光催化分解水制氢中硫化物空心结构的研究进展

doi:10.16085/j.issn.1000-6613.2021-0315

摘要/Abstract

摘要：

利用太阳能进行的分解水制氢技术，可以促进太阳能的有效利用和清洁能源氢能的研发。在光催化制氢中，半导体光催化材料的性能是光催化反应性能提升的核心要素，制备优异、高效的光催化剂是提升光催化反应活性的关键步骤。本文从材料形貌和制备角度出发，选取金属硫化物为光催化中的主体半导体，对国内外金属硫化物空心结构的研究、应用和进展进行了回顾，分析了空心结构对增大材料比表面积、增强太阳光吸收、加速载流子分离以及提升反应活性的重要性，提出了空心结构在光催化发展中的优势，对空心结构的发展提出了展望，为这些新型材料的未来研发提供参考，从而能尽快提高光催化反应的太阳光利用率和氢气产量，有助于进一步实现光催化技术的工业化应用。

关键词: 太阳能, 制氢, 光催化, 催化剂, 硫化物, 空心结构

Abstract:

The research of photocatalytic water splitting for hydrogen (H₂) generation has been devoted a lot to the efficient utilization of solar energy and the development of hydrogen energy. The design of photocatalysts in photocatalytic hydrogen production is the key step of photocatalytic reaction. The preparation of outstanding and highly efficient photocatalyst is a vital point to improve the photocatalytic performance. In this review, the study of metal sulfides with hollow structures were comprehensively reviewed, including the preparation, application and further progress of the hollow materials. Further, the importance of hollow structure to increase surface area, enhance light absorption, accelerate charge separation and enhance reaction performance was analyzed. Herein, we propose the advantages and future development of hollow-structure in the development of photocatalysis, and provide a reference for the future design of novel photocatalysts, aiming to improve the utilization efficiency of sunlight and accelerate H₂ evolution for the industrial applications of photocatalytic H₂ generation.

Key words: solar energy, hydrogen production, photocatalysis, catalyst, sulfides, hollow-structure

中图分类号:

朱乔虹, 邢明阳, 张金龙. 光催化分解水制氢中硫化物空心结构的研究进展[J]. 化工进展, 2021, 40(9): 4774-4781.

ZHU Qiaohong, XING Mingyang, ZHANG Jinlong. Progress of hollow-structured-based sulfides in photocatalytic water splitting for hydrogen production[J]. Chemical Industry and Engineering Progress, 2021, 40(9): 4774-4781.

图/表 4

图1 具有空心结构硫化物光照分解水制氢示意图

图2 MnOx@CdS和MnOx@CdS/CoP的形貌及光催化机理[48]

图3 CdS/Co9S8的形貌及光解水产氢机制[37]

图4 Co9S8@ZnIn2S4空心结构及ZnIn2S4纳米片的形貌及光解水产氢机制[50](a), (b), (c) Co9S8@ZnIn2S4空心结构的FESEM图；(d), (e) Co9S8@ZnIn2S4空心结构的TEM图；(f) ZnIn2S4纳米片的HRTEM图；(g) Co9S8@ZnIn2S4用于光催化析氢机理示意图

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