黄铁矿浮选的抑制与解抑活化研究进展

doi:10.16085/j.issn.1000-6613.2018-1351

摘要/Abstract

摘要：

黄铁矿浮选问题是金属矿、煤矿以及某些非金属矿等开发利用过程中通常需要面临的问题，其浮选的抑制、解抑活化以及影响其浮选行为的一些因素一直是矿物加工领域的研究热点。本文分析了矿物学因素、难免离子和伽伐尼电偶作用对黄铁矿的浮选行为的影响，着重从浮选药剂与矿物的作用机理方面综述了黄铁矿的抑制与解抑活化；黄铁矿与不同种类的抑制剂作用后通过生成亲水膜、阻止黄药氧化、占据黄铁矿表面捕收剂能作用的活性位点、生成络合物以及多糖、蛋白质等微生物细菌胞外分泌物的吸附等作用对黄铁矿产生抑制作用；高碱环境下常用酸和盐类活化剂对受抑黄铁矿表面的亲水膜溶解进行活化，实现黄铁矿的回收利用。分析认为目前对矿物内部和矿浆的复杂环境研究仍不到位，应通过现代分析测试手段和计算机技术加强研究；黄铁矿不仅仅作为一种矿物资源，黄铁矿等环境矿物在环保领域的研究应用对缓解经济发展与环境保护的矛盾起着至关重要的作用。

关键词: 黄铁矿, 浮选行为, 浮选药剂, 作用机理, 抑制, 解抑活化

Abstract:

The flotation of pyrite is a common problem in the development and utilization of metal, coal and non-metallic minerals. Depression, derepression and some influence factors of pyrite flotation have been the research focus in the field of mineral processing. The impact of mineralogy factors, unavoidable ions and galvanic effect on pyrite flotation behavior are analyzed, and the progress of depression and activation of lime-depressed pyrite is reviewed emphatically from the aspect of action mechanism between flotation agents and minerals. Different kinds of depressants interact with pyrite to form hydrophilic film, prevent the oxidation of xanthate, occupy active sites of collector on pyrite surface, generate complexes, and adsorb extracellular secretion from microbial bacteria such as polysaccharides and proteins on pyrite; high alkali environment commonly used acid and salt activator to dissolve the hydrophilized film of pyrite to activate and recycle pyrite. The analysis suggested that the current research on the complex environment of minerals and pulp is still unclear, and it should be strengthened by means of modern analysis and testing and computer technology. Pyrite is not only a mineral resource, but also plays an important role in alleviating the contradiction between economic development and environmental protection by the research and application of environmental minerals such as pyrite in the field of environmental protection.

Key words: pyrite, flotation behaviour, flotation agents, action mechanism, depression, derepression

中图分类号:

TD952
TD923

苏超, 申培伦, 李佳磊, 蔡锦鹏, 刘思言, 曹阳, 刘殿文. 黄铁矿浮选的抑制与解抑活化研究进展[J]. 化工进展, 2019, 38(04): 1921-1929.

Chao SU, Peilun SHEN, Jialei LI, Jinpeng CAI, Siyan LIU, Yang CAO, Dianwen LIU. A review on depression and derepression of pyrite flotation[J]. Chemical Industry and Engineering Progress, 2019, 38(04): 1921-1929.

