Cr(Ⅵ)去除用功能化纤维素纳米材料的结构设计研究进展

doi:10.16085/j.issn.1000-6613.2022-1696

化工进展 ›› 2023, Vol. 42 ›› Issue (2): 585-594.DOI: 10.16085/j.issn.1000-6613.2022-1696

• 专栏：工业污泥/精馏釜残的热化学转化利用 • 上一篇下一篇

Cr(Ⅵ)去除用功能化纤维素纳米材料的结构设计研究进展

唐春霞¹^,²(), 李萌¹^,², 王玉玺¹^,², 宗永忠³, 付少海¹^,²

^1.江苏省纺织品数字喷墨印花工程技术研究中心（江南大学），江苏无锡 214122
^2.生态纺织教育部重点实验室（江南大学），江苏无锡 214122
^3.昆明南方水务有限公司，云南昆明 650217

收稿日期:2022-09-13 修回日期:2022-11-11 出版日期:2023-02-25 发布日期:2023-03-13
通讯作者: 唐春霞
作者简介:唐春霞（1990—），女，博士，副教授，研究方向为重金属离子吸附。E-mail：chunxia.tang@jiangnan.edu.cn。
基金资助:
国家重点研发计划(2018YFC1902100);中央高校基本科研计划(JUSRP122005)

Progress in structural design of functionalized cellulose nanomaterials for Cr(Ⅵ) removal

TANG Chunxia¹^,²(), LI Meng¹^,², WANG Yuxi¹^,², ZONG Yongzhong³, FU Shaohai¹^,²

^1.Jiangsu Engineering Research Center for Digital Textile Ink Jet Printing (Jiangnan University), Wuxi 214122, Jiangsu, China
^2.Key Laboratory of Eco-Textiles (Jiangnan University), Ministry of Education, Wuxi 214122, Jiangsu, China
^3.Kunming South Water Company Limited, Kunming 650217, Yunnan, China

Received:2022-09-13 Revised:2022-11-11 Online:2023-02-25 Published:2023-03-13
Contact: TANG Chunxia

摘要/Abstract

摘要：

以Cr(Ⅵ)为代表的重金属离子是一类常见的水体污染物，它具有微量剧毒、难以降解、迁移性强和易在生物体内累积等特点，可对生态系统和人体健康造成严重的危害。纤维素纳米材料（cellulose nanomaterials，CNM）是地球上储量最丰富的一种纤维素衍生物，具有环境友好、生物相容性高和原料来源丰富等优势，其作为绿色经济的重金属离子吸附材料对促进社会可持续性发展和水污染治理具有重要意义。然而纤维素纳米材料对Cr(Ⅵ)的吸附性能差，需对其进行化学改性和组装以提升其对Cr(Ⅵ)的去除效率。本综述系统地介绍和总结了Cr(Ⅵ)去除用CNM的化学改性策略及其几何结构设计的研究进展，并对目前研究中存在的问题进行总结，对未来的发展趋势进行展望。本综述对高效吸附剂的结构设计具有参考价值。

关键词: 纤维素纳米纤维, Cr(Ⅵ)去除, 结构设计

Abstract:

As a typical kind of heavy metal ions, Cr(Ⅵ) seriously threatens the eco-system and human health due to its high toxicity, non-degradability, high mobility and bio-accumulation characteristics. As a derivative of cellulose, cellulose nanomaterials (CNM) is the most abundant natural material on earth, which is eco-friendly, highly biocompatible and rich raw material sources. Thus, the use of CNMs as heavy metal ion adsorbents for water treatment is of great significance to promote the sustainability of the society. However, pristine CNM exhibits poor affinity towards Cr(‍Ⅵ), so it is desirable to perform chemical modification and macroscopic geometry structure design for CNM to improve its removal efficiency towards Cr species. This review systematically introduces and summarizes the recent advances on the functionalization and macroscopic structure design strategies of CNM, covers the problems existing in the current field and provides an insight for the future development of CNM-based adsorbents on Cr(Ⅵ) removal application. The review is valuable for the structural design of high-performance adsorbents.

