稠环芳烃加氢饱和催化剂研究进展

doi:10.16085/j.issn.1000-6613.2020-0651

摘要/Abstract

摘要：

受共振能、空间位阻和竞争吸附等方面的影响，稠环芳烃末环的吸附活化是其加氢饱和反应的重点和难点之一。本文系统综述了稠环芳烃加氢饱和反应特点及各类稠环芳烃加氢饱和催化剂。分析表明，稠环芳烃吸附活化与其分子自身的属性和催化剂的性质密切相关，调控催化剂中活性金属的电子状态可有效促进稠环芳烃分子的吸附活化。针对常见稠环芳烃加氢饱和催化剂，本文分类阐述了各类稠环芳烃加氢饱和催化剂的活性相结构、活性位点数量和活性金属电子密度的调控方法。分析指出，提高活性组分的分散度和形成活性金属的缺电子状态能够提升催化剂的加氢活性，可通过调节载体的酸性和添加助剂等方法实现。

关键词: 稠环芳烃, 加氢, 吸附活化, 催化剂, 分散度, 电子状态, 载体酸性

Abstract:

The hydrogenation of polycyclic aromatic hydrocarbons can be inhibited by the adsorption and activation of their final aromatic ring, which is attributed to the increased resonance energy, steric hindrance and competitive adsorption among saturated products. In this work, the characteristics of hydrogenation process and hydrogenation catalysts were reviewed. The analysis indicated that the adsorption and activation process was closely related to the properties of the molecules and the catalysts. Moreover, tuning the electronic state of the active metal could promote the adsorption and activation of polycyclic aromatic hydrocarbons effectively. Meanwhile, the methods of adjusting active phase structure, increasing the number of active sites and modifying the active metal electron density of several hydrogenation saturated catalysts were also described in detail. It was concluded that improving the dispersion of active component and forming the electron-deficient state of active metals were beneficial to the further improvement of the hydrogenation activity of the catalysts, which could be effectively realized by adjusting the support's acidity and introducing additives.

Key words: polycyclic aromatic hydrocarbons, hydrogenation, adsorption and activation, catalyst, dispersion, electronic state, support acidity

中图分类号:

TQ536

刘道诚, 王九占, 荆洁颖, 杨志奋, 冯杰, 李文英. 稠环芳烃加氢饱和催化剂研究进展[J]. 化工进展, 2021, 40(2): 835-844.

Daocheng LIU, Jiuzhan WANG, Jieying JING, Zhifen YANG, Jie FENG, Wenying LI. Research progress on the catalysts for saturated hydrogenation of polycyclic aromatic hydrocarbons[J]. Chemical Industry and Engineering Progress, 2021, 40(2): 835-844.

