基于专利申请分析改性石油沥青路用发展态势

doi:10.16085/j.issn.1000-6613.2021-0473

摘要/Abstract

摘要：

近年来，技术创新在各个行业的发展中发挥着越来越重要的作用，随着知识经济新时代的到来，专利已经被公认为是衡量技术创新能力的一个重要科学指标。我国大量的石油沥青路面破损严重，各种非常规的问题相继出现，为了更好地了解改性石油沥青路用发展的研究现状和趋势，本文围绕近年来公开的专利成果并结合文献报道，归纳总结并分析了国内改性石油沥青专利技术路线的特点，结果说明了其改性剂必将更加环保，多种改性剂复合改性的效果良好，并提出了在物理方法制备的基础上，配合适当的化学稳定法，必能得到性能优异的路用改性石油沥青，最后对改性石油沥青的研究重点和方向进行了探讨，认为其材料会趋向于乳化高黏沥青，功能会趋向于复合化，施工机械小型化。旨在为国内改性石油沥青的研究和应用提供参考。

关键词: 石油, 专利, 路用性能, 混合物, 混合

Abstract:

In recent years, technological innovation plays a more and more important role in the development of various industries. With the arrival of a new era of knowledge economy, patents have been recognized as an important scientific index to measure the ability of technological innovation. A large number of petroleum asphalt pavement in China is seriously damaged, and various unconventional problems have appeared one after another,in order to better understand the research status and trend of modified petroleum asphalt pavement, this review summarizes and analyzes the characteristics of domestic modified petroleum asphalt patent technology route around the patent achievements published in recent years and combined with literature reports. The results show that the modifier will be more environmentally friendly, and the effect of compound modification of various modifiers is good. On the basis of physical preparation and appropriate chemical stabilization method, it is necessary to obtain road modified petroleum asphalt with excellent performance. On this basis, the research emphasis and direction of modified petroleum asphalt are discussed, and the material will tend to emulsify high viscosity asphalt, The function will tend to compound and the construction machinery will be miniaturized in order to provide reference for the research and application of modified petroleum asphalt in China.

Key words: petroleum, patent, road performance, mixtures, blend

中图分类号:

TE99

储一帆, 薛永兵, 李韬, 丁佳瑛, 王潇潇, 刘振民. 基于专利申请分析改性石油沥青路用发展态势[J]. 化工进展, 2021, 40(S2): 232-240.

CHU Yifan, XUE Yongbing, LI Tao, DING Jiaying, WANG Xiaoxiao, LIU Zhenmin. Analysis of development situation of modified petroleum asphalt road based on patent application[J]. Chemical Industry and Engineering Progress, 2021, 40(S2): 232-240.

