FeCu-ZSM-5分子筛的绿色合成及其NH3-SCR性能

doi:10.16085/j.issn.1000-6613.2024-1142

化工进展 ›› 2025, Vol. 44 ›› Issue (6): 3017-3030.DOI: 10.16085/j.issn.1000-6613.2024-1142

• 专栏：化工生态环境前沿交叉新技术 •

FeCu-ZSM-5分子筛的绿色合成及其NH₃-SCR性能

徐景东¹^,²(), 刘奔³(), 汪雪琴³, 董鹏⁴, 席志祥¹^,², 徐人威¹^,², 岳源源³^,⁴()

^1.中化石油化工研究院（泉州）有限责任公司，福建泉州 362100
^2.中化泉州石化有限公司，福建泉州 362103
^3.福州大学化工学院，福建福州 350106
^4.清源创新实验室，福建泉州 362801

收稿日期:2024-07-17 修回日期:2024-09-29 出版日期:2025-06-25 发布日期:2025-07-08
通讯作者: 岳源源
作者简介:徐景东（1984—），男，博士，研究方向为炼化催化技术。E-mail：xujingdong01@sinochem.com
刘奔（1995—），男，博士，研究方向为工业催化。E-mail：1794569717@qq.com。
基金资助:
国家自然科学基金(22322803);国家自然科学基金(22178059);国家自然科学基金(U23A20113);中化泉州能源科技有限责任公司技术开发合作项目(ZHQZKJ-19-F-ZS-0076)

Green synthesis and NH₃-SCR performance of FeCu-ZSM-5 zeolite

XU Jingdong¹^,²(), LIU Ben³(), WANG Xueqin³, DONG Peng⁴, XI Zhixiang¹^,², XU Renwei¹^,², YUE Yuanyuan³^,⁴()

^1.Sinochem Petroleum Chemical Research Institute(Quanzhou) Co. , Ltd. , Quanzhou 362100, Fujian, China
^2.Sinochem Quanzhou Petrochemical Co. , Ltd. , Quanzhou 362103, Fujian, China
^3.College of Chemical Engineering, Fuzhou University, Fuzhou 350106, Fujian, China
^4.Qingyuan Innovation Laboratory, Quanzhou 362801, Fujian, China

Received:2024-07-17 Revised:2024-09-29 Online:2025-06-25 Published:2025-07-08
Contact: YUE Yuanyuan

摘要/Abstract

摘要：

FeCu-ZSM-5杂双金属分子筛因在NH₃选择催化还原（NH₃-SCR）反应中表现出互补优势和协同效应而展现出广阔的应用前景，然而，其制备面临着原料和能源消耗高及污染严重的问题。基于此，开展了以天然矿物为原料无模板剂绿色制备等级孔FeCu-ZSM-5分子筛新工艺的合成研究。在合成过程中以天然矿物为全部硅铝铁源，无外加任何有机模板剂，采用晶种导向合成等级孔FeCu-ZSM-5分子筛。系统考察合成过程关键影响因素，进而确定了最佳的合成条件。考察所制得的等级孔FeCu-ZSM-5分子筛的NH₃-SCR性能，并结合一系列表征手段探究等级孔FeCu-ZSM-5分子筛的构效关系。结果表明，Cu的加入可以显著提高FeCu-ZSM-5分子筛的低温脱硝活性，从而拓宽其温窗。Cu的引入不影响FeCu-ZSM-5的拓扑结构，但可对Fe和Cu在分子筛中的位置和分布、分子筛的还原性和酸性进行调控。较高占比的骨架Fe和孤立Cu²⁺、良好的氧化还原能力和适宜的酸性共同促使FeCu2-ZSM-5分子筛呈现最优异的脱硝性能。

关键词: FeCu-ZSM-5分子筛, 等级孔, 绿色合成, NH₃选择催化还原, 协同效应

Abstract:

FeCu-ZSM-5 heterobimetallic zeolite exhibits a broad application prospect in the selective catalytic reduction with ammonia (NH₃-SCR) due to the advantage complementary and synergistic effect of different metals, however, its preparation faces serious problems of high material and energy consumption as well as environmental pollution. In view of this, a synthetic study was conducted to explore a new green preparation process for hierarchical FeCu-ZSM-5 zeolite using natural minerals as precursors and without templating agents. During the synthesis process, natural minerals served as the sole source of silica, alumina, and iron, with no organic templating agents added, and a crystal seed inducing synthesis approach was employed. The optimal synthesis conditions were determined by systematically investigating the key influencing factors. The NH₃-SCR performance of the synthesized hierarchical FeCu-ZSM-5 was examined, and various characterization techniques were used to probe the structure-performance relationship of the hierarchical FeCu-ZSM-5. The results indicate that the incorporation of Cu significantly enhances the low-temperature denitration activity of the FeCu-ZSM-5 zeolite, thereby expanding its temperature window. The introduction of Cu does not alter the topology of FeCu-ZSM-5 but can modulate the location and distribution of Fe and Cu within the zeolite, as well as its reducing and acidic properties. The presence of higher framework Fe, isolated Cu²⁺ ions, and good redox capacity and suitable acidity collectively contribute to the superior denitration performance of the FeCu2-ZSM-5 zeolite.

Key words: FeCu-ZSM-5 zeolite, hierarchical pores, green synthesis, NH₃-SCR, synergistic effect

中图分类号:

TQ426

徐景东, 刘奔, 汪雪琴, 董鹏, 席志祥, 徐人威, 岳源源. FeCu-ZSM-5分子筛的绿色合成及其NH₃-SCR性能[J]. 化工进展, 2025, 44(6): 3017-3030.

XU Jingdong, LIU Ben, WANG Xueqin, DONG Peng, XI Zhixiang, XU Renwei, YUE Yuanyuan. Green synthesis and NH₃-SCR performance of FeCu-ZSM-5 zeolite[J]. Chemical Industry and Engineering Progress, 2025, 44(6): 3017-3030.

图/表 22

表1 累托土及硅藻土的化学组成（质量分数）

组成/%	累托土/%	硅藻土/%
Na₂O	1.03	0.40
MgO	0.23	0.34
Al₂O₃	37.2	3.22
SiO₂	43.2	92.14
P₂O₅	3.05	—
SO₃	0.07	0.70
K₂O	1.03	0.53
CaO	7.05	0.85
TiO₂	5.94	0.16
Fe₂O₃	0.51	1.53

图1 不同钠硅比下晶化产物的XRD谱图

图2 不同水硅比下晶化产物的XRD谱图

图3 不同晶种添加量下晶化产物的XRD谱图

图4 不同晶种添加量下晶化产物的SEM照片

图5 不同Fe2O3添加量下晶化产物的XRD谱图

图6 不同Fe2O3添加量下晶化产物的SEM照片

图7 不同CuO添加量下晶化产物的XRD谱图

图8 不同CuO添加量下晶化产物的SEM照片

图9 FeCux-ZSM-5的NO转化率、N2选择性和N2O产率

图10 FexCu-ZSM-5的NO转化率、N2选择性和N2O产率

图11 不同催化剂的NO转化率、N2选择性和N2O产率

图12 FeCu2-ZSM-5催化剂的NH3-SCR长周期测试

图13 FeCux-ZSM-5分子筛的N2吸附-脱附等温线和孔径分布

表2 FeCux-ZSM-5分子筛的织构参数

样品	S_BET/m²·g^-1	S_micro/m²·g^-1	V_total/cm³·g^-1	V_meso/cm³·g^-1
Fe-ZSM-5	275	197	0.17	0.07
FeCu1-ZSM-5	234	153	0.15	0.07
FeCu2-ZSM-5	283	158	0.19	0.12
FeCu3-ZSM-5	289	136	0.20	0.13

表3 由XRF测得的FeCux-ZSM-5分子筛中的Fe和Cu质量分数

样品	Fe₂O₃/%	CuO/%
Fe-ZSM-5	2.49	—
FeCu1-ZSM-5	2.57	1.11
FeCu2-ZSM-5	2.22	2.01
FeCu3-ZSM-5	2.39	3.74