图/表 3

参考文献 59

60	LIU J, ZHANG H, LU N, et al. Influence of acidity of mesoporous ZSM-5-supported Pt on naphthalene hydrogenation[J]. Industrial & Engineering Chemistry Research, 2020, 59(3): 1056-1064.
61	YANG H, CHEN H L, CHEN J W, et al. Shape selective and hydrogen spillover approach in the design of sulfur-tolerant hydrogenation catalysts[J]. Journal of Catalysis, 2006, 243(1): 36-42.
62	LIN Q, SHIMIZU K I, SATSUMA A. Hydrogenation of pyrene using Pd catalysts supported on tungstated metal oxides[J]. Applied Catalysis A: General, 2010, 387(1/2): 166-172.
63	TANG T D, YIN C Y, WANG L F, et al. Good sulfur tolerance of a mesoporous Beta zeolite-supported palladium catalyst in the deep hydrogenation of aromatics[J]. Journal of Catalysis, 2008, 257(1): 125-133.
64	侯朝鹏, 李永丹, 赵地顺. 芳烃加氢金属催化剂抗硫性研究的进展[J]. 化工进展, 2003, 22(4): 366-371.
	HOU C P, LI Y D, ZHAO D S. Research on sulfur tolerance of metal catalysts in aromatics hydrogenation[J]. Chemical Industry and Engineering Progress, 2003, 22(4): 366-371.
1	中华人民共和国国家质量监督检验检疫总局, 环境保护部. 轻型汽车污染物排放限值及测量方法（中国第六阶段）: [S]. 北京: 中国标准出版社, 2016.
	General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China, Ministry of Ecology and Environment of the People’s Republic of China. Limits and measurement methods for emissions from light-duty vehicles (): GB 18352.6—2016[S]. Beijing: Standards Press of China, 2016.
65	TREESUKOL P, SRISUK K, LIMTRAKUL J, et al. Nature of the metal-support interaction in bifunctional catalytic Pt/H-ZSM-5 zeolite[J]. Journal of Physical Chemistry B, 2005, 109(24): 11940-11945.
66	邓澄浩, 祁晓岚, 郑均林, 等. 贵金属/分子筛催化芳烃转化的研究进展[J]. 化工进展, 2017, 36(5): 1711-1718.
2	董立霞, 夏步田, 罗凯威, 等. 清洁油品升级背景下加氢脱硫技术研究进展[J]. 化工进展, 2019, 38(1): 215-223.
	DONG L X, XIA B T, LUO K W, et al. Review of hydrodesulfurization technology based on the upgrading requirement of clean gasoline[J]. Chemical Industry and Engineering Progress, 2019, 38(1): 215-223.
66	DENG C H, QI X L, DENG J L, et al. Advances in the noble metal-zeolite catalysts for aromatic conversion[J]. Chemical Industry and Engineering Progress, 2017, 36(5): 1711-1718.
67	姬宝艳, 吴彤彤, 周可, 等. 稠环芳烃加氢裂化机理和催化剂研究进展[J]. 石油化工, 2006, 45(10): 1263-1271.
3	谷小会. 煤焦油分离方法及组分性质研究现状与展望[J]. 洁净煤技术, 2018, 24(4): 1-6, 12.
	GU X H. Status and prospect of separation methods and composition characteristics of coal tar[J]. Clean Coal Technology, 2018, 24(4):1-6, 12.
4	徐春霞. 煤焦油的性质与加工利用[J]. 洁净煤技术, 2013, 19(5): 63-67.
	XU C X. Characteristics and processing utilization of coal tar[J]. Clean Coal Technology, 2013, 19(5): 63-67.
5	姚春雷, 全辉, 张忠清. 中、低温煤焦油加氢生产清洁燃料油技术[J]. 化工进展, 2013, 32(3): 501-507.
	YAO C L, QUAN H, ZHANG Z Q. Hydrogenation of medium and low temperature coal tars for production of clean fuel oil[J]. Chemical Industry and Engineering Progress, 2013, 32(3): 501-507.
6	范启明, 米镇涛, 张香文, 等. 提高航空燃料热安定性的研究进展[J]. 石化技术与应用, 2002, 20(4): 261-263, 272.
	FANG Q M, MI Z T, ZHANG X W, et al. Progress in research of improving thermal stability of aviation fuels[J]. Petrochemical Technology & Application, 2002, 20(4): 261-263, 272.
7	胡意文, 达志坚, 王子军. 几种芳烃加氢反应的热力学分析[J]. 石油学报, 2015, 31(1): 7-17.
