醇酸树脂微胶囊的制备及环氧涂层自修复性能

doi:10.16085/j.issn.1000-6613.2019-1669

化工进展 ›› 2020, Vol. 39 ›› Issue (7): 2782-2787.DOI: 10.16085/j.issn.1000-6613.2019-1669

醇酸树脂微胶囊的制备及环氧涂层自修复性能

雷瑞¹(), 马养民¹^,²(), 杨秀芳¹^,²

^1.陕西科技大学化学与化工学院，陕西西安 710021
^2.陕西省轻化工助剂重点实验室，陕西西安 710021

出版日期:2020-07-05 发布日期:2020-07-10
通讯作者: 马养民
作者简介:雷瑞（1995—），女，硕士研究生，研究方向为改性醇酸树脂。E-mail: 180379797@qq.com。
基金资助:
陕西省重点研发计划(2018ZDXM-NY-083);西安市未央区科技计划(201909)

Self-healing performance of epoxy coating containing microencapsulated alkyd resin

Rui LEI¹(), Yangmin MA¹^,²(), Xiufang YANG¹^,²

^1.College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi’an 710021, Shaanxi, China
^2.Shaanxi Key Laboratory of Chemical Additives for Industry, Xi’an 710021, Shaanxi, China

Online:2020-07-05 Published:2020-07-10
Contact: Yangmin MA

摘要/Abstract

摘要：

采用三聚氰胺-脲醛树脂（MUF）为壁材、合成的花椒籽油醇酸树脂为芯材，原位聚合法制备自修复微胶囊，探讨了微胶囊的制备工艺。并采用扫描电子显微镜（SEM）、红外光谱仪（FTIR）、热重分析仪（TGA）和粒径分析仪对微胶囊的表面形貌、化学结构、热稳定性及其粒径分布进行了测试表征。将醇酸树脂微胶囊分散到环氧基体中，研究了环氧涂层的力学性能和自修复性能。实验结果表明，当乳化剂浓度为2.0g/L、芯壁比为2∶1、终点pH为3.5时，微胶囊呈球形结构，无明显的缺陷和损伤，平均粒径为97.44μm，热稳定性良好。当添加质量分数5%的微胶囊时，与未添加微胶囊的自修复涂层相比，其弯曲强度、拉伸强度、黏结强度及其冲击强度分别提高了50.4%、50.0%、40.0%及25.2%，且涂层的自修复性能良好。

关键词: 环氧树脂, 微胶囊, 醇酸树脂, 修复, 聚合物, 复合材料

Abstract:

The self-healing microcapsules were prepared by in-situ polymerization with melamine urea formaldehyde resin (MUF) as shell material and Zanthoxylum bungeanum seed oil-based alkyd resin as core material. The surface morphology, chemical structure, thermal stability and size distribution of the microcapsules were characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), thermal gravimetric analysis (TGA) and particle size analyzer. The mechanical and self-healing properties of epoxy coating were investigated by dispersing alkyd microcapsules into epoxy matrix. The microcapsules were uniform sphere with no obvious defects and damages with an average particle size of 97.44μm when the concentration of emulsifier is 2.0g/L and the core/wall was 2∶1 with the end point pH of 3.5. The microcapsules possessed good thermal stability. When the content of microcapsule was 5%, the bending strength, tensile strength, bonding strength and impact strength of the coating were increased by 50.4%, 50.0%, 40.0% and 25.2%, respectively and the self-healing performance of the coating significantly enhanced, as compared with the unmodified one.

Key words: epoxy resin, microencapsulation, alkyd resin, healing, polymer, composites

中图分类号:

TG174.46

雷瑞, 马养民, 杨秀芳. 醇酸树脂微胶囊的制备及环氧涂层自修复性能[J]. 化工进展, 2020, 39(7): 2782-2787.

Rui LEI, Yangmin MA, Xiufang YANG. Self-healing performance of epoxy coating containing microencapsulated alkyd resin[J]. Chemical Industry and Engineering Progress, 2020, 39(7): 2782-2787.