图14 FeCux-ZSM-5分子筛的Fe 2p和Cu 2p XPS谱图

表4 FeCux-ZSM-5分子筛的XPS定量结果

样品	Fe物种		Cu物种
样品	Fe²⁺/%	Fe³⁺/%	CuO/%	Cu²⁺/%
Fe-ZSM-5	41.31	58.69	—	—
FeCu1-ZSM-5	38.86	61.14	52.57	47.43
FeCu2-ZSM-5	28.95	71.05	45.65	54.35
FeCu3-ZSM-5	41.81	58.19	51.45	48.55

图15 FeCux-ZSM-5的UV-vis DRS谱图

图16 FeCux-ZSM-5分子筛的H2-TPR曲线

表5 由XRF测得的FeCux-ZSM-5分子筛中的Si、Al及Na含量

组成	SiO₂/%	Al₂O₃/%	Na₂O/%	n(SiO₂)/n(Al₂O₃)
Fe-ZSM-5	88.41	7.23	0.37	20.77
FeCu1-ZSM-5	87.57	7.15	0.41	20.83
FeCu2-ZSM-5	87.55	6.94	0.38	21.44
FeCu3-ZSM-5	85.39	6.92	0.35	20.97

图17 FeCux-ZSM-5分子筛的NH3-TPD曲线

参考文献 1

[2]	邹润, 董霄, 矫义来, 等. 等级孔分子筛的可控合成、扩散研究及催化应用[J]. 高等学校化学学报, 2021, 42(1): 74-100.
	ZOU Run, DONG Xiao, JIAO Yilai, et al. Controllable synthesis, diffusion study and catalysis of hierarchical zeolites[J]. Chemical Journal of Chinese Universities, 2021, 42(1): 74-100.
[3]	HARTMANN Martin, THOMMES Matthias, SCHWIEGER Wilhelm. Hierarchically-ordered zeolites: A critical assessment[J]. Advanced Materials Interfaces, 2021, 8(4): 2001841.
[4]	SUN Minghui, ZHOU Jian, HU Zhiyi, et al. Hierarchical zeolite single-crystal reactor for excellent catalytic efficiency[J]. Matter, 2020, 3(4): 1226-1245.
[5]	Javier PÉREZ-RAMÍREZ, CHRISTENSEN Claus H, EGEBLAD Kresten, et al. Hierarchical zeolites: Enhanced utilisation of microporous crystals in catalysis by advances in materials design[J]. Chemical Society Reviews, 2008, 37(11): 2530-2542.
[6]	CHOI Minkee, NA Kyungsu, KIM Jeongnam, et al. Stable single-unit-cell nanosheets of zeolite MFI as active and long-lived catalysts[J]. Nature, 2009, 461(7261): 246-249.
[7]	PLANK Charles J, ROSINSKI Edward J, RUBIN Mae K. Crystalline zeolite and method of preparing same: US04016245[P]. 1977-04-05.
[8]	LI Junhua, CHANG Huazhen, MA Lei, et al. Low-temperature selective catalytic reduction of NO _x with NH₃ over metal oxide and zeolite catalysts—A review[J]. Catalysis Today, 2011, 175(1): 147-156.
[9]	Feng BIN, SONG Chonglin, Gang LYU, et al. Selective catalytic reduction of nitric oxide with ammonia over zirconium-doped copper/ZSM-5 catalysts[J]. Applied Catalysis B: Environmental, 2014, 150: 532-543.
[10]	CHEN Zhen, FAN Chi, PANG Lei, et al. One-pot synthesis of high performance Cu-SAPO-18 catalyst for NO reduction by NH₃-SCR: Influence of silicon content on the catalytic properties of Cu-SAPO-18[J]. Chemical Engineering Journal, 2018, 348: 608-617.
[11]	ZHANG Tao, CHANG Huazhen, YOU Yanchen, et al. Excellent activity and selectivity of one-pot synthesized Cu-SSZ-13 catalyst in the selective catalytic oxidation of ammonia to nitrogen[J]. Environmental Science & Technology, 2018, 52(8): 4802-4808.
[12]	YUE Yuanyuan, LIU Haiyan, YUAN Pei, et al. From natural aluminosilicate minerals to hierarchical ZSM-5 zeolites: A nanoscale depolymerization-reorganization approach[J]. Journal of Catalysis, 2014, 319: 200-210.
[13]	LI Tiesen, LIU Haiyan, FAN Yu, et al. Synthesis of zeolite Y from natural aluminosilicate minerals for fluid catalytic cracking application[J]. Green Chemistry, 2012, 14(12): 3255-3259.
[14]	YUE Yuanyuan, KANG Ying, BAI Yu, et al. Seed-assisted, template-free synthesis of ZSM-5 zeolite from natural aluminosilicate minerals[J]. Applied Clay Science, 2018, 158: 177-185.
