Y/β复合分子筛制备方法及应用研究进展

doi:10.16085/j.issn.1000-6613.2016.s2.026

化工进展 ›› 2016, Vol. 35 ›› Issue (S2): 155-159.DOI: 10.16085/j.issn.1000-6613.2016.s2.026

Y/β复合分子筛制备方法及应用研究进展

王迎运, 周亚松, 魏强, 杨晓宇

中国石油大学(北京)化学工程学院, 北京 102249

收稿日期:2016-05-16 修回日期:2016-07-03 出版日期:2016-12-31 发布日期:2016-12-22
通讯作者: 周亚松,教授,博士生导师。E-mail:zhys01@cup.edu.cn。
作者简介:王迎运(1990-),女,硕士研究生。

Advances in synthesis and applications of Y/β core-shell composite molecular sieves

WANG Yingyun, ZHOU Yasong, WEI Qiang, YANG Xiaoyu

Department of Chemical Engineering, China University of Petroleum, Beijing 102249, China

Received:2016-05-16 Revised:2016-07-03 Online:2016-12-31 Published:2016-12-22

摘要/Abstract

摘要： Y/β核壳结构复合分子筛具有适宜可调的酸性和孔道结构，既具有Y分子筛较好的裂化性能，又具有β分子筛较好的异构化性能，在催化领域受到较为广泛的关注。两种分子筛的有效复合是其发挥作用的重要前提。本文综述了近年来Y/β核壳结构复合分子筛的制备方法，包括硅铝源法、两步晶化法、离子交换法、前体处理法及预置晶种法；分析比较了各种方法的优点以及不足。介绍了该核壳结构复合分子筛在催化裂化、加氢裂化、异构化、有机化工体合成等催化过程方面的应用。在此基础上提出了纳米级壳层厚度的Y/β核壳结构复合分子筛是未来发展趋势，且其在催化领域有着广泛的应用前景。

关键词: 分子筛, 复合材料, 制备

Abstract: The studies on synthesis and applications of Y/β core-shell composite molecular sieves in recent years are reviewed in this paper.There are good prospects in Y/β core-shell composites with the abilities of hydrocracking and isomerization.The key to playing its role is the preparation method.Five methods are introduced,including zeolite as silica/aluminum sources method,two-step crystallization process,ion-exchanging,precursor-treating,seeding method.Advantages and disadvantages are also discussed in this paper.The composite molecular sieves are applied in catalytic cracking,hydrocracking,isomerization,synthesis of organic compound and so on.Finally,the developing trend of Y/β core-shell composite is reducing the thickness of the core to nanoscale.

Key words: molecular sieves, composites, preparation

中图分类号:

TE65

王迎运, 周亚松, 魏强, 杨晓宇. Y/β复合分子筛制备方法及应用研究进展[J]. 化工进展, 2016, 35(S2): 155-159.

WANG Yingyun, ZHOU Yasong, WEI Qiang, YANG Xiaoyu. Advances in synthesis and applications of Y/β core-shell composite molecular sieves[J]. Chemical Industry and Engineering Progree, 2016, 35(S2): 155-159.

