直接空气捕碳固体多孔材料的研究进展

doi:10.16085/j.issn.1000-6613.2022-1000

化工进展 ›› 2023, Vol. 42 ›› Issue (3): 1471-1483.DOI: 10.16085/j.issn.1000-6613.2022-1000

直接空气捕碳固体多孔材料的研究进展

孔祥如¹(), 张肖阳¹^,², 孙鹏翔¹, 崔琳¹, 董勇¹()

^1.山东大学能源与动力工程学院，燃煤污染物减排国家工程实验室，环境热工技术教育部工程研究中心，山东省能源碳减排技术与资源化利用重点实验室，山东济南 250061
^2.山东大学环境科学与工程学院，山东青岛 266237

收稿日期:2022-05-30 修回日期:2022-08-20 出版日期:2023-03-15 发布日期:2023-04-10
通讯作者: 董勇
作者简介:孔祥如（1998—），女，硕士研究生，研究方向为空气捕碳技术。E-mail：202014450@mail.sdu.edu.cn。
基金资助:
山东省重大科技创新工程项目(2020CXGC011402)

Research progress of solid porous materials for direct CO₂ capture from air

KONG Xiangru¹(), ZHANG Xiaoyang¹^,², SUN Pengxiang¹, CUI Lin¹, DONG Yong¹()

^1.National Engineering Laboratory for Reducing Emissions from Coal Combustion, Engineering Research Center of Environmental Thermal Technology of Ministry of Education, Shandong Key Laboratory of Energy Carbon Reduction and Resource Utilization, School of Energy and Power Engineering, Shandong University, Jinan 250061, Shandong, China
^2.School of Environment Science and Engineering, Shandong University, Qingdao 266237, Shandong, China

Received:2022-05-30 Revised:2022-08-20 Online:2023-03-15 Published:2023-04-10
Contact: DONG Yong

摘要/Abstract

摘要：

直接空气捕碳（DAC）技术属于一种负碳技术，作为碳捕集、存储和利用（CCUS）技术的有效补充，是助力实现“双碳”目标的重要技术之一。由于吸附能力强、再生能耗低、应用场景灵活以及结构可调性强，固体多孔材料在降低DAC经济成本和运行能耗方面具有不可替代的优势。本文从固体多孔材料的DAC原理出发，重点综述了包括沸石吸附剂、硅基吸附剂、炭基吸附剂、纳米氧化铝吸附剂、金属有机框架（MOF）材料吸附剂和多孔树脂材料吸附剂等DAC的研究现状，系统介绍和比较了固体多孔吸附材料的吸附容量、吸附选择性、水热稳定性、再生能耗以及循环稳定性方面的优缺点。本文着重分析了胺功能化改性和载体孔隙结构等因素对吸附CO₂性能的影响规律，对各类固体多孔材料在DAC应用中面临的挑战提出了具体的优化方向，并指出未来固体多孔吸附材料的设计开发应兼顾经济性和高效性，加快开展中试规模的DAC试验研究。

关键词: 直接空气捕集, CO₂捕集, 物理吸附, 化学吸附, 固体多孔材料

Abstract:

Direct air capture (DAC) technology is a negative carbon technology, which is an effective supplement to the carbon capture, utilization and storage (CCUS) technology and one of the important technologies to help achieve the carbon peaking and carbon neutrality goals. Solid porous materials have irreplaceable advantages in reducing the economic cost and operating energy consumption of DAC due to their strong adsorption capacity, low regeneration energy consumption, flexible application scenarios and adjustable structure. Starting from the principles of DAC of solid porous materials, this paper focused on reviewing DAC adsorbents, such as zeolite adsorbents, silica-based adsorbents, carbon-based adsorbents, nano-alumina adsorbents, MOF adsorbents and porous resin adsorbents. The advantages and disadvantages on adsorption capacity, adsorption selectivity, hydrothermal stability, regeneration energy consumption and cycle stability of solid porous materials are introduced and compared. The effects of amine functionalization modification and carrier pore structure on the adsorption performance of CO₂ are emphatically analyzed, and specific optimization directions for the challenges faced by various solid porous materials in the application of DAC are prospected. It is pointed out that the design and development of solid porous adsorbents in the future should take both economy and efficiency into account, and further pilot-scale DAC experiments should be carried out.

Key words: direct air capture, CO₂ capture, physisorption, chemisorption, solid porous materials

中图分类号:

TQ028

孔祥如, 张肖阳, 孙鹏翔, 崔琳, 董勇. 直接空气捕碳固体多孔材料的研究进展[J]. 化工进展, 2023, 42(3): 1471-1483.

KONG Xiangru, ZHANG Xiaoyang, SUN Pengxiang, CUI Lin, DONG Yong. Research progress of solid porous materials for direct CO₂ capture from air[J]. Chemical Industry and Engineering Progress, 2023, 42(3): 1471-1483.

