化工进展 ›› 2022, Vol. 41 ›› Issue (8): 4432-4440.DOI: 10.16085/j.issn.1000-6613.2022-0202

• 材料科学与技术 • 上一篇    下一篇

界面聚合聚脲/聚氨酯复合壳体香精微胶囊的制备及性能

王乔逸1,2(), 陆少锋1,2(), 师文钊1,2, 洪勋1,2, 姚东霞1,2, 张领1,2   

  1. 1.西安工程大学纺织科学与工程学院,陕西 西安 710048
    2.西安工程大学功能性纺织材料及制品教育部重点实验室,陕西 西安 710048
  • 收稿日期:2022-02-06 修回日期:2022-05-16 出版日期:2022-08-25 发布日期:2022-08-22
  • 通讯作者: 陆少锋
  • 作者简介:王乔逸(1997—),男,硕士研究生,研究方向为功能性微胶囊材料。E-mail:wangqiaoyi123456@163.com
  • 基金资助:
    陕西省重点研发计划(2022GY-351);西安市科技创新人才服务企业项目(2020KJRC0024);西安市碑林区2020年应用技术研发类项目(GX2001);西安工程大学研究生创新基金(chx2022001);国家自然科学基金青年科学基金(21908171);陕西省自然科学基础研究计划(2020JQ-825)

Preparation and properties of polyurea/polyurethane shell microencapsulated essence by interfacial polymerization

WANG Qiaoyi1,2(), LU Shaofeng1,2(), SHI Wenzhao1,2, HONG Xun1,2, YAO Dongxia1,2, ZHANG Ling1,2   

  1. 1.School of Textile Science and Engineering, Xi’an Polytechnic University, Xi’an 710048, Shaanxi, China
    2.Key Laboratory of Functional Textile Material and Product(Xi’an Polytechnic University), Ministry of Education, Xi’an 710048, Shaanxi, China
  • Received:2022-02-06 Revised:2022-05-16 Online:2022-08-25 Published:2022-08-22
  • Contact: LU Shaofeng

摘要:

以茉莉香精为芯材,以异氟尔酮二异氰酸酯(IPDI)分别与二乙烯三胺(DETA)、β-环糊精(β-CD)及β-CD/DETA反应物为壁材,采用界面聚合法制备了聚脲、聚氨酯、聚脲/聚氨酯3种不同结构壳体的香精微胶囊。探究了不同微胶囊壳体对微胶囊表观形貌、热稳定性、香精微胶囊缓释性的影响并通过动力学模型分析了香精扩散方式。结果表明,以β-CD/DETA制备的聚脲/聚氨酯复合壳体微胶囊成囊性优异,壳体致密完整,热稳定性和缓释性能最好,经其整理的纺织品可保持较浓香味90多天。3种香精微胶囊在100℃、120℃高温缓释数据均符合零级、一级、Ritger-Peppas及Higuchi动力学模型。聚脲/聚氨酯复合壳体Ritger-Peppas方程拟合后n值更加接近0.45,更符合Fick扩散,缓释性能更好。

关键词: 界面, 聚合, 香精, 微胶囊, 动力学模型

Abstract:

Flavor microcapsules with three different structural shells of polyurea, polyurethane and polyurea/polyurethane were prepared by interfacial polymerization using jasmine flavor as the core material and isoflurone diisocyanate (IPDI) with diethylenetriamine (DETA), β-cyclodextrin (β-CD) and β-CD/DETA reactants as the wall material, respectively. The effects of different microcapsules shells on the microcapsules’ apparent morphology, thermal stability and flavor microcapsules’ slow release were investigated, and the flavor diffusion mode was analyzed by kinetic model. The results showed that the polyurea/polyurethane composite shell microcapsules prepared with β-CD/DETA had excellent capsule formation, dense and complete shells, the best thermal stability and slow release performance, and the textiles finished by them could maintain a strong fragrance for more than 90 days. The data of high-temperature slow release of the three flavor microcapsules at 100℃ and 120℃ were in accordance with the zero-level, first-level, Ritger-Peppas and Higuchi kinetic models. The Ritger-Peppas equation fitted to the polyurea/polyurethane composite shell had an n-value closer to 0.45, which was more consistent with Fick diffusion and better retarding performance.

Key words: interface, polymerization, essence, microencapsulation, kinetic modeling

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