	HU Y W, DA Z J, WANG Z J. Thermodynamic analysis on the hydrogenation reaction of several aromatic hydrocarbons[J]. Acta Petrolei Sinica (Petroleum Processing Section), 2015, 31(1): 7-17.
67	JI B Y, WU T T, ZHOU K, et al. Progresses in research for hydrocracking mechanism and catalysts of polycyclic aromatic hydrocarbons[J]. Petrochemical Technology, 2006, 45(10): 1263-1271.
68	CUI S, WANG G, YANG Y, et al. Influence of Si/Al molar ratio on the hydrogenation, isomerization and ring opening of naphthalene over silica-alumina supported Ni₂P catalyst[J]. Fuel, 2018, 225: 10-17.
69	ZHANG L, FU W Q, YU Q Y, et al. Effect of citric acid addition on the morphology and activity of Ni₂P supported on mesoporous zeolite ZSM-5 for the hydrogenation of 4,6-DMDBT and phenanthrene[J]. Journal of Catalysis, 2017, 345: 295-307.
70	QIU S B, ZHANG X, LIU Q Y, et al. A simple method to prepare highly active and dispersed Ni/MCM-41 catalysts by co-impregnation[J]. Catalysis Communications, 2013, 42(23): 73-78.
71	VARGAS-VILLAGRÁN H, RAMÍREZ-SUÁREZ D, RAMÍREZ-MUÑOZ G, et al. Tuning of activity and selectivity of Ni/(Al)SBA-15 catalysts in naphthalene hydrogenation[J]. Catalysis Today, 2021, 360: 27-37.
72	NAVARRO R M, PAWELEC B, TREJO J M, et al. Hydrogenation of aromatics on sulfur-resistant PtPd bimetallic catalysts[J]. Journal of Catalysis, 2000, 189(1): 184-194.
73	MATSUBAYASHI N, YASUDA H, IMAMURA M, et al. EXAFS study on Pd-Pt catalyst supported on USY zeolite[J]. Catalysis Today, 1998, 45(1-4): 375-380.
74	LUO M J, WANG Q F, LI G Z, et al. AlCl₃-promoted MCM-41-supported platinum catalysts with high activity and sulfur-tolerance for tetralin hydrogenation: effect of Al/Pt ratio[J]. Catalysis Letters, 2013, 143(5): 454-462.
75	RUBAN A, HAMMER B, STOLTZE P, et al. Surface electronic structure and reactivity of transition and noble metals[J]. Journal of Molecular Catalysis A: Chemical, 1997, 115(3): 421-429.
76	NØRSKOV J K, BLIGAARD T, ROSSMEISL J, et al. Towards the computational design of solid catalysts[J]. Nature Chemistry, 2009, 1(1): 37-46.
8	BELTRAMONE A R, DANIEL E R, ALVAREZ W E, et al. Simultaneous hydrogenation of multiring aromatic compounds over NiMo catalyst[J]. Industrial & Engineering Chemistry Research, 2008, 47(19): 7161-7166.
9	包洪洲, 方向晨, 刘继华, 等. 柴油加氢脱芳烃动力学模型研究进展[J]. 化工进展, 2011, 30(5): 948-952, 1018.
	BAO H Z, FANG X C, LIU J H, et al. Advance in kinetics model of diesel hydrodearomatization reaction[J]. Chemical Industry and Engineering Progress, 2011, 30(5): 948-952, 1018.
10	JONGPATIWUT S, LI Z R, RESASCO D E, et al. Competitive hydrogenation of poly-aromatic hydrocarbons on sulfur-resistant bimetallic Pt-Pd catalysts[J]. Applied Catalysis A: General, 2004, 262(2): 241-253.
11	侯朝鹏, 李永丹, 夏国富, 等. 蒽和菲加氢反应热力学分析[J]. 石油化工, 2013, 42(7): 761-766.
	HOU C P, LI Y D, XIA G F, et al. Thermodynamic analysis for hydrogenation of anthracene and phenanthrene[J]. Petrochemical Technology, 2013, 42(7): 761-766.
12	NARANOV E R, MAXIMOV A L. Selective conversion of aromatics into cis-isomers of naphthenes using Ru catalysts based on the supports of different nature[J]. Catalysis Today, 2019, 329: 94-101.
13	段爱军, 万国赋, 赵震. 柴油催化加氢脱芳烃研究进展[J]. 现代化工, 2005, 25(3): 14-18.