图/表 3

参考文献 64

1	WÄCHTERSHÄUSER G . Pyrite formation, the first energy source for life: a hypothesis[J]. Systematic & Applied Microbiology, 1988, 10(3): 207-210.
2	CHEN J , ZHOU X , MEI C , et al . Pyrite FeS₂, nanobelts as high-performance anode material for aqueous pseudocapacitor[J]. Electrochimica Acta, 2016, 222: 172-176.
3	乐长高, 姜国芳, 刘云海 . 氧化亚铁硫杆菌生物冶金的新进展[J]. 生物技术, 2003, 13(3): 45-47.
	LE Changgao , JIANG Guofang , LIU Yunhai . Mechanism on Thiobacilus ferrooxidans bioleaching[J]. Biotechnology, 2003, 13(3): 45-47.
4	张鹏羽, 欧乐明, 曾令明, 等 . 隐晶质石墨浮选脱硫试验研究[J]. 中国矿业, 2018(1): 143-147.
	ZHANG Pengyu , Leming OU , ZENG Lingming , et al . Research on desulfurization of aphanitic graphite[J]. China Mining Magazine, 2018(1): 143-147.
5	刘成 . 德兴铜矿酸性废水成因的研究[J]. 中国矿山工程, 2001, 30(4): 49-53.
	LIU Cheng . Study on the cause of formation of acidic waste water in Dexing copper mine[J]. Nonferrous Mines, 2001, 30(4): 49-53.
6	解文康, 周杰强, 陈兴华, 等 . 河南某高硫铝土矿浮选脱硫试验研究[J]. 有色金属(选矿部分), 2017(1): 43-45.
	XIE Wenkang , ZHOU Jieqiang , CHEN Xinghua , et al . Study on the flotation desulfurization of high-sulfur bauxite in henan[J]. Nonferrous Metals Mieral Processing Section, 2017(1): 43-45.
7	洪微 . 煤尾矿中硬质高岭土选矿提纯试验研究[D]. 武汉: 武汉理工大学, 2014.
	HONG wei . Study of benefication and purification on hard kaolin from coal tailings[D]. Wuhan: Wuhan University of Technology, 2014.
8	邱仙辉, 于洋, 张春菊 . 鞣酸体系下黄铜矿与黄铁矿浮选动力学分析[J]. 化工进展, 2016, 35(7): 2258-2262.
	QIU Xianhui , YU Yang , ZHANG Chunju . Flotation kinetics of chalcopyrite and pyrite in tannic acid system[J]. Chemical Industry and Engineering Progress, 2016, 35(7): 2258-2262.
9	陈建华 . 硫化矿物浮选晶格缺陷理论[M]. 长沙: 中南大学出版社, 2012.
	CHEN Jianhua . Principles of the flotation of sulphide minerals bearing lattice defects[M]. Changsha: Central South University Press, 2012.
10	李玉琼 . 晶格缺陷对黄铁矿晶体电子结构和浮选行为影响的第一性原理研究[D]. 南宁: 广西大学, 2011.
	LI Yuqiong . First principle study of the influences of lattice defects on the electronic structures and flotation behavlours of pyrite crytal[D]. Nanning: Guangxi University, 2011.
11	李玉琼, 陈建华, 陈晔 . 空位缺陷黄铁矿的电子结构及其浮选行为[J]. 物理化学学报, 2010, 26(5): 1435-1441.
	LI Yuqiong , CHEN Jianhua , CHEN Ye . Electronic structures and flotation behavior of pyrite containing vacancy defects[J]. Acta Physico-Chimica Sinica, 2010, 26(5): 1435-1441.
12	先永骏 . 黄铁矿晶体缺陷及其表面吸附特性的研究[D]. 昆明: 昆明理工大学, 2013.
	XIAN Yongjun . Study on crystal defects and adsorption characteristics of pyrite[D]. Kunming: Kunming University of Science and Technology, 2013.
13	郗朋, 刘文礼, 韩永华, 等 . 煤系黄铁矿晶格缺陷与可浮性的机理研究[J]. 煤炭学报,2016, 41(4): 997-1003.
XI	LIU Peng , , HAN Yonghua , et al . Study on the mechanism of coal pyrite crystal lattice defects and floatability[J]. Journal of China Coal Society, 2016, 41(4): 997-1003.
14	于进喜 . 碳掺杂对黄铁矿电子结构性质与浮选行为的影响[J]. 矿冶工程, 2013, 33(5): 63-67.
	YU Jinxi . Influence of carbon doping on electronic properties and flotation behavior of pyrite[J]. Mining and Metallurgical Engineering, 2013, 33(5): 63-67.
15	杨多, 黄菲, 姚健鹏, 等 . 热硫化纳米黄铁矿的晶体结构特征及其热电性能研究[J]. 人工晶体学报, 2014, 43(12): 3086-3092.
	YANG Duo , HUANG Fei , YAO Jianpeng , et al . Study on crystalline structure characterization and thermoelectric properties of nano-pyrite[J]. Journal of Synthetic Crystals, 2014, 43(12): 3086-3092.
16	郭永文 . 影响黄铁矿可浮性的若干问题[J]. 有色金属(选矿部分), 1982(6): 37-44.
