钴酸镍基纳米材料在超级电容器中的研究进展

doi:10.16085/j.issn.1000-6613.2020-1540

摘要/Abstract

摘要：

电极材料是决定超级电容器性能的关键因素。钴酸镍纳米材料因其合成简单，价格低廉，储量丰富且理论比电容较高等优点，成为超级电容器电极材料的研究热点。但钴酸镍纳米材料导电率较低、比表面积较小且电化学稳定性较差等缺点严重影响了其实际应用。本文简单介绍了钴酸镍纳米材料的晶体结构以及其作为超级电容器电极材料时的储能机理，同时结合一些示例归纳总结了钴酸镍基纳米材料的制备方法以及钴酸镍纳米材料的改性研究现状，包括形貌改性、复合改性及引入缺陷。最后指出，钴酸镍基纳米材料的环保且高效的制备方法，通过掺杂或缺陷等方法改善其电化学性能，增大其工作电压窗口以及探索适用于钴酸镍基超级电容器工作的电解液，将是未来研究的重点。

关键词: 超级电容器, 钴酸镍, 制备方法, 复合电极材料, 赝电容

Abstract:

Electrode materials play a vital role on the performance of supercapacitors. Hence, it is important to develop novel electrode materials with excellent properties. NiCo₂O₄ has the advantages of easy synthesis, low cost, abundant natural resources and high theoretical capacitance, and has been widely studied as novel electrode materials for supercapacitors. However, the low conductivity, small specific surface area and poor electrochemical stability of NiCo₂O₄ has seriously limited its application. In this review, we present a brief description of the structure of NiCo₂O₄ and the energy storage mechanism of supercapacitors. Furthermore, we review several synthetic methods of NiCo₂O₄ and current modification researches, including morphology modification, composite modification and imported defects. In the future, the research should focus on the environmental friendly and efficient preparation method, improving the electrochemical performance by doping or defects, increasing the working voltage window and exploring suitable electrolytes.

Key words: supercapacitor, nickel cobaltate, synthesis method, composite electrode material, pseudocapacitors

中图分类号:

TB33

何广源, 陈学敏, 王雨婷, 李发堂, 张子健, 许文浩. 钴酸镍基纳米材料在超级电容器中的研究进展[J]. 化工进展, 2021, 40(7): 3813-3825.

HE Guangyuan, CHEN Xuemin, WANG Yuting, LI Fatang, ZHANG Zijian, XU Wenhao. Research progress of nickel cobaltite based nanomaterials in supercapacitors[J]. Chemical Industry and Engineering Progress, 2021, 40(7): 3813-3825.

图/表 11

图1 三种NiCo2O4尖晶石的代表晶体结构[13]蓝色多面体和紫色多面体—分别代表金属原子占据的四面体和八面体

图2 NiCo2O4的电荷存储机制示意图[20]

表1 不同制备方法得到的NiCo2O4基电极材料电化学性能对比

材料	合成方法	理论比电容/F·g^-1	循环性	参考文献
NiCo₂O_4NSs@HfC_NWs/CC	电沉积法	2102（1A/g）	98%（10A/g，5000）	［22］
rGO/NiCo₂O₄ 纳米复合材料	水热法	1003（1A/g）	57%（10A/g，10000）	［27］
层级NiCo₂O₄	水热法	2623.3（1A/g）	94%（10A/g，3000）	［29］
花状NiCo₂O₄	微波法	1006（1A/g）	93.2%（8A/g，1000）	［34］
微球
微米级NiCo₂O₄绒球	共模板法	2201.7（2A/g）	85.8%（10A/g，3000）	［39］
3D多孔NiCo₂O₄	硬模板法	1389（1A/g）	80%（4A/g，2500）	［42］
NiCo₂O₄薄膜	溶胶-凝胶法	2157（0.133mA/cm²）	96.5%（0.53mA/cm²，10000）	［50］
NiCo₂O₄空心微球	热分解法	902（1A/g）	89%（20mV/s，2500）	［53］

图3 不同放大倍数下NiCo2O4和rGO/NiCo2O4的SEM图[27]

图4 反应温度为100℃时不同反应时间所得NiCo2O4花状微球的SEM图[34]