	DUAN A J, WANG G F, ZHAO Z. Research advances in catalytic hydro-dearomatization of diesel fuel[J]. Modern Chemical Industry, 2005, 25(3): 14-18.
14	ESCOBAR J, BARRERA M C, SANTES V, et al. Naphthalene hydrogenation over Mg-doped Pt/Al₂O₃[J]. Catalysis Today, 2017, 296: 197-204.
15	STANISLAUS A, COOPER B H. Aromatic hydrogenation catalysis: a review[J]. Catalysis Reviews, 1994, 36(1): 75-123.
16	BOND G C, WELLS P B. The mechanism of the hydrogenation of unsaturated hydrocarbons on transition metal catalysts[J]. Advances in Catalysis, 1965, 15(12): 91-226.
17	MORIN C, SIMON D, SAUTET P. Chemisorption of benzene on Pt(111), Pd(111), and Rh(111) metal surfaces: a structural and vibrational comparison from first principles[J]. Journal of Physical Chemistry B, 2004, 108(18): 5653-5665.
18	PRIMET M, GARBOWSKI E, MATHIEU M, et al. Spectroscopic studies of benzene hydrogenation on platinum-loaded zeolites. Part 2.Hydrogenation of adsorbed species[J]. Journal of the Chemical Society Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1980, 76: 1953-1961.
19	王红梅, 李美元, 白金, 等. 新型类贵金属加氢脱氧催化剂的研究进展[J]. 精细石油化工, 2017, 34(3): 75-80.
	WANG H M, LI M Y, BAI J, et al. Progress of novel similar noble metal catalysts for hydrodeoxygenation[J]. Speciality Petrochemicals, 2017, 34(3): 75-80.
20	DAAGE M, CHIANELLI R R. Structure-function relations in molybdenum sulfide catalysts: the “rim-edge”model[J]. Journal of Catalysis, 1994, 149(2): 414-427.
21	SCHACHTL E, ZHONG L, KONDRATIEVA E, et al. Understanding Ni promotion of MoS₂/γ-Al₂O₃ and its implications for the hydrogenation of phenanthrene[J]. ChemCatChem, 2015, 7: 4118-4130.
22	SCHACHTL E, YOO J S, GUTIéRREZ O Y, et al. Impact of Ni promotion on the hydrogenation pathways of phenanthrene on MoS₂/ γ-Al₂O₃[J]. Journal of Catalysis, 2017, 352: 171-181.
23	LUO W Q, SHI H, SCHACHTL E, et al. Active sites on nickel-promoted transition-metal sulfides that catalyze hydrogenation of aromatic compounds[J]. Angewandte Chemie (International ed. in English), 2018, 57: 14555-14559.
24	FU W Q, ZHANG L, WU D F, et al. Mesoporous zeolite-supported metal sulfide catalysts with high activities in the deep hydrogenation of phenanthrene[J]. Journal of Catalysis, 2015, 330: 423-433.
25	JIANG Y X, WANG D G, LI J H, et al. Designing MoS₂ nanocatalysts with increased exposure of active edge sites for anthracene hydrogenation reaction[J]. Catalysis Science & Technology, 2017, 7: 2998-3007.
26	WANG D G, LI J H, ZHENG A D, et al. Quasi-single-layer MoS₂ on MoS₂/TiO₂ nanoparticles for anthracene hydrogenation[J]. ACS Applied Nano Materials, 2019, 2(8): 5096-5107.
27	JACINTO M J, GONZALES M G, ZANATO A F S, et al. Rh nanoparticles grafted on mesoporous silica support as a high-efficiency catalyst for anthracene hydrogenation[J]. Sustainable Chemistry and Pharmacy, 2017, 6: 90-95.
28	MORIN C, SIMON D, SAUTET P. Trends in the chemisorption of aromatic molecules on a Pt(111) surface: benzene, naphthalene, and anthracene from first principles calculations[J]. Journal of Physical Chemistry B, 2004, 108(32): 12084-12091.
