化工进展 ›› 2024, Vol. 43 ›› Issue (6): 3209-3220.DOI: 10.16085/j.issn.1000-6613.2023-0753
• 材料科学与技术 • 上一篇
孙悦1(), 邢宝林1,2(
), 张耀杰1, 冯来宏3, 曾会会1, 蒋振东1, 徐冰1, 贾建波1, 张传祥1,2, 谌伦建1, 张越1, 张文豪1
收稿日期:
2023-05-08
修回日期:
2023-08-11
出版日期:
2024-06-15
发布日期:
2024-07-02
通讯作者:
邢宝林
作者简介:
孙悦(1992—),女,博士研究生,研究方向为矿产资源加工利用。E-mail:1509047307@qq.com。
基金资助:
SUN Yue1(), XING Baolin1,2(
), ZHANG Yaojie1, FENG Laihong3, ZENG Huihui1, JIANG Zhendong1, XU Bing1, JIA Jianbo1, ZHANG Chuanxiang1,2, CHEN Lunjian1, ZHANG Yue1, ZHANG Wenhao1
Received:
2023-05-08
Revised:
2023-08-11
Online:
2024-06-15
Published:
2024-07-02
Contact:
XING Baolin
摘要:
负极材料是影响锂离子电池(LIBs)性能的关键因素之一,孔隙结构调控和杂原子掺杂是提高负极材料电化学性能的有效手段。以褐煤为前体,采用化学氧化法制备煤基碳纳米片(CS),再以氧化硼(B2O3)为添加剂,得到B掺杂多孔碳纳米片(BPCS);采用扫描电镜(SEM)、透射电镜(TEM)、X射线衍射(XRD)、拉曼光谱(Raman)、氮气吸附仪、X射线光电子能谱(XPS)等手段对CS和BPCS微观结构和用作锂离子电池负极材料的电化学性能表征与测试。结果表明,B2O3具有模板、造孔、掺杂三重作用,当B2O3用量为0.5g时,BPCS-0.5呈现三维多孔结构,比表面积为1216.20m2/g,总孔容1.027cm3/g,B原子含量为4.20%;BPCS-0.5的多孔结构为离子的存储和传输提供足够的空间和通道,B元素的引入增加了BPCS的表面化学活性,从而增强了储锂性能。BPCS-0.5用作锂离子电池负极材料时,在0.05A/g电流密度下首次可逆容量达826mA·h/g,且在5A/g大电流密度下可逆容量仍有143mA·h/g,循环500次的容量保持率为172%,表明该材料具有较高的储锂容量和优异的循环寿命。
中图分类号:
孙悦, 邢宝林, 张耀杰, 冯来宏, 曾会会, 蒋振东, 徐冰, 贾建波, 张传祥, 谌伦建, 张越, 张文豪. B掺杂多孔碳纳米片的制备及其储锂性能[J]. 化工进展, 2024, 43(6): 3209-3220.
SUN Yue, XING Baolin, ZHANG Yaojie, FENG Laihong, ZENG Huihui, JIANG Zhendong, XU Bing, JIA Jianbo, ZHANG Chuanxiang, CHEN Lunjian, ZHANG Yue, ZHANG Wenhao. Preparation of B-doped porous carbon nanosheets and their lithium storage performance[J]. Chemical Industry and Engineering Progress, 2024, 43(6): 3209-3220.
样品名称 | 比表面积/m2·g-1 | 总孔容/cm3·g-1 | 微孔孔容/cm3·g-1 | 微孔率/% | 中孔孔容/cm3·g-1 | 中孔率/% | 大孔孔容/cm3·g-1 | 大孔率/% |
---|---|---|---|---|---|---|---|---|
CS | 440.78 | 0.316 | 0.292 | 92.40 | 0.055 | 5.53 | 0.007 | 2.21 |
BPCS-0.25 | 1298.10 | 1.174 | 0.474 | 40.41 | 0.611 | 52.05 | 0.088 | 7.53 |
BPCS-0.5 | 1216.20 | 1.027 | 0.415 | 40.37 | 0.561 | 54.66 | 0.051 | 4.95 |
BPCS-1 | 301.04 | 0.451 | 0.087 | 19.31 | 0.222 | 49.33 | 0.141 | 31.35 |
表1 CS和BPCS的比表面积和孔径参数
样品名称 | 比表面积/m2·g-1 | 总孔容/cm3·g-1 | 微孔孔容/cm3·g-1 | 微孔率/% | 中孔孔容/cm3·g-1 | 中孔率/% | 大孔孔容/cm3·g-1 | 大孔率/% |
---|---|---|---|---|---|---|---|---|
CS | 440.78 | 0.316 | 0.292 | 92.40 | 0.055 | 5.53 | 0.007 | 2.21 |
BPCS-0.25 | 1298.10 | 1.174 | 0.474 | 40.41 | 0.611 | 52.05 | 0.088 | 7.53 |
BPCS-0.5 | 1216.20 | 1.027 | 0.415 | 40.37 | 0.561 | 54.66 | 0.051 | 4.95 |
BPCS-1 | 301.04 | 0.451 | 0.087 | 19.31 | 0.222 | 49.33 | 0.141 | 31.35 |
样品名称 | C含量 | O含量 | B含量 | ||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
总含量 | C—B | C | C—O | C | COOH | 总含量 | 总含量 | BC3 | BC2O | BCO2 | |