图5 新型微米级NiCo2O4绒球[39]（插图：波黑孔径分布）

图6 NiCo2O4纳米线与NiCo2O4纳米颗粒的场发射扫描电子显微镜（FESEM）图[55]

图7 碳纤维织物上制备NiCo2-xFexO4纳米管阵列的实验过程[59]

图8 二维超薄NiCo2O4纳米片阵列制备过程和结构[62]

图9 泡沫镍上三维NiCo2O4@NiCo2O4核壳纳米锥阵列的制备工艺示意[63]

图10 氧空位形成示意[84]

参考文献 85

1	SIMON P, GOGOTSI Y, DUNN B. Where do batteries end and supercapacitors begin?[J]. Science, 2014, 343(6167): 1210-1211.
2	WANG Y, SONG Y, XIA Y. Electrochemical capacitors: mechanism, materials, systems, characterization and applications[J]. Chemical Society Reviews, 2016, 45(21): 5925-5950.
3	MURALEE GOPI C V V, VINODH R, SAMBASIVAM S, et al. Recent progress of advanced energy storage materials for flexible and wearable supercapacitor: from design and development to applications[J]. Journal of Energy Storage, 2020, 27: 101035.
4	LIU Z, TIAN D, SHEN F, et al. Valorization of composting leachate for preparing carbon material to achieve high electrochemical performances for supercapacitor electrode[J]. Journal of Power Sources, 2020, 458: 228057.
5	LI J, LIU Z, ZHANG Q, et al. Anion and cation substitution in transition-metal oxides nanosheets for high-performance hybrid supercapacitors[J]. Nano Energy, 2019, 57: 22-33.
6	LI H, CHEN X, ZALNEZHAD E, et al. 3D hierarchical transition-metal sulfides deposited on Mxene as binder-free electrode for high-performance supercapacitors[J]. Journal of Industrial and Engineering Chemistry, 2020, 82: 309-316.
7	MENG Q, CAI K, CHEN Y, et al. Research progress on conducting polymer based supercapacitor electrode materials[J]. Nano Energy, 2017, 36: 268-285
8	TAREEN J A K, MALECKI A, DOUMERC J P, et al. Growth and electrical properties of pure and Ni-doped Co₃O₄ single crystals[J]. Materials Research Bulletin, 1984, 19(8): 989-997.
9	SICKAFUS K E, WILLS J M. Spinel compounds: structure and property relations[J]. Journal of American Ceramic Society, 1999, 82(12): 3279-3292.
10	SEKO A, YUGE K, OBA F, et al. Prediction of ground-state structures and order-disorder phase transitions in Ⅱ‍-‍Ⅲ spinel oxides: a combined cluster-expansion method and first-principles study[J]. Physical Review B, 2006, 73(18): 184117.
11	BASHIR A, SHUKLA S, BASHIR R, et al. Low temperature, solution processed spinel NiCo₂O₄ nanoparticles as efficient hole transporting material for mesoscopic n-i-p perovskite solar cells[J]. Solar Energy, 2020, 196: 367-378.
12	HILL R J, CRAIG J R, GIBBS G V. Systematics of the spinel structure type[J]. Physics and Chemistry of Minerals, 1979, 4(4): 317-339.
13	陈祥, 雷凯翔, 孙洪明, 等. 尖晶石型氧化物催化剂与金属-空气电池[J]. 储能科学与技术, 2017, 6(5): 904-923.
	CHEN Xiang, LEI Kaixiang, SUN Hongming, et al. Spinel-type transition metal oxide electrocatalysts for metal-air batteries[J]. Energy Storage Science and Technology, 2017, 6(5): 904-923
14	GRIMES R W, ANDERSON A B, HEUER A H. Predictions of cation distributions in AB₂O₄ spinels from normalized ion energies[J]. Journal of the American Chemical Society, 1989, 111(1): 1-7.
15	许家胜, 宋忠笑, 张杰, 等. 尖晶石结构的钴基金属氧化物超级电容器电极材料的研究进展[J]. 电子元件与材料, 2016, 35(5): 1-6.
	XU Jiasheng, SONG Zhongxiao, ZHANG Jie, et al. Research progress of cobalt based metal oxides with spinel structure for supercapacitor electrodes[J]. Electronic Components and Materials, 2016, 35(5): 1-6.
16	NIKOLOV I, DARKAOUI R, ZHECHEVA E, et al. Electrocatalytic activity of spinel related cobaltites M_xCo_3-_xO₄ (M = Li, Ni, Cu) in the oxygen evolution reaction[J]. Journal of Electroanalytical Chemistry, 1997, 429(1/2): 157-168.
