关键词: 模板剂, ZSM-5分子筛膜, 脱硫, 噻吩, 模板剂, ZSM-5分子筛膜, 脱硫, 噻吩, 合成

Abstract: The ratio and kind of template agent were investigated for the preparation of ZSM-5 zeolite membranes using the two-steps hydrothermal synthesis method. The membranes were characterized with X-ray diffraction (XRD) and scanning electron microscope (SEM). Desulfurization experiments were conducted in model gasoline. With increasing ratio of TPAOH，membrane particle shape gradually became regular，but an overly high ratio of TPAOH could make membrane particles irregular. Membrane structure was the most regular and thiophene removal was the best when ZSM-5 zeolite membrane was prepared with TPAOH ratio of 30. Membranes prepared by double template agent of “TPAOH+absolute ethylalcohol” could achieve the highest removal of sulfides. The membrane was used to remove bicomponent model gasoline，and removal of bicomponent sulfides was better than removal of sulfides in single component model gasoline.

Key words: template agent, ZSM-5 zeolite membranes, desulfurization, TP, template agent, ZSM-5 zeolite membranes, desulfurization, thiophene, synthesis