图/表 13

参考文献 80

1	LUEKING Angela D, COLE Milton W. Energy and mass balances related to climate change and remediation[J]. Science of the Total Environment, 2017, 590/591: 416-429.
2	KOVEN Charles D, RINGEVAL Bruno, FRIEDLINGSTEIN Pierre, et al. Permafrost carbon-climate feedbacks accelerate global warming[J]. Proceedings of the National Academy of Sciences of the United States of America, 2011, 108(36): 14769-14774.
3	LACKNER Klaus S, BRENNAN Sarah, MATTER Jürg M, et al. The urgency of the development of CO₂ capture from ambient air[J]. Proceedings of the National Academy of Sciences of the United States of America, 2012, 109(33): 13156-13162.
4	REGUFE Maria João, PEREIRA Ana, FERREIRA Alexandre F P, et al. Current developments of carbon capture storage and/or utilization–looking for net-zero emissions defined in the Paris agreement[J]. Energies, 2021, 14(9): 2406.
5	International Energy Agency. Direct air capture 2022: a key technology for net zero[R]. Paris: IEA, 2022.
6	KEITH David W, HOLMES Geoffrey, ANGELO David ST, et al. A process for capturing CO₂ from the atmosphere[J]. Joule, 2018, 2(8): 1573-1594.
7	GUTKNECHT Valentin, SNÆBJÖRNSDÓTTIR Sandra Ósk, Bergur SIGFÚSSON, et al. Creating a carbon dioxide removal solution by combining rapid mineralization of CO₂ with direct air capture[J]. Energy Procedia, 2018, 146: 129-134.
8	Thermostat Global. Core solution-Direct air capture[EB/OL]. [2022-08-18]. .
9	宋珂琛, 崔希利, 邢华斌. 二氧化碳直接空气捕集材料与技术研究进展[J]. 化工进展, 2022, 41(3): 1152-1162.
	SONG Kechen, CUI Xili, XING Huabin. Progress on direct air capture of carbon dioxide[J]. Chemical Industry and Engineering Progress, 2022, 41(3): 1152-1162.
10	SHI Xiaoyang, XIAO Hang, AZARABADI Habib, et al. Sorbents for the direct capture of CO₂ from ambient air[J]. Angewandte Chemie, 2020, 59(18): 6984-7006.
11	LACKNER Klaus S. Capture of carbon dioxide from ambient air[J]. The European Physical Journal Special Topics, 2009, 176(1): 93-106.
12	LACKNER Klaus S. The thermodynamics of direct air capture of carbon dioxide[J]. Energy, 2013, 50: 38-46.
13	MARCO-LOZAR Juan Pablo, KUNOWSKY Mirko, Fabián SUÁREZ-GARCÍA, et al. Sorbent design for CO₂ capture under different flue gas conditions[J]. Carbon, 2014, 72: 125-134.
14	DUTCHER Bryce, FAN Maohong, RUSSELL Armistead G. Amine-based CO₂ capture technology development from the beginning of 2013—A review[J]. ACS Applied Materials & Interfaces, 2015, 7(4): 2137-2148.
15	BONENFANT Danielle, KHAROUNE Mourad, NIQUETTE Patrick, et al. Advances in principal factors influencing carbon dioxide adsorption on zeolites[J]. Science and Technology of Advanced Materials, 2008, 9(1): 013007.
16	GARGIULO Nicola, PEPE Francesco, CAPUTO Domenico. CO₂ adsorption by functionalized nanoporous materials: a review[J]. Journal of Nanoscience and Nanotechnology, 2014, 14(2): 1811-1822.
17	KUMAR Santosh, SRIVASTAVA Rohit, Joonseok KOH. Utilization of zeolites as CO₂ capturing agents: advances and future perspectives[J]. Journal of CO₂ Utilization, 2020, 41: 101251.
18	STUCKERT Nicholas R, YANG Ralph T. CO₂ capture from the atmosphere and simultaneous concentration using zeolites and amine-grafted SBA-15[J]. Environmental Science & Technology, 2011, 45(23): 10257-10264.
19	LEE Shih Ching, HSIEH Chu Chin, CHEN Chien Hung, et al. CO₂ adsorption by Y-type zeolite impregnated with amines in indoor air[J]. Aerosol and Air Quality Research, 2013, 13(1): 360-366.
20	THAKKAR Harshul V, ISSA A, ROWNAGHI A, et al. CO₂ capture from air using amine functionalized Kaolin-based zeolites[J]. Chemical Engineering & Technology, 2017, 40(11): 1999-2007.
21	SU Fengsheng, LU Chungsying. CO₂ capture from gas stream by zeolite 13X using a dual-column temperature/vacuum swing adsorption[J]. Energy & Environmental Science, 2012, 5(10): 9021-9027.
22	Solutions Greencap. ESC Project[EB/OL]. [2022-08-18]. .
23	CHEN Chao, KIM Jun, Wha-Seung AHN. CO₂ capture by amine-functionalized nanoporous materials: a review[J]. Korean Journal of Chemical Engineering, 2014, 31(11): 1919-1934.