	GUO Yongwen . Some problems affecting the floatability of pyrite[J]. Nonferrous Metals Mieral Processing Section, 1982(6): 37-44.
17	陈述文, 胡熙庚 . 黄铁矿的温差电动势率与可浮性关系[J]. 矿冶工程, 1990, 10(3): 17-21.
	CHEN Shuwen , HU Xigeng . Relations between thermoelectromotive force ratio of pyrite and its flotability[J]. Mining and Metallurgical Engineering, 1990, 10(3): 17-21
18	凌竞宏, 胡熙庚 . 黄铁矿的可浮性与半导性的关系[J]. 化工矿物与加工, 1988(5): 15-21.
	LING Jinghong , HU Xigeng . The relationship between floatability and semiconductivity of pyrite[J]. Industrial Minerals & Processing, 1988(5): 15-21.
19	于宏东, 孙传尧 . 不同成因黄铁矿的物性差异及浮游性研究[J]. 中国矿业大学学报, 2010, 39(5): 758-764.
	YU Hongdong , SUN Chuanyao . Study of divergences of floatability and physical property of pyrite from different geo-genetic deposits[J]. Journal of China University of Mining & Technology, 2010, 39(5): 758-764.
20	卢龙 . 黄铁矿表面反应研究[D]. 南京: 南京大学, 2002.
	LU Long . Study on surface reaction of pyrite[D]. Nanjing : Nanjing University, 2002.
21	张胜男, 黄菲, 黄涛,等 . 红透山黄铁矿的热电性研究[J]. 沈阳师范大学学报(自然科学版), 2011, 29(2): 181-184.
	ZHANG Shengnan , HUANG Fei , HUANG Tao , et al . Pyroelectricity of Hongtoushan pyrite[J]. Journal of Shenyang Normal University(Natural Science Edition), 2011, 29(2): 181-184.
22	姜毛, 张覃, 李龙江 . 杂质对黄铁矿电子性质及可浮性影响的密度泛函理论研究[J]. 矿物学报, 2014, 34(4): 528-534.
	JIANG Mao , ZHANG Qin , LI Longjiang . A DFT study on the effect of lattice impurities on the electronic structures and floatability of pyrite[J]. Acta Mineralogica Sinica, 2014, 34(4): 528-534.
23	EJTEMAEI M , NGUYEN A V . Characterisation of sphalerite and pyrite surfaces activated by copper sulphate[J]. Minerals Engineering, 2017, 100: 223-232.
24	PENG Y , WANG B , GERSON A . The effect of electrochemical potential on the activation of pyrite by copper and lead ions during grinding[J]. International Journal of Mineral Processing, 2012, 102(s 102/103): 141-149.
25	CHANDRA A P , PUSKAR L , SIMPSON D J , et al . Copper and xanthate adsorption onto pyrite surfaces: implications for mineral separation through flotation[J]. International Journal of Mineral Processing, 2012, 114-117(8): 16-26.
26	陈建华 . 硫化矿物浮选固体物理研究[M]. 长沙: 中南大学出版社, 2015.
	CHEN Jianhua . The solide physics of sulphide minerals flotation[M]. Changsha: Central South University Press, 2015.
27	李佳磊, 宋凯伟, 刘殿文, 等 . 闪锌矿浮选的活化与去活化研究进展[J]. 过程工程学报, 2018(1): 11-19.
	LI Jialei , SONG Kaiwei , LIU Dianwen , et al . Research progress on activation and deactivation of sphalerite flotation[J]. The Chinese Journal of Process Engineering, 2018(1): 11-19.
28	SUI C C, BRIENNE S H R , RAO S R , et al . Metal ion production and transfer between sulphide minerals[J]. Minerals Engineering, 1995, 8(12): 1523-1539.
29	EKMEKQI Z , DEMIREL H . Effects of galvanic interaction on collectorless flotation behaviour of chalcopyrite and pyrite[J]. International Journal of Mineral Processing, 1997, 52: 31-48.
30	周丽, 李和平, 徐丽萍 . 开放体系下方铅矿和黄铁矿之间原电池反应的实验研究[J]. 矿物岩石, 2006, 26(1): 110-115.
	ZHOU Li , LI Heping , XU Liping . An experimental study on galvanic interaction between galena and pyrite in an open system[J]. Journal of Mineralogy and Petrology, 2006, 26(1): 110-115.
31	覃文庆, 龙怀中, 邱冠周, 等 . 高碱(石灰)体系中黄铁矿表面性质及其活化[J]. 有色金属工程, 1996(4): 35-38.
	QIN Wenqing , LONG Huaizhong , QIU Guanzhou , et al . Surface characteristics and activation of pyrite in high alkaline and calcium medium[J]. Nonferrous Metals Engineering, 1996(4): 35-38.
