耐高温丙烯酸酯类压敏胶的研究进展

doi:10.16085/j.issn.1000-6613.2018-1847

摘要/Abstract

摘要：

丙烯酸酯类压敏胶（APSA）具有粘接性能优异、耐老化性能好、成本低、性能稳定、合成工艺简单等优点，由于其优异的性能被广泛应用于自黏带、标签、医药、家庭护理、汽车零部件等领域。但目前APSA应用领域仍较窄，大多数产品耐热性较差，不能在高温条件下使用。因此，开发耐高温性能的压敏胶（HTRAPSA）具有重要意义。文章综述了近年来国内外对HTRAPSA的研究进展，重点阐述了提高溶剂型和乳液型APSA耐高温性的相关研究工作。主要改性方法包括引入交联剂改性、引入特殊的改性单体、引入耐高温性物质改性和改进加料方式、聚合工艺、共混改性等方法来提高APSA的耐高温性能。同时，也指出了这些改性方法存在的问题与不足，以及所制备出的HTRAPSA存在的问题，并对今后相关研究的发展进行了展望。

关键词: 耐高温, 压敏胶, 丙烯酸酯, 改性

Abstract:

Acrylic pressure sensitive adhesives (APSA) have many advantages, such as excellent adhesion strength, good aging resistance, well stability, low-cost, and easy preparation. They are used in a broad range of fields, including self-adhesive tape, labels, pharmaceuticals, homecare and auto parts. However, the poor heat resistance of the APSA has always limited their further applications at higher temperatures. Therefore, it is of great significance to research the APSA with high temperature resistance (HTRAPSA). In this work, recent advances in improving both solvent-based and waterborne HTRAPSA were reviewed, and several major modification methods for HTRAPSA including crosslinking, introducing modified monomers and heat-resistant materials, improving feed-type and polymerization process, blending were stated, as well as the shortcomings and the existing problems of those modification methods for HTRAPSA were discussed. Finally, the future development of HTRAPSA was prospected.

Key words: high temperature resistance, pressure sensitive adhesive, acrylate, modification

中图分类号:

TQ436.3

鲁道欢, 王斌, 黄月文. 耐高温丙烯酸酯类压敏胶的研究进展[J]. 化工进展, 2019, 38(05): 2269-2275.

Daohuan LU, Bin WANG, Yuewen HUANG. Progress on acrylic pressure sensitive adhesive with high temperature resistance[J]. Chemical Industry and Engineering Progress, 2019, 38(05): 2269-2275.

图/表 2

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