24	XU Xiaochun, SONG Chunshan, ANDRESEN John M, et al. Novel polyethylenimine-modified mesoporous molecular sieve of MCM-41 type as high-capacity adsorbent for CO₂ capture[J]. Energy & Fuels, 2002, 16(6): 1463-1469.
25	LIU Lina, CHEN Jian, TAO Lin, et al. Aminopolymer confined in ethane-silica nanotubes for CO₂ capture from ambient air[J]. ChemNanoMat, 2020, 6(7): 1096-1103.
26	DIDAS Stephanie A, KULKARNI Ambarish R, SHOLL David S, et al. Role of amine structure on carbon dioxide adsorption from ultradilute gas streams such as ambient air[J]. ChemSusChem, 2012, 5(10): 2058-2064.
27	GOEPPERT Alain, METH Sergio, G K Surya PRAKASH, et al. Nanostructured silica as a support for regenerable high-capacity organoamine-based CO₂ sorbents[J]. Energy & Environmental Science, 2010, 3(12): 1949-1960.
28	GOEPPERT Alain, ZHANG Hang, CZAUN Miklos, et al. Easily regenerable solid adsorbents based on polyamines for carbon dioxide capture from the air[J]. ChemSusChem, 2014, 7(5): 1386-1397.
29	MIAO Yihe, HE Zhijun, ZHU Xuancan, et al. Operating temperatures affect direct air capture of CO₂ in polyamine-loaded mesoporous silica[J]. Chemical Engineering Journal, 2021, 426: 131875.
30	WANG Xiaoxing, MA Xiaoliang, SONG Chunshan, et al. Molecular basket sorbents polyethylenimine-SBA-15 for CO₂ capture from flue gas: characterization and sorption properties[J]. Microporous and Mesoporous Materials, 2013, 169: 103-111.
31	SAKWA-NOVAK Miles A, TAN Shuai, JONES Christopher W. Role of additives in composite PEI/oxide CO₂ adsorbents: enhancement in the amine efficiency of supported PEI by PEG in CO₂ capture from simulated ambient air[J]. ACS Applied Materials & Interfaces, 2015, 7(44): 24748-24759.
32	BELMABKHOUT Youssef, Rodrigo SERNA-GUERRERO, SAYARI Abdelhamid. Adsorption of CO₂-containing gas mixtures over amine-bearing pore-expanded MCM-41 silica: application for gas purification[J]. Industrial & Engineering Chemistry Research, 2010, 49(1): 359-365.
33	WAGNER Annemarie, STEEN Bengt, Göran JOHANSSON, et al. Carbon dioxide capture from ambient air using amine-grafted mesoporous adsorbents[J]. International Journal of Spectroscopy, 2013, 2013: 690186.
34	CHAIKITTISILP Watcharop, KHUNSUPAT Ratayakorn, CHEN Thomas T, et al. Poly(allylamine)-mesoporous silica composite materials for CO₂ capture from simulated flue gas or ambient air[J]. Industrial & Engineering Chemistry Research, 2011, 50(24): 14203-14210.
35	CHAIKITTISILP Watcharop, LUNN Jonathan D, SHANTZ Daniel F, et al. Poly(L-lysine) brush-mesoporous silica hybrid material as a biomolecule-based adsorbent for CO₂ capture from simulated flue gas and air[J]. Chemistry, 2011, 17(38): 10556-10561.
36	CHOI Sunho, DRESE Jeffrey H, EISENBERGER Peter M, et al. Application of amine-tethered solid sorbents for direct CO₂ capture from the ambient air[J]. Environmental Science & Technology, 2011, 45(6): 2420-2427.
37	ZHAO An, SAMANTA Arunkumar, SARKAR Partha, et al. Carbon dioxide adsorption on amine-impregnated mesoporous SBA-15 sorbents: experimental and kinetics study[J]. Industrial & Engineering Chemistry Research, 2013, 52(19): 6480-6491.
38	KUWAHARA Yasutaka, KANG Dun-Yen, COPELAND John R, et al. Dramatic enhancement of CO₂ uptake by poly(ethyleneimine) using zirconosilicate supports[J]. Journal of the American Chemical Society, 2012, 134(26): 10757-10760.
39	CHAIKITTISILP Watcharop, KIM Hyung-Ju, JONES Christopher W. Mesoporous alumina-supported amines as potential steam-stable adsorbents for capturing CO₂ from simulated flue gas and ambient air[J]. Energy & Fuels, 2011, 25(11): 5528-5537.
40	GOEPPERT Alain, CZAUN Miklos, Robert B MAY, et al. Carbon dioxide capture from the air using a polyamine based regenerable solid adsorbent[J]. Journal of the American Chemical Society, 2011, 133(50): 20164-20167.
41	WURZBACHER Jan Andre, GEBALD Christoph, STEINFELD Aldo. Separation of CO₂ from air by temperature-vacuum swing adsorption using diamine-functionalized silica gel[J]. Energy & Environmental Science, 2011, 4(9): 3584-3592.
42	BRILMAN D W F, VENEMAN R. Capturing atmospheric CO₂ using supported amine sorbents[J]. Energy Procedia, 2013, 37: 6070-6078.
