多孔g-C3N4基光催化材料的制备及应用研究进展

doi:10.16085/j.issn.1000-6613.2021-0288

化工进展 ›› 2022, Vol. 41 ›› Issue (1): 300-309.DOI: 10.16085/j.issn.1000-6613.2021-0288

多孔g-C₃N₄基光催化材料的制备及应用研究进展

王文霞¹^,²(), 刘小丰¹, 陈浠¹, 许艳虹¹, 蒙振邦¹, 郑俊霞¹, 安太成²()

^1.广东工业大学生物医药学院，广东广州 510006
^2.广东工业大学环境健康与污染控制研究院，广东省环境催化与污染控制重点实验室和粤港澳污染物暴露与健康联合实验室，广东广州 510006

收稿日期:2021-02-07 修回日期:2021-04-06 出版日期:2022-01-05 发布日期:2022-01-24
通讯作者: 安太成
作者简介:王文霞（1990—），女，博士，讲师，研究方向为环境光催化。E-mail：fewwxia@gdut.edu.cn。
基金资助:
广东省珠江本土人才创新团队项目(2017BT01Z032);广东省重点研发项目(2019B110206002);广东省基础与应用基础研究基金(2020A1515110718)

Research advances of synthesis and applications of porous g-C₃N₄-based photocatalyst

WANG Wenxia¹^,²(), LIU Xiaofeng¹, CHEN Xi¹, XU Yanhong¹, MENG Zhenbang¹, ZHENG Junxia¹, AN Taicheng²()

^1.School of Biomedical and Pharmaceutical Sciences, Guangdong University of Technology, Guangzhou 510006, Guangdong, China
^2.Institute of Environmental Health and Pollution Control, Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control and Guangdong-Hong Kong-Macao Joint Laboratory for Contaminants Exposure and Health, Guangdong University of Technology, Guangzhou 510006, Guangdong, China

Received:2021-02-07 Revised:2021-04-06 Online:2022-01-05 Published:2022-01-24
Contact: AN Taicheng

摘要/Abstract

摘要：

多孔g-C₃N₄基光催化材料由于具有较高的比表面积、丰富的反应活性位点和较短的电子传递路径等特点，能较好地解决块体g-C₃N₄基材料存在的比表面积小、光生载流子复合快及可见光利用效率低等问题，因而具有广阔的发展前景和应用潜力。本文主要从以下方面进行综述：多孔g-C₃N₄基光催化材料常用的制备方法，包括硬模板法、软模板法、水热合成法、热聚合法、超分子自组装法；多孔g-C₃N₄基材料在光催化领域的应用，包括光解水制氢、光催化降解有机污染物、光催化去除氮氧化物和光催化还原CO₂等；最后指出了当前影响多孔g-C₃N₄基光催化材料发展的关键问题，并对其在光催化领域的应用前景进行了展望。

关键词: 多孔材料, 石墨相氮化碳, 合成, 催化, 制氢, 降解有机污染物, CO₂还原

Abstract:

The porous g-C₃N₄-based photocatalysts have broad application prospects due to their unique properties such as large specific surface area, abundant surface reaction active sites and short electron transfer pathway, which can well overcome the disadvantages as compared with the bulk g-C₃N₄ including low specific surface area, fast recombination possibility of photogenerated electron-hole pairs and low utilization of visible light. In the review, the general synthetic strategies applied to prepare porous g-C₃N₄-based photocatalyst, such as hard template method, soft template method, hydrothermal methods, thermal polymerization and supramolecular self-assembly, are briefly introduced. Besides, the potential applications of porous g-C₃N₄-based photocatalyst in photocatalytic water splitting, photocatalytic degradation of organic pollutants, photocatalytic CO₂ reduction and photocatalytic NO_x abatement are discussed in detail. Finally, several comments to the challenges and the development trends of porous g-C₃N₄-based photocatalyst are also prospected.

