关键词: 锐钛矿TiO2, 高能晶面, 形貌理论预测, 制备策略, 掺杂, 高能晶面TiO2应用, 锐钛矿TiO2, 高能晶面, 形貌理论预测, 制备策略, 掺杂

Abstract: Theoretical predictions on morphologies of TiO2 crystals are summarized，and the synthesis processes and related control mechanisms of the high energy facets dominated anatase TiO2 crystals with different morphologies are systematically reviewed. Besides the anatase TiO2 crystals with micro-scale sizes，the high energy facets dominated anatase TiO2 nanocrystals and the nanostructures composed of nanoscale units are synthesized by controlling the preparing processes as well as adjusting Ti resources and structure-directing agents. Researches on doping high energy facets dominated anatase TiO2 with different elements to improve their optical absorption properties and photocatalysis activities are also described in this paper. Moreover，the performances of the high energy facets dominated anatase TiO2 materials in the application fields，including photocatalytic degradation of pollutants，and water splitting to produce hydroten，solar cells，and Li-ion batteries，are introduced. It is shown that the high energy facets dominated anatase TiO2 materials exhibit superior activities compared with traditional TiO2 materials. The problems related to the research on the synthesis and applications of high energy facets dominated anatase TiO2 and the future development are presented.

Key words: Anatase TiO2, High energy facets, Theoretic predictions of the morphology, Synthetic strategies, Doping, Application of high energy facets dominated anatase TiO2, anatase TiO2, high energy facets, theoretic predictions of the morphology, synthetic strategies, doping