43	CHOI Sunho, GRAY McMahan L, JONES Christopher W. Amine-tethered solid adsorbents coupling high adsorption capacity and regenerability for CO₂ capture from ambient air[J]. ChemSusChem, 2011, 4(5): 628-635.
44	OKUMURA Takeshi, YOSHIZAWA Katsuhiro, NUMAGUCHI Ryohei, et al. Demonstration plant of the Kawasaki CO₂ capture (KCC) system with solid sorbent for coal-fired power station[J]. SSRN Electronic Journal, 2018. .
45	SAKWA-NOVAK Miles A, JONES Christopher W. Steam induced structural changes of a poly(ethylenimine) impregnated γ-alumina sorbent for CO₂ extraction from ambient air[J]. ACS Applied Materials & Interfaces, 2014, 6(12): 9245-9255.
46	VESELOVSKAYA Janna V, LYSIKOV Anton I, NETSKINA Olga V, et al. K₂CO₃-containing composite sorbents based on thermally modified alumina: synthesis, properties, and potential application in a direct air capture/methanation process[J]. Industrial & Engineering Chemistry Research, 2020, 59(15): 7130-7139.
47	KAMRAN Urooj, PARK Soo Jin. Chemically modified carbonaceous adsorbents for enhanced CO₂ capture: a review[J]. Journal of Cleaner Production, 2021, 290: 125776.
48	WANG Mei, WANG Jitong, QIAO Wenming, et al. Scalable preparation of nitrogen-enriched carbon microspheres for efficient CO₂ capture[J]. RSC Advances, 2014, 4(106): 61456-61464.
49	陈爱兵, 于奕峰, 臧文伟, 等. 掺氮多孔碳在二氧化碳吸附分离中的应用[J]. 无机材料学报, 2015, 30(1): 9-16.
	CHEN Aibing, YU Yifeng, ZANG Wenwei, et al. Nitrogen-doped porous carbon for CO₂ adsorption[J]. Journal of Inorganic Materials, 2015, 30(1): 9-16.
50	WANG Jitong, HUANG Haihong, WANG Mei, et al. Direct capture of low-concentration CO₂ on mesoporous carbon-supported solid amine adsorbents at ambient temperature[J]. Industrial & Engineering Chemistry Research, 2015, 54(19): 5319-5327.
51	KELLER Laura, Burkhard OHS, LENHART Jelena, et al. High capacity polyethylenimine impregnated microtubes made of carbon nanotubes for CO₂ capture[J]. Carbon, 2018, 126: 338-345.
52	MADDEN David G, SCOTT Hayley S, KUMAR Amrit, et al. Flue-gas and direct-air capture of CO₂ by porous metal-organic materials[J]. Philosophical Transactions of the Royal Society A, Mathematical, Physical and Engineering Sciences, 2017, 375(2084): 20160025.
53	CASKEY Stephen R, WONG-FOY Antek G, MATZGER Adam J. Dramatic tuning of carbon dioxide uptake via metal substitution in a coordination polymer with cylindrical pores[J]. Journal of the American Chemical Society, 2008, 130(33): 10870-10871.
54	LEE Woo Ram, HWANG Sang Yeon, Dae Won RYU, et al. Diamine-functionalized metal-organic framework: exceptionally high CO₂ capacities from ambient air and flue gas, ultrafast CO₂ uptake rate, and adsorption mechanism[J]. Energy & Environmental Science, 2014, 7(2): 744-751.
55	CHOI Sunho, WATANABE Taku, Tae-Hyun BAE, et al. Modification of the Mg/DOBDC MOF with amines to enhance CO₂ adsorption from ultradilute gases[J]. The Journal of Physical Chemistry Letters, 2012, 3(9): 1136-1141.
56	MCDONALD Thomas M, LEE Woo Ram, MASON Jarad A, et al. Capture of carbon dioxide from air and flue gas in the alkylamine-appended metal-organic framework mmen-Mg₂(dobpdc)[J]. Journal of the American Chemical Society, 2012, 134(16): 7056-7065.
57	LIAO Peiqin, CHEN Xunwei, LIU Siyang, et al. Putting an ultrahigh concentration of amine groups into a metal-organic framework for CO₂ capture at low pressures[J]. Chemical Science, 2016, 7(10): 6528-6533.
58	LI Hao, WANG Kecheng, FENG Dawei, et al. Incorporation of alkylamine into metal-organic frameworks through a Brønsted acid-base reaction for CO₂ capture[J]. ChemSusChem, 2016, 9(19): 2832-2840.
59	KUMAR Amrit, MADDEN David G, LUSI Matteo, et al. Direct air capture of CO₂ by physisorbent materials[J]. Angewandte Chemie International Edition, 2015, 54(48): 14372-14377.
60	SHEKHAH Osama, BELMABKHOUT Youssef, ADIL Karim, et al. A facile solvent-free synthesis route for the assembly of a highly CO₂ selective and H₂S tolerant NiSIFSIX metal-organic framework[J]. Chemical Communications, 2015, 51(71): 13595-13598.
