柔性吸附材料最新研究进展

doi:10.16085/j.issn.1000-6613.2023-0537

摘要/Abstract

摘要：

近年来，具有柔性三维框架结构的吸附分离材料逐渐引起研究人员极大兴趣，其独特的动态吸附行为和富化学环境的结构框架赋予了其完全不同于传统刚性吸附材料的特性，这种特殊的柔性吸附材料在吸附分离、环境净化和传感等领域显示出巨大潜力。然而，由于研究者们缺少对柔性吸附现象的深入理解和相应的理论研究方法，该领域的发展较为缓慢。本文立足于作者自身研究工作，对柔性吸附的定义、理论发展和分类等方面的最新研究进展以及其在污染物去除、共沸物分离等方面的应用实例进行深度分析，力求为该领域发展提供相应的理论支撑。文中也指出了柔性吸附材料的产业化方向及前景，即应该努力探索柔性吸附材料大规模、高效率地处理环境中高浓度（低浓度）的液相（气相）污染物的应用前景，以此来推动柔性吸附材料的产业化。

关键词: 柔性吸附, 弱相互作用, 三维框架, 机械形变

Abstract:

In recent years, adsorption and separation materials with a flexible three-dimensional framework have attracted significant interest from researchers. Their unique dynamic adsorption behavior and chemically rich structural framework give them properties utterly different from those of traditional rigid adsorption materials. These unique flexible adsorption materials have shown great potential in adsorption and separation, and environmental purification and sensing. However, the development of this field has needed to be faster due to the lack of in-depth understanding of flexible adsorption phenomena and corresponding theoretical research methods by researchers. In this paper, based on the latest research progress in the definition, theoretical development, and classification of flexible adsorption, we provided an in-depth analysis of its application examples in the removal of pollutants and separation of azeotropes and aim to provide the corresponding theoretical help for the development of this field. The article also pointed out the direction and prospect of industrialization of flexible adsorption materials, and efforts should be made to explore the application prospect of flexible adsorption materials for large-scale and high-efficiency treatment of liquid-phase (gas-phase) environmental pollutants with high (low) concentrations so as to promote the industrialization of flexible adsorption materials.

Key words: flexible adsorption, weak interaction, three-dimensional framework, mechanical deformation

中图分类号:

路建美. 柔性吸附材料最新研究进展[J]. 化工进展, 2023, 42(6): 2781-2798.

LU Jianmei. Recent research progress of flexible adsorption materials[J]. Chemical Industry and Engineering Progress, 2023, 42(6): 2781-2798.

图/表 13

图1 柔性吸附现象示意图

图2 柔性三维氢键框架在水分子吸脱附后发生的结构转变[31]

图3 纤维素吸水膨胀的分子动力学建模及吸附动力学模拟[24]

图4 吸油效率和单体酯基长度之间的关系[26]（a）；含不同大小芳香环的单体结构[56]（b）；刚性柔性并存的柔性吸附高分子框架模型示意图[57]（c）；TPC-cPS高效能吸附有机溶剂示意图[7]（d）

图5 柔性交联苯基框架的记忆吸附特性示意图[22]

图6 柔性吸附胶束的结构示意图（a）；本体聚合物的TEM图（b）；柔性吸附胶束的TEM图和尺寸分布图[58]（c）、（d）

图7 SuFEx改性丝素蛋白气凝胶结构及制备过程示意图[63]

图8 HATT吸水前后的晶体结构示意图[30]

图9 单体比例对吸油性能的影响（单体1—丙烯酸2-乙基己酯；单体2—丙烯酸羟乙酯）[28]（a）；交联剂种类对吸油性能的影响[单体—丙烯酸-2-乙基己酯（60%）与丙烯酸-羟乙酯（40%）][21]（b）

图10 柔性胶束高效吸附降解双酚A示意图[58]

图11 吡啶包封的柔性交联聚硫酸盐凝胶吸附去除碘甲烷示意图[7]

图12 柔性苯基框架通过膨胀吸附二氧化碳示意图[25]

图13 柔性氢键框架吸附水前后晶体结构及荧光变化示意图[31]

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