参考文献

[1] YOUNES Bouizi,LOLC Rouleau,VALENTIN P Valtchev. Bi-phase MOR/MFI-type zeolite core-shell composite[J]. Microporous and Mesoporous Materials,2006,91:70-77.
[2] KONG Dejin,ZHENG Junlin,YUAN Xiaohong,et al. Fabrication of core/shell structure via overgrowth of ZSM-5 layers on mordenite crystals[J].Microporous and Mesoporous Materials,2009,119:91-96.
[3] ZHENG Jiajun,ZHANG Xiweng,WANG Yan,et al. Structural effects of hierarchical pores in zeolite composite[J]. Microporous and Mesoporous Materials,2009,122:264-269.
[4] YOUNES Bouizi,GERARDO Majano,SVETLANA Mintova,et al.Beads comprising a hierarchical porous core and a microporous shell[J].J. Phys. Chem.,2007,111:4535-4542.
[5] VENKATA Siva Prasad Ganjala,CHINNA Krishna Prasad Neeli,CHODIMELLA Venkata Pramod,et al.Eco-friendly nitration of benzenes over zeolite-β-SBA-15 composite catalyst[J].Catalysis Communications,2014,49:82-86.
[6] ZHU Shujin,LIU Suyao,ZHANG Huaike,et al. Investigation of synthesis and hydroisomerization performance of SAPO-11/Beta composite molecular sieve[J]. Chinese Journal of Catalysis,2014,35:1676-1686.
[7] ZHAO Qiangqiang,QIN Bo,ZHENG Jiajun,et al.Core-shell structured zeolite-zeolite composites comprising Y zeolite cores and nano-B zeolite shells:synthesis and application in hydrocracking of VGO oil[J].Chemical Engineering Journal,2014,257:262-272.
[8] 李瑞丰,陈萍,李志锋,等.十二元环双微孔复合分子筛及制备方法:200410012336.6[P].2004-06-08.
[9] 秦波,孙万富,张喜文,等.一种Y-Beta复合分子筛的快速合成方法:201010509199.2[P].2010-10-13.
[10] 杜君,王艳,孟双明,等.Y/Beta微孔-微孔分子筛的合成、表征及其催化性能[J].山西大同大学学报(自然科学版),2009,25(2):40-42.
[11] 董思洋,马波,凌凤香,等.Y-β复合分子筛催化裂化性能研究[J].当代化工,2011,40(5):447-450.
[12] WANG Yan,WANG Wenli,CHEN Yuexian,et al. Synthesis of dimethyl ether from syngas using a hierarchically porous composite zeolite as the methanol dehydration catalyst[J]. Journal of Fuel Chemistry and Technology,2013,41(7):873-882.
[13] ZHANG Jinqiao,HE Yong,LIU Yuying,et al.Study on adsorption of NO_x over CoH-FBZ by temperature-programmed desorption technique[J].Journal of Fuel Chemistry and Technology,2007,35(4):452-457.
[14] ZHANG Jinqiao,FAN Weibin,LIU Yuying,et al. Synthesis and catalytic property of a Co²⁺ exchanged Beta/Y composite for the selective catalytic reduction of NO by CH₄ in the presence of excess oxygen[J].Applied Catalysis B:Environmental,2007,76:174-184.
[15] ZHANG Xiwen,GUO Qun,QIN Bo,et al.Structural features of binary microporous zeolite composite Y-Beta and its hydrocracking performance[J].Catalysis Today,2010,149:212-217.
[16] ZHENG Jiajun,ZENG Qinghu,YI Yuming,et al.The hierarchical effects of zeolite composites in catalysis[J]. Catalysis Today,2011,168:124-132.
[17] 秦波,孙万富,张喜文,等.具有核壳结构的Y-Beta复合分子筛的合成方法:201110217551.X[P].2011-08-01.
[18] FU H,LI H P,ZHAO H,et al.Preparation and modification of NaY/Beta composite zeolite and adsorption performance[J]. Petroleum Chemistry,2014,54(3):239-244.
[19] ZHANG Jinqiao,ZHANG Xiweng,WANG Yan,et al. Synthesis and catalytic performance of a bi-phase core-shell zeolite composite[J].J.Porous Mater.,2009,16:731-736.
[20] 秦波,张喜文,凌凤香,等.一种双微孔复合分子筛的制备方法:200810228417.8[P].2008-10-29.
[21] 秦波,凌凤香,尹泽群,等.Y-β复合分子筛的导向剂法合成与表征[J].石油学报(石油加工),2012,28:92-95.
[22] 高力丹,巩雁军,雷小松,等.高产低碳烯烃Y/β复合分子筛的合成研究[C]//第七届全国催化剂制备科学与技术研讨会,2010.
[23] 王东青,于秀娟,杨晓东,等.中油型加氢裂化催化剂的研制[C]//第十届全国工业催化技术及应用年会论文集,2013.
[24] 杜君,王艳,孟双明,等.Y/Beta双微孔复合分子筛的合成、表征及其催化性能[J].石油学报(石油加工),2010,26(5):773-778.
[25] 程云,杨莹,罗根祥.H₃PW₁₂O₄₀/Y-β催化油酸甲酯的绿色合成[J].辽宁石油化工大学学报,2014,31(5):11-14.
[26] 阮艳军,秦波,秦玉才,等.CuY/Beta对燃料油吸附脱硫性能的研究[J].石油化工高等学校学报,2013,26(6):26-30.
[27] 许一博,孙万付,马波,等.Y-β复合分子筛甲醇脱水性能的研究[J].当代化工,2011,40(4):331-339.
[28] 刘春生,李哲武,罗根祥.Y-β复合分子筛负载磷钨酸催化合成乙酸仲丁酯[J].当代化工,2012,41(5):452-454.
[29] 刘春生,罗根祥.Y-β复合分子筛负载磷钨酸催化合成乙酸环己酯[J].辽宁石油化工大学学报,2012,32(4):24-27.
[30] 郑家军,郭群,张喜文,等.FAU-BEA核-壳结构沸石复合物及其对枯烯的催化裂解作用[J].石油学报(石油加工),2008(s1):208-212.
[31] 秦波,张喜文,贾立明,等.Y-β复合分子筛的环己烷加氢开环催化性能[J].石油学报(石油加工),2009(s1):45-48.

Y/β复合分子筛制备方法及应用研究进展

Advances in synthesis and applications of Y/β core-shell composite molecular sieves

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