Key words: cellulose nanomaterials (CNM), Cr(Ⅵ) removal, structural design

中图分类号:

X703.1

唐春霞, 李萌, 王玉玺, 宗永忠, 付少海. Cr(Ⅵ)去除用功能化纤维素纳米材料的结构设计研究进展[J]. 化工进展, 2023, 42(2): 585-594.

TANG Chunxia, LI Meng, WANG Yuxi, ZONG Yongzhong, FU Shaohai. Progress in structural design of functionalized cellulose nanomaterials for Cr(Ⅵ) removal[J]. Chemical Industry and Engineering Progress, 2023, 42(2): 585-594.

图/表 9

参考文献 47

1	ZHAO Rongrong, ZHOU Zuoming, ZHAO Xiaodan, et al. Enhanced Cr(Ⅵ) removal from simulated electroplating rinse wastewater by amino-functionalized vermiculite-supported nanoscale zero-valent iron[J]. Chemosphere, 2019, 218: 458-467.
2	WANG Ting, ZHANG Liyuan, LI Chaofang, et al. Synthesis of core-shell magnetic Fe₃O₄@poly(m-phenylenediamine) particles for chromium reduction and adsorption[J]. Environmental Science & Technology, 2015, 49(9): 5654-5662.
3	FRANCISCO Paul Clarence M, SATO Tsutomu, OTAKE Tsubasa, et al. Mechanisms of Se(Ⅳ) co-precipitation with ferrihydrite at acidic and alkaline conditions and its behavior during aging[J]. Environmental Science & Technology, 2018, 52(8): 4817-4826.
4	PAN Zezhen, ZHU Xiaoming, SATPATHY Anshuman, et al. Cr(‍Ⅵ) adsorption on engineered iron oxide nanoparticles: Exploring complexation processes and water chemistry[J]. Environmental Science & Technology, 2019, 53(20): 11913-11921.
5	STERN Callie M, JEGEDE Temitope O, HULSE Vanessa A, et al. Electrochemical reduction of Cr(‍Ⅵ) in water: Lessons learned from fundamental studies and applications[J]. Chemical Society Reviews, 2021, 50(3): 1642-1667.
6	RAJAPAKSHA Anushka Upamali, SELVASEMBIAN Rangabhashiyam, ASHIQ Ahamed, et al. A systematic review on adsorptive removal of hexavalent chromium from aqueous solutions: Recent advances[J]. Science of the Total Environment, 2022, 809: 152055.
7	JIN Wei, DU Hao, ZHENG Shili, et al. Electrochemical processes for the environmental remediation of toxic Cr(Ⅵ): A review[J]. Electrochimica Acta, 2016, 191: 1044-1055.
8	SYEDA Hina Iqbal, Pow-Seng YAP. A review on three-dimensional cellulose-based aerogels for the removal of heavy metals from water[J]. Science of the Total Environment, 2022, 807: 150606.
9	MOON Robert J, MARTINI Ashlie, NAIRN John, et al. Cellulose nanomaterials review: Structure, properties and nanocomposites[J]. Chemical Society Reviews, 2011, 40(7): 3941-3994.
10	NISHIMURA Hiroshi, KAMIYA Akihiro, NAGATA Takashi, et al. Direct evidence for α ether linkage between lignin and carbohydrates in wood cell walls[J]. Scientific Reports, 2018, 8: 6538.
11	李若男, 周丽莎, 陈舜胜, 等. 纤维素纳米纤维及其改性产物吸附重金属的研究进展[J]. 化工进展, 2022, 41(1): 310-319.
	LI Ruonan, ZHOU Lisha, CHEN Shunsheng, et al. Research progress on adsorption of heavy metals by cellulose nanofibers and their modified products[J]. Chemical Industry and Engineering Progress, 2022, 41(1): 310-319.
12	ZHAO Jiangqi, ZHANG Xiaofang, HE Xu, et al. A super biosorbent from dendrimer poly(amidoamine)-grafted cellulose nanofibril aerogels for effective removal of Cr(‍Ⅵ)[J]. Journal of Materials Chemistry A, 2015, 3(28): 14703-14711.
13	HASHEM Tawheed, IBRAHIM Ahmed H, Christof WÖLL, et al. Grafting zirconium-based metal-organic framework UiO-66-NH₂ nanoparticles on cellulose fibers for the removal of Cr(Ⅵ) ions and methyl orange from water[J]. ACS Applied Nano Materials, 2019, 2(9): 5804-5808.
14	Wei LYU, WU Jiamin, ZHANG Wenlong, et al. Easy separated 3D hierarchical coral-like magnetic polyaniline adsorbent with enhanced performance in adsorption and reduction of Cr(Ⅵ) and immobilization of Cr(Ⅲ)[J]. Chemical Engineering Journal, 2019, 363: 107-119.
15	KRETSCHMER Imme, SENN Alejandro M, Martin MEICHTRY J, et al. Photocatalytic reduction of Cr(Ⅵ) on hematite nanoparticles in the presence of oxalate and citrate[J]. Applied Catalysis B: Environmental, 2019, 242: 218-226.
16	YANG Shanye, LI Qian, CHEN Liang, et al. Synergistic removal and reduction of U(‍Ⅵ) and Cr(‍Ⅵ) by Fe₃S₄ micro-crystal[J]. Chemical Engineering Journal, 2020, 385: 123909.
17	LIU Chao, JIN Runa, OUYANG Xiaokun, et al. Adsorption behavior of carboxylated cellulose nanocrystal—Polyethyleneimine composite for removal of Cr(Ⅵ) ions[J]. Applied Surface Science, 2017, 408: 77-87.
18	LI Meng, TANG Chunxia, FU Shaohai, et al. Cellulose-based aerogel beads for efficient adsorption-reduction-sequestration of Cr(Ⅵ)[J]. International Journal of Biological Macromolecules, 2022, 216: 860-870.
19	XUE Fei, HE Hui, ZHU Hongxiang, et al. Structural design of a cellulose-based solid amine adsorbent for the complete removal and colorimetric detection of Cr(Ⅵ)[J]. Langmuir, 2019, 35(39): 12636-12646.
20	YANG Pengfei, SHU Yufang, ZHUANG Qixin, et al. Metal-organic frameworks bearing dense alkyl thiol for the efficient degradation and concomitant removal of toxic Cr(Ⅵ)[J]. Langmuir, 2019, 35(49): 16226-16233.
21	WANG Wenxuan, YU Feihan, BA Zhichen, et al. In-depth sulfhydryl-modified cellulose fibers for efficient and rapid adsorption of Cr(Ⅵ)[J]. Polymers, 2022, 14(7): 1482.
22	RONG Liduo, ZHU Zumei, WANG Bijia, et al. Facile fabrication of thiol-modified cellulose sponges for adsorption of Hg²⁺from aqueous solutions[J]. Cellulose, 2018, 25(5): 3025-3035.
23	KARA Hizkeal Tsade, ANSHEBO Sisay Tadesse, SABIR Fedlu Kedir. A novel modified cellulose nanomaterials (CNMs) for remediation of chromium (Ⅵ) ions from wastewater[J]. Materials Research Express, 2020, 7(11): 115008.