32	张英, 覃武林, 孙伟, 等 . 石灰和氢氧化钠对黄铁矿浮选抑制的电化学行为[J]. 中国有色金属学报, 2011, 21(3): 675-679.
	ZHANG Ying , QIN Wulin , SUN Wei , et al . Electrochemical behaviors of pyrite flotation using lime and sodium hydroxide as depressantors[J]. The Chinese Journal of Nonferrous Metals, 2011, 21(3): 675-679.
33	孙体昌, 李定一, 张润仙 . 石灰与黄铁矿作用时间对抑制效果的影响及机理[J]. 有色金属(选矿部分), 2002(2): 41-44.
	SUN Tichang , LI Dingyi , ZHANG Runxian . The effect of action time of lime on the depression of pyrite[J]. Nonferrous Metals Mieral Processing Section, 2002(2): 41-44.
34	JANETSKI N D , WOODBURN S I , WOODS R . An electrochemical investigation of pyrite flotation and depression[J]. International Journal of Mineral Processing, 1977, 4(3): 227-239.
35	HE S , SKINNER W , FORNASIERO D . Effect of oxidation potential and zinc sulphate on the separation of chalcopyrite from pyrite[J]. International Journal of Mineral Processing, 2006, 80(2): 169-176.
36	SHEN W Z , FORNASIERO D , RALSTON J . Flotation of sphalerite and pyrite in the presence of sodium sulfite[J]. International Journal of Mineral Processing, 2001, 63(1): 17-28.
37	ELGILLANI D A , FUERSTENAU M C . Mechanisms involved in cyanide depression of pyrite[J]. Trans. AIME, Soc. Min. Eng., 1968, 241: 437-445.
38	GUO B , PENG Y , PARKER G . Electrochemical and spectroscopic studies of pyrite-cyanide interactions in relation to the depression of pyrite flotation[J]. Minerals Engineering, 2016, 92: 78-85.
39	AGORHOM E A , SKINNER W , ZANIN M . Post-regrind selective depression of pyrite in pyritic copper-gold flotation using aeration and diethylenetriamine[J]. Minerals Engineering, 2015, 72: 36-46.
40	HE M F , QIN W Q , LI W Z , et al . Pyrite depression in marmatite flotation by sodium glycerine-xanthate[J]. Transactions of Nonferrous Metals Society of China, 2011, 21(5): 1161-1165.
41	WANG Z , QIAN Y , XU L H , et al . Selective chalcopyrite flotation from pyrite with glycerine-xanthate as depressant[J]. Minerals Engineering, 2015, 74: 86-90.
42	BOULTON A , FORNASIERO D , RALSTON J . Selective depression of pyrite with polyacrylamide polymers[J]. International Journal of Mineral Processing, 2001, 61(1): 13-22.
43	RATH R K , SUBRAMANIAN S , PRADEEP T . Surface chemical studies on pyrite in the presence of polysaccharide-based flotation depressants[J]. Journal of Colloid & Interface Science, 2000, 229(1): 82-91.
44	MU Y , PENG Y , LAUTEN R A . The mechanism of pyrite depression at acidic pH by lignosulfonate-based biopolymers with different molecular compositions[J]. Minerals Engineering, 2016, 92: 37-46.
45	MU Y , PENG Y , LAUTEN R A . The depression of copper-activated pyrite in flotation by biopolymers with different compositions[J]. Minerals Engineering, 2016, 96/97: 113-122.
46	LIU Runqing , SUN Wei , HU Yuehua , et al . Effect of organic depressant lignosulfonate calcium on separation of chalcopyrite from pyrite[J]. Journal of Central South University, 2009, 16(5): 753-757.
47	朱玉霜, 朱建光 . 浮选药剂的化学原理[M]. 长沙: 中南工业大学出版社, 1987.
	ZHU Yushuang , ZHU Jianguang . Chemical principle of flotation reagents[M]. Changsha: Central South University of Technology Press, 1987.
48	CHEN J , LI Y , CHEN Y . CuS flotation separation via the combination of sodium humate and lime in a low pH medium[J]. Minerals Engineering, 2011, 24(1): 58-63.
