掺硼金刚石阳极电催化降解新兴抗生素类污染物研究进展

doi:10.16085/j.issn.1000-6613.2022-0247

化工进展 ›› 2022, Vol. 41 ›› Issue (12): 6615-6626.DOI: 10.16085/j.issn.1000-6613.2022-0247

掺硼金刚石阳极电催化降解新兴抗生素类污染物研究进展

翟重渊¹(), 赵丹荻¹, 何亚鹏¹^,²(), 黄惠¹^,²^,³, 陈步明¹^,²^,³, 郭忠诚¹^,²^,³

^1.昆明理工大学冶金与能源工程学院，云南昆明 650093
^2.云南省冶金电极材料工程技术中心，云南昆明 650106
^3.昆明理工恒达科技股份有限公司，云南昆明 650106

收稿日期:2022-02-16 修回日期:2022-04-11 出版日期:2022-12-20 发布日期:2022-12-29
通讯作者: 何亚鹏
作者简介:翟重源（2001—），男，硕士研究生，研究方向为环境电化学。E-mail：2536316492@qq.com。
基金资助:
国家自然科学基金(22002054);云南省基础研究计划(202101AU070157);昆明理工大学分析测试基金(2021T20200004)

Recent development on boron-doped diamond anodes in electrochemical degradation of emerging antibiotic pollutants

ZHAI Chongyuan¹(), ZHAO Dandi¹, HE Yapeng¹^,²(), HUANG Hui¹^,²^,³, CHEN Buming¹^,²^,³, GUO Zhongcheng¹^,²^,³

^1.Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, Yunnan, China
^2.Metallurgical Electrode Material Engineering Technology Research Center of Yunnan Province, Kunming 650106, Yunnan, China
^3.Kunming Hendera Technology Co. , Ltd. , Kunming 650106, Yunan, China

Received:2022-02-16 Revised:2022-04-11 Online:2022-12-20 Published:2022-12-29
Contact: HE Yapeng

摘要/Abstract

摘要：

抗生素类药物是目前水环境中出现的一类新兴有机污染物，具有难自然降解、环境刺激性、生物毒性及耐药性等特点，高效去除抗生素类污染物是近年来环境工作者重点探讨的内容。掺硼金刚石（boron-doped diamond，BDD）电极由于自身优异的物理和化学性质，被认作为目前电催化氧化水中有机污染物最为理想高效的阳极材料，但关于BDD阳极在新兴抗生素类污染物的研究情况尚未进行及时的总结。本文首先论述了BDD阳极在电催化氧化有机污染物的降解过程和基于强氧化性物种的电催化氧化机理，进而分析了BDD阳极在电催化降解水中新兴抗生素类污染物的研究进展，探讨了影响抗生素类污染物电催化降解过程的关键影响因素，总结了BDD阳极材料的开发情况，同时，总结了以BDD阳极电催化氧化为基础发展而来的其他水处理联合方法，最后，进一步展望了BDD阳极在未来电催化降解抗生素类污染物存在的问题及未来的重点发展方向。

关键词: 掺硼金刚石, 电催化氧化, 抗生素类污染物, 降解机理, 过程动力学

Abstract:

Antibiotics are considered as a kind of emerging organic contaminants in water environment, which have features of difficult to naturally degrade, environmental irritation, biological toxicity and drug resistance, etc. Therefore, the elimination of antibiotics in water environment has become the focus of environmental researchers in recent years. Benefitting from excellent physical and chemical properties, boron-doped diamond (BDD) electrode has been regarded as the most ideal and efficient electrode material for electrocatalytic oxidation of organic pollutants. However, there is lack of summary for the current research status of BDD anode in emerging antibiotic pollutants. This review firstly discusses the degradation process and mechanisms of organic pollutants involving oxidation species during electrocatalytic oxidation on BDD anode, and then analysis the research progress of electrocatalytic degradation of emerging antibiotic pollutants in recent years. In the following, the key influencing factors on electrocatalytic degradation process of antibiotics are discussed, and the development progress of BDD anode materials is further summarized. At the same time, the combined techniques based on electrocatalytic oxidation on BDD anode are also summarized. Finally, the problems existing in electrocatalytic degradation of antibiotic pollutants with BDD anode and key development direction in the future are further prospected.

Key words: boron doped diamond, electrochemical oxidation, antibiotic pollutants, degradation mechanism, process kinetics

中图分类号:

O646

翟重渊, 赵丹荻, 何亚鹏, 黄惠, 陈步明, 郭忠诚. 掺硼金刚石阳极电催化降解新兴抗生素类污染物研究进展[J]. 化工进展, 2022, 41(12): 6615-6626.

ZHAI Chongyuan, ZHAO Dandi, HE Yapeng, HUANG Hui, CHEN Buming, GUO Zhongcheng. Recent development on boron-doped diamond anodes in electrochemical degradation of emerging antibiotic pollutants[J]. Chemical Industry and Engineering Progress, 2022, 41(12): 6615-6626.

图/表 7

表1 抗生素的分类与代表性物质[4]

分类	主体结构	代表性物质
氨基糖苷类	氨基糖与氨基环醇连接	链霉素、庆大霉素、链霉素
β-内酰胺类	β-内酰胺环	青霉素、头孢菌素、硫霉素类
糖肽类	高度修饰的七肽骨架	万古霉素、去甲万古霉素、替考拉宁
四环素类	并四苯	四环素、金霉素、土霉素
大环内酯类	14~16碳内酯环	红霉素、阿奇霉素、罗红霉素
磺胺类	磺胺	磺胺甲𫫇唑、磺胺嘧啶
喹诺酮类	4-喹诺酮	诺氟沙星、环丙沙星、氧氟沙星
硝基咪唑类	硝基咪唑环	甲硝唑、罗硝唑、奥硝唑

图1 金刚石阳极在不同介质中活性物种的产生及氧化机理示意图[17]

图2 过硫酸盐的活化过程中阳极和阴极活性物种及对环丙沙星的去除[29]

图3 不同硼掺杂量BDD阳极对尿液样本中青霉素G的电化学降解及毒性演变[40]

图4 二维BDD和三维BDD电极基础结构单元的计算流体力学模拟分析[50](b)、(e)、(h)—截面区域湍流强度；(c)、(f)、(i)—表面区域湍流强度

图5 纳滤与电化学氧化-纳滤组合技术对于抗生素废水的处理及膜污染情况[69]

图6 不同阳极和阴极对电芬顿过程降解对氨基水杨酸影响[79]

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掺硼金刚石阳极电催化降解新兴抗生素类污染物研究进展

Recent development on boron-doped diamond anodes in electrochemical degradation of emerging antibiotic pollutants

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