61	SHEKHAH Osama, BELMABKHOUT Youssef, CHEN Zhijie, et al. Made-to-order metal-organic frameworks for trace carbon dioxide removal and air capture[J]. Nature Communications, 2014, 5: 4228.
62	SADIQ Muhammad Munir, BATTEN Michael P, MULET Xavier, et al. A pilot-scale demonstration of mobile direct air capture using metal-organic frameworks[J]. Advanced Sustainable Systems, 2020, 4(12): 2000101.
63	DING Meili, FLAIG Robinson W, JIANG Hailong, et al. Carbon capture and conversion using metal-organic frameworks and MOF-based materials[J]. Chemical Society Reviews, 2019, 48(10): 2783-2828.
64	CHEN Zhenhe, DENG Shubo, WEI Haoran, et al. Polyethylenimine-impregnated resin for high CO₂ adsorption: an efficient adsorbent for CO₂ capture from simulated flue gas and ambient air[J]. ACS Applied Materials & Interfaces, 2013, 5(15): 6937-6945.
65	WANG Jitong, WANG Mei, LI Wencheng, et al. Application of polyethylenimine-impregnated solid adsorbents for direct capture of low-concentration CO₂ [J]. AIChE Journal, 2015, 61(3): 972-980.
66	WANG Tao, LIU Jun, LACKNER Klaus S, et al. Characterization of kinetic limitations to atmospheric CO₂ capture by solid sorbent[J]. Greenhouse Gases: Science and Technology, 2016, 6(1): 138-149.
67	WANG Tao, LIU Jun, HUANG Hao, et al. Preparation and kinetics of a heterogeneous sorbent for CO₂ capture from the atmosphere[J]. Chemical Engineering Journal, 2016, 284: 679-686.
68	吴禹松. 用于空气二氧化碳捕集的多孔树脂吸附剂成型及性能研究[D]. 杭州: 浙江大学, 2020.
	WU Yusong. Research on formation and performance of porous resin adsorbent for direct air capture of CO₂ [D]. Hangzhou: Zhejiang University, 2020.
69	WANG Tao, LACKNER Klaus S, WRIGHT Allen. Moisture swing sorbent for carbon dioxide capture from ambient air[J]. Environmental Science & Technology, 2011, 45(15): 6670-6675.
70	HE Leilei, FAN Maohong, DUTCHER Bryce, et al. Dynamic separation of ultradilute CO₂ with a nanoporous amine-based sorbent[J]. Chemical Engineering Journal, 2012, 189/190: 13-23.
71	HE Hongkun, ZHONG Mingjiang, KONKOLEWICZ Dominik, et al. Carbon black functionalized with hyperbranched polymers: synthesis, characterization, and application in reversible CO₂ capture[J]. Journal of Materials Chemistry A, 2013, 1(23): 6810-6821.
72	HE Hongkun, LI Wenwen, ZHONG Mingjiang, et al. Reversible CO₂ capture with porous polymers using the humidity swing[J]. Energy & Environmental Science, 2013, 6(2): 488-493.
73	LU Weigang, SCULLEY Julian P, YUAN Daqiang, et al. Carbon dioxide capture from air using amine-grafted porous polymer networks[J]. The Journal of Physical Chemistry C, 2013, 117(8): 4057-4061.
74	Guanhe RIM, FERIC Tony G, MOORE Thomas, et al. Solvent impregnated polymers loaded with liquid-like nanoparticle organic hybrid materials for enhanced kinetics of direct air capture and point source CO₂ capture[J]. Advanced Functional Materials, 2021, 31(21): 2010047.
75	GEBALD Christoph, WURZBACHER Jan Andre, TINGAUT Philippe, et al. Amine-based nanofibrillated cellulose as adsorbent for CO₂ capture from air[J]. Environmental Science & Technology, 2011, 45(20): 9101-9108.
76	GEBALD Christoph, WURZBACHER Jan A, BORGSCHULTE Andreas, et al. Single-component and binary CO₂ and H₂O adsorption of amine-functionalized cellulose[J]. Environmental Science & Technology, 2014, 48(4): 2497-2504.
77	HE Hongkun, ZHONG Mingjiang, KONKOLEWICZ Dominik, et al. Colloidal crystals: three-dimensionally ordered macroporous polymeric materials by colloidal crystal templating for reversible CO₂ capture [J]. Advanced Functional Materials, 2013, 23(37): 4719.
78	HE Hongkun, LI Wenwen, LAMSON Melissa, et al. Porous polymers prepared via high internal phase emulsion polymerization for reversible CO₂ capture[J]. Polymer, 2014, 55(1): 385-394.
79	XU Xingguang, MYERS Matthew B, VERSTEEG Friso G, et al. Direct air capture (DAC) of CO₂ using polyethylenimine (PEI) “snow”: a scalable strategy[J]. Chemical Communications, 2020, 56(52): 7151-7154.
80	SUJAN Achintya R, PANG Simon H, ZHU Guanghui, et al. Direct CO₂ capture from air using poly(ethylenimine)-loaded polymer/silica fiber sorbents[J]. ACS Sustainable Chemistry & Engineering, 2019, 7(5): 5264-5273.

