耐高温聚胺类页岩抑制剂的研究现状

doi:10.16085/j.issn.1000-6613.2019-0886

摘要/Abstract

摘要：

聚胺类抑制剂是一种分子链上含有胺基的钻井液添加剂，与无机盐、单分子铵盐等页岩抑制剂相比，其对页岩地层的强抑制性受到大量学者的关注。但在高温下聚胺分子的分解会影响其抑制效果，而作业井深增加，开发难度增大往往使温度成为限制抑制剂应用的决定因素，因此目前研发耐高温强抑制性的页岩抑制剂对钻井作业来说具有重要意义。本文将具有耐高温性能的聚胺类页岩抑制剂按聚合物分子链的形态分为链状聚胺类、超支化聚胺类、特殊功能性基团类，评述了这三类耐高温页岩抑制剂的抑制性、耐温性、生物毒性等性质和应用现状，对聚胺类页岩抑制剂今后在提升耐温性、抑制性等方面的研究提出了建议，以期为相关研究提供参考。

关键词: 耐高温, 页岩抑制剂, 有机胺, 钻井泥浆材料

Abstract:

Polyamine inhibitors are drilling fluid additives containing amine groups in the molecular chain. Compared with shale inhibitors such as inorganic salts and monomolecular ammonium salts, their strong inhibition to shale formations has attracted much attention. However, the decomposition of polyamine molecules at high temperatures affects the inhibitory effect, while the depth of the working well increases, and the difficulty of development tends to make temperature a decisive factor in limiting the application of inhibitors. Therefore, the development of high temperature and high inhibition shale inhibitors is of great significance for drilling operations. The authors classify polyamine shale inhibitors with high temperature resistance into chain polyamines, hyper branched polyamines, and special functional groups according to the molecular chain form of the polymer. The properties and application status of these three types of high temperature shale inhibitors were reviewed. The future research of polyamine shale inhibition in improving the temperature resistance and inhibition was proposed to provide reference for related research.

Key words: high temperature resistance, shale inhibitor, organic amine, drilling mud material

中图分类号:

TQ0621.1

潘一,廖松泽,杨双春,马迪,丛禾. 耐高温聚胺类页岩抑制剂的研究现状[J]. 化工进展, 2020, 39(2): 686-695.

Yi PAN,Songze LIAO,Shuangchun YANG,Dinar NIGMATULLIN,Di MA,He CONG. Research on high temperature resistant polyamine shale inhibitors[J]. Chemical Industry and Engineering Progress, 2020, 39(2): 686-695.

图/表 16

参考文献 46

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低温油藏/℃	中温油藏/℃	高温油藏/℃
低温油藏/℃	中温油藏/℃	低高温	中高温	高高温	特高温
＜70	70～80	80～90	90～120	120～150	150～180

低温油藏/℃	中温油藏/℃	高温油藏/℃
低温油藏/℃	中温油藏/℃	低高温	中高温	高高温	特高温
＜70	70～80	80～90	90～120	120～150	150～180

名称	耐温性/℃	滚动回收率/%	生物毒性/mg·L^-1	与钻井液配伍性	不足/继续研究的性质
JY-2	＜180	70	EC₅₀＞12000	与硅基阳离子淡水、盐水钻井液体系配伍性良好	生产过程繁琐，需高温高压（220~240℃、2.6~3.2MPa）
RZPA	＜210	80	EC₅₀=54000	与复合粒子聚合物钻井液体系配伍性良好	研究在较低pH地层的适用性
JAI	＜200	64.2	—	与甲酸盐、KCl钻井液体系配伍性良好	继续研究其抑制水化分散的能力
PF-UHIB	＜150	—	—	与海水基聚合物钻井液配伍性良好	—
SDJA-1	＜200	59.7	EC₅₀=33000	与海水基聚合物钻井液配伍性良好	对产品的成本进行评价
ATROL	＜120	98.8	LC₅₀＞32000（凡纳滨虾仔） LC₅₀＞64000（裸项栉虾虎鱼仔）	与PEM聚合物、PEC有机正电胶钻井液体系配伍性良好	未对泥页岩强度的评价

名称	耐温性/℃	滚动回收率/%	生物毒性/mg·L^-1	与钻井液配伍性	不足/继续研究的性质
JY-2	＜180	70	EC₅₀＞12000	与硅基阳离子淡水、盐水钻井液体系配伍性良好	生产过程繁琐，需高温高压（220~240℃、2.6~3.2MPa）
RZPA	＜210	80	EC₅₀=54000	与复合粒子聚合物钻井液体系配伍性良好	研究在较低pH地层的适用性
JAI	＜200	64.2	—	与甲酸盐、KCl钻井液体系配伍性良好	继续研究其抑制水化分散的能力
PF-UHIB	＜150	—	—	与海水基聚合物钻井液配伍性良好	—
SDJA-1	＜200	59.7	EC₅₀=33000	与海水基聚合物钻井液配伍性良好	对产品的成本进行评价
ATROL	＜120	98.8	LC₅₀＞32000（凡纳滨虾仔） LC₅₀＞64000（裸项栉虾虎鱼仔）	与PEM聚合物、PEC有机正电胶钻井液体系配伍性良好	未对泥页岩强度的评价

名称	耐温性/℃	滚动回收率/%	生物毒性/mg·L^-1	与钻井液配伍性	不足/继续研究的性质
HP-NH₂	＜120	72.69	—	与钾钙基聚磺钻井液体系配伍性良好	提高抑制水化膨胀的性能，原料具有毒性，合成复杂
PAMAM（G0）	＜200	73.48	—	与钾基聚合物钻井液体系配伍性良好	提升抑制泥页岩水化分散能力
PAMAM（G5）	＜200	85.45	—	与钾基聚合物钻井液体系配伍性良好	加强对岩屑硬度的提升，抑制泥页岩水化膨胀能力不强
HBP-NH₂	＜200	60.79	—	—	抑制水化分散的能力需要提高，而且分子支化结构不完善且难以控制
HBO-NH₂	＜180	76.85	—	—	继续研究其环保性与钻井液配伍性