参考文献

1	WHITE S R, SOTTOS N R, GEUBELLE P H, et al. Autonomic healing of polymer composites[J]. Nature, 2001, 409(6822): 794-797.
2	童晓梅, 郝芹芹, 闫子英, 等. 硅烷改性环氧树脂自修复微胶囊的制备及应用[J]. 化工进展, 2018, 37(9): 3555-3561.
2	TONG X M, HAO Q Q, YAN Z Y, et al. Preparation and application of epoxy resin self-healing microcapsules modified by silicone[J]. Chemical Industry and Engineering Progress, 2018, 37(9): 3555-3561.
3	ATAEI S, KHORASANI S N, NEISIANY R E. Biofriendly vegetable oil healing agents used for developing self-healing coatings: a review[J]. Progress in Organic Coatings, 2019, 129: 77-95.
4	叶三男，王培，孙阳超, 等. 微胶囊填充型自修复涂层材料研究进展[J]. 表面技术, 2016, 45(6): 91-99.
4	YE S N, WANG P, SUN Y C, et al. Research advances in microcapsuled self-healing coatings materials[J]. Surface Technology, 2016, 45(6): 91-99.
5	李海燕, 张丽冰, 李杰, 等. 外援型自修复聚合物材料研究进展[J]. 化工进展, 2014, 33(1): 133-139.
5	LI H Y, ZHANG L B, LI J, et al. Research progresses in extrinsic self-healing polymer materials[J]. Chemical Industry and Engineering Progress, 2014, 33(1): 133-139.
6	BLAISZIK B J, CARUSO M M, MCILROY D A, et al. Microcapsules filled with reactive solutions for self-healing materials[J]. Polymer, 2009, 50(4): 990-997.
7	MIRABEDINI S M, ESFANDEH M, FARNOOD R R, et al. Amino-silane surface modification of urea-formaldehyde microcapsules containing linseed oil for improved epoxy matrix compatibility. Part Ⅰ: Optimizing silane treatment conditions[J]. Progress in Organic Coatings, 2019, 136: 105242-105251.
8	JIALAN Y, CHENPENG Y, CHENGFEI Z, et al. Preparation process of epoxy resin microcapsules for self-healing coatings[J]. Progress in Organic Coatings, 2019, 132: 440-444.
9	ZHU Y, YE X J, RONG M Z, et al. Self-healing glass fiber/epoxy composites with polypropylene tubes containing self-pressurized epoxy and mercaptan healing agents[J]. Composites Science and Technology, 2016, 135: 146-152.
10	MA Y, LU P, CHEN W, et al. Preparation of isocyanate microcapsules as functional crosslinking agent by minimalist interfacial polymerization[J]. Advanced Powder Technology, 2019, 30(10): 1995-2002.
11	ATTA A M, AL-LOHEDAN H A, EL-SAEED A M, et al. Epoxy embedded with TiO₂ nanogel composites as promising self-healing organic coatings of steel[J]. Progress in Organic Coatings, 2017, 105: 291-302.
12	WANG L, SHAO F, ZHONG X H, et al. Tailoring of self-healing thermal barrier coatings via finite element method[J]. Applied Surface Science, 2017, 431: 60-74.
13	HU M M, GUO J T, YU Y J, et al. Research advances of microencapsulation and its prospects in the petroleum industry[J]. Materials, 2017, 10(4): 369-387.
14	GIRARDI N S, GARCIA D, ROBLEDO S N, et al. Microencapsulation of peumus boldus oil by complex coacervation to provide peanut seeds protection against fungal pathogens[J]. Industrial Crops and Products2016, 92: 93-101.
15	ATAEI S, KHORASANI S N, TORKAMAN R, et al. Self-healing performance of an epoxy coating containing microencapsulated alkyd resin based on coconut oil[J]. Progress in Organic Coatings, 2018, 120: 160-166.
16	ABDIPOUR H, REZAEI M, ABBASI F. Synthesis and characterization of high durable linseed oil-urea formaldehyde micro/nanocapsules and their self-healing behaviour in epoxy coating[J]. Progress in Organic Coatings, 2018, 124: 200-214.
17	雷瑞, 马养民, 杨秀芳. 废弃 PET瓶降解制备花椒籽油水性醇酸树脂[J]. 涂料工业, 2019, 49(4): 34-40.
17	LEI R, MA Y M, YANG X F. Preparation of zanthoxylum bungeanum seed oil-based waterborne alkyd resin based on postconsumer PET bottles[J]. Paint & Coatings Industry, 2019, 49(4): 34-40.

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醇酸树脂微胶囊的制备及环氧涂层自修复性能

Self-healing performance of epoxy coating containing microencapsulated alkyd resin

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