29	CORMA A, MARTı́NEZ A, MARTı́NEZ-SORIA V. Hydrogenation of aromatics in diesel fuels on Pt/MCM-41 catalysts[J]. Journal of Catalysis, 1997, 169(2): 480-489.
30	WILLIAMS M F, FONFé B, SIEVERS C, et al. Hydrogenation of tetralin on silica-alumina-supported Pt catalysts I. Physicochemical characterization of the catalytic materials[J]. Journal of Catalysis, 2007, 251(2): 485-496.
31	WILLIAMS M F, FONFé B, WOLTZ C, et al. Hydrogenation of tetralin on silica-alumina-supported Pt catalysts II. Influence of the support on catalytic activity[J]. Journal of Catalysis, 2007, 251(2): 497-506.
32	LIU Z Q, WEI X Y, LIU F J, et al. Temperature-controlled hydrogenation of anthracene over nickel nanoparticles supported on attapulgite powder[J]. Fuel, 2018, 223: 222-229.
33	GHADAMI Y M, MOUD P H, MARKS K, et al. Naphthalene on Ni(111): experimental and theoretical insights into adsorption, dehydrogenation, and carbon passivation[J]. The Journal of Physical Chemistry C, 2017, 121(40): 22199-22207.
34	WU J, REN S, ZHAO R, et al. Promotion of the Ni/γ-Al₂O₃ catalyst for the hydrogenation of naphthalene by silica coating[J]. Reaction Kinetics, Mechanisms and Catalysis, 2019, 128(2): 793-807.
35	WANG M L, QIAN X Q, XIE L Q, et al. Synthesis of a Ni phyllosilicate with controlled morphology for deep hydrogenation of polycyclic aromatic hydrocarbons[J]. ACS Sustainable Chemistry & Engineering, 2019, 7(2): 1989-1997.
36	GONG P, LI B, KONG X, et al. Well-dispersed Ni nanoclusters on the surfaces of MFI nanosheets as highly efficient and selective catalyst for the hydrogenation of naphthalene to tetralin[J]. Applied Surface Science, 2017, 423: 433-442.
37	杨仁春, 吴俊升, 田然, 等. 镍/氧化铝型催化剂表面结构的研究进展[J]. 化工进展, 2014, 33(1): 92-98, 164.
	YANG R C, WU J S, TIAN R, et al. Research progress in the surface structure of Ni/Al₂O₃ catalysts[J]. Chemical Industry and Engineering Progress, 2014, 33(1): 92-98, 164.
38	CHEN J G. Carbide and nitride overlayers on early transition metal surfaces: preparation, characterization, and reactivities[J]. Chemical Reviews, 1996, 96: 1477-1498.
39	OYAMA S T. Novel catalysts for advanced hydroprocessing: transition metal phosphides[J]. Journal of Catalysis, 2003, 216(1): 343-352.
40	OYAMA S T, LEE Y K. The active site of nickel phosphide catalysts for the hydrodesulfurization of 4,6-DMDBT[J]. Journal of Catalysis, 2008, 258(2): 393-400.
41	ARDAKANI S J, LIU X B, SMITH K J. Hydrogenation and ring opening of naphthalene on bulk and supported Mo₂C catalysts[J]. Applied Catalysis A: General, 2007, 324: 9-19.
42	COSTA P D, LEMBERTON J L, POTVIN C, et al. Tetralin hydrogenation catalyzed by Mo₂C/Al₂O₃ and WC/Al₂O₃ in the presence of H₂S[J]. Catalysis Today, 2001, 65(2): 195-200.
43	SAJKOWSKI D J, OYAMA S T. Catalytic hydrotreating by molybdenum carbide and nitride: unsupported Mo₂N and Mo₂C/Al₂O₃[J]. Applied Catalysis A: General, 1996, 134(2): 339-349.
44	WANG X Q, CLARK P, OYAMA S T. Synthesis, characterization, and hydrotreating activity of several iron group transition metal phosphides[J]. Journal of Catalysis, 2002, 208(2): 321-331.
45	MAMèDE A S, GIRAUDON J M, LöFBERG A, et al. Hydrogenation of toluene over β-Mo₂C in the presence of thiophene[J]. Applied Catalysis A: General, 2002, 227(1): 73-82.