Key words: porous materials, graphite phases-C₃N₄(g-C₃N₄), synthesis methods, catalysis, hydrogen production, degradation of organic pollutants, CO₂ reduction

中图分类号:

王文霞, 刘小丰, 陈浠, 许艳虹, 蒙振邦, 郑俊霞, 安太成. 多孔g-C₃N₄基光催化材料的制备及应用研究进展[J]. 化工进展, 2022, 41(1): 300-309.

WANG Wenxia, LIU Xiaofeng, CHEN Xi, XU Yanhong, MENG Zhenbang, ZHENG Junxia, AN Taicheng. Research advances of synthesis and applications of porous g-C₃N₄-based photocatalyst[J]. Chemical Industry and Engineering Progress, 2022, 41(1): 300-309.

图/表 8

参考文献 60

1	WANG Zheng, LI Can, DOMEN Kazunari. Recent developments in heterogeneous photocatalysts for solar-driven overall water splitting[J]. Chemical Society Reviews, 2019, 48(7): 2109-2125.
2	WANG Wanjun, LI Guiying, AN Taicheng, et al. Photocatalytic hydrogen evolution and bacterial inactivation utilizing sonochemical-synthesized g-C₃N₄/red phosphorus hybrid nanosheets as a wide-spectral-responsive photocatalyst: the role of type I band alignment[J]. Applied Catalysis B: Environmental, 2018, 238: 126-135.
3	杨冬, 周致远, 丁菲, 等. 特殊形貌g-C₃N₄ 基光催化材料的研究进展[J]. 化工进展, 2019，38(1)：495-504.
	YANG Dong, ZHOU Zhiyuan, DING Fei, et al. Research advances of g-C₃N₄-based photocatalytic materials with special morphologies[J]. Chemical Industry and Engineering Progress, 2019, 38(1): 495-504.
4	ZHANG Yuye, ZHOU Zhixin, SHEN Yanfei, et al. Reversible assembly of graphitic carbon nitride 3D network for highly selective dyes absorption and regeneration[J]. ACS Nano, 2016, 10(9): 9036-9043.
5	LI Wei, CHU Xiaoshan, WANG Fei, et al. Enhanced cocatalyst-support interaction and promoted electron transfer of 3D porous g-C₃N₄/GO-M (Au, Pd, Pt) composite catalysts for hydrogen evolution[J]. Applied Catalysis B: Environmental, 2021, 288: 120034.
6	王悦, 蒋权, 尚介坤, 等. 介孔氮化碳材料合成的研究进展[J]. 物理化学学报, 2016, 32(8): 1913-1928.
	WANG Yue, JIANG Quan, SHANG Jiekun, et al. Advances in the synthesis of mesoporous carbon nitride materials[J]. Acta Physico-Chimica Sinica, 2016, 32(8): 1913-1928.
7	WANG Xinchen, MAEDA Kazuhiko, CHEN Xiufang, et al. Polymer semiconductors for artificial photosynthesis: hydrogen evolution by mesoporous graphitic carbon nitride with visible light[J]. Journal of the American Chemical Society, 2009, 131(5): 1680-1681.
8	FUKASAWA Yuki, TAKANABE Kazuhiro, SHIMOJIMA Atsushi, et al. Synthesis of ordered porous graphitic-C₃N₄ and regularly arranged Ta₃N₅ nanoparticles by using self-assembled silica nanospheres as a primary template[J]. Chemistry: An Asian Journal, 2011, 6(1): 103-109.
9	YANG Zhenxing, CHU Dongliang, JIA Guangri, et al. Significantly narrowed bandgap and enhanced charge separation in porous, nitrogen-vacancy red g-C₃N₄ for visible light photocatalytic H₂ production[J]. Applied Surface Science, 2020, 504: 144407.
10	LIANG Qinghua, LI Zhi, YU Xiaoliang, et al. Macroscopic 3D porous graphitic carbon nitride monolith for enhanced photocatalytic hydrogen evolution[J]. Advanced Materials, 2015, 27(31): 4634-4639.
11	CHEN Daimei, YANG Jinjin, DING Hao. Synthesis of nanoporous carbon nitride using calcium carbonate as templates with enhanced visible-light photocatalytic activity[J]. Applied Surface Science, 2017, 391: 384-391.
12	TANG Qingquan, NIU Ran, GONG Jiang. Salt-templated synthesis of 3D porous foam-like C₃N₄towards high-performance photodegradation of tetracyclines[J]. New Journal of Chemistry, 2020, 44(40): 17405-17412.
13	ZHENG Yun, LIN Lihua, WANG Bo, et al. Graphitic carbon nitride polymers toward sustainable photoredox catalysis[J]. Angewandte Chemie International Edition, 2015, 54(44): 12868-12884.