17	CUI B, LIN H, LIU Y, et al. Photophysical and photocatalytic properties of core-ring structured NiCo₂O₄ nanoplatelets[J]. Journal of Physical Chemistry C, 2009, 113(32): 14083-14087.
18	LI Y, HAN X, YI T, et al. Review and prospect of NiCo₂O₄-based composite materials for supercapacitor electrodes[J]. Journal of Energy Chemistry, 2019, 31: 54-78.
19	WANG G, ZHANG L, ZHANG J. A review of electrode materials for electrochemical supercapacitors[J]. Chemical Society Reviews, 2012, 41(2): 797-828.
20	ZHANG Y, LI L, SU H, et al. Binary metal oxide: advanced energy storage materials in supercapacitors[J]. Journal of Materials Chemistry A, 2015, 3(1): 43-59.
21	WU Z, ZHU Y, JI X. NiCo₂O₄-based materials for electrochemical supercapacitor[J]. Journal of Materials Chemistry A, 2014, 2(36): 14759-14772.
22	YIN X, LI H, FU Y, et al. Hierarchical core-shell structure of NiCo₂O₄ nanosheets@HfC nanowires networks for high performance flexible solid-state hybrid supercapacitor[J]. Chemical Engineering Journal, 2020, 392: 124820.
23	WANG N, SUN B, ZHAO P， ‍al et. Electrodeposition preparation of NiCo₂O₄ mesoporous film on ultrafine nickel wire for flexible asymmetric supercapacitors[J]. Chemical Engineering Journal, 2018, 345: 31-38.
24	FENG H, GAO S, SHI J, et al. Construction of 3D hierarchical porous NiCo₂O₄/graphene hydrogel/Ni foam electrode for high-performance supercapacitor[J]. Electrochimica Acta, 2019, 299: 116-124.
25	WALSH F C, WANG S, ZHOU N. The electrodeposition of composite coatings: diversity, applications and challenges[J]. Current Opinion in Electrochemistry, 2020, 20: 8-19.
26	FENG S, XU R. New materials in hydrothermal synthesis[J]. Accounts of Chemical Research, 2001, 34(3): 239-247.
27	ZHANG S, GAO H, ZHOU J, et al. Hydrothermal synthesis of reduced graphene oxide-modified NiCo₂O₄ nanowire arrays with enhanced reactivity for supercapacitors[J]. Journal of Alloys and Compounds, 2019, 792: 474-480.
28	SIWATCH P, SHARMA K, TRIPATHI S K. Facile synthesis of NiCo₂O₄ quantum dots for asymmetric supercapacitor[J]. Electrochimica Acta, 2020, 329: 135084.
29	GAO J, LIU Z, LIN Y, et al. NiCo₂O₄ nanofeathers derived from prussian blue analogues with enhanced electrochemical performance for supercapacitor[J]. Chemical Engineering Journal, 2020, 388: 124368.
30	WANG J, ZHANG Y, YE J, et al. Facile synthesis of three-dimensional NiCo₂O₄ with different morphology for supercapacitors[J]. RSC Advances, 2016, 6(74): 70077-70084.
31	GIGUERE R J, BRAY T L, DUNCAN S M, et al. Application of commercial microwave ovens to organic synthesis[J]. Tetrahedron Letters, 1986, 27(41): 4945-4948.
32	HARUNA A B, OZOEMENA K I. Effects of microwave irradiation on the electrochemical performance of manganese-based cathode materials for lithium-ion batteries[J]. Current Opinion in Electrochemistry, 2019, 18: 16-23.
33	BILECKA I, NIEDERBERGER M. Microwave chemistry for inorganic nanomaterials synthesis[J]. Nanoscale, 2010, 2(8): 1358-1374.
34	LEI Y, LI J, WANG Y, et al. Rapid microwave-assisted green synthesis of 3D hierarchical flower-shaped NiCo₂O₄ microsphere for high-performance supercapacitor[J]. ACS Applied Materials Interfaces, 2014, 6(3): 1773-1780.