46	OYAMA S T, WANG X, LEE Y K, et al. Effect of phosphorus content in nickel phosphide catalysts studied by XAFS and other techniques[J]. Journal of Catalysis, 2002, 210(1): 207-217.
47	HU D, DUAN A, XU C, et al. Ni₂P promotes the hydrogenation activity of naphthalene on wrinkled silica nanoparticles with tunable hierarchical pore sizes in a large range[J]. Nanoscale, 2019, 11(33): 15519-15529.
48	郄志强, 张子毅, 荆洁颖, 等. Ni₂P负载量对Ni₂P/Ce-Al₂O₃催化剂结构及萘加氢性能的影响[J]. 燃料化学学报, 2019, 47(6): 718-724.
	QIE Z Q, ZHANG Z Y, JING J Y, et al. Effect of Ni₂P loading on the structure and naphthalene hydrogenation performance of Ni₂P/Ce-Al₂O₃ catalyst[J]. Journal of Fuel Chemistry and Technology, 2019, 47(6): 718-724.
49	郄志强. Ni₂P/Ce-Al₂O₃催化剂的低温制备及其萘加氢饱和性能研究[D]. 太原: 太原理工大学, 2019.
	QIE Z Q. Low temperature synthesis of Ni₂P/Ce-Al₂O₃ catalyst and its hydrogenation saturation performance of naphthalene[D]. Taiyuan: Taiyuan University of Technology, 2019.
50	张子毅. Ni₂P/Ce-Al₂O₃催化剂制备及其萘饱和加氢性能研究[D]. 太原: 太原理工大学, 2018.
	ZHANG Z Y. Preparation of Ni₂P/Ce-Al₂O₃ catalyst and its saturated hydrogenation performance of naphthalene[D]. Taiyuan: Taiyuan University of Technology, 2018.
51	杨志奋. 负载型Ni₂P催化剂结构调控及萘加氢性能研究[D]. 太原: 太原理工大学, 2020.
	YANG Z F. Structure adjustment of supported Ni₂P catalyst and its naphthalene hydrogenation performance[D]. Taiyuan: Taiyuan University of Technology, 2020.
52	JIANG C G, WANG Y G, ZHANG H Y, et al. Effect of initial Si/Al ratios on the performance of low crystallinity Hβ-X zeolite supported NiMo carbide catalysts for aromatics hydrogenation[J]. Catalysis Science & Technology, 2019, 9(18): 5031-5044.
53	任艳群, 王冲, 莫家乐, 等. 介孔分子筛载体在油品深度加氢脱硫中的应用研究进展[J]. 化工进展, 2011, 30(4): 743-752.
	REN Y Q, WANG C, MO J L, et al. Review of application of mesoporous molecular sieves in deep hydrodesulfurization of oil products[J]. Chemical Industry and Engineering Progress, 2011, 30(4): 743-752.
54	SHELIMOV B, LAMBERT J F, CHE M, et al. Initial steps of the alumina-supported platinum catalyst preparation: a molecular study by ¹⁹⁵Pt NMR, UV-visible, EXAFS, and Raman spectroscopy[J]. Journal of Catalysis, 1999, 185(2): 462-478.
55	DU M X, QIN Z F, HUI G, et al. Enhancement of Pd-Pt/Al₂O₃ catalyst performance in naphthalene hydrogenation by mixing different molecular sieves in the support[J]. Fuel Processing Technology, 2010, 91(11): 1655-1661.
56	FU W Q, ZHAO W B, ZHANG L, et al. ZSM-5 microspheres consisting of nanocrystals for preparing highly dispersed MoP clusters with good activity in phenanthrene hydrogenation[J]. Industrial & Engineering Chemistry Research, 2019, 58(37): 17289-17299.
57	SIMON L J, OMMEN V J G, JENTYS A, et al. Sulfur tolerance of Pt/mordenites for benzene hydrogenation do Brønsted acid sites participate in hydrogenation?[J]. Catalysis Today, 2002, 73(1): 105-112.
58	DANG Y, LIU Y, FENG X, et al. Effect of dispersion on the adsorption of polycyclic aromatic hydrocarbons over the γ-Al₂O₃(110) surface[J]. Applied Surface Science, 2019, 486: 137-143.
59	KARIM W, SPREAFICO C, KLEIBERT A, et al. Catalyst support effects on hydrogen spillover[J]. Nature, 2017, 541(7635): 68-71.