14	WANG Yong, WANG Xinchen, ANTONIETTI Markus, et al. Facile one‐pot synthesis of nanoporous carbon nitride solids by using soft templates[J]. ChemSusChem: Chemistry & Sustainability Energy & Materials, 2010, 3(4): 435-439.
15	YAN Qingyun, ZHAO Chaocheng, ZHANG Liang, et al. Facile two-step synthesis of porous carbon nitride with enhanced photocatalytic activity using a soft template[J]. ACS Sustainable Chemistry & Engineering, 2019, 7(4): 3866-3874.
16	MARYAM Peer, LUSARDI Marcella, JENSEN Klavs F. Facile soft-templated synthesis of high-surface area and highly porous carbon nitrides[J]. Chemistry of Materials, 2017, 29(4): 1496-1506.
17	ZHANG Juan, LI Jinyi, WANG Wenpeng, et al. Microemulsion assisted assembly of 3D porous S/graphene@g-C₃N₄ hybrid sponge as free-standing cathodes for high energy density Li-S batteries[J]. Advanced Energy Materials, 2018, 8(14): 1702839.
18	HUANG Hongwei, XIAO Ke, TIAN Na, et al. Template-free precursor-surface-etching route to porous, thin g-C₃N₄ nanosheets for enhancing photocatalytic reduction and oxidation activity[J]. Journal of Materials Chemistry A, 2017, 5(33): 17452-17463.
19	MO Zhao, ZHU Xingwang, JING Zhifeng, et al. Porous nitrogen-rich g-C₃N₄ nanotubes for efficient photocatalytic CO₂ reduction[J]. Applied Catalysis B: Environmental, 2019, 256: 117854.
20	WU Mao, ZHANG Jin, HE Beibei, et al. In-situ construction of coral-like porous P-doped g-C₃N₄ tubes with hybrid 1D/2D architecture and high efficient photocatalytic hydrogen evolution[J]. Applied Catalysis B: Environmental, 2019, 241: 159-166.
21	ZHENG Yanmei, LIU Yuanyuan, GUO Xinli, et al. Sulfur-doped g-C₃N₄/rGO porous nanosheets for highly efficient photocatalytic degradation of refractory contaminants[J]. Journal of Materials Science & Technology, 2020, 41: 117-126.
22	LI Wei, WANG Xiao, LI Min, et al. Construction of Z-scheme and p-n heterostructure: three-dimensional porous g-C₃N₄/graphene oxide-Ag/AgBr composite for high-efficient hydrogen evolution[J]. Applied Catalysis B: Environmental, 2020, 268: 118384.
23	LI Xibao, XIONG Jie, GAO Xiaoming, et al. Recent advances in 3D g-C₃N₄ composite photocatalysts for photocatalytic water splitting, degradation of pollutants and CO₂ reduction[J]. Journal of Alloys and Compounds, 2019, 802: 196-209.
24	CHEN Yanglin, QU Ye, ZHOU Xin, et al. Phenyl-bridged graphitic carbon nitride with a porous and hollow sphere structure to enhance dissociation of photogenerated charge carriers and visible-light-driven H₂ generation[J]. ACS Applied Materials & Interfaces, 2020, 12(37): 41527-41537.
25	LI Yongting, ZHANG Xiaoli, PENG Zhikun, et al. Hierarchical porous g-C₃N₄ coupled ultrafine RuNi alloys as extremely active catalysts for the hydrolytic dehydrogenation of ammonia borane[J]. ACS Sustainable Chemistry & Engineering, 2020, 8(22): 8458-8468.
26	SHALOM Menny, INAL Sahika, FETTKENHAUER Christian, et al. Improving carbon nitride photocatalysis by supramolecular preorganization of monomers[J]. Journal of the American Chemical Society, 2013, 135(19): 7118-7121.
27	CHEN Xianjie, SHI Run, CHEN Qian, et al. Three-dimensional porous g-C₃N₄ for highly efficient photocatalytic overall water splitting[J]. Nano Energy, 2019, 59: 644-650.
28	JORDAN Thomas, FECHLER Nina, XU Jingsan, et al. “Caffeine doping” of carbon/nitrogen-based organic catalysts: caffeine as a supramolecular edge modifier for the synthesis of photoactive carbon nitride tubes[J]. ChemCatChem, 2015, 7(18): 2826-2830.
29	WANG Wanjun, AN Taicheng, LI Guiying, et al. Earth-abundant Ni₂P/g-C₃N₄ lamellar nanohydrids for enhanced photocatalytic hydrogen evolution and bacterial inactivation under visible light irradiation[J]. Applied Catalysis B: Environmental, 2017, 217: 570-580.
