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燃料电池用质子交换膜电渗拖曳的研究进展

屈树国1,刘欣2,盖恒军1,李建隆1   

  1. 1青岛科技大学化工学院,山东 青岛 266042;2青岛双瑞海洋环境工程股份有限公司,山东 青岛 266101
  • 出版日期:2014-04-05 发布日期:2014-04-05

Research progress of electro-osmotic drag coefficient of proton exchange membranes for fuel cells

QU Shuguo1,LIU Xin2,GAI Hengjun1,LI Jianlong1   

  1. 1Department of Chemical Engineering,Qingdao University of Science & Technology,Qingdao 266042,Shandong,China;2Sunrui Marine Environment Engineering Co.,Ltd.,Qingdao 266101,Shandong,China
  • Online:2014-04-05 Published:2014-04-05

摘要: 质子交换膜的电渗拖曳直接影响燃料电池的水管理和电池系统复杂性。本文对质子交换膜电渗拖曳系数的测量方法进行了综述,并指出了各种方法的优缺点。经比较发现:电渗拖曳池、氢泵、电泳核磁共振法可测量质子交换膜与液态水接触时的电渗拖曳系数,其值一般在2~5;活度梯度法和电泳核磁共振法可测量质子交换膜与气态水接触时的电渗拖曳系数。随着复合质子交换膜的发展,亟需普遍性的测量方法测定复合膜的电渗拖曳系数,为燃料电池模型提供相关的参数,以利于数学模型对质子交换膜的准确描述。

关键词: 燃料电池, 质子交换膜, 电渗拖曳系数, 测量, 复合膜

Abstract: Electro-osmotic drag of proton exchange membrane is important in fuel cells because it directly affects water management and the complexity of fuel cell system. The electro-osmotic drag coefficient is the number of water molecules transported per proton. Measurement methods of electro-osmosis drag coefficient of proton exchange membranes are reviewed and their advantages and disadvantages are pointed out in this paper. The electro-osmotic drag coefficient of membrane contacting liquid water could be measured by electro-osmotic drag cell,hydrogen pump and electrophoretic nuclear magnetic resonance,while the electro-osmotic drag coefficient of membrane contacting gaseous water could be measured by the activity gradient method and electrophoretic nuclear magnetic resonance. With the development of composite proton exchange membrane,universal methods are urgently needed to acquire the electro-osmotic drag coefficient of compsite membrane with the purpose of providing parameters for the accurate description of the proton exchange membrane in fuel cells models.

Key words: fuel cells, proton exchange membrane, electro-osmotic drag coefficient, measurement, composite membrane

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