[15]	ITABASHI Keiji, KAMIMURA Yoshihiro, IYOKI Kenta, et al. A working hypothesis for broadening framework types of zeolites in seed-assisted synthesis without organic structure-directing agent[J]. Journal of the American Chemical Society, 2012, 134(28): 11542-11549.
[16]	KIM Shin Dong, Shi Hyun NOH, SEONG Kyeong Hak, et al. Compositional and kinetic study on the rapid crystallization of ZSM-5 in the absence of organic template under stirring[J]. Microporous and Mesoporous Materials, 2004, 72(1/2/3): 185-192.
[17]	PAN Feng, LU Xuchen, WANG Yun, et al. Synthesis and crystallization kinetics of ZSM-5 without organic template from coal-series kaolinite[J]. Microporous and Mesoporous Materials, 2014, 184: 134-140.
[18]	Jan PŘECH, STROSSI PEDROLO Debora R, MARCILIO Nilson R, et al. Core-shell metal zeolite composite catalysts for in situ processing of Fischer-Tropsch hydrocarbons to gasoline type fuels[J]. ACS Catalysis, 2020, 10(4): 2544-2555.
[19]	YANG Guangpeng, DU Xuesen, RAN Jingyu, et al. Irregular influence of alkali metals on Cu-SAPO-34 catalyst for selective catalytic reduction of NO _x with ammonia[J]. Journal of Hazardous Materials, 2020, 387: 122007.
[20]	FRITZ A., PITCHON V. The current state of research on automotive lean NO _x catalysis[J]. Applied Catalysis B: Environmental, 1997, 13(1): 1-25.
[21]	BUSCA Guido, LIETTI Luca, RAMIS Gianguido, et al. Chemical and mechanistic aspects of the selective catalytic reduction of NO _x by ammonia over oxide catalysts: A review[J]. Applied Catalysis B: Environmental, 1998, 18(1/2): 1-36.
[22]	YUE Yuanyuan, LIU Haiyan, ZHOU Yanni, et al. Pure-phase zeolite beta synthesized from natural aluminosilicate minerals and its catalytic application for esterification[J]. Applied Clay Science, 2016, 126: 1-6.
[23]	YUE Yuanyuan, LIU Haiyan, YUAN Pei, et al. One-pot synthesis of hierarchical FeZSM-5 zeolites from natural aluminosilicates for selective catalytic reduction of NO by NH₃ [J]. Scientific Reports, 2015, 5: 9270.
[24]	MOHAN Sooraj, DINESHA P, KUMAR Shiva. NO _x reduction behaviour in copper zeolite catalysts for ammonia SCR systems: A review[J]. Chemical Engineering Journal, 2020, 384: 123253.
[25]	BRANDENBERGER Sandro, Oliver KRÖCHER, TISSLER Arno, et al. The state of the art in selective catalytic reduction of NO _x by ammonia using metal-exchanged zeolite catalysts[J]. Catalysis Reviews, 2008, 50(4): 492-531.
[26]	YUE Yuanyuan, LIU Ben, Nangui LYU, et al. Direct synthesis of hierarchical FeCu-ZSM-5 zeolite with wide temperature window in selective catalytic reduction of NO by NH₃ [J]. ChemCatChem, 2019, 11(19): 4744-4754.
[27]	SHEN Qun, ZHANG Lingyun, WU Minfang, et al. High-silica nanoflower hierarchical Fe-MFI with excellent catalytic performance for N₂O decomposition[J]. Materials Research Bulletin, 2017, 87: 1-5.
[28]	ANUNZIATA Oscar A, BELTRAMONE Andrea R, JURIC Zoran, et al. Fe-containing ZSM-11 zeolites as active catalyst for SCR of NO _x Part I. Synthesis, characterization by XRD, BET and FTIR and catalytic properties[J]. Applied Catalysis A: General, 2004, 264(1): 93-101.