49	LÜ C C , WANG Y L , QIAN P , et al . Separation of chalcopyrite and pyrite from a copper tailing by ammonium humate[J]. Chinese Journal of Chemical Engineering, 2018.
50	CHANDRAPRABHA M N , NATARAJAN K A , MODAK J M . Selective separation of pyrite and chalcopyrite by biomodulation[J]. Colloids & Surfaces B: Biointerfaces, 2004, 37(3): 93-100.
51	MARTÍN F S , KRACHT W , VARGAS T . Biodepression of pyrite using Acidithiobacillus ferrooxidans in seawater[J]. Minerals Engineering, 2017, 117: 127-131.
52	PATRA P , NATARAJAN K A . Surface chemical studies on selective separation of pyrite and galena in the presence of bacterial cells and metabolic products of Paenibacillus polymyxa [J]. J. Colloid Interface Sci., 2006, 298(2): 720-729.
53	CHANDRAPRABHA M N , NATARAJAN K A . Surface chemical and flotation behaviour of chalcopyrite and pyrite in the presence of Acidithiobacillus thiooxidans [J]. Hydrometallurgy, 2006, 83(1): 146-152.
54	王李鹏 . 高碱高钙受抑黄铁矿浮选活化剂的性能研究[J]. 化工矿物与加工, 2013(4): 12-14.
	WANG Lipeng . Study on performance of high lime inhibition pyrite activator[J]. Industrial Minerals & Processing, 2013(4): 12-14.
55	胡岳华, 王淀佐 . 石灰抑制的黄铁矿的活化及活化剂结构-性能[J]. 有色金属工程, 1996(4): 24-28.
	HU Yuehua , WANG Dianzuo . Activation of pyrite depressed by lime and structure-property of activators[J]. Nonferrous Metals Engineering, 1996(4): 24-28.
56	HUANG Hongjun , HU Yuehua , SUN Wei . Activation flotation and mechanism of lime-depressed pyrite with oxalic acid[J]. International Journal of Mining Science and Technology, 2012, 22(1): 63-67.
57	孙伟, 张英, 覃武林, 等 . 被石灰抑制的黄铁矿的活化浮选机理[J]. 中南大学学报(自然科学版), 2010, 41(3): 813-818.
	SUN Wei , ZHANG Ying , QIN Wulin , et al . Activated flotation of pyrite once depressed by lime[J]. Journal of Central South University (Science and Technology), 2010, 41(3): 813-818.
58	覃武林 . 高碱抑制硫铁矿及活化浮选机理研究[D]. 长沙: 中南大学, 2009.
	QIN Wulin . Study on mechanism of high alkaline depression and activation of pyrite flotation[D]. Changsha: Central South University, 2009.
59	黄尔君, 冯育武 . 铵盐对黄铁矿的活化作用及其机理研究[J]. 有色金属(选矿部分), 1996(2): 33-37.
	HUANG Erjun , FENG Yuwu . Study on the activation and mechanism of ammonium salts on pyrite flotation[J]. Nonferrous Metals Mieral Processing Section, 1996(2): 33-37.
60	田震 . 浅析结晶工艺参数的优化[J]. 无机盐工业, 2008, 40(6): 37-38.
	TIAN Zhen . Simple analysis on optimization of technological parameters of crystallization[J]. Inorganic Chemicals Industry, 2008, 40(6): 37-38.
61	XIE Xiaojun , KELEBEK S . Activation of xanthate flotation of pyrite by ammonium salts following it's depression by lime[J]. Developments in Mineral Processing, 2000, 13: C8b-43-C8b-50.
62	肖骏, 黄圣淇, 董艳红, 等 . 某铅锌尾矿中被石灰抑制黄铁矿活化试验研究[J]. 湖南有色金属, 2017, 33(3): 9-12.
	XIAO Jun , HUANG Shengqi , DONG Yanhong , et al . Activation experimental study on the pyrite suppressed by lime from a lead-zinc Tailing[J]. Hunan Nonferrous Metals, 2017, 33(3): 9-12.
63	LI Y , CHEN J , KANG D , et al . Depression of pyrite in alkaline medium and its subsequent activation by copper[J]. Minerals Engineering, 2012, 26(1): 64-69.
64	尹启华, 冯其明 . 高碱高钙介质中黄铁矿活化机理的研究[J]. 有色金属(选矿部分), 1997(3): 18-21.
	YIN Qihua , FENG Qiming . Study on the activation mechanism of pyrite in high alkali and high calcium medium[J]. Nonferrous Metals (Mineral Processing Section), 1997(3): 18-21.

