化工进展 ›› 2023, Vol. 42 ›› Issue (5): 2626-2637.DOI: 10.16085/j.issn.1000-6613.2022-1347
孙闫晨昊(), 王维(), 李一喆, 祝妍妮, 刘学武, 张大为
收稿日期:
2022-07-18
修回日期:
2022-09-21
出版日期:
2023-05-10
发布日期:
2023-06-02
通讯作者:
王维
作者简介:
孙闫晨昊(1997—),男,硕士研究生,研究方向为喷雾干燥。E-mail:sych808@mail.dlut.edu.cn。
基金资助:
SUN Yanchenhao(), WANG Wei(), LI Yizhe, ZHU Yanni, LIU Xuewu, ZHANG Dawei
Received:
2022-07-18
Revised:
2022-09-21
Online:
2023-05-10
Published:
2023-06-02
Contact:
WANG Wei
摘要:
橘皮油的易挥发、易氧化等特点使其难以长期保存。为了延长橘皮油的保质期并丰富其应用范围,本文利用微胶囊技术,以麦芽糊精和阿拉伯胶为复配壁材,分别采用喷雾干燥法和冷冻干燥法对橘皮油进行包埋,并对所得产品进行质量评价。喷雾干燥的最佳工艺参数为:进风温度194℃、进料速度90.2mL/min和料液固含量34.7%。冷冻干燥的工艺参数为冷冻温度-30℃、干燥室压力30Pa和干燥室温度30℃。在此工艺条件下,喷雾干燥法和冷冻干燥法制备的橘皮油微胶囊包埋率分别为90.17%和82.48%。喷雾干燥产品呈规则球形、质感细腻并且囊壁致密,而冷冻干燥产品呈不规则的薄片状,但水分含量较低并且流动性好。2种干燥产品都具有一定的耐热能力,可以减少芯材在贮存和使用过程中的受热损失。综合比较,喷雾干燥法比冷冻干燥法更适合应用于制备橘皮油微胶囊产品。
中图分类号:
孙闫晨昊, 王维, 李一喆, 祝妍妮, 刘学武, 张大为. 橘皮油微胶囊制备及其产品质量评价[J]. 化工进展, 2023, 42(5): 2626-2637.
SUN Yanchenhao, WANG Wei, LI Yizhe, ZHU Yanni, LIU Xuewu, ZHANG Dawei. Preparation of mandarin oil microcapsules and its product quality evaluation[J]. Chemical Industry and Engineering Progress, 2023, 42(5): 2626-2637.
因素 | -1 | 0 | 1 |
---|---|---|---|
A:进风温度/℃ | 180 | 190 | 200 |
B:进料速度/mL·min–1 | 80 | 90 | 100 |
C:固含量质量分数/% | 30 | 35 | 40 |
表1 响应面因素水平表
因素 | -1 | 0 | 1 |
---|---|---|---|
A:进风温度/℃ | 180 | 190 | 200 |
B:进料速度/mL·min–1 | 80 | 90 | 100 |
C:固含量质量分数/% | 30 | 35 | 40 |
编号 | 进风温度 /℃ | 进料速度 /mL·min–1 | 固含量(质量分数) /% | 包埋率 /% |
---|---|---|---|---|
1 | 180 | 80 | 35 | 88.17 |
2 | 200 | 80 | 35 | 86.76 |
3 | 180 | 100 | 35 | 85.37 |
4 | 200 | 100 | 35 | 87.55 |
5 | 180 | 90 | 30 | 81.98 |
6 | 200 | 90 | 30 | 87.43 |
7 | 180 | 90 | 40 | 86.46 |
8 | 200 | 90 | 40 | 84.80 |
9 | 190 | 80 | 30 | 85.03 |
10 | 190 | 100 | 30 | 83.49 |
11 | 190 | 80 | 40 | 85.08 |
12 | 190 | 100 | 40 | 84.83 |
13 | 190 | 90 | 35 | 89.51 |
14 | 190 | 90 | 35 | 89.34 |
15 | 190 | 90 | 35 | 88.97 |
16 | 190 | 90 | 35 | 90.00 |
