瓶 | 添加0.4g/L PANI可以使厌氧污泥的脱色效率提高约20% | [ |
PANI纳米棒 | 蔗糖 | 0.6 | 血清瓶 | 0.6g/L PANI纳米棒的剂量使CH4的产生加速了约2倍 | [ |
Fe3O4@PANI | 葡萄糖 | 0.6~5.4 | 血清瓶 | CH4产率提高26.98%;最佳用量为0.6g/L | [ |
Fe2O3@PANI | 葡萄糖 | 1.2 | 血清瓶 | Fe2O3@PANI复合改良厌氧系统的CH4产量是添加氧化铁和PANI的系统总和的约1.5倍 | [ |
ZVI@C@PANI | 合成废水 | 1.8~2.5 | 血清瓶 | 在最佳剂量(2g/L)下,与未添加纳米复合材料的厌氧系统相比,CH4产量增加了71.36% | [ |
PPy@PANI | 葡萄糖 | 0.2~1.4 | 血清瓶 | 在初始4h内,CH4产率提高70.2%,产量增加28.3%;最佳用量为0.6g/L | [ |
PU/(PPy+PANI) | 城市废水 | 1.8 | nMBR | 投加PU/(PPy+PANI)的中试组在间歇模式下COD去除率为80% | [ |
PANI水凝胶 | 蔗糖 | 0.1~0.4 | 血清瓶 | 材料添加0.3g/L,CH4生成率提高了28.77% | [ |
PANI + PET | 醋酸钠 | — | 血清瓶 | 与空白组相比,CH4产率提高9% | [ |
PANI + PVDF | 醋酸钠 | — | 血清瓶 | 与空白组相比,CH4产率提高25% | [ |
PPy | 废弃污泥 | 0.3 | 血清瓶 | PPy使累积CH4产量提高了27.83% | [ |
聚乙烯+石墨粉 | 合成废水 | 0.0181~0.0354 | 连续流反应器 | 与无石墨的HDPE组相比,CH4的产率提高7.8%~26.6%;与空白组相比,提高了15.5%~31.3% | [ |
改性黑磷 | 合成废水 | 0.03%~0.15% | 玻璃反应釜 | 质量分数0.03%组沼气产量和TCOD去除率(387.6mL/g和71.5%)高于空白组(326.3mL/g和55.5%) | [ |
高炉粉尘 | 合成废水 | 0.02~0.05 | UASB | CH4产量增加了73%~346% | [ |
胆碱 | 废弃活性污泥 | 0~1 | 蒸煮器 | 以0.75g/L作为最佳胆碱给药浓度,EGs中的累积沼气产量增加了35.55%~36.73% | [ |
次氯酸钙 | 废弃活性污泥 | 0~1.25 | 血清瓶 | CH4含量从0提高到1.0g/L,CH4的产量从(164.8±4.2)mL/g增加到(220.5±6.2)mL/g | [ |
钨酸钠 | 废弃污水污泥 | 0~0.25 | 分批厌氧消化器 | 在钨酸钠存在下,甲烷菌的占比从3.02%显著增加到31.20% | [ |
不锈钢 | 合成废水 | 0~6.4 | UASB | CH4产量从39.4mL/d增加到159.9mL/d | [ |
TiO2 | 合成废水 | 0~2 | 厌氧间歇反应器 | CH4产量相比于对照组提高14% | [ |
泡沫镍 | 乙醇 | 2.45 | 槽式反应器 | CH4的最大产率达到94.5mL/(g·d),与对照相比增加了27.4% | [ |
导电材料 | 反应底物 | 投加量 | 反应器 | 强化效果 | 参考文献 |
---|---|---|---|---|---|
Fe3O4+GAC | 合成废水 | 25g/L+40g/L | 两相厌氧反应器 | 与对照组、GAC组和磁铁矿组相比,最高OLR下CH4生产率分别提高80%、70%和31% | [ |
ZVI+GAC | 橘皮废弃物 | 0.3g/g+20g/L | 半连续反应器 | CH4总产量比单一GAC反应器高112% | [ |
ETEA+AC | 合成废水 | 0.005g/L+15g/L | 密封蒸煮器 | 与不添加添加剂的对照组相比,AC+ETEA的平均CH4产量提高50% | [ |
Fe3O4@N-BC | 合成废水 | 5g/L | 血清瓶 | Fe3O4@N-BC组最高累积CH4产量增长1.75倍 | [ |
MGAC | 模拟生活污水 | 6g/L | 血清瓶 | MGAC组CH4产量是对照组的3.6倍,GAC组的1.57倍 | [ |
GAC-Ni | 乙酸盐、丙酸盐 | 0.1g/L | 血清瓶 | 补充GAC-Ni后,以乙酸盐和丙酸盐为原料的反应器的CH4最大产量分别增加54.06%和16.55% | [ |
导电碳布 | 丙酸盐 | 2cm×2cm×0.111mm | 血清瓶 | 与对照相比,累积CH4产量和丙酸盐降解率分别增加15.4%和19.67% | [ |
导电材料 | 反应底物 | 投加量 | 反应器 | 强化效果 | 参考文献 |
---|---|---|---|---|---|
Fe3O4+GAC | 合成废水 | 25g/L+40g/L | 两相厌氧反应器 | 与对照组、GAC组和磁铁矿组相比,最高OLR下CH4生产率分别提高80%、70%和31% | [ |
ZVI+GAC | 橘皮废弃物 | 0.3g/g+20g/L | 半连续反应器 | CH4总产量比单一GAC反应器高112% | [ |
ETEA+AC | 合成废水 | 0.005g/L+15g/L | 密封蒸煮器 | 与不添加添加剂的对照组相比,AC+ETEA的平均CH4产量提高50% | [ |
Fe3O4@N-BC | 合成废水 | 5g/L | 血清瓶 | Fe3O4@N-BC组最高累积CH4产量增长1.75倍 | [ |
MGAC | 模拟生活污水 | 6g/L | 血清瓶 | MGAC组CH4产量是对照组的3.6倍,GAC组的1.57倍 | [ |
GAC-Ni | 乙酸盐、丙酸盐 | 0.1g/L | 血清瓶 | 补充GAC-Ni后,以乙酸盐和丙酸盐为原料的反应器的CH4最大产量分别增加54.06%和16.55% | [ |
导电碳布 | 丙酸盐 | 2cm×2cm×0.111mm | 血清瓶 | 与对照相比,累积CH4产量和丙酸盐降解率分别增加15.4%和19.67% | [ |
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