30	WANG Xinchen, MAEDA Kazuhiko, THOMAS Arne, et al. A metal-free polymeric photocatalyst for hydrogen production from water under visible light[J]. Nature Materials, 2009, 8(1): 76-80.
31	CHE Huinan, LIU Chunbo, CHE Guangbo, et al. Facile construction of porous intramolecular g-C₃N₄-based donor-acceptor conjugated copolymers as highly efficient photocatalysts for superior H₂ evolution[J]. Nano Energy, 2020, 67: 104273.
32	WANG Yong, DU Peipei, PAN Hongzhe, et al. Increasing solar absorption of atomically thin 2D carbon nitride sheets for enhanced visible-light photocatalysis[J]. Advanced Materials, 2019, 31(40): 1807540.
33	HUANG Yanbin, LIU Jun, ZHAO Chao, et al. Facile synthesis of defect-modified thin-layered and porous g-C₃N₄ with synergetic improvement for photocatalytic H₂ production[J]. ACS Applied Materials & Interfaces, 2020, 12(47): 52603-52614.
34	JIANG Yabin, SUN Zongzhao, TANG Chao, et al. Enhancement of photocatalytic hydrogen evolution activity of porous oxygen doped g-C₃N₄ with nitrogen defects induced by changing electron transition[J]. Applied Catalysis B: Environmental, 2019, 240: 30-38.
35	ZENG Deqian, WU Wanjie, Wee Jun ONG, et al. Toward noble-metal-free visible-light-driven photocatalytic hydrogen evolution: monodisperse sub-15nm Ni₂P nanoparticles anchored on porous g-C₃N₄ nanosheets to engineer 0D-2D heterojunction interfaces[J]. Applied Catalysis B: Environmental, 2018, 221: 47-55.
36	AZIMI Elham Boorboor, BADIEI Alireza, SADR Moayad Hossaini, et al. A template-free method to synthesize porous g-C₃N₄ with efficient visible light photodegradation of organic pollutants in water[J]. Advanced Powder Technology, 2018, 29(11): 2785-2791.
37	XU Jing, WANG Zhouping, ZHU Yongfa. Enhanced visible-light-driven photocatalytic disinfection performance and organic pollutant degradation activity of porous g-C₃N₄ nanosheets[J]. ACS Applied Materials & Interfaces, 2017, 9(33): 27727-27735.
38	LI Guiying, NIE Xin, GAO Yanpeng, et al. Can environmental pharmaceuticals be photocatalytically degraded and completely mineralized in water using g-C₃N₄/TiO₂ under visible light irradiation? —Implications of persistent toxic intermediates[J]. Applied Catalysis B: Environmental, 2016, 180: 726-732.
39	LI Guiying, NIE Xin, GAO Yanpeng, et al. Enhanced visible-light-driven photocatalytic inactivation of Escherichia coli using g-C₃N₄/TiO₂ hybrid photocatalyst synthesized using a hydrothermal-calcination approach[J]. Water Research, 2015, 86: 17-24.
40	ZHANG Sai, LIU Yang, GU Pengcheng, et al. Enhanced photodegradation of toxic organic pollutants using dual-oxygen-doped porous g-C₃N₄: mechanism exploration from both experimental and DFT studies[J]. Applied Catalysis B: Environmental, 2019, 248: 1-10.
41	JIANG Jingjing, WANG Xingyue, ZHANG Chongjun, et al. Porous 0D/3D NiCo₂O₄/g-C₃N₄ accelerate emerging pollutant degradation in PMS/Vis system: degradation mechanism, pathway and toxicity assessment[J]. Chemical Engineering Journal, 2020, 397: 125356.
42	HE Huijuan, HUANG Langhuan, ZHONG Zijun, et al. Constructing three-dimensional porous graphene-carbon quantum dots/g-C₃N₄ nanosheet aerogel metal-free photocatalyst with enhanced photocatalytic activity[J]. Applied Surface Science, 2018, 441: 285-294.
43	ZHANG Jinfeng, Jiali LYU, DAI Kai, et al. Facile and green synthesis of novel porous g-C₃N₄/Ag₃PO₄ composite with enhanced visible light photocatalysis[J]. Ceramics International, 2017, 43(1): 1522-1529.
44	ZHANG Shouwei, LI Jiaxing, WANG Xiangke, et al. In situ ion exchange synthesis of strongly coupled Ag@AgCl/g-C₃N₄ porous nanosheets as plasmonic photocatalyst for highly efficient visible-light photocatalysis[J]. ACS Applied Materials & Interfaces, 2014, 6(24): 22116-22125.