载体	胺种类	CO₂浓度/气氛	吸附温度/℃	CO₂吸附量/mmol·g^-1	再生温度/℃	循环次数/性能	测量方式	参考文献
Li-LSX	—	0.0395%	25	1.34	240	—	PB	[18]
Zeolite Y8	TEPA	0.15%	30～70	3.14	—	—	PB	[19]
Zeolite Y	TEPA	0.5%	25	1.12	100	5/稳定	TGA	[20]
Zeolite 13X	—	0.04%	25	0.03（RH=49%）	140	—	TPD	[21]

载体	胺种类	CO₂浓度/气氛	吸附温度/℃	CO₂吸附量/mmol·g^-1	再生温度/℃	循环次数/性能	测量方式	参考文献
Li-LSX	—	0.0395%	25	1.34	240	—	PB	[18]
Zeolite Y8	TEPA	0.15%	30～70	3.14	—	—	PB	[19]
Zeolite Y	TEPA	0.5%	25	1.12	100	5/稳定	TGA	[20]
Zeolite 13X	—	0.04%	25	0.03（RH=49%）	140	—	TPD	[21]

载体	胺种类	CO₂浓度/气氛	吸附温度/℃	CO₂吸附量/mmol·g^-1	再生温度/℃	循环次数/性能	测量方式	参考文献
MCM-41	TRI	0.04%	25	0.98	—	—	TGA	[32]
MCM-41	TRI	0.04%	25	0.9 1.40（RH=64%）	—	—	PB	[32]
MCM-41	TRI	空气	(+5)~(-5)	1.16（RH=60%~80%）	100	3/迅速下降	TGA	[33]
SBA-15	PEI	0.04%	25	1.90	90	10/稳定	TGA	[29]
SBA-15	TEPA	0.04%	25	3.44	90	10/稳定	TGA	[29]
SBA-15+PEG200	PEI	0.04%/He	30	0.79	—	—	TGA	[31]
SBA15+PEG1000	PEI	0.04%/He	30	0.71	—	—	TGA	[31]
SBA-15+CTAB	PEI	0.04%/He	30	0.55	—	—	TGA	[31]
SBA-15	APTMS	0.04%/Ar	25	0.60	110	3/稳定	TGA	[35]
SBA-15	Aziridine	0.04%	25	1.72	110	4/稳定	MS	[36]
SBA-15	TEPA	0.04%	25	3.59（RH=49%）	—	—	TPD	[37]
Zr7-SBA-15	PEI(800)	0.04%/Ar	25	0.85	110	4/稳定	TGA	[38]
SBA-15	PEI	0.04%/Ar	25	1.05	110	3/稳定	TGA	[39]

载体	胺种类	CO₂浓度/气氛	吸附温度/℃	CO₂吸附量/mmol·g^-1	再生温度/℃	循环次数/性能	测量方式	参考文献
MCM-41	TRI	0.04%	25	0.98	—	—	TGA	[32]
MCM-41	TRI	0.04%	25	0.9 1.40（RH=64%）	—	—	PB	[32]
MCM-41	TRI	空气	(+5)~(-5)	1.16（RH=60%~80%）	100	3/迅速下降	TGA	[33]
SBA-15	PEI	0.04%	25	1.90	90	10/稳定	TGA	[29]
SBA-15	TEPA	0.04%	25	3.44	90	10/稳定	TGA	[29]
SBA-15+PEG200	PEI	0.04%/He	30	0.79	—	—	TGA	[31]
SBA15+PEG1000	PEI	0.04%/He	30	0.71	—	—	TGA	[31]
SBA-15+CTAB	PEI	0.04%/He	30	0.55	—	—	TGA	[31]
SBA-15	APTMS	0.04%/Ar	25	0.60	110	3/稳定	TGA	[35]
SBA-15	Aziridine	0.04%	25	1.72	110	4/稳定	MS	[36]
SBA-15	TEPA	0.04%	25	3.59（RH=49%）	—	—	TPD	[37]
Zr7-SBA-15	PEI(800)	0.04%/Ar	25	0.85	110	4/稳定	TGA	[38]
SBA-15	PEI	0.04%/Ar	25	1.05	110	3/稳定	TGA	[39]