图/表 4

图1 改性石油沥青专利申请量（随年份分布）

图2 改性石油沥青专利授权公开量（随年份分布）

图3 改性石油沥青专利申请技术的构成数字1~12—分别表示C08、C09、B32、E01、C04、F16、B01、C10、E02、E04、G01、H01

表1 申请人属性分布

申请人类别	高等院校	科研院所	各类企业	个人及其他
申请数量占比/％	28	14	44	14

参考文献 18

18	CAO Dongwei, WANG Shifeng, ZHANG Haiyan, et al. The invention relates to a thermoplastic elastomer, a preparation method and application thereof, and a composite modified asphalt mixture and a preparation method thereof: CN101885867B[P]. 2010-04-27.
19	吕伟民, 李立寒. 几种聚合物改性沥青性能的比较[J].石油沥青,1998(3):3-5.
	Weimin LYU, LI Lihan. Performance comparison of several polymer modified asphalt[J]. Petroleum Asphalt, 1998(3):3-5.
20	廖明义, 王强. 端胺基和羧基苯乙烯/丁二烯共聚物的合成及其制备贮存稳定的改性沥青的方法:CN 100448906C[P]. 2006-08-10.
	LIAO Mingyi, WANG Qiang. Synthesis of amine terminated and carboxyl terminated styrene/butadiene copolymers and preparation of storage stable modified asphalt: CN100448906C[P]. 2006-08-10.
21	陈凯, 权慧文, 高曰义, 等. 改性沥青及其制备方法:CN 1414038A[P]. 2003-04-30.
	CHEN Kai, QUAN Huiwen, GAO Yueyi, et al. Modified asphalt and its preparation method: CN1414038A[P]. 2003-04-30.
22	梁红文, 罗红平. 一种提高SBS与沥青相容稳定性的办法:CN 1365986A[P].2002-08-28.
	LIANG Hongwen, LUO Hongping. A method to improve the compatibility and stability of SBS and asphalt: CN1365986A[P]. 2002-08-28.
23	闫炳润. 一种废胶塑用于沥青路桥面再生养护材料的制造方法:CN 103388299A[P]. 2012-05-09.
	YAN Bingrun. A manufacturing method of recycled maintenance material for asphalt pavement deck using waste plastic: CN 103388299A[P]. 2012-05-09.
24	徐松, 胡昌斌, 张峰, 等. 一种湖沥青/SBS复合改性剂及其制备方法和应用: CN103497523B[P]. 2015-02-04.
1	沙庆林.沥青和沥青混凝土现状[J].交通运输工程学报, 2001, 1(3):1-6.
	SHA Qinglin. The development of asphalt and asphalt-concrete[J]. Journal of Traffic and Transportation Engineering, 2001, 1(3):1-6.
24	XU Song, HU Changbin, ZHANG Feng, et al. A lake asphalt/SBS composite modifier and its preparation method and application: CN103497523B[P].2015-02-04.
25	宋涛. 青川天然沥青矿制品在铺筑石油沥青路面中的应用:CN 1733869A[P].2004-08-11.
	SONG Tao. Application of Qingchuan natural asphalt mineral products in paving petroleum asphalt pavement: CN 1733869A[P].2004-08-11.
26	刘捷, 姚晓光.天然沥青改性沥青性能研究[J].公路交通科技, 2016,12(7):38-41.
	LIU Jie, YAO Xiaoguang. Study on properties of natural asphalt modified asphalt[J]. Journal of Highway and Transportion Research and Development, 2016, 12(7):38-41.
27	曾赟, 张彬, 张俊搏, 等. 一种天然沥青成品胶结料的加工工艺及配方: CN 107057386B[P]. 2017-05-26.
2	李涌. 关于等级公路沥青路面预防性养护决策的研究[J]. 科技展望, 2014(12): 53-54.
	LI Yong. Research on preventive maintenance decision of asphalt pavement of grade highway[J]. Science and Technology, 2014(12):53-54.
3	李潇,蒋福山,时敬涛, 等.胶粉沥青行业专利分析与探讨[J].化学世界, 2015, 56(8): 496-500.
	LI Xiao, JIANG Fushan, SHI Jingtao, et al. Patent analysis and discussion of rubberized asphalt industry[J]. Chemical World, 2015, 56(8):496-500.
4	杨剑, 杨安, 徐万昌, 等.石油沥青生产技术及质量要求探讨[J].化工管理, 2016(32): 159.