24	ZHANG Xiaofang, ZHAO Jiangqi, CHENG Long, et al. Acrylic acid grafted and acrylic acid/sodium humate grafted bamboo cellulose nanofibers for Cu²⁺ adsorption[J]. RSC Advances, 2014, 4(98): 55195-55201.
25	BARBOSA Rennan F S, SOUZA Alana G, MALTEZ Heloísa F, et al. Chromium removal from contaminated wastewaters using biodegradable membranes containing cellulose nanostructures[J]. Chemical Engineering Journal, 2020, 395: 125055.
26	BRANDES Ricardo, BROUILLETTE François, CHABOT Bruno. Phosphorylated cellulose/electrospun chitosan nanofibers media for removal of heavy metals from aqueous solutions[J]. Journal of Applied Polymer Science, 2021, 138(11): 50021.
27	ABOUZEID Ragab E, KHIARI Ramzi, Nahla EL-WAKIL, et al. Current state and new trends in the use of cellulose nanomaterials for wastewater treatment[J]. Biomacromolecules, 2019, 20(2): 573-597.
28	MA Liang, SHI Xuejuan, ZHANG Xiaoxiao, et al. Electrospun cellulose acetate-polycaprolactone/chitosan core-shell nanofibers for the removal of Cr(Ⅵ)[J]. Physica Status Solidi (a), 2019, 216(22): 1900379.
29	JIN Xin, WANG Hongjie, JIN Xu, et al. Preparation of keratin/PET nanofiber membrane and its high adsorption performance of Cr(Ⅵ)[J]. Science of the Total Environment, 2020, 710: 135546.
30	XU Dandan, YAN Shan, WENG Wei, et al. Cost effective nanofiber composite membranes for Cr(ⅵ) adsorption with high durability[J]. RSC Advances, 2016, 6(50): 44723-44731.
31	ZHANG Youwei, XU Ling, ZHAO Long, et al. Radiation synthesis and Cr(Ⅵ) removal of cellulose microsphere adsorbent[J]. Carbohydrate Polymers, 2012, 88(3): 931-938.
32	KIM Yunjin, PARK Jinseok, BANG Junsik, et al. Highly efficient Cr(Ⅵ) remediation by cationic functionalized nanocellulose beads[J]. Journal of Hazardous Materials, 2022, 426: 128078.
33	LUO Qiuyan, HUANG Xiaohui, LUO Yong, et al. Fluorescent chitosan-based hydrogel incorporating titanate and cellulose nanofibers modified with carbon dots for adsorption and detection of Cr(Ⅵ)[J]. Chemical Engineering Journal, 2021, 407: 127050.
34	KIM Yunjin, BANG Junsik, KIM Jungkyu, et al. Cationic surface-modified regenerated nanocellulose hydrogel for efficient Cr(Ⅵ) remediation[J]. Carbohydrate Polymers, 2022, 278: 118930.
35	CHEN Xueqi, SONG Zihui, YUAN Bingnan, et al. Fluorescent carbon dots crosslinked cellulose Nanofibril/Chitosan interpenetrating hydrogel system for sensitive detection and efficient adsorption of Cu (Ⅱ) and Cr (Ⅵ)[J]. Chemical Engineering Journal, 2022, 430: 133154.
36	PENG Junwen, YUAN Hanmeng, REN Tingting, et al. Fluorescent nanocellulose-based hydrogel incorporating titanate nanofibers for sorption and detection of Cr(Ⅵ)[J]. International Journal of Biological Macromolecules, 2022, 215: 625-634.
37	XUE Xiaolin, YUAN Wei, ZHENG Zhuo, et al. Iron-loaded carbon aerogels derived from bamboo cellulose fibers as efficient adsorbents for Cr(Ⅵ) removal[J]. Polymers, 2021, 13(24): 4338.
38	TAN Luon Nguyen, NGUYEN Nhung Cam Thi, TRINH Anh Mai Hoang, et al. Eco-friendly synthesis of durable aerogel composites from chitosan and pineapple leaf-based cellulose for Cr(Ⅵ) removal[J]. Separation and Purification Technology, 2023, 304: 122415.
39	ZHOU Hang, ZHU Hongxiang, SHI Xiaoyu, et al. Design of amphoteric bionic fibers by imitating spider silk for rapid and complete removal of low-level multiple heavy metal ions[J]. Chemical Engineering Journal, 2021, 412: 128670.
40	KHALID Aina Mardhia, HOSSAIN Md Sohrab, ISMAIL Norli, et al. Isolation and characterization of magnetic oil palm empty fruits bunch cellulose nanofiber composite as a bio-sorbent for Cu(Ⅱ) and Cr(Ⅵ) removal[J]. Polymers, 2020, 13(1): 112.
41	HAO Shuang, JIA Zhiqian, WEN Jianping, et al. Progress in adsorptive membranes for separation—A review[J]. Separation and Purification Technology, 2021, 255: 117772.
42	LU Wanli, DUAN Chao, ZHANG Yanling, et al. Cellulose-based electrospun nanofiber membrane with core-sheath structure and robust photocatalytic activity for simultaneous and efficient oil emulsions separation, dye degradation and Cr(‍Ⅵ) reduction[J]. Carbohydrate Polymers, 2021, 258: 117676.
43	霍丹, 张希鹏, 孙悦凯, 等. 纳米纤维素吸附材料的制备及在工业废水处理中的应用[J]. 中国造纸, 2021, 40(11): 90-97.
	HUO Dan, ZHANG Xipeng, SUN Yuekai, et al. Research progress on the preparation and application of nanocellulose adsorbent in industrial wastewater treatment[J]. China Pulp & Paper, 2021, 40(11): 90-97.
44	CHEN Shujun, LU Wangyang, HAN Jiale, et al. Robust three-dimensional g-C₃N₄@cellulose aerogel enhanced by cross-linked polyester fibers for simultaneous removal of hexavalent chromium and antibiotics[J]. Chemical Engineering Journal, 2019, 359: 119-129.
45	LIU Ju, HAO Dandan, SUN Huiwen, et al. Integration of MIL-101-NH₂ into cellulosic foams for efficient Cr(Ⅵ) reduction under visible light[J]. Industrial & Engineering Chemistry Research, 2021, 60(33): 12220-12227.
46	HE Xu, CHENG Long, WANG Yaru, et al. Aerogels from quaternary ammonium-functionalized cellulose nanofibers for rapid removal of Cr(Ⅵ) from water[J]. Carbohydrate Polymers, 2014, 111: 683-687.
47	WANG Qinyu, TIAN Yu, KONG Lingchao, et al. A novel 3D superelastic polyethyleneimine functionalized chitosan aerogels for selective removal of Cr(‍Ⅵ) from aqueous solution: Performance and mechanisms[J]. Chemical Engineering Journal, 2021, 425: 131722.