35	WANG J, FANG Z, LI T, et al. Highly hydrophilic carbon dots’ decoration on NiCo₂O₄ nanowires for greatly increased electric conductivity, supercapacitance, and energy density[J]. Advanced Materials Interfaces, 2019, 6(9): 1900049.
36	SHANMUGAVANI A, SELVAN R K. Microwave assisted reflux synthesis of NiCo₂O₄/NiO composite: fabrication of high performance asymmetric supercapacitor with Fe₂O₃[J]. Electrochimica Acta, 2016, 189: 283-294.
37	GU D, SCHÜTH F. Synthesis of non-siliceous mesoporous oxides[J]. Chemical Society Reviews, 2014, 43(1): 313-344.
38	YANG P, ZHAO D, MARGOLESE D I, et al. Block copolymer templating syntheses of mesoporous metal oxides with large ordering lengths and semicrystalline framework[J]. Chemistry of Materials, 1999, 11(10): 2813-2826.
39	LI C, GAO X, LI S, et al. Novel micron-sized NiCo₂O₄pompon directed by a co-template methodas capacitor electrode[J]. Materials Letters, 2019, 244: 74-77.
40	RUMPLECKER A, KLEITZ F, SALABAS E, et al. Hard templating pathways for the synthesis of nanostructured porous Co₃O₄[J]. Chemistry of Materials, 2007, 19(3): 485-496.
41	LU A, SCHÜTH F. Nanocasting: a versatile strategy for creating nanostructured porous materials[J]. Advanced Materials, 2006, 18(14): 1793-1805.
42	BAI Y, WANG R, LU X, et al. Template method to controllable synthesis 3D porous NiCo₂O₄withenhanced capacitance and stability for supercapacitors[J]. Journal of Colloid and Interface Science, 2016, 468: 1-9.
43	HUANG L, ZHANG W, XIANG J, et al. Porous NiCo₂O₄/C nanoﬁbers replicated by cotton template as high-rate electrode materials for supercapacitors[J]. Journal of Materiomics, 2016, 2(3): 248-255.
44	GRAHAM T. ⅩⅩⅩⅤ.-On the properties of silicic acid and other analogous colloidal substances[J]. Journal of the Chemical Society, 1864, 17: 318-327.
45	HENCE L L, WEST J K. The sol-gel process[J]. Chemical Reviews, 1990, 90(1): 33-72.
46	CIRIMINNA R, FIDALGO A, PANDARUS V, et al. The sol-gel route to advanced silica-based materials and recent applications[J]. Chemical Reviews, 2013, 113(8): 6592-6620.
47	NISTICÒ R, SCALARONE D, MAGNACCA G. Sol-gel chemistry, templating and spin-coating deposition: a combined approach to control in a simple way the porosity of inorganic thin films/coatings[J]. Microporous and Mesoporous Materials, 2017, 248: 18-29.
48	武志刚, 高建峰. 溶胶-凝胶法制备纳米材料的研究进展[J]. 精细化工, 2010, 27(1): 21-25.
	WU Zhigang, GAO Jianfeng. Advances in synthesis of nanomaterials by sol-gel method[J]. Fine Chemicals, 2010, 27(1): 21-25.
49	WU Y Q, CHEN X Y, JI P T, et al. Sol-gel approach for controllable synthesis and electrochemical properties of NiCo₂O₄ crystals as electrode materials for application in supercapacitors[J]. Electrochimica Acta, 2011, 56(22): 7517-7522.
50	LIU Y, WANG N, YANG C, et al. Sol-gel synthesis of nanoporous NiCo₂O₄ thin films on ITO glass as high-performance supercapacitor electrodes[J]. Ceramics International, 2016, 42(9): 11411-11416.
51	WEI T, CHEN C, CHIEN H, et al. A cost-effective supercapacitor material of ultrahigh specific capacitances: spinel nickel cobaltite aerogels from an epoxide-driven sol-gel process[J]. Advanced Materials (Deerfield Beach, Fla), 2010, 22(3): 347-351.
52	XU L, ZHANG L, CHENG B, et al. Rationally designed hierarchical NiCo₂O₄-C@Ni(OH)₂ core-shell nanofibers for high performance supercapacitors[J]. Carbon, 2019, 152: 652-660.