45	ZHOU Yaju, LI Jinze, LIU Chongyang, et al. Construction of 3D porous g-C₃N₄/AgBr/rGO composite for excellent visible light photocatalytic activity[J]. Applied Surface Science, 2018, 458: 586-596.
46	GUO Feng, LI Mingyang, REN Hongji, et al. Facile bottom-up preparation of Cl-doped porous g-C₃N₄ nanosheets for enhanced photocatalytic degradation of tetracycline under visible light[J]. Separation and Purification Technology, 2019, 228: 115770.
47	YANG Yang, ZHANG Chen, HUANG Danlian, et al. Boron nitride quantum dots decorated ultrathin porous g-C₃N₄: intensified exciton dissociation and charge transfer for promoting visible-light-driven molecular oxygen activation[J]. Applied Catalysis B: Environmental, 2019, 245: 87-99.
48	SHANG Yanyang, CHEN Xi, LIU Wenwen, et al. Photocorrosion inhibition and high-efficiency photoactivity of porous g-C₃N₄/Ag₂CrO₄ composites by simple microemulsion-assisted co-precipitation method[J]. Applied Catalysis B: Environmental, 2017, 204: 78-88.
49	NGUYEN Van Huy, NGUYEN Ba Son, HUANG Chaowei, et al. Photocatalytic NO_x abatement: recent advances and emerging trends in the development of photocatalysts[J]. Journal of Cleaner Production, 2020, 270: 121912.
50	WU Hongxin, CHEN Dongyun, LI Najun, et al. Hollow porous carbon nitride immobilized on carbonized nanofibers for highly efficient visible light photocatalytic removal of NO[J]. Nanoscale, 2016, 8(23): 12066-12072.
51	HU Jundie, JI Yujin, MO Zhao, et al. Engineering black phosphorus to porous g-C₃N₄-metal-organic framework membrane: a platform for highly boosting photocatalytic performance[J]. Journal of Materials Chemistry A, 2019, 7(9): 4408-4414.
52	ZHANG Wendong, ZHAO Zaiwang, DONG Fan, et al. Solvent-assisted synthesis of porous g-C₃N₄ with efficient visible-light photocatalytic performance for NO removal[J]. Chinese Journal of Catalysis, 2017, 38(2): 372-378.
53	WANG Zhenyu, HUANG Yu, CHEN Meijuan, et al. Roles of N-vacancies over porous g-C₃N₄ microtubes during photocatalytic NO_x removal[J]. ACS Applied Materials & Interfaces, 2019, 11(11): 10651-10662.
54	FU Junwei, ZHU Bicheng, JIANG Chuanjia, et al. Hierarchical porous O-doped g-C₃N₄ with enhanced photocatalytic CO₂ reduction activity[J]. Small, 2017, 13(15): 1603938.
55	WANG Yangang, XIA Qineng, BAI Xia, et al. Carbothermal activation synthesis of 3D porous g-C₃N₄/carbon nanosheets composite with superior performance for CO₂ photoreduction[J]. Applied Catalysis B: Environmental, 2018, 239: 196-203.
56	SUN Zhimin, FANG Wei, ZHAO Lei, et al. 3D porous Cu-NPs/g-C₃N₄ foam with excellent CO₂ adsorption and Schottky junction effect for photocatalytic CO₂ reduction[J]. Applied Surface Science, 2020, 504: 144347.
57	Man OU, TU Wenguang, YIN Shengming, et al. Amino-assisted anchoring of CsPbBr₃ perovskite quantum dots on porous g-C₃N₄ for enhanced photocatalytic CO₂ reduction[J]. Angewandte Chemie International Edition, 2018, 57(41): 13570-13574.
58	HUO Yao, ZHANG Jinfeng, DAI Kai, et al. All-solid-state artificial Z-scheme porous g-C₃N₄/Sn₂S₃-DETA heterostructure photocatalyst with enhanced performance in photocatalytic CO₂ reduction[J]. Applied Catalysis B: Environmental, 2019, 241: 528-538.
59	WANG Yanan, GUO Lina, ZENG Yiqing, et al. Amino-assisted NH₂-UiO-66 anchored on porous g-C₃N₄ for enhanced visible-light-driven CO₂ reduction[J]. ACS Applied Materials & Interfaces, 2019, 11(34): 30673-30681.
60	LI Pengyan, LIU Li, AN Weijia, et al. Ultrathin porous g-C₃N₄ nanosheets modified with AuCu alloy nanoparticles and C-C coupling photothermal catalytic reduction of CO₂ to ethanol[J]. Applied Catalysis B: Environmental, 2020, 266: 118618.