	YANG Jian, YANG An, XU Wanchang, et al. Chemical discussion on production technology and quality requirements of petroleum asphalt[J]. Chemical Enterprise Management, 2016(32): 159.
5	董克学.石油沥青的生产技术及质量要求[J].化工管理, 2015(28): 143.
	DONG Kexue. Production technology and quality requirements of petroleum asphalt[J]. Chemical Enterprise Management, 2015(28): 143.
6	卞文志.交通“十三五”规划:将为提升综合运输服务能力插上翅膀[J].大陆桥视野, 2016(11): 36-38.
	BIAN Wenzhi. The 13th five year plan of transportation: to improve the comprehensive transportation service capacity[J]. New Silk Road Horizon, 2016(11): 36-38.
7	贺利良.浅谈对授权专利的检索[J].专利代理, 2019(1): 81-84.
	HE Liliang. On the retrieval of authorized patents[J]. Patent Agency, 2019(1): 81-84.
8	马勇平.CPC分类号与IPC分类号在专利检索中的应用比较[J].河南科技, 2020(12): 77-79.
	MA Yongping. Comparison of CPC classification number and IPC classification number in patent retrieval[J]. Journal of Henan Science and Technology, 2020(12): 77-79.
9	刘淑昌, 张敬义, 周文生, 等. 丁苯橡胶改性沥青及制法:CN 1053438A[P].1990-12-21.
	LIU Shuchang, ZHANG Jingyi, ZHOU Wensheng, et al. Styrene butadiene rubber modified asphalt and its preparation: CN1053438A[P]. 1990-12-21.
10	龙军, 李首先, 郭淑华, 等. 一种改善老化性能的道路沥青生产方法: CN1093154C[P].1998-04-07.
	LONG Jun, LI Shouxian, GUO Shuhua, et al. A production method of road asphalt for improving aging performance: CN1093154C[P].1998-04-07.
11	黄贵秋. 聚合物改性沥青的制备及性能研究[D]. 钦州: 钦州学院,2013.
	HUANG Guiqiu. Preparation and properties of polymer modified asphalt[D]. Qinzhou: Qinzhou University, 2013.
12	郭淑华, 黄伟祈, 王子军, 等. 一种提高储存稳定性的改性沥青制备方法: CN 1111195C[P]. 2000-08-18.
	GUO Shuhua, HUANG Weiqi, WANG Zijun, et al. A preparation method of modified asphalt for improving storage stability:CN 1111195C[P].2000-08-18.
13	吉永海, 郭淑, 华李锐. 储存稳定、高低温性能良好的沥青组合物及其制备方法:CN 1175050C[P]. 2001-04-28.
	JI Yonghai,GUO Shu,HUA Lirui. Asphalt composition with stable storage and good high and low temperature performance and its preparation method: CN1175050C[P].2001-04-28.
14	梁清源, 柯荣卿. 沥青共聚烯烃复合材料及其制造方法:CN 1103353C[P].2000-09-18.
	LIANG Qingyuan, KE Rongqing. Asphalt copolyolefin composite and its manufacturing method: CN1103353C[P].2000-09-18.
27	ZENG Yun, ZHANG Bin, ZHANG Junbo, et al. Processing technology and formula of a natural asphalt binder:CN107057386B[P].2017-05-26.
28	申力涛, 杜素军, 薛君, 等.一种煤油共处理残渣改性石油沥青的生产方法: CN103497523B[P]. 2015-02-04.
	SHEN Litao, DU Sujun, XUE Jun, et al. A production method of modified petroleum asphalt with kerosene CO treatment residue: CN103497523B[P]. 2015-02-04.
29	蔡丽娜, 穆建青, 刘哲, 等. 一种复合改性混合沥青及其制备方法:CN105482472B[P]. 2015-12-25.
	CAI Lina, MU Jianqing, LIU Zhe, et al.A composite modified mixed asphalt and its preparation method: CN105482472B[P]. 2015-12-25.
30	杨建丽, 刘振宇, 王寨霞, 等. 一种道路沥青改性剂及其应用方法: CN100439449C[P]. 2006-03-30.
	YANG Jianli, LIU Zhenyu, WANG Zhaixia, et al. A road asphalt modifier and its application: CN100439449C[P].2006-03-30.
31	王寨霞, 杨建丽, 刘振宇. 煤直接液化残渣对道路沥青改性作用的初步评价[J].燃料化学学报, 2007, 35(1): 109-112.