53	MA Y, YU Z, LIU M, et al. Deposition of binder-free oxygen-vacancies NiCo₂O₄ based films with hollow microspheres via solution precursor thermal spray for supercapacitors[J]. Ceramics International, 2019, 45(8): 10722-10732.
54	WEI Z, GUO J, QU M, et al. Honeycombed-like nanosheet array composite NiCo₂O₄/rGO for eﬃcient methanol electrooxidation and supercapacitors[J]. Electrochimica Acta, 2020, 362: 137145.
55	CHATTERJEE M, SAHA S, DAS S, et al. Advanced asymmetric supercapacitor with NiCo₂O₄ nanoparticles and nanowires electrodes: a comparative morphological hierarchy[J]. Journal of Alloys and Compounds, 2020, 821: 153503.
56	DING R, QI L, WANG H. A facile and cost-effective synthesis of mesoporous NiCo₂O₄ nanoparticles and their capacitive behavior in electrochemical capacitors[J]. Journal of Solid State Electrochemistry, 2012, 16(11): 3621-3633.
57	ZHANG G, XIAO X, LI B, et al. Transition metal oxides with one-dimensional/one-dimensional-analogue nanostructures for advanced supercapacitors[J]. Journal of Materials Chemistry A, 2017, 5(18): 8155-8186.
58	HAO C, ZHOU S, WANG J, et al. Preparation of hierarchical spinel NiCo₂O₄ nanowires for high-performance supercapacitors[J]. Industrial & Engineering Chemistry Research, 2018, 57(7): 2515-2525.
59	LIU Z, WANG Z, CHENG Y, et al. Facile synthesis of NiCo_2-_xFe_xO₄ nanotubes/carbon textiles composites for high-performance electrochemical energy storage devices[J]. ACS Applied Nano Materials, 2018, 1(2): 997-1002.
60	YUNG W K C, LI G, LIEM H M, et al. Eye-friendly reduced graphene oxide circuits with nonlinear optical transparency on flexible poly(ethylene terephthalate) substrates[J]. Journal of Materials Chemistry C, 2015, 3(43): 11294-11299.
61	LIU Y, PENG X. Recent advances of supercapacitors based on two-dimensional materials[J]. Applied Materials Today, 2017, 8: 104-115.
62	ZHANG X, YANG F, CHEN H, et al. In situ growth of 2D ultrathin NiCo₂O₄ nanosheet arrays on Ni foam for high performance and flexible solid-state supercapacitors[J]. Small, 2020, 16(44): 2004188.
63	LI W, HUANG Y, LIU Y, et al. Three dimensional nanosuperstructures made of two-dimensional materials by design: synthesis, properties, and applications[J]. Nano Today, 2019, 29: 100799.
64	WANG H, FANG Y, SHI B, et al. Three-dimensional NiCo₂O₄@NiCo₂O₄ core-shell nanocones arrays for high performance supercapacitors[J]. Chemical Engineering Journal, 2018, 344: 311-319.
65	JIANG H, MA J, LI C. Hierarchical porous NiCo₂O₄ nanowires for high-rate supercapacitors[J]. Chemical Communications, 2012, 48(37): 4465.
66	SINGH A, OJHA S K, OJHA A K. Facile synthesis of porous nanostructures of NiCo₂O₄ grown on rGO sheet for high performance supercapacitors[J]. Synthetic Metals, 2020, 259: 116215.
67	MAO N, WANG H, SUI Y, et al. Extremely high-rate aqueous supercapacitor fabricated using doped carbon nanoflakes with large surface area and mesopores at near-commercial mass loading[J]. Nano Research, 2017, 10(5): 1767-1783.
68	金玉红, 王莉, 尚玉明, 等. 尖晶石结构NiCo₂O₄材料在超级电容器中的应用进展[J]. 储能科学与技术, 2015, 4(1): 44-54.
	JIN Yuhong, WANG Li, SHANG Yuming, et al. Development of spinel Ni Co₂O₄ nanostructure material for application in supercapacitors[J]. Energy Storage Science and Technology, 2015, 4(1): 44-54.