多孔催化剂	催化剂质量/mg	反应溶剂	光源（>420nm）	产氢速率/μmol?g^-1?h^-1	参考文献
P掺杂g-C₃N₄	50	TEOA（体积分数为10%）	300W 氙灯	2020	［20］
Ph-CN-MCA	20	TEOA/H₂PtCl₆?H₂O	300W 氙灯	4455	［24］
3D g-C₃N₄	50	H₂O	300W 氙灯	101.4	［27］
g-C₃N₄-MF_x	50	TEOA（体积分数为20%）	300W 氙灯	3612.6	［31］
O掺杂g-C₃N₄	50	TEOA/H₂PtCl₆?H₂O	300W 氙灯	396	［34］
g-C₃N₄/Ni₂P	50	TEOA	300W 氙灯	474.7	［35］

多孔催化剂	催化剂质量/mg	反应溶剂	光源（>420nm）	产氢速率/μmol?g^-1?h^-1	参考文献
P掺杂g-C₃N₄	50	TEOA（体积分数为10%）	300W 氙灯	2020	［20］
Ph-CN-MCA	20	TEOA/H₂PtCl₆?H₂O	300W 氙灯	4455	［24］
3D g-C₃N₄	50	H₂O	300W 氙灯	101.4	［27］
g-C₃N₄-MF_x	50	TEOA（体积分数为20%）	300W 氙灯	3612.6	［31］
O掺杂g-C₃N₄	50	TEOA/H₂PtCl₆?H₂O	300W 氙灯	396	［34］
g-C₃N₄/Ni₂P	50	TEOA	300W 氙灯	474.7	［35］