[29]	HAN Lina, ZHAO Xiaoge, YU Huafeng, et al. Preparation of SSZ-13 zeolites and their NH₃-selective catalytic reduction activity[J]. Microporous and Mesoporous Materials, 2018, 261: 126-136.
[30]	HU Xiaoqian, YANG Ming, FAN Dequan, et al. The role of pore diffusion in determining NH₃ SCR active sites over Cu/SAPO-34 catalysts[J]. Journal of Catalysis, 2016, 341: 55-61.
[31]	ANDONOVA Stanislava, VOVK Evgeny, Jonas SJÖBLOM, et al. Chemical deactivation by phosphorous under lean hydrothermal conditions over Cu/BEA NH₃-SCR catalysts[J]. Applied Catalysis B: Environmental, 2014, 147: 251-263.
[32]	WEN Chengyan, WANG Chenguang, CHEN Lungang, et al. Effect of hierarchical ZSM-5 zeolite support on direct transformation from syngas to aromatics over the iron-based catalyst[J]. Fuel, 2019, 244: 492-498.
[33]	HAN Zeyu, ZHANG Feng, ZHAO Xinhong. Green energy-efficient synthesis of Fe-ZSM-5 zeolite and its application for hydroxylation of phenol[J]. Microporous and Mesoporous Materials, 2019, 290, 109679.
[34]	PORNRATTANAPIMOLCHAI Choompoonut, WORATHANAKUL Patcharin. Physicochemical properties and different sequence of metal loading (CuFe) over nanoporous of SUZ-4 zeolite[J]. Journal of Nanoscience and Nanotechnology, 2013, 13(4): 3110-3114.
[35]	YIN Chengyang, CHENG Peifu, LI Xiang, et al. Selective catalytic reduction of nitric oxide with ammonia over high-activity Fe/SSZ-13 and Fe/one-pot-synthesized Cu-SSZ-13 catalysts[J]. Catalysis Science & Technology, 2016, 6(20): 7561-7568.
[36]	GURGUL Jacek, Kazimierz ŁĄTKA, HNAT Izabela, et al. Identification of iron species in FeSiBEA by DR UV-vis, XPS and Mössbauer spectroscopy: Influence of Fe content[J]. Microporous and Mesoporous Materials, 2013, 168: 1-6.
[37]	XU Li, SHI Chuan, CHEN Bingbing, et al. Improvement of catalytic activity over Cu-Fe modified Al-rich beta catalyst for the selective catalytic reduction of NO _x with NH₃ [J]. Microporous and Mesoporous Materials, 2016, 236: 211-217.
[38]	LIU Xiaojiao, LI Yonghong, ZHANG Ranran. Ammonia selective catalytic reduction of NO over Ce-Fe/Cu-SSZ-13 catalysts[J]. RSC Advances, 2015, 5(104): 85453-85459.
[39]	Beñat PEREDA-AYO, DE LA TORRE Unai, Manuel ROMERO-SÁEZ, et al. Influence of the washcoat characteristics on NH₃-SCR behavior of Cu-zeolite monoliths[J]. Catalysis Today, 2013, 216: 82-89.
[40]	PUTLURU Siva Sankar Reddy, SCHILL Leonhard, JENSEN Anker Degn, et al. Selective catalytic reduction of NO _x with NH₃ on Cu-, Fe-, and Mn-zeolites prepared by impregnation: Comparison of activity and hydrothermal stability[J]. Journal of Chemistry, 2018, 2018(1): 8614747.
[41]	METKAR Pranit S, HAROLD Michael P, BALAKOTAIAH Vemuri. Selective catalytic reduction of NO _x on combined Fe- and Cu-zeolite monolithic catalysts: Sequential and dual layer configurations[J]. Applied Catalysis B: Environmental, 2012, 111: 67-80.
[42]	SCHWIDDER M, Santhosh KUMAR M, BRÜCKNER A, et al. Active sites for NO reduction over Fe-ZSM-5 catalysts[J]. Chemical Communications, 2005(6): 805-807.