69	WANG K, HUANG J, WEI Z. Conducting polyaniline nanowire arrays for high performance supercapacitors[J]. Journal of Physical Chemistry C, 2010, 114(17): 8062-8067.
70	LI C, BAI H, SHI G. Conducting polymer nanomaterials: electrosynthesis and applications[J]. Chemical Society Reviews, 2009, 38(8): 2397-2409.
71	BOOPATHIRAJA R, PARTHIBAVARMAN M. Desert rose like heterostructure of NiCo₂O₄/NF@PPy composite has high stability and excellent electrochemical performance for asymmetric super capacitor application[J]. Electrochimica Acta, 2020, 346: 136270.
72	LI Y, ZHANG Z, CHEN Y, et al. Facile synthesis of a Ni-based NiCo₂O₄-PANI composite for ultrahigh specific capacitance[J]. Applied Surface Science, 2020, 506: 144646.
73	LI Y, PAN J, WU J, et al. Mesoporous NiCo₂O₄, nanoneedles@MnO₂, nanoparticles grown on nickel foam for electrode used in high-performance supercapacitors[J]. Journal of Energy Chemistry, 2019, 31: 167-177.
74	CHEN D, PANG D, ZHANG S, et al. Synergistic coupling of NiCo₂O₄ nanorods onto porous Co₃O₄ nanosheet surface for tri-functional glucose, hydrogen-peroxide sensors and supercapacitor[J]. Electrochimica Acta, 2020, 330: 135326.
75	BARIK R, INGOLE P P. Challenges and prospects of metal sulfide materials for supercapacitors[J]. Current Opinion in Electrochemistry, 2020, 21: 327-334.
76	CAO L, TANG G, MEI J, et al. Construct hierarchical electrode with Ni_xCo_3-_xS₄ nanosheet coated on NiCo₂O₄ nanowire arrays grown on carbon fiber paper for high-performance asymmetric supercapacitors[J]. Journal of Power Sources, 2017, 359: 262-269.
77	WANG X, SHI B, HUANG F, et al. Fabrication of hierarchical NiCo₂O₄@NiCo₂S₄ core/shell nanowire arrays by an ion-exchange route and application to asymmetric supercapacitors[J]. Journal of Alloys and Compounds, 2018, 767: 232-240.
78	CHANG L, LI C, OUYANG H, et al. Flexible NiCo₂O₄@carbon/carbon nanoﬁber electrodes fabricated by a combined electrospray/electrospinning technique for supercapacitors[J]. Materials Letters, 2019, 240: 21-24.
79	LUO J H, WANG J, LIU S, et al. Graphene quantum dots encapsulated tremella-like NiCo₂O₄ for advanced asymmetric supercapacitors[J]. Carbon, 2019, 146: 1-8.
80	ZHANG J N, LIU P, JIN L N, et al. Three-dimensional hierarchical NiCo₂O₄ nanosheets/carbon nanotubes/carbon cloth as a flexible electrode material for electrochemical capacitors[J]. ChemistrySelect, 2017, 2(27): 8618-8624.
81	WANG L, XIE X, DINH K N, et al. Synthesis, characterizations, and utilization of oxygen-deficient metal oxides for lithium/sodium-ion batteries and supercapacitors[J]. Coordination Chemistry Reviews, 2019, 397: 138-167.
82	WANG G, YANG Y, HAN D, et al. Oxygen defective metal oxides for energy conversion and storage[J]. Nano Today, 2017, 13: 23-39.
83	YAN D, WANG W, LUO X, et al. NiCo₂O₄ with oxygen vacancies as better performance electrode material for supercapacitor[J]. Chemical Engineering Journal, 2018, 334: 864-872.
84	ZHAO T, LIU C, YI F, et al. Hollow N-doped carbon @ O-vacancies NiCo₂O₄ nanocages with a built-in electric ﬁeld as high-performance cathodes for hybrid supercapacitor[J]. Electrochimica Acta, 2020, 364: 137260.
85	CAO Z, LIU C, HUANG Y, et al. Oxygen-vacancy-rich NiCo₂O₄ nanoneedles electrode with poor crystallinity for high energy density all-solid-state symmetric supercapacitors[J]. Journal of Power Sources, 2020, 449: 227571.