成因类型	内部结构	破碎方式	破碎后表面形貌
中低温热液型	交代环状、聚型变晶	晶界处破裂	椭圆形，表面有凸起和台阶
中高温热液型	微裂隙	形成新鲜破裂面	板条状，破裂面平滑
热水沉积性	聚型变晶、重结晶	形成新鲜破裂面	板条状，破裂面平滑
矽卡岩型	结构缺陷少	形成新鲜破裂面	板条状，破裂面平滑
煤系沉积型	草莓微晶	结构缺陷处破裂	保留原始的矿物微球集合体

成因类型	内部结构	破碎方式	破碎后表面形貌
中低温热液型	交代环状、聚型变晶	晶界处破裂	椭圆形，表面有凸起和台阶
中高温热液型	微裂隙	形成新鲜破裂面	板条状，破裂面平滑
热水沉积性	聚型变晶、重结晶	形成新鲜破裂面	板条状，破裂面平滑
矽卡岩型	结构缺陷少	形成新鲜破裂面	板条状，破裂面平滑
煤系沉积型	草莓微晶	结构缺陷处破裂	保留原始的矿物微球集合体

[1]	刘佳, 梁德青, 李君慧, 林德才, 吴思婷, 卢富勤. 油水体系水合物浆液流动保障研究进展[J]. 化工进展, 2023, 42(4): 1739-1759.
[2]	蒲福龙, 伍尚炜, 郑映玲, 郑玉意, 侯雪丹. 基于乳酸的深度共熔溶剂提取秸秆木质素对纤维素酶水解效率的影响[J]. 化工进展, 2022, 41(9): 4937-4945.
[3]	汪潇, 金彪, 张小婷, 张建武, 王宇斌, 苑冬冬, 杨留栓. 氯盐体系下阳离子对脱硫石膏晶须水热结晶的影响及其机理[J]. 化工进展, 2022, 41(7): 3957-3965.
[4]	阮敏, 孙宇桐, 黄忠良, 李辉, 张轩, 吴希锴, 赵成, 姚世蓉, 张拴保, 张巍, 黄兢. 污泥预处理-厌氧消化体系的能源经济性评价[J]. 化工进展, 2022, 41(3): 1503-1516.
[5]	苏洋, 罗振敏, 王涛. CO₂/海泡石抑爆剂对氢气/甲烷爆炸特性参数的影响[J]. 化工进展, 2022, 41(11): 5731-5736.
[6]	隋金昊, 王智, 梁璇玑, 张烜玮, 朱羽墨, 宋尚飞, 史博会, 宫敬, LOU Xia. 动力学抑制剂与乙二醇协同作用下甲烷水合物再生成[J]. 化工进展, 2022, 41(10): 5373-5380.
[7]	王云飞, 孙长宇, 喻西崇, 王清, 李清平, 陈光进. 中试装置内水合物注抑制剂的分解规律[J]. 化工进展, 2022, 41(10): 5354-5362.
[8]	刘树根, 孔馨, 吕学斌, 刘庆岭, 陈冠益. 有机固体废物好氧处理抑制作用研究进展[J]. 化工进展, 2021, 40(12): 6818-6828.
[9]	孙玥, 刘玲玲, 李鑫泉, 潘建锋, 刘嘉斌. 添加剂对电解铜箔作用机理及作用效果的研究进展[J]. 化工进展, 2021, 40(11): 5861-5874.
[10]	刘丁仪, 王冰玉, 李姝霖, 谢慧芳. 固废基无机高分子混凝剂研究进展及改进途径[J]. 化工进展, 2021, 40(10): 5660-5669.
[11]	刘雪玲, 付伟娟, 牛锦涛, 王源铭. 平抑电耗波动的热泵蓄热-供热系统优化[J]. 化工进展, 2021, 40(10): 5424-5430.
[12]	邹联沛, 宋琳, 李小伟, 万雨岚, 李曼, 刘建勇, 欧阳创, 奚慧, 钱光人, 戴晓虎. 湿垃圾组分对厌氧消化抑制作用的研究进展[J]. 化工进展, 2020, 39(S2): 362-371.
[13]	邵正昌, 伍连松, 刘家才, 王平全, 杜琨, 任妍君, 余永平. 新型聚合物钾盐抑制泥页岩水化的性能与机理[J]. 化工进展, 2020, 39(S1): 225-231.
[14]	徐克耐, 王国成, 王征, 李德馨, 李宏玲. PARP抑制剂HD199胶囊的研制[J]. 化工进展, 2020, 39(6): 2447-2452.
[15]	章骅,杨瑞,邵立明,何品晶. 二恶英生成抑制剂及其阻滞机理研究现状与展望[J]. 化工进展, 2020, 39(4): 1485-1492.