17 | 190 | 90 | 35 | 90.30 |
表2 响应面实验设计及结果
编号 | 进风温度 /℃ | 进料速度 /mL·min–1 | 固含量(质量分数) /% | 包埋率 /% |
---|---|---|---|---|
1 | 180 | 80 | 35 | 88.17 |
2 | 200 | 80 | 35 | 86.76 |
3 | 180 | 100 | 35 | 85.37 |
4 | 200 | 100 | 35 | 87.55 |
5 | 180 | 90 | 30 | 81.98 |
6 | 200 | 90 | 30 | 87.43 |
7 | 180 | 90 | 40 | 86.46 |
8 | 200 | 90 | 40 | 84.80 |
9 | 190 | 80 | 30 | 85.03 |
10 | 190 | 100 | 30 | 83.49 |
11 | 190 | 80 | 40 | 85.08 |
12 | 190 | 100 | 40 | 84.83 |
13 | 190 | 90 | 35 | 89.51 |
14 | 190 | 90 | 35 | 89.34 |
15 | 190 | 90 | 35 | 88.97 |
16 | 190 | 90 | 35 | 90.00 |
17 | 190 | 90 | 35 | 90.30 |
方差分析 | 平方和 | 自由度 | 均方 | F值 | p值 |
---|---|---|---|---|---|
模型 | 100.01 | 9 | 11.11 | 59.23 | < 0.0001 |
A | 5.54 | 1 | 5.54 | 29.55 | 0.0010 |
B | 2.29 | 1 | 2.29 | 12.21 | 0.0101 |
C | 1.31 | 1 | 1.31 | 6.99 | 0.0332 |
AB | 8.09 | 1 | 8.09 | 43.14 | 0.0003 |
AC | 12.64 | 1 | 12.64 | 67.37 | < 0.0001 |
BC | 0.4160 | 1 | 0.4160 | 2.22 | 0.1801 |
A2 | 5.19 | 1 | 5.19 | 27.69 | 0.0012 |
B2 | 11.75 | 1 | 11.75 | 62.65 | < 0.0001 |
C2 | 47.13 | 1 | 47.13 | 251.24 | < 0.0001 |
残差 | 1.31 | 7 | 0.1876 | — | — |
失拟项 | 0.1935 | 3 | 0.0645 | 0.2304 | 0.8711 |
纯误差 | 1.12 | 4 | 0.2799 | — | — |
总和 | 101.32 | 16 | — | — | — |
表3 响应面模型方差分析
方差分析 | 平方和 | 自由度 | 均方 | F值 | p值 |
---|---|---|---|---|---|
模型 | 100.01 | 9 | 11.11 | 59.23 | < 0.0001 |
A | 5.54 | 1 | 5.54 | 29.55 | 0.0010 |
B | 2.29 | 1 | 2.29 | 12.21 | 0.0101 |
C | 1.31 | 1 | 1.31 | 6.99 | 0.0332 |
AB | 8.09 | 1 | 8.09 | 43.14 | 0.0003 |
AC | 12.64 | 1 | 12.64 | 67.37 | < 0.0001 |
BC | 0.4160 | 1 | 0.4160 | 2.22 | 0.1801 |
A2 | 5.19 | 1 | 5.19 | 27.69 | 0.0012 |
B2 | 11.75 | 1 | 11.75 | 62.65 | < 0.0001 |
C2 | 47.13 | 1 | 47.13 | 251.24 | < 0.0001 |
残差 | 1.31 | 7 | 0.1876 | — | — |
失拟项 | 0.1935 | 3 | 0.0645 | 0.2304 | 0.8711 |
纯误差 | 1.12 | 4 | 0.2799 | — | — |
总和 | 101.32 | 16 | — | — | — |
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