Chemical Industry and Engineering Progress ›› 2024, Vol. 43 ›› Issue (8): 4601-4613.DOI: 10.16085/j.issn.1000-6613.2023-1208
• Resources and environmental engineering • Previous Articles
LI Weijie1(), LU Leilei1(), LI Deke2, WANG Chunhang2, ZHANG Zuming2, TAN Qiang3
Received:
2023-07-16
Revised:
2023-10-20
Online:
2024-09-02
Published:
2024-08-15
Contact:
LU Leilei
黎伟杰1(), 路蕾蕾1(), 李得科2, 王春航2, 张祖铭2, 谭强3
通讯作者:
路蕾蕾
作者简介:
黎伟杰(1999—),男,硕士研究生,研究方向为废旧锂离子电池正极材料回收。E-mail:weijie990701@163.com。
基金资助:
CLC Number:
LI Weijie, LU Leilei, LI Deke, WANG Chunhang, ZHANG Zuming, TAN Qiang. Lithium-ion battery disassembly and recycling technology and progress[J]. Chemical Industry and Engineering Progress, 2024, 43(8): 4601-4613.
黎伟杰, 路蕾蕾, 李得科, 王春航, 张祖铭, 谭强. 锂离子电池拆解回收技术及进展[J]. 化工进展, 2024, 43(8): 4601-4613.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2023-1208
序号 | 无机浸出剂 | 还原剂 | 固液比/mL·g-1 | 时间/min | 温度 /℃ | 浸出效率/% | 参考文献 | |||
---|---|---|---|---|---|---|---|---|---|---|
锂 | 镍 | 锰 | 钴 | |||||||
1 | 硫酸(2.0mol·L-1) | 双氧水(0.97mol·L-1) | 10 | 30 | 80 | 100 | 100 | 94 | 100 | [ |
2 | 硫酸(1.0mol·L-1) | 亚硫酸氢钠(0.075mol·L-1) | 50 | 240 | 95 | 96.7 | 96.4 | 87.9 | 91.6 | [ |
3 | 硫酸(1.0mol·L-1) | 双氧水(体积分数1%) | 25 | 60 | 40 | 99.7 | 99.7 | 99.7 | 99.7 | [ |
4 | 硫酸(1.0mol·L-1) | — | 10 | 60 | 90 | 100 | 100 | 93.0 | 100 | [ |
5 | 硫酸(2.0mol·L-1) | 双氧水(体积分数2%) | 10 | 60 | 75 | 99.1 | — | — | 70 | [ |
6 | 盐酸(3.0mol·L-1) | — | 50 | 90 | 80 | 99.4 | — | — | — | [ |
7 | 盐酸(2.0mol·L-1) | 双氧水(体积分数5%) | 33 | 150 | 60 | >99 | >99 | >99 | >99 | [ |
8 | 硝酸(1.0mol·L-1) | 双氧水(体积分数1.7%) | 50 | 60 | 75 | 85 | — | — | 85 | [ |
9 | 磷酸(0.7mol·L-1) | 双氧水(体积分数4.0%) | 20 | 60 | 40 | >99 | — | — | >99 | [ |
序号 | 无机浸出剂 | 还原剂 | 固液比/mL·g-1 | 时间/min | 温度 /℃ | 浸出效率/% | 参考文献 | |||
---|---|---|---|---|---|---|---|---|---|---|
锂 | 镍 | 锰 | 钴 | |||||||
1 | 硫酸(2.0mol·L-1) | 双氧水(0.97mol·L-1) | 10 | 30 | 80 | 100 | 100 | 94 | 100 | [ |
2 | 硫酸(1.0mol·L-1) | 亚硫酸氢钠(0.075mol·L-1) | 50 | 240 | 95 | 96.7 | 96.4 | 87.9 | 91.6 | [ |
3 | 硫酸(1.0mol·L-1) | 双氧水(体积分数1%) | 25 | 60 | 40 | 99.7 | 99.7 | 99.7 | 99.7 | [ |
4 | 硫酸(1.0mol·L-1) | — | 10 | 60 | 90 | 100 | 100 | 93.0 | 100 | [ |
5 | 硫酸(2.0mol·L-1) | 双氧水(体积分数2%) | 10 | 60 | 75 | 99.1 | — | — | 70 | [ |
6 | 盐酸(3.0mol·L-1) | — | 50 | 90 | 80 | 99.4 | — | — | — | [ |