载体	胺种类	CO₂浓度/气氛	吸附温度/℃	CO₂吸附量/mmol·g^-1	再生温度/℃	循环次数/性能	测量方式	参考文献
EtSNTs	PEI	0.04%/N₂	30	1.05	100	8/N含量下降7%	PB	[25]
MCF	APS	0.04%/He	25	0.54	—	—	TGA	[26]
	MAPS	0.04%/He	25	0.17	—	—	TGA	[26]
MCF	PEI(800)	0.04%/Ar	25	1.74	110	—	TGA	[34]
	PEI(2500)	0.04%/Ar	25	1.05	110	3/稳定	TGA	[34]
	PAA	0.04%/Ar	25	0.86	110	—	TGA	[34]
纳米二氧化硅	PEI-LMW	空气	23	2.6	80	—	PB	[27]
	PEI-HMW	空气	23	2.0	80	—	PB	[27]
	PEI-Linear	空气	23	3.2	80	—	PB	[27]
白炭黑	PEI-ln	0.04%/N₂/O₂	25	2.34	140	—	IR	[28]
	PEI(800)	0.04%/N₂/O₂	25	2.44	140	—	IR	[28]
	PEI-M	0.04%/N₂/O₂	25	1.69	140	—	IR	[28]
	PEI-H	0.04%/N₂/O₂	25	1.67	140	—	IR	[28]
白炭黑	PEI(25000) 33%	0.042%	25	1.18 1.77（RH=67%）	85	—	IR	[40]
	PEI(25000) 50%	0.042%	25	1.70 1.41（RH=67%）	85	—	IR	[40]
硅胶	AEATPMS	0.04%～0.044%	25	0.4 0.44（RH=40%）	90	40/稳定	PB	[41]
HP2MG	TEPA	0.04%	35	2.50	80	—	TGA	[42]
CARiACT G10 HPV	PEI	0.04%/Ar	25	2.36	110	4/下降30%	TGA	[43]
	PEI+AP	0.04%/Ar	25	2.26	110	4/下降9%	TGA	[43]
	PEI+TP	0.04%/Ar	25	2.19	110	4/下降1%	TGA	[43]

直接空气捕碳固体多孔材料的研究进展

Research progress of solid porous materials for direct CO₂ capture from air

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 13

参考文献 80

相关文章 15

编辑推荐

Metrics

本文评价

载体/名称	胺种类	CO₂浓度/气氛	吸附温度/℃	CO₂吸附量/mmol·g^-1	再生温度/℃	循环次数/性能	测量方式	参考文献
PEI-syna50	PEI	0.04%/Ar	25	1.74	110	3/稳定	TGA	[39]
γ-Al₂O₃	PEI	0.04%/He	30	1.71（RH=50%）	—	—	IR	[45]
γ-Al₂O₃+5min steam	PEI	0.04%/He	30	1.96（RH=50%）	—	—	IR	[45]
γ-Al₂O₃ 40%	PEI	0.04%/He	30	1.23	—	—	TGA	[45]
Boehmite/alumina 40%	PEI	0.04%/He	30	1.12	—	—	TGA	[45]
K₂CO₃/Al₂O₃-750	—	0.04%～0.044%	25	0.93（RH=25%）	200	—	PB	[46]

载体/名称	胺种类	CO₂浓度/气氛	吸附温度/℃	CO₂吸附量/mmol·g^-1	再生温度/℃	循环次数/性能	测量方式	参考文献
Mg-MOF-74	—	0.04%	23.4	0.14（RH=49%）	—	—	TPD	[53]
Mg₂(dobpdc)	EN	0.039%	25	2.83	120	20/下降4%	vol.	[54]
Mg₂(dobdc)	EN	0.04%	22	1.51	110	4/稳定	TGA	[55]
Mg₂(dobpdc)	—	0.039%	25	0.13	—	—	vol.	[56]
Mg₂(dobpdc)	mmen	0.039%	25	1.05	150	6/稳定	TGA	[56]
Mg₂(dobdc)	N₂H₄	0.04%	25	3.89	130	—	TGA	[57]
Cr-MIL-101-SO₃H	TAEA	0.04%	20	1.72	80	15/稳定	vol.	[58]
HKUST-1	—	0.04%	23.4	0.05（RH=49%）	—	—	TPD	[59]
SIFSIX-3-Ni	—	0.04%	23.4	0.18（RH=49%）	—	—	TPD	[60]
SIFSIX-3-Cu	—	0.04%	25	1.24	—	—	vol.	[61]

载体/名称	胺种类	CO₂浓度/气氛	吸附温度/℃	CO₂吸附量/mmol·g^-1	再生温度/℃	循环次数/性能	测量方式	参考文献
HP20	PEI(600)	0.04%	25	2.26	100	5/稳定	PB	[64]
HP2MGL	PEI(600)	0.04%/N₂	25	1.96 3.16（RH=10%）	100	5/稳定	PB	[65]
HP2MGL	PEI(600)	0.04%/79.5%N₂/20.5%O₂	25	2.44（RH=10%）	—	—	PB	[65]
HP2MGL-CTAB	PEI(600)	0.04%/79.5%N₂/20.5%O₂	25	2.63（RH=10%）	—	—	PB	[65]
D201	季胺	0.04%	20	1.02（RH=21.2%）	变湿	—	TGA	[68]
D290	季胺	0.04%	20	1.03（RH=21.2%）	变湿	—	TGA	[68]