CS | 91.11 | — | 79.40 | 12.00 | 5.40 | 3.00 | 7.24 | — | — | — | — |
BPCS-0.25 | 85.07 | 1.48 | 75.41 | 14.49 | 5.72 | 2.89 | 11.73 | 3.20 | 23.33 | 72.39 | 4.27 |
BPCS-0.5 | 83.49 | 1.73 | 72.61 | 15.89 | 6.22 | 3.35 | 12.31 | 4.20 | 17.54 | 74.37 | 8.00 |
BPCS-1 | 77.21 | 2.40 | 71.78 | 16.53 | 5.43 | 3.84 | 16.25 | 6.54 | 14.87 | 80.23 | 4.89 |
表2 CS和BPCS官能团的相对含量
样品名称 | C含量 | O含量 | B含量 | ||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
总含量 | C—B | C | C—O | C | COOH | 总含量 | 总含量 | BC3 | BC2O | BCO2 | |
CS | 91.11 | — | 79.40 | 12.00 | 5.40 | 3.00 | 7.24 | — | — | — | — |
BPCS-0.25 | 85.07 | 1.48 | 75.41 | 14.49 | 5.72 | 2.89 | 11.73 | 3.20 | 23.33 | 72.39 | 4.27 |
BPCS-0.5 | 83.49 | 1.73 | 72.61 | 15.89 | 6.22 | 3.35 | 12.31 | 4.20 | 17.54 | 74.37 | 8.00 |
BPCS-1 | 77.21 | 2.40 | 71.78 | 16.53 | 5.43 | 3.84 | 16.25 | 6.54 | 14.87 | 80.23 | 4.89 |
样品 | 不同电流密度下的第10次充电比容量/mA·h·g-1 | |||||||
---|---|---|---|---|---|---|---|---|
0.05A·g-1 | 0.1A·g-1 | 0.2A·g-1 | 0.5A·g-1 | 1A·g-1 | 2A·g-1 | 5A·g-1 | 0.05A·g-1 | |
CS | 285 | 246 | 218 | 184 | 164 | 143 | 88 | 312 |
BPCS-0.25 | 641 | 471 | 390 | 302 | 234 | 171 | 94 | 498 |
BPCS-0.5 | 715 | 559 | 457 | 360 | 296 | 231 | 143 | 571 |
BPCS-1 | 570 | 443 | 375 | 304 | 250 | 195 | 124 | 507 |
表3 CS和BPCS在不同电流密度下第10次的可逆比容量
样品 | 不同电流密度下的第10次充电比容量/mA·h·g-1 | |||||||
---|---|---|---|---|---|---|---|---|
0.05A·g-1 | 0.1A·g-1 | 0.2A·g-1 | 0.5A·g-1 | 1A·g-1 | 2A·g-1 | 5A·g-1 | 0.05A·g-1 | |
CS | 285 | 246 | 218 | 184 | 164 | 143 | 88 | 312 |
BPCS-0.25 | 641 | 471 | 390 | 302 | 234 | 171 | 94 | 498 |
BPCS-0.5 | 715 | 559 | 457 | 360 | 296 | 231 | 143 | 571 |
BPCS-1 | 570 | 443 | 375 | 304 | 250 | 195 | 124 | 507 |
序号 | 样品 | 比容量/mA·h·g-1,电流密度/A·g-1 | 比容量/mA·h·g-1,循环次数,电流密度/A·g-1 | 参考文献 |
---|---|---|---|---|
1 | 0.5BN-CQD | 130,3 | 485,100,0.1 | [ |
2 | B-CNT | 345,0.1 | 261,500,0.5 | [ |
3 | B-G | 353,0.5 | 548,30,0.1 | [ |
4 | BNCF-800 | 417,0.1 | 416,450,0.1 | [ |
5 | Py-B-CNTs | 474,0.05 | 548,300,0.1 | [ |
6 | B-CQD | 443,0.1 | 405,100,0.1 | [ |
7 | BPCS-0.5 | 715,0.05 559,0.1 360,0.5 | 486,500,1 | 本工作 |
表4 BPCS-0.5和其他碳材料储锂性能的对比
序号 | 样品 | 比容量/mA·h·g-1,电流密度/A·g-1 | 比容量/mA·h·g-1,循环次数,电流密度/A·g-1 | 参考文献 |
---|---|---|---|---|
1 | 0.5BN-CQD | 130,3 | 485,100,0.1 | [ |
2 | B-CNT | 345,0.1 | 261,500,0.5 | [ |
3 | B-G | 353,0.5 | 548,30,0.1 | [ |
4 | BNCF-800 | 417,0.1 | 416,450,0.1 | [ |
5 | Py-B-CNTs | 474,0.05 | 548,300,0.1 | [ |
6 | B-CQD | 443,0.1 | 405,100,0.1 | [ |
7 | BPCS-0.5 | 715,0.05 559,0.1 360,0.5 | 486,500,1 | 本工作 |
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