类型	吸附剂	pH	吸附能力/mg·g^-1	优缺点	参考文献
纤维	CA-PCL/CS	3	126	具有高比表面积，但其表面能高，易发生团聚，难以从水体中分离，造成二次污染	[28]
薄膜	K-PET-5	3	75.86	操作简单、节省空间和处理效率高；纯CNF薄膜的耐水性差且寿命短	[29]
薄膜	PANI/EVOH	2	93.09	操作简单、节省空间和处理效率高；纯CNF薄膜的耐水性差且寿命短	[30]
微球	AEM-Ⅱ	3.1	123.4	比表面积大、传质路径短	[31]
微球	P/CMCNF	2	1302.3	比表面积大、传质路径短	[32]
水凝胶	FCH-6	—	228.2	水凝胶价格低、亲水性、安全性、生物相容性和生物降解性等；结构稳定性较差、不易回收	[33]
	P/RC	2	578		[34]
	NCDs-CNF/CSgel	2	294.46		[35]
	FNH-5	2	648.4		[36]
气凝胶	Fe/CA	3	182	高比表面积、高吸附、多次使用、结构完整、高孔隙率和超低密度等；易吸水坍塌	[37]
	CGP	2	386.40		[18]
	i-PL/CSA	3	210.6		[38]
	PAMAM-g-CNF	2	377.36		[12]