多孔催化剂	催化剂质量/mg	有机污染物	光源	降解率	参考文献
g-C₃N₄	40	RhB（5mg/L）	300W 卤钨灯	100%，60min	［36］
g-C₃N₄纳米片	10	MB（1.2×10^-5mol/L）	300W 氙灯	100%，300min	［37］
双氧掺杂g-C₃N₄	50	BA（20mg/L）	300W 氙灯	99%，50min	［40］
石墨烯-碳量子点/g-C₃N₄	30	MO（30mg/L）	300W 氙灯	91.1%，240min	［42］
g-C₃N₄/Ag₃PO₄	50	MB（10mg/L）	300W 氙灯	96%	［43］
Ag@AgCl/g?C₃N₄	25	RhB（10mg/L）	300W 氙灯	100%，30min	［44］
g-C₃N₄/AgBr/rGO	50	TC（20mg/L）	250W 氙灯	79.8%，90min	［45］
Cl掺杂g-C₃N₄	50	TC（20mg/L）	300W 氙灯	92%，120min	［46］
氮化硼量子点/g-C₃N₄	50	OTC-HCl（10mg/L）	300W 氙灯	82%，60min	［47］
g-C₃N₄/Ag₂CrO₄	10	RhB（10mg/L）	300W 氙灯	99.2%，90min	［48］

多孔催化剂	催化剂质量/mg	有机污染物	光源	降解率	参考文献
g-C₃N₄	40	RhB（5mg/L）	300W 卤钨灯	100%，60min	［36］
g-C₃N₄纳米片	10	MB（1.2×10^-5mol/L）	300W 氙灯	100%，300min	［37］
双氧掺杂g-C₃N₄	50	BA（20mg/L）	300W 氙灯	99%，50min	［40］
石墨烯-碳量子点/g-C₃N₄	30	MO（30mg/L）	300W 氙灯	91.1%，240min	［42］
g-C₃N₄/Ag₃PO₄	50	MB（10mg/L）	300W 氙灯	96%	［43］
Ag@AgCl/g?C₃N₄	25	RhB（10mg/L）	300W 氙灯	100%，30min	［44］
g-C₃N₄/AgBr/rGO	50	TC（20mg/L）	250W 氙灯	79.8%，90min	［45］
Cl掺杂g-C₃N₄	50	TC（20mg/L）	300W 氙灯	92%，120min	［46］
氮化硼量子点/g-C₃N₄	50	OTC-HCl（10mg/L）	300W 氙灯	82%，60min	［47］
g-C₃N₄/Ag₂CrO₄	10	RhB（10mg/L）	300W 氙灯	99.2%，90min	［48］

多孔催化剂	催化剂质量/mg	反应溶剂	光源（>420nm）	产物产生速率/μmol?g^-1?h^-1	参考文献
富氮g-C₃N₄	10	H₂O/TEOA/CoCl₂/MeCN	300W 氙灯	103.6	［19］
O掺杂g-C₃N₄	50	H₂O	350W 氙灯	0.88	［54］
3D g-C₃N₄/C	100	H₂O	500W 氙灯	112	［55］
Cu-NPs/g-C₃N₄	50	H₂O	300W 氙灯	10.25	［56］
CsPbBr₃ QDs/g-C₃N₄	8	乙腈/H₂O	300W 氙灯	148.9	［57］
g-C₃N₄/Sn₂S₃-DETA	100	H₂O	300W 氙灯	4.84	［58］
NH₂-UiO-66/g-C₃N₄	10	H₂O/TEOA	300W 氙灯	31.7	［59］

多孔g-C₃N₄基光催化材料的制备及应用研究进展

Research advances of synthesis and applications of porous g-C₃N₄-based photocatalyst

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