[43]	LONG Richard Q, YANG Ralph T. Superior Fe-ZSM-5 catalyst for selective catalytic reduction of nitric oxide by ammonia[J]. Journal of the American Chemical Society, 1999, 121(23): 5595-5596.
[44]	ZHANG Yiwei, ZHOU Yuming, HUANG Li, et al. Structure and catalytic properties of the Zn-modified ZSM-5 supported platinum catalyst for propane dehydrogenation[J]. Chemical Engineering Journal, 2015, 270: 352-361.
[45]	DOU Baojuan, Gang LYU, WANG Chang, et al. Cerium doped copper/ZSM-5 catalysts used for the selective catalytic reduction of nitrogen oxide with ammonia[J]. Chemical Engineering Journal, 2015, 270: 549-556.
[46]	PANG Lei, FAN Chi, SHAO Lina, et al. The Ce doping Cu/ZSM-5 as a new superior catalyst to remove NO from diesel engine exhaust[J]. Chemical Engineering Journal, 2014, 253: 394-401.
[47]	TAO Haixiang, YANG Hong, LIU Xiaohui, et al. Highly stable hierarchical ZSM-5 zeolite with intra- and inter-crystalline porous structures[J]. Chemical Engineering Journal, 2013, 225: 686-694.
[48]	TEMPELMAN Christiaan H L, DE RODRIGUES Victor O, VAN ECK Ernst R H, et al. Desilication and silylation of Mo/HZSM-5 for methane dehydroaromatization[J]. Microporous and Mesoporous Materials, 2015, 203: 259-273.
[49]	BOUKOUSSA Bouhadjar, AOUAD Nafissa, HAMACHA Rachida, et al. Key factor affecting the structural and textural properties of ZSM-5/MCM-41 composite[J]. Journal of Physics and Chemistry of Solids, 2015, 78: 78-83.
[50]	YUE Chuanjun, GAN Miaomiao, GU Liping, et al. In situ synthesized nano-copper over ZSM-5 for the catalytic dehydration of glycerol under mild conditions[J]. Journal of the Taiwan Institute of Chemical Engineers, 2014, 45(4): 1443-1448.
[51]	LI Rui, LI Zhibin, CHEN Liqiang, et al. Synthesis of MnNi-SAPO-34 by a one-pot hydrothermal method and its excellent performance for the selective catalytic reduction of NO by NH₃ [J]. Catalysis Science & Technology, 2017, 7(21): 4984-4995.
[52]	SUTTIPAT Duangkamon, YUTTHALEKHA Thittaya, WANNAPAKDEE Wannaruedee, et al. Tunable acid-base bifunction of hierarchical aluminum-rich zeolites for the one-pot tandem deacetalization-henry reaction[J]. ChemPlusChem, 2019, 84(10): 1503-1507.
[53]	WANG Qinqin, ZHU Mingyuan, ZHANG Haiyang, et al. Enhanced catalytic performance of Zr-modified ZSM-5-supported Zn for the hydration of acetylene to acetaldehyde[J]. Catalysis Communications, 2019, 120: 33-37.
[54]	TIEULI Sebastiano, Päivi MÄKI-ARVELA, PEURLA Markus, et al. Hydrodeoxygenation of isoeugenol over Ni-SBA-15: Kinetics and modelling[J]. Applied Catalysis A: General, 2019, 580: 1-10.
[55]	GHANI N N M, JALIL A A, TRIWAHYONO S, et al. Tailored mesoporosity and acidity of shape-selective fibrous silica beta zeolite for enhanced toluene co-reaction with methanol[J]. Chemical Engineering Science, 2019, 193: 217-229.
[1]	BONILLA Griselda, Isabel DÍAZ, TSAPATSIS Michael, et al. Zeolite (MFI) crystal morphology control using organic structure-directing agents[J]. Chemistry of Materials, 2004, 16(26): 5697-5705.

FeCu-ZSM-5分子筛的绿色合成及其NH₃-SCR性能

Green synthesis and NH₃-SCR performance of FeCu-ZSM-5 zeolite

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