名称	载体	CO₂浓度/气氛	吸附温度 /℃	CO₂吸附量/mmol·g^-1	再生温度 /℃	循环次数/性能	测量方式	参考文献
RFAS4	甲醛、苯二酚APTES	0.04%/N₂	30	1.78（体积分数H₂O=0.15%）	80	10/略有下降	IR	[70]
CB-N-g-PCMS-OH^-	炭黑	压缩空气	15	0.36（RH=95%）	变湿	—	IR	[71]
Colloidal crystal	交联多孔聚合物	压缩空气	15	0.5（RH=95%）	变湿	—	IR	[72]
HIPE	高内相乳化体系	压缩空气	15	0.14（RH=95%）	变湿	—	IR	[72]
PPN-6-CH2DETA	PPN-6	0.04%/N₂/O₂	22	1.04	120	—	vol.	[73]
NPEI-SIPs	溶剂浸渍聚合物	0.04%/N₂	25	1.05 1.66（湿）	120	—	PB	[74]
AEAPDMS-NFC-FD	纳米纤维素	0.0506%	25	1.39（RH=40%）	80	20/稳定	IR	[75]
APDES-NFC	纳米纤维素	0.04%	23	1.11 2.13（RH=97%）	—	—	IR	[76]
PS-CC	聚苯乙烯	0.04%	20	0.57	变湿	—	IR	[77]
HIPES	交联多孔聚合物	压缩空气	15	0.72	变湿	15/稳定	IR	[78]
PEI snow	聚乙烯亚胺	空气	20±2	1.29	120	10/稳定	PB	[79]
PEI-CA-SiO₂	聚合物/二氧化硅整体纤维	0.0395%/He	35	0.59 1.6（RH=85%）	110	6/下降7%	TGA	[80]

[1]	陈崇明, 陈秋, 宫云茜, 车凯, 郁金星, 孙楠楠. 分子筛基CO₂吸附剂研究进展[J]. 化工进展, 2023, 42(S1): 411-419.
[2]	杨莹, 侯豪杰, 黄瑞, 崔煜, 王兵, 刘健, 鲍卫仁, 常丽萍, 王建成, 韩丽娜. 利用煤焦油中酚类物质Stöber法制备碳纳米球用于CO₂吸附[J]. 化工进展, 2023, 42(9): 5011-5018.
[3]	王久衡, 荣鼐, 刘开伟, 韩龙, 水滔滔, 吴岩, 穆正勇, 廖徐情, 孟文佳. 水蒸气强化纤维素模板改性钙基吸附剂固碳性能及强度[J]. 化工进展, 2023, 42(6): 3217-3225.
[4]	陆诗建, 张媛媛, 吴文华, 杨菲, 刘玲, 康国俊, 李清方, 陈宏福, 王宁, 王风, 张娟娟. 百万吨级CO₂捕集项目亚硝胺污染物扩散健康风险评估[J]. 化工进展, 2023, 42(6): 3209-3216.
[5]	桑伟, 唐建峰, 花亦怀, 陈洁, 孙培源, 许义飞. 物理溶剂及有机胺的性质对相变吸收性能的影响[J]. 化工进展, 2023, 42(4): 2151-2159.
[6]	陆诗建, 刘苗苗, 刘玲, 康国俊, 毛松柏, 王风, 张娟娟, 贡玉萍. 烟气胺法CO₂捕集技术进展与未来发展趋势[J]. 化工进展, 2023, 42(1): 435-444.
[7]	孟令玎, 毛梦雷, 廖奇勇, 孟子晖, 刘文芳. 碳酸酐酶和甲酸脱氢酶的稳定性研究进展[J]. 化工进展, 2022, 41(S1): 436-447.
[8]	刘畅, 李玉宝, 左奕, 李吉东. 羟基磷灰石负载黄芩苷的不同载药方法比较分析[J]. 化工进展, 2022, 41(9): 4995-5002.
[9]	方龙龙, 郑文姬, 宁梦佳, 张明扬, 杨雨晴, 代岩, 贺高红. 功能化Zr-MOF强化混合基质膜CO₂分离[J]. 化工进展, 2022, 41(9): 4954-4962.
[10]	陆诗建, 刘玲, 刘滋武, 郭伯文, 俞徐林, 梁艳, 赵东亚, 朱全民. AEP-DPA-CuO相变纳米流体吸收CO₂稳定性[J]. 化工进展, 2022, 41(8): 4555-4561.
[11]	王震, 闫霆, 霍英杰. 氯化锰/氨热化学吸附储热的特性[J]. 化工进展, 2022, 41(8): 4425-4431.
[12]	吴佳佳, 潘振, 商丽艳, 孙秀丽, 孙超, 孙祥广. 中空纤维膜接触器中N,N-二甲基乙醇胺吸收CO₂的特性[J]. 化工进展, 2022, 41(4): 2132-2139.
[13]	黄晟, 王静宇, 李振宇. 碳中和目标下石油与化学工业绿色低碳发展路径分析[J]. 化工进展, 2022, 41(4): 1689-1703.
[14]	宋珂琛, 崔希利, 邢华斌. 二氧化碳直接空气捕集材料与技术研究进展[J]. 化工进展, 2022, 41(3): 1152-1162.
[15]	张陆, 杨声. 低温甲醇洗碳捕集改进与优化[J]. 化工进展, 2022, 41(11): 6167-6175.

直接空气捕碳固体多孔材料的研究进展

Research progress of solid porous materials for direct CO2 capture from air

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 13

参考文献 80

相关文章 15

编辑推荐

Metrics

本文评价

Research progress of solid porous materials for direct CO₂ capture from air