[1]	张明焱, 刘燕, 张雪婷, 刘亚科, 李从举, 张秀玲. 非贵金属双功能催化剂在锌空气电池研究进展[J]. 化工进展, 2023, 42(S1): 276-286.
[2]	时永兴, 林刚, 孙晓航, 蒋韦庚, 乔大伟, 颜彬航. 二氧化碳加氢制甲醇过程中铜基催化剂活性位点研究进展[J]. 化工进展, 2023, 42(S1): 287-298.
[3]	谢璐垚, 陈崧哲, 王来军, 张平. 用于SO₂去极化电解制氢的铂基催化剂[J]. 化工进展, 2023, 42(S1): 299-309.
[4]	杨霞珍, 彭伊凡, 刘化章, 霍超. 熔铁催化剂活性相的调控及其费托反应性能[J]. 化工进展, 2023, 42(S1): 310-318.
[5]	王乐乐, 杨万荣, 姚燕, 刘涛, 何川, 刘逍, 苏胜, 孔凡海, 朱仓海, 向军. SCR脱硝催化剂掺废特性及性能影响[J]. 化工进展, 2023, 42(S1): 489-497.
[6]	邓丽萍, 时好雨, 刘霄龙, 陈瑶姬, 严晶颖. 非贵金属改性钒钛基催化剂NH₃-SCR脱硝协同控制VOCs[J]. 化工进展, 2023, 42(S1): 542-548.
[7]	程涛, 崔瑞利, 宋俊男, 张天琪, 张耘赫, 梁世杰, 朴实. 渣油加氢装置杂质沉积规律与压降升高机理分析[J]. 化工进展, 2023, 42(9): 4616-4627.
[8]	王鹏, 史会兵, 赵德明, 冯保林, 陈倩, 杨妲. 过渡金属催化氯代物的羰基化反应研究进展[J]. 化工进展, 2023, 42(9): 4649-4666.
[9]	张启, 赵红, 荣峻峰. 质子交换膜燃料电池中氧还原反应抗毒性电催化剂研究进展[J]. 化工进展, 2023, 42(9): 4677-4691.
[10]	王伟涛, 鲍婷玉, 姜旭禄, 何珍红, 王宽, 杨阳, 刘昭铁. 醛酮树脂基非金属催化剂催化氧气氧化苯制备苯酚[J]. 化工进展, 2023, 42(9): 4706-4715.
[11]	葛亚粉, 孙宇, 肖鹏, 刘琦, 刘波, 孙成蓥, 巩雁军. 分子筛去除VOCs的研究进展[J]. 化工进展, 2023, 42(9): 4716-4730.
[12]	毛善俊, 王哲, 王勇. 基团辨识加氢：从概念到应用[J]. 化工进展, 2023, 42(8): 3917-3922.
[13]	向阳, 黄寻, 魏子栋. 电催化有机合成反应的活性和选择性调控研究进展[J]. 化工进展, 2023, 42(8): 4005-4014.
[14]	王耀刚, 韩子姗, 高嘉辰, 王新宇, 李思琪, 杨全红, 翁哲. 铜基催化剂电还原二氧化碳选择性的调控策略[J]. 化工进展, 2023, 42(8): 4043-4057.
[15]	刘毅, 房强, 钟达忠, 赵强, 李晋平. Ag/Cu耦合催化剂的Cu晶面调控用于电催化二氧化碳还原[J]. 化工进展, 2023, 42(8): 4136-4142.