类型	吸附剂	pH	吸附能力/mg·g^-1	优缺点	参考文献
纤维	CA-PCL/CS	3	126	具有高比表面积，但其表面能高，易发生团聚，难以从水体中分离，造成二次污染	[28]
薄膜	K-PET-5	3	75.86	操作简单、节省空间和处理效率高；纯CNF薄膜的耐水性差且寿命短	[29]
薄膜	PANI/EVOH	2	93.09	操作简单、节省空间和处理效率高；纯CNF薄膜的耐水性差且寿命短	[30]
微球	AEM-Ⅱ	3.1	123.4	比表面积大、传质路径短	[31]
微球	P/CMCNF	2	1302.3	比表面积大、传质路径短	[32]
水凝胶	FCH-6	—	228.2	水凝胶价格低、亲水性、安全性、生物相容性和生物降解性等；结构稳定性较差、不易回收	[33]
	P/RC	2	578		[34]
	NCDs-CNF/CSgel	2	294.46		[35]
	FNH-5	2	648.4		[36]
气凝胶	Fe/CA	3	182	高比表面积、高吸附、多次使用、结构完整、高孔隙率和超低密度等；易吸水坍塌	[37]
	CGP	2	386.40		[18]
	i-PL/CSA	3	210.6		[38]
	PAMAM-g-CNF	2	377.36		[12]

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Cr(Ⅵ)去除用功能化纤维素纳米材料的结构设计研究进展

Progress in structural design of functionalized cellulose nanomaterials for Cr(Ⅵ) removal

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