7 | 盐酸(2.0mol·L-1) | 双氧水(体积分数5%) | 33 | 150 | 60 | >99 | >99 | >99 | >99 | [ |
8 | 硝酸(1.0mol·L-1) | 双氧水(体积分数1.7%) | 50 | 60 | 75 | 85 | — | — | 85 | [ |
9 | 磷酸(0.7mol·L-1) | 双氧水(体积分数4.0%) | 20 | 60 | 40 | >99 | — | — | >99 | [ |
序号 | 有机浸出剂 | 还原剂 | 固液比/mL·g-1 | 时间/min | 温度/℃ | 浸出效率/% | 参考文献 | |||
---|---|---|---|---|---|---|---|---|---|---|
锂 | 镍 | 锰 | 钴 | |||||||
1 | DL-苹果酸 (1.2mol·L-1) | 双氧水 (体积分数1.5%) | 25 | 30 | 80 | 98.9 | 95.1 | 96.4 | 94.3 | [ |
2 | DL-苹果酸 (1.0mol·L-1) | 双氧水 (体积分数4.0%) | 200 | 30 | 80 | 98 | 97.8 | 97.3 | 97.6 | [ |
3 | 柠檬酸 (1.2mol·L-1) | 硫代硫酸钠 (0.3 mol·L-1) | 50 | 30 | 70 | 99 | — | — | 96 | [ |
4 | 柠檬酸 (0.5mol·L-1) | 双氧水 (体积分数1.5%) | 50 | 60 | 90 | >95 | >95 | >95 | >95 | [ |
5 | 抗坏血酸 (1.24mol·L-1) | — | 31.30 | 59.79 | 69.26 | 92.75 | 56.83 | 89.91 | 96.78 | [ |
6 | 草酸 (1.0mol·L-1) | — | 67 | 150 | 95 | 98 | — | — | 97 | [ |
8 | 乙酸 (3.0mol·L-1) | 双氧水 (体积分数7.5%) | 50 | 40 | 70 | 99.9 | — | 99.5 | 98.7 | [ |
9 | 酒石酸 (4倍LiCoO2的物质的量) | — | 67 | 300 | 90 | 91.9 | — | — | 93.0 | [ |
序号 | 有机浸出剂 | 还原剂 | 固液比/mL·g-1 | 时间/min | 温度/℃ | 浸出效率/% | 参考文献 | |||
---|---|---|---|---|---|---|---|---|---|---|
锂 | 镍 | 锰 | 钴 | |||||||
1 | DL-苹果酸 (1.2mol·L-1) | 双氧水 (体积分数1.5%) | 25 | 30 | 80 | 98.9 | 95.1 | 96.4 | 94.3 | [ |
2 | DL-苹果酸 (1.0mol·L-1) | 双氧水 (体积分数4.0%) | 200 | 30 | 80 | 98 | 97.8 | 97.3 | 97.6 | [ |
3 | 柠檬酸 (1.2mol·L-1) | 硫代硫酸钠 (0.3 mol·L-1) | 50 | 30 | 70 | 99 | — | — | 96 | [ |
4 | 柠檬酸 (0.5mol·L-1) | 双氧水 (体积分数1.5%) | 50 | 60 | 90 | >95 | >95 | >95 | >95 | [ |
5 | 抗坏血酸 (1.24mol·L-1) | — | 31.30 | 59.79 | 69.26 | 92.75 | 56.83 | 89.91 | 96.78 | [ |
6 | 草酸 (1.0mol·L-1) | — | 67 | 150 | 95 | 98 | — | — | 97 | [ |
8 | 乙酸 (3.0mol·L-1) | 双氧水 (体积分数7.5%) | 50 | 40 | 70 | 99.9 | — | 99.5 | 98.7 | [ |
9 | 酒石酸 (4倍LiCoO2的物质的量) | — | 67 | 300 | 90 | 91.9 | — | — | 93.0 | [ |
方法 | 优势 | 劣势 |
---|---|---|
共沉淀法 | 获得正极材料颗粒细小、形态规则、元素分布均匀,有良好的电化学性能 | 设备要求高、工艺复杂、成本高 |
溶胶-凝胶法 | 可以在不添加锂源的情况下合成正极材料,高度可控性 | 制造时间长、成本高等不足大大限制了其工业化发展 |
固相合成法 | 流程简单、成本低 | 很难除去其中的杂质,杂质的含量及分布将会影响其电化学性能 |
水热法 | 无杂质引入,步骤简单 | 需注意废液处理,防止环境污染 |
方法 | 优势 | 劣势 |
---|---|---|
共沉淀法 | 获得正极材料颗粒细小、形态规则、元素分布均匀,有良好的电化学性能 | 设备要求高、工艺复杂、成本高 |
溶胶-凝胶法 | 可以在不添加锂源的情况下合成正极材料,高度可控性 | 制造时间长、成本高等不足大大限制了其工业化发展 |
固相合成法 | 流程简单、成本低 | 很难除去其中的杂质,杂质的含量及分布将会影响其电化学性能 |
水热法 | 无杂质引入,步骤简单 | 需注意废液处理,防止环境污染 |
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