化工进展 ›› 2023, Vol. 42 ›› Issue (3): 1508-1514.DOI: 10.16085/j.issn.1000-6613.2022-0909

• 材料科学与技术 • 上一篇    下一篇

Fe3+诱导聚多巴胺-聚乙烯亚胺电沉积制备单价选择性膜

赵王瑞(), 刘燕, 张伟(), 邓会宁()   

  1. 河北工业大学化工学院,天津 300130
  • 收稿日期:2022-05-17 修回日期:2022-05-26 出版日期:2023-03-15 发布日期:2023-04-10
  • 通讯作者: 张伟,邓会宁
  • 作者简介:赵王瑞(1997—),女,硕士研究生,研究方向为膜分离。E-mail:nhhhh16@163.com
  • 基金资助:
    河北省高等学校科学研究项目(ZD2021033)

Fe3+ ions induced rapid electrodeposition of polydopamine-polyethyleneimine for monovalent selective membrane fabrication

ZHAO Wangrui(), LIU Yan, ZHANG Wei(), DENG Huining()   

  1. School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, China
  • Received:2022-05-17 Revised:2022-05-26 Online:2023-03-15 Published:2023-04-10
  • Contact: ZHANG Wei, DENG Huining

摘要:

仿生黏合剂聚多巴胺(polydopamine,PDA)与聚乙烯亚胺(polyethyleneimine,PEI)共沉积是构建单价选择性分离层的有效方法。本实验通过浸泡预处理将Fe3+引入阳离子交换膜,并利用电场作用和Fe3+诱导PDA-PEI在膜面沉积改性。结果表明,该方法大大缩短了单价选择性膜的改性时间,制备了单价选择性阳离子交换膜。利用扫描电子显微镜、紫外可见分光光度计、红外光谱仪、zeta电位对制得的膜进行表征和性能测试,探讨了Fe3+浓度对改性膜性能的影响。表明随着Fe3+浓度的增加改性膜的膜电阻呈上升趋势,而表面荷正电性和选择性均呈先增加后降低的趋势。由于电场和Fe3+对多巴胺聚合过程的共同影响,当Fe3+的浓度为0.001mol/L时,改性膜Na+/Mg2+选择性高达12.8,并且具有较低的膜电阻和优异的稳定性。

关键词: 离子交换, 膜, 聚合, 电沉积, 单价离子选择性

Abstract:

Co-deposition of biomimetic adhesive polydopamine (PDA) and polyethyleneimine (PEI) has emerged as an effective approach for building monovalent perm-selectivity functional coatings. In this experiment, Fe3+ ions were introduced into the cation exchange membrane by immersion pretreatment, and the PDA-PEI was deposited on the membrane surface by using the electric field effect and Fe3+ ions induction. The results showed that the method greatly shortened the modification time and prepared the monovalent selective cation exchange membrane. Scanning electron microscope, UV-visible spectrophotometer, infrared spectrometer and zeta potential were used to analyze the surface properties and structure of the modified membrane, and the effects of concentration of Fe3+ ions of the separation performance were investigated. With the increase of the concentration of Fe3+ ions, the membrane resistance of the modified films indicated an upward trend, while the surface positivity charge and perm-selectivity both increased first and then decreased. When the concentration of Fe3+ ions was 0.001mol/L, the surface of the modified membrane showed remarkably enhanced Na+/Mg2+ selectivity of 12.8, low electrical resistance and excellent stability due to the combined effect of the electric field and Fe3+ ions on the dopamine (DA) polymerization process.

Key words: ion exchange, membrane, polymerization, electrodeposition, monovalent perm-selectivity

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