	WANG Zhaixia, YANG Jianli, LIU Zhenyu. Preliminary study on direct coal liquefaction residue as paving asphalt modifier[J]. Journal of Fuel Chemistry and Technology, 2007, 35(1): 109-112.
32	蔡丽娜, 穆建青, 刘清波, 等. 一种复合改性混合沥青及其制备方法:CN 105482472B[P].2018-02-09.
	CAI Lina, MU Jianqing, LIU Qingbo, et al. A composite modified mixed asphalt and its preparation method: CN 105482472B[P].2018-02-09.
33	季节, 徐世法, 王迪, 等. 煤直接液化残渣改性沥青混合料及其制备方法:CN 105174824B[P]. 2015-09-10.
	JI Jie, XU Shifa, WANG Di, et al. Direct coal liquefaction residue modified asphalt mixture and its preparation method: CN105174824B[P]. 2015-09-10.
34	张胜振, 宫晓颐, 赖世耀, 等. 含煤直接液化残渣的道路沥青改性剂和改性道路沥青及其制备方法: CN104513488 B[P]. 2013-09-30.
	ZHANG Shengzhen, GONG Xiaoying, LAI Shiyao, et al. Road asphalt modifier containing coal direct liquefaction residue, modified road asphalt and its preparation method: CN104513488 B[P]. 2013-09-30.
35	曹嘉慧, 申峻, 王玉高, 等. 共混沥青烟中16种多环芳烃的释放规律[J]. 煤炭转化, 2019, 42(5): 88-96.
15	佘玉成, 王子军, 龙军, 等. 一种接枝型沥青改性母料及其制备方法:CN 1281677C[P]. 2006-10-25.
	SHE Yucheng, WANG Zijun, LONG Jun, et al. A kind of grafted asphalt modified masterbatch and its preparation method: CN1281677C[P]. 2006-10-25.
35	CAO Jiahui, SHEN Jun, WANG Yugao, et al. Release of 16 polycyclic aromatic hydrocarbons from blended asphalt smoke[J]. Coal Conversion,2019,42(5):88-96.
36	许振明, 郭久勇, 郭杰, 等. 利用废弃电路板非金属粉制备改性沥青的方法: CN101353585B[P]. 2011-08-31.
16	李志军, 宁爱民, 程国香. 一种开级配路面用的聚合物改性沥青胶结料及其制备方法:CN 1325568C[P].2004-10-29.
	LI Zhijun, NING Aimin, CHENG Guoxiang. A polymer modified asphalt binder for open graded pavement and its preparation method:CN 1325568C[P].2004-10-29.
36	XU Zhenming, GUO Jiuyong, GUO Jie, et al. The method of preparing modified asphalt by using scrap circuit board non-metallic powder: CN101353585B[P]. 2011-08-31.
37	季节, 索智, 石越峰, 等. 煤直接液化残渣与沥青共混后的性能试验研究[J].公路交通科技, 2016, 33(5): 33-38.
	JI Jie, SUO Zhi, SHI Yuefeng, et al.Experimental study on properties of asphalt blended with direct coal liquefaction residue[J]. Journal of Highway and Transportation Research and Development,2016,33(5):33-38.
38	苏建丽. 一种石油沥青改性剂及其制备: CN105153717A[P]. 2015-12-16.
	SU Jianli. A petroleum asphalt modifier and its preparation: CN 105153717A[P]. 2015-12-16.
39	王翠红, 余玉成, 王红. 硬质道路石油沥青产品开发[J].石油沥青,2019, 33(2): 1-4.
	WANG Cuihong, YU Yucheng, WANG Hong. Development of hard pavement asphalt[J]. Petroleum Asphalt, 2019, 33(2): 1-4.
40	王翠红. 硬质道路石油沥青关键组分的研制[J].石油炼制与化工,2019,50(2):36-39.
	WANG Cuihong. Development of key component of hard pavement bitumen[J]. Petroleum Processing and Petrochemicals,2019,50(2):36-39.
17	余剑英, 吴少鹏, 曾旋, 等. 一种耐老化改性沥青及其制备方法:CN1935905B[P].2010-05-12.
	YU Jianying, WU Shaopeng, ZENG Xuan, et al. An aging resistant modified asphalt and its preparation method:CN1935905B[P].2010-05-12.
18	曹东伟, 王仕峰, 张海燕, 等. 一种热塑性弹性体、其制备方法和用途以及一种复合改性沥青混合料及其制备方法:CN101885867B[P]. 2010-04-27.

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