[1]	张耀杰, 张传祥, 孙悦, 曾会会, 贾建波, 蒋振东. 煤基石墨烯量子点在超级电容器中的应用[J]. 化工进展, 2023, 42(8): 4340-4350.
[2]	陈怡欣, 甄摇摇, 陈瑞浩, 吴继伟, 潘丽美, 姚翀, 罗杰, 卢春山, 丰枫, 王清涛, 张群峰, 李小年. 铂基纳米催化剂的制备及在加氢领域的进展[J]. 化工进展, 2023, 42(6): 2904-2915.
[3]	朱薇, 齐鹏刚, 苏银海, 张书平, 熊源泉. 生物油分级多孔碳超级电容器电极材料的制备及性能[J]. 化工进展, 2023, 42(6): 3077-3086.
[4]	陈飞, 刘成宝, 陈丰, 钱君超, 邱永斌, 孟宪荣, 陈志刚. g-C₃N₄基超级电容器用电极材料的研究进展[J]. 化工进展, 2023, 42(5): 2566-2576.
[5]	王钰琢, 李刚. 硫、氮共掺杂三维石墨烯的全固态超级电容器[J]. 化工进展, 2023, 42(4): 1974-1982.
[6]	万茂华, 张小红, 安兴业, 龙垠荧, 刘利琴, 管敏, 程正柏, 曹海兵, 刘洪斌. MXene在生物质基储能纳米材料领域中的应用研究进展[J]. 化工进展, 2023, 42(4): 1944-1960.
[7]	蔡江涛, 候刘华, 兰雨金, 张晨陈, 刘国阳, 朱由余, 张建兰, 赵世永, 张亚婷. 沥青基多孔炭材料的制备及在超级电容器中的应用进展[J]. 化工进展, 2023, 42(4): 1895-1906.
[8]	杜保宁, 赵珊, 刘向卿, 张毅, 肖雅茹, 张少飞, 李田田, 孙金峰. 纳米多孔CuMn基氧化物电极的制备及性能[J]. 化工进展, 2023, 42(3): 1484-1492.
[9]	张育新, 王灿, 舒文祥. 二氧化碳的还原及其利用研究进展[J]. 化工进展, 2023, 42(2): 944-956.
[10]	卓祖优, 宋生南, 黄明堦, 杨旋, 卢贝丽, 陈燕丹. 草酸钾-尿素协同活化法制备超大比表面积面粉基多级孔炭及其电化学储能应用[J]. 化工进展, 2023, 42(2): 925-933.
[11]	杨泛明, 贺国文. 颗粒状NiO的制备及其电化学性能和CO₂吸附性能[J]. 化工进展, 2023, 42(2): 907-916.
[12]	田甜, 雷西萍, 于婷, 樊凯, 宋晓琪, 朱航. 碳材料在柔性超级电容器中的研究进展[J]. 化工进展, 2023, 42(2): 884-896.
[13]	杨凯璐, 陈明星, 王新亚, 张威, 肖长发. 染料废水处理用纳滤膜制备及改性研究进展[J]. 化工进展, 2023, 42(10): 5470-5486.
[14]	王晓亮, 于振秋, 常雷明, 赵浩男, 宋晓琦, 高靖淞, 张一波, 黄传辉, 刘忆, 杨绍斌. 电沉积法制备氢氧化物/氧化物超级电容器电极的研究进展[J]. 化工进展, 2023, 42(10): 5272-5285.
[15]	龙垠荧, 杨健, 管敏, 杨怡洛, 程正柏, 曹海兵, 刘洪斌, 安兴业. 木质素基材料在混合型超级电容器电极材料中的研究进展[J]. 化